A new example of intra­molecular C—H⋯Ni anagostic inter­actions: synthesis, crystal structure and Hirshfeld analysis of cis-bis­[4-methyl-2-(1,2,3,4-tetra­hydro­naphthalen-1-yl­idene)hydrazinecarbo­thio­amidato-κ2N1,S]nickel(II) di­methyl­formamide monosolvate

Oliveira, A.B. de; Beck, J.; Mellone, S.E.B.S.; Daniels, J.

doi:10.1107/S2056989017007198

Acta Crystallographica Section E
Acta Crystallographica
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Figure 5
The Hirshfeld surface graphical representation (d_norm) for: (a) the asymmetric unit of the title compound and (b) the asymmetric unit of the comparison compound, bis{cis-(2-(1,2,3,4-tetrahydronaphthalen-1-ylidene)-4-phenyl-hydrazinecarbothioamidate-κ²N¹,S)}nickel(II) monohydrate bis(tetrahydrofurane) solvate (de Oliveira et al. 2014b

). The surface regions with the strongest intermolecular interactions are drawn in magenta. The figure is simplified for clarity. [Symmetry code: (i) −x + 1, y − $[{1\over 2}]$ , −z + $[{1\over 2}]$ .]

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 73| Part 6| June 2017| Pages 859-863

https://doi.org/10.1107/S2056989017007198

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