An unprecedented binuclear cadmium di­thio­carbamate adduct: bis­[μ2-N-(2-hydroxy­eth­yl)-N-iso­propyl­carbamodi­thio­ato-κ3S:S,S′]bis­{[N-(2-hydroxy­eth­yl)-N-iso­propyl­carbamodi­thio­ato-κ2S,S′](3-{(1E)-[(E)-2-(pyridin-3-yl­methyl­idene)hydrazin-1-yl­idene]meth­yl}pyridine-κN)cadmium]} dihydrate

Arman, H.D.; Poplaukhin, P.; Tiekink, E.R.T.

doi:10.1107/S2056989016012214

Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

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Figure 2
Molecular packing: (a) view of the supramolecular layer sustained by hydroxy-O—H⋯O(hydroxy) and hydroxy-O—H⋯O(water) hydrogen bonds, shown as orange dashed lines. Only the pyridyl N atoms of the 3-pyridinealdazine ligands are shown. (b) A side-on view of the layer in (a) extended to show the two central 3-pyridinealdazine ligands (see text). The putative water-O—H⋯N(pyridyl) hydrogen bonds are shown as blue dashed lines. In both images, only acidic hydrogen atoms are included.

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 72| Part 9| September 2016| Pages 1234-1238

https://doi.org/10.1107/S2056989016012214

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