research communications\(\def\hfill{\hskip 5em}\def\hfil{\hskip 3em}\def\eqno#1{\hfil {#1}}\)

Journal logoCRYSTALLOGRAPHIC
COMMUNICATIONS
ISSN: 2056-9890

Crystal structure of [1,2-bis­­(di­phenyl­phosphan­yl)benzene]­hepta­carbonyldi-μ-hydrido-(μ3-2,4,6-tri­methyl­phenyl­phosphin­­idene)-triangulo-triruthenium

aDepartment of Chemistry and Biochemistry, School of Advanced Science and Engineering, Waseda University, Shinjuku, Tokyo 169-8555, Japan
*Correspondence e-mail: w499487@aoni.waseda.jp

Edited by H. Ishida, Okayama University, Japan (Received 21 April 2017; accepted 25 May 2017; online 2 June 2017)

The title trinuclear ruthenium cluster, [Ru3(C30H24P2)(C9H11P)(CO)7(μ-H)2], has a triangular Ru3 core that is capped with a mesitylphosphin­idene ligand, μ3-PMes (Mes = mesityl = 2,4,6-tri­methyl­phen­yl). The 1,2-bis­(di­phenyl­phosphan­yl)benzene mol­ecule acts as a bidentate phosphine ligand via two P atoms connecting to a single Ru atom. The title compound crystallizes with two independent mol­ecules in the asymmetric unit.

1. Chemical context

In previous reports for cluster syntheses, bidentate phosphines occasionally act as spacer ligands that connect two cluster units to build up large clusters. For example, we have reported the successful synthesis of [Ru3(CO)8(μ-H)2(μ3-PMes)]2(μ-diphosphine) (Mes = mesityl = 2,4,6-tri­methyl­phen­yl) (Kakizawa et al., 2015[Kakizawa, T., Hashimoto, H. & Tobita, H. (2015). Inorg. Chim. Acta, 425, 7-10.]) by the linking of two phosphin­idene-capped Ru3 clusters formulated as Ru3(CO)9(μ-H)2(μ3-PMes) (Kakizawa et al., 2006[Kakizawa, T., Hashimoto, H. & Tobita, H. (2006). J. Organomet. Chem. 691, 726-736.]) with chelating diphosphine moieties such as 1,2-bis­(di­phenyl­phosphan­yl)ethane by thermal reaction. In the case of BDP [1,2-bis­(di­phenyl­phosphan­yl)benzene], the linking of two Ru3 units did not occur, and the title triangular–pyramidal cluster, Ru3(μ-BDP)(CO)7(μ-H)2(μ3-PMes), was obtained.

[Scheme 1]

2. Structural commentary

The title compound crystallizes with two independent mol­ecules A and B (Fig. 1[link]), which show quite similar conformations to each other. The mol­ecules have a trigonal–pyramidal structure of the phosphin­idene-capped triruthenium core. One CO ligand and two phospho­rus atoms of BDP coordinate to a single Ru atom (Ru1 for molecule A and Ru4 for molecule B). In the triangular Ru3 moiety, the Ru1—Ru2, Ru1—Ru3 and Ru2—Ru3 bond lengths are 2.9297 (8), 3.0089 (8) and 2.7945 (8) Å, respectively, for mol­ecule A, and Ru4—Ru5, Ru4—Ru6 and Ru5—Ru6 are 2.9220 (8), 3.0018 (8) and 2.7902 (8) Å, respectively, for mol­ecule B. The longest bond lengths are for Ru1—Ru3 and Ru4—Ru6 in the two mol­ecules and might be caused by steric repulsion between the phenyl groups of BDP, the mesityl group on the phosphin­idene ligand, and the carbonyl groups. The coordin­ating BDP moiety shows a distorted five-membered ring with the Ru1—P2—C29—C34 and Ru1—P3—C34—C29 torsion angles being −13.9 (6) and 19.4 (6)°, respectively, for mol­ecule A, and Ru4—P5—C75—C80 and Ru4—P6—C80—C75 being −14.7 (6) and 21.8 (6)°, respectively, for mol­ecule B.

[Figure 1]
Figure 1
The structures of the two independent mol­ecules A and B of the title compound. Displacement ellipsoids are drawn at the 50% probability level for non-H atoms.

3. Supra­molecular features

The packing of the title compound is shown in Fig. 2[link]. No significant C—H⋯π or ππ inter­actions are observed within each independent mol­ecule or between adjacent mol­ecules.

[Figure 2]
Figure 2
A packing diagram of the title compound, viewed along the a axis. Displacement ellipsoids are drawn at the 50% probability level for non-H atoms.

4. Database survey

The crystal structures of similar coordination modes of BDP in which two phospho­rus atoms connect to one Ru atom in the polynuclear clusters have been observed, i.e., HRu6(μ5-C)(μ3-P)(CO)14(BDP) (Watson et al., 2007[Watson, W. H., Kandala, S. & Richmond, M. G. (2007). J. Organomet. Chem. 692, 1648-1652.]), 1,1-H4Ru4(CO)10(BDP) (Nesterov et al., 2007[Nesterov, V. N., Watson, W. H., Kandala, S. & Richmond, M. G. (2007). Polyhedron, 26, 3602-3608.]), and the cationic trinuclear ruthenium complex [Ru3(μ2-Cl)3(μ3-Cl)2(BDP)3]PF6 (Mashima et al., 1997[Mashima, K., Komura, N., Yamagata, T., Tani, K. & Haga, M. (1997). Inorg. Chem. 36, 2908-2912.]). Mononuclear ruthenium complexes with BDP have also been reported, i.e., Ru(CO)3(BDP) (Bunten et al., 2000[Bunten, K. A., Farrar, D. H., Poë, A. J. & Lough, A. J. (2000). Organometallics, 19, 3674-3682.]), [CpRu(PPh3)(BDP)]Cl (Guan et al., 2003[Guan, H., Iimura, M., Magee, M. P., Norton, J. R. & Janak, K. E. (2003). Organometallics, 22, 4084-4089.]), CpRu(BDP)H (Guan et al., 2003[Guan, H., Iimura, M., Magee, M. P., Norton, J. R. & Janak, K. E. (2003). Organometallics, 22, 4084-4089.]), [RuCl(BDP)(cis-1,3,5-tri­amino­cyclohex­ane)]Cl (Gamble et al., 2013[Gamble, A. J., Lynam, J. M., Thatcher, R. J., Walton, P. H. & Whitwood, A. C. (2013). Inorg. Chem. 52, 4517-4527.]), [Ru(2,2′:6′,2′′-terpyrid­ine)(BDP)(CH3CN)](PF6)2 (Nakamura et al., 2014[Nakamura, G., Okamura, M., Yoshida, M., Suzuki, T., Takagi, H. D., Kondo, M. & Masaoka, S. (2014). Inorg. Chem. 53, 7214-7226.]), [Ru(2,2′:6′,2′′-terpyridine))(BDP)(NO2)](PF6) (Nakamura et al., 2015[Nakamura, G., Kondo, M., Crisalli, M., Lee, S. K., Shibata, A., Ford, P. C. & Masaoka, S. (2015). Dalton Trans. 44, 17189-17200.]) and Cp*Ru(BDP)(PPh2) (Sues et al., 2014[Sues, P. E., Lough, A. J. & Morris, R. H. (2014). J. Am. Chem. Soc. 136, 4746-4760.]).

5. Synthesis and crystallization

The title compound was synthesized following a literature procedure (Kakizawa et al., 2015[Kakizawa, T., Hashimoto, H. & Tobita, H. (2015). Inorg. Chim. Acta, 425, 7-10.]) with Ru3(CO)9(μ-H)2(μ3-PMes) (Kakizawa et al., 2006[Kakizawa, T., Hashimoto, H. & Tobita, H. (2006). J. Organomet. Chem. 691, 726-736.]) and 1,2-bis­(di­phenyl­phosphan­yl)benzene in a 2:1 molar ratio. Purification of the reaction mixture with silica-gel chromatography gave the title compound in high yield along with unreacted Ru3(CO)9(μ-H)2(μ3-PMes). Recrystallization from di­chloro­methane and hexane gave the title compound as yellow platelets.

6. Refinement

Crystal data, data collection and structure refinement details are summarized in Table 1[link]. Two H atoms bridging Ru atoms were found in a difference-Fourier map and were refined freely. All other H atoms were placed at their geometrically calculated positions with C—H = 0.95 or 0.98 Å. Fifty outliers were omitted in the final refinement.

Table 1
Experimental details

Crystal data
Chemical formula [Ru3(C30H24P2)(C9H11P)(CO)7H2]
Mr 1097.88
Crystal system, space group Triclinic, P[\overline{1}]
Temperature (K) 150
a, b, c (Å) 10.9732 (2), 19.4127 (3), 22.1186 (2)
α, β, γ (°) 114.1719 (11), 90.2641 (14), 92.5256 (13)
V3) 4293.07 (11)
Z 4
Radiation type Mo Kα
μ (mm−1) 1.21
Crystal size (mm) 0.20 × 0.20 × 0.10
 
Data collection
Diffractometer Rigaku R-AXIS RAPID imaging plate
Absorption correction Numerical (NUMABS; Higashi, 1999[Higashi, T. (1999). NUMABS. Rigaku Corporation, Tokyo, Japan.])
Tmin, Tmax 0.795, 0.889
No. of measured, independent and observed [I > 2σ(I)] reflections 30808, 14332, 12888
Rint 0.060
(sin θ/λ)max−1) 0.595
 
Refinement
R[F2 > 2σ(F2)], wR(F2), S 0.057, 0.146, 1.15
No. of reflections 14332
No. of parameters 1084
H-atom treatment H atoms treated by a mixture of independent and constrained refinement
Δρmax, Δρmin (e Å−3) 2.40, −1.06
Computer programs: PROCESS-AUTO (Rigaku, 1998[Rigaku (1998). PROCESS-AUTO. Rigaku Corporation, Tokyo, Japan.]), TEXSAN (Molecular Structure Corporation & Rigaku, 2000[Molecular Structure Corporation & Rigaku (2000). TEXSAN. MSC, The Woodlands, Texas, USA, and Rigaku Corporation, Tokyo, Japan.]), SHELXS97 and SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]) and Mercury (Macrae et al., 2008[Macrae, C. F., Bruno, I. J., Chisholm, J. A., Edgington, P. R., McCabe, P., Pidcock, E., Rodriguez-Monge, L., Taylor, R., van de Streek, J. & Wood, P. A. (2008). J. Appl. Cryst. 41, 466-470.]).

Supporting information


Computing details top

Data collection: PROCESS-AUTO (Rigaku, 1998); cell refinement: PROCESS-AUTO (Rigaku, 1998); data reduction: TEXSAN (Molecular Structure Corporation & Rigaku, 2000); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: Mercury (Macrae et al., 2008); software used to prepare material for publication: SHELXL97 (Sheldrick, 2008).

[1,2-Bis(diphenylphosphanyl)benzene]heptacarbonyldi-µ-hydrido-(µ3-2,4,6-trimethylphenylphosphinidene)-triangulo-triruthenium top
Crystal data top
[Ru3(C30H24P2)(C9H11P)(CO)7H2]Z = 4
Mr = 1097.88F(000) = 2184
Triclinic, P1Dx = 1.699 Mg m3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71069 Å
a = 10.9732 (2) ÅCell parameters from 17326 reflections
b = 19.4127 (3) Åθ = 3.7–54.9°
c = 22.1186 (2) ŵ = 1.21 mm1
α = 114.1719 (11)°T = 150 K
β = 90.2641 (14)°Platelet, yellow
γ = 92.5256 (13)°0.20 × 0.20 × 0.10 mm
V = 4293.07 (11) Å3
Data collection top
Rigaku R-AXIS RAPID imaging plate
diffractometer
14332 independent reflections
Radiation source: fine-focus sealed tube12888 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.060
ω scansθmax = 25.0°, θmin = 1.2°
Absorption correction: numerical
(NUMABS; Higashi, 1999)
h = 1313
Tmin = 0.795, Tmax = 0.889k = 2323
30808 measured reflectionsl = 2526
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.057Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.146H atoms treated by a mixture of independent and constrained refinement
S = 1.15 w = 1/[σ2(Fo2) + (0.0424P)2 + 58.9367P]
where P = (Fo2 + 2Fc2)/3
14332 reflections(Δ/σ)max = 0.002
1084 parametersΔρmax = 2.40 e Å3
0 restraintsΔρmin = 1.06 e Å3
Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > 2sigma(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Ru10.31256 (5)0.26028 (3)0.75171 (3)0.01095 (13)
Ru20.46980 (5)0.14462 (3)0.66411 (3)0.01404 (14)
H10.476 (7)0.245 (4)0.734 (4)0.009 (18)*
Ru30.32957 (5)0.10606 (3)0.75184 (3)0.01345 (14)
H20.339 (9)0.200 (5)0.795 (5)0.04 (3)*
P10.25754 (17)0.14136 (10)0.67012 (9)0.0129 (4)
P20.13347 (16)0.31589 (10)0.79671 (9)0.0120 (4)
P30.40423 (17)0.35848 (10)0.84357 (9)0.0129 (4)
O10.3105 (5)0.3441 (3)0.6639 (3)0.0265 (13)
O20.7107 (5)0.1556 (4)0.7402 (3)0.0351 (15)
O30.4961 (6)0.0170 (3)0.5614 (3)0.0312 (14)
O40.5533 (6)0.2249 (4)0.5763 (3)0.0423 (17)
O50.5549 (6)0.1033 (3)0.8335 (3)0.0290 (13)
O60.3259 (6)0.0617 (3)0.6626 (3)0.0311 (14)
O70.1338 (6)0.0692 (4)0.8334 (3)0.0357 (15)
C10.3093 (7)0.3127 (4)0.6981 (4)0.0174 (16)
C20.6206 (7)0.1514 (5)0.7123 (4)0.0200 (16)
C30.4858 (7)0.0438 (5)0.5995 (4)0.0213 (17)
C40.5209 (7)0.1923 (5)0.6072 (4)0.0254 (18)
C50.4721 (7)0.1063 (4)0.8044 (4)0.0183 (16)
C60.3291 (7)0.0008 (4)0.6957 (4)0.0165 (15)
C70.2031 (8)0.0875 (4)0.8042 (4)0.0211 (17)
C80.1249 (7)0.1149 (4)0.6131 (4)0.0179 (16)
C90.0131 (7)0.0926 (4)0.6318 (4)0.0170 (15)
C100.0904 (7)0.0792 (4)0.5911 (4)0.0237 (17)
H30.16580.06480.60460.028*
C110.0857 (7)0.0864 (4)0.5310 (4)0.0230 (18)
C120.0259 (8)0.1060 (4)0.5117 (4)0.0231 (18)
H40.03020.11020.47040.028*
C130.1334 (7)0.1200 (4)0.5511 (4)0.0178 (16)
C140.0027 (7)0.0839 (5)0.6958 (4)0.0229 (17)
H50.08980.07700.70270.034*
H60.03150.12930.73260.034*
H70.03980.03970.69380.034*
C150.1997 (8)0.0746 (5)0.4889 (5)0.034 (2)
H80.17790.07530.44620.051*
H90.25490.11510.51160.051*
H100.24030.02570.48140.051*
C160.2493 (8)0.1401 (5)0.5258 (4)0.0268 (18)
H110.27730.19190.55480.040*
H120.23520.13630.48080.040*
H130.31150.10510.52530.040*
C170.0234 (7)0.3264 (4)0.7393 (4)0.0154 (15)
C180.0664 (7)0.2694 (4)0.7084 (4)0.0187 (16)
H140.07350.22690.71930.022*
C190.1455 (7)0.2749 (5)0.6616 (4)0.0224 (17)
H150.20720.23620.64100.027*
C200.1357 (7)0.3356 (5)0.6447 (4)0.0235 (17)
H160.18960.33840.61220.028*
C210.0471 (8)0.3926 (5)0.6752 (4)0.0247 (18)
H170.04140.43520.66440.030*
C220.0335 (7)0.3875 (4)0.7216 (4)0.0206 (16)
H180.09580.42600.74150.025*
C230.0430 (7)0.2847 (4)0.8510 (3)0.0140 (14)
C240.0835 (7)0.2969 (4)0.8594 (4)0.0194 (16)
H190.12590.31750.83360.023*
C250.1440 (8)0.2781 (5)0.9057 (4)0.0252 (18)
H200.22910.28500.91080.030*
C260.0844 (8)0.2497 (5)0.9446 (4)0.0233 (17)
H210.12780.23750.97630.028*
C270.0399 (8)0.2389 (5)0.9373 (4)0.0239 (17)
H220.08230.21990.96430.029*
C280.1020 (7)0.2563 (4)0.8899 (4)0.0216 (17)
H230.18680.24830.88460.026*
C290.1736 (7)0.4141 (4)0.8553 (4)0.0148 (15)
C300.0865 (7)0.4675 (5)0.8825 (4)0.0246 (18)
H240.00350.45440.86850.029*
C310.1184 (8)0.5396 (5)0.9297 (4)0.0259 (18)
H250.05770.57500.94910.031*
C320.2408 (8)0.5591 (4)0.9481 (4)0.0219 (17)
H260.26430.60890.97880.026*
C330.3288 (7)0.5064 (4)0.9219 (4)0.0190 (16)
H270.41150.51990.93630.023*
C340.2975 (7)0.4340 (4)0.8747 (3)0.0137 (14)
C350.5467 (7)0.4072 (4)0.8360 (4)0.0159 (15)
C360.5693 (7)0.4159 (5)0.7780 (4)0.0253 (18)
H280.51230.39530.74180.030*
C370.6753 (8)0.4548 (5)0.7723 (5)0.0289 (19)
H290.68950.46110.73250.035*
C380.7601 (8)0.4843 (5)0.8242 (5)0.0282 (19)
H300.83230.51080.82020.034*
C390.7388 (8)0.4748 (5)0.8811 (4)0.0280 (19)
H310.79800.49390.91630.034*
C400.6333 (7)0.4380 (4)0.8888 (4)0.0207 (16)
H320.61910.43350.92940.025*
C410.4316 (7)0.3373 (4)0.9156 (3)0.0161 (15)
C420.5178 (7)0.2834 (4)0.9100 (4)0.0211 (17)
H330.56430.26260.87100.025*
C430.5347 (7)0.2609 (4)0.9606 (4)0.0231 (17)
H340.59420.22530.95680.028*
C440.4660 (8)0.2894 (4)1.0168 (4)0.0246 (18)
H350.47660.27221.05090.029*
C450.3815 (8)0.3431 (5)1.0237 (4)0.0245 (18)
H360.33480.36311.06260.029*
C460.3655 (7)0.3674 (5)0.9726 (4)0.0225 (17)
H370.30890.40480.97740.027*
Ru40.77029 (5)0.25228 (3)0.74916 (3)0.01190 (13)
Ru50.94605 (5)0.13718 (3)0.83747 (3)0.01403 (14)
H380.927 (9)0.22710.769 (5)0.04 (3)*
Ru60.81076 (5)0.09780 (3)0.75031 (3)0.01341 (14)
H390.790 (7)0.197 (4)0.707 (4)0.01 (2)*
P40.73332 (17)0.13435 (10)0.83138 (9)0.0132 (4)
P50.58284 (17)0.30934 (10)0.70325 (9)0.0146 (4)
P60.84595 (17)0.34968 (10)0.65773 (9)0.0143 (4)
O80.7578 (6)0.3344 (3)0.8385 (3)0.0281 (13)
O91.1827 (6)0.1484 (4)0.7605 (3)0.0379 (16)
O101.0006 (6)0.0239 (3)0.9413 (3)0.0299 (14)
O111.0190 (6)0.2175 (4)0.9243 (3)0.0369 (16)
O121.0304 (6)0.1009 (3)0.6637 (3)0.0315 (14)
O130.8434 (6)0.0700 (3)0.8399 (3)0.0292 (13)
O140.6197 (6)0.0579 (4)0.6711 (3)0.0366 (16)
C470.7611 (7)0.3053 (4)0.8032 (4)0.0185 (16)
C481.0960 (7)0.1437 (5)0.7896 (4)0.0223 (17)
C490.9797 (7)0.0358 (5)0.9024 (4)0.0194 (16)
C500.9908 (7)0.1858 (5)0.8935 (4)0.0199 (17)
C510.9495 (7)0.1000 (4)0.6951 (4)0.0185 (16)
C520.8327 (7)0.0072 (5)0.8064 (4)0.0216 (17)
C530.6867 (8)0.0769 (4)0.6997 (4)0.0219 (17)
C540.6061 (7)0.1109 (4)0.8879 (3)0.0135 (14)
C550.4958 (7)0.0884 (4)0.8698 (4)0.0200 (16)
C560.3966 (8)0.0769 (4)0.9104 (4)0.0243 (18)
H400.32310.06200.89750.029*
C570.4001 (8)0.0863 (4)0.9694 (4)0.0236 (17)
C580.5077 (7)0.1054 (4)0.9881 (4)0.0196 (16)
H410.51230.11031.02910.024*
C590.6120 (8)0.1182 (4)0.9492 (4)0.0227 (17)
C600.4810 (7)0.0774 (5)0.8062 (4)0.0226 (17)
H420.39800.06230.80280.034*
H430.49550.12480.76810.034*
H440.54000.03780.80650.034*
C610.2873 (8)0.0769 (5)1.0112 (4)0.0282 (19)
H450.23740.12430.99430.042*
H460.23970.03651.00870.042*
H470.31210.06371.05730.042*
C620.7273 (8)0.1390 (5)0.9740 (4)0.0247 (18)
H480.71290.14041.01720.037*
H490.79300.10120.97860.037*
H500.75070.18880.94240.037*
C630.4730 (6)0.3206 (4)0.7608 (4)0.0168 (15)
C640.3901 (7)0.2650 (4)0.7910 (4)0.0218 (17)
H510.38590.22360.77880.026*
C650.3129 (8)0.2703 (5)0.8395 (4)0.0275 (19)
H520.25650.23230.86020.033*
C660.3185 (8)0.3300 (5)0.8571 (4)0.0276 (19)
H530.26560.33340.88970.033*
C670.4010 (8)0.3855 (5)0.8274 (4)0.0275 (19)
H540.40410.42710.83940.033*
C680.4787 (7)0.3804 (5)0.7803 (4)0.0237 (17)
H550.53660.41790.76100.028*
C690.4935 (7)0.2793 (4)0.6491 (4)0.0198 (16)
C700.3682 (7)0.2961 (5)0.6383 (4)0.0234 (17)
H560.32550.32150.66110.028*
C710.3065 (8)0.2754 (5)0.5940 (4)0.0282 (19)
H570.22090.28550.58750.034*
C720.3678 (8)0.2403 (5)0.5592 (4)0.0256 (18)
H580.32420.22690.52870.031*
C730.4930 (8)0.2245 (5)0.5684 (4)0.0246 (18)
H590.53600.20070.54440.029*
C740.5532 (8)0.2443 (4)0.6137 (4)0.0232 (17)
H600.63860.23340.62060.028*
C750.6098 (7)0.4080 (4)0.6468 (4)0.0181 (15)
C760.5137 (8)0.4625 (5)0.6205 (4)0.0277 (19)
H610.43170.44920.63110.033*
C770.5391 (9)0.5362 (5)0.5787 (5)0.036 (2)
H620.47430.57360.56140.043*
C780.6579 (8)0.5555 (5)0.5621 (4)0.030 (2)
H630.67400.60610.53360.036*
C790.7532 (8)0.5022 (5)0.5864 (4)0.0256 (18)
H640.83450.51620.57480.031*
C800.7305 (7)0.4267 (4)0.6286 (4)0.0177 (15)
C810.9866 (6)0.3947 (4)0.6631 (4)0.0159 (15)
C821.0196 (7)0.3937 (5)0.7252 (4)0.0230 (17)
H650.97230.36780.76290.028*
C831.1215 (8)0.4307 (5)0.7308 (5)0.0292 (19)
H661.14400.43000.77260.035*
C841.1894 (8)0.4680 (5)0.6770 (5)0.031 (2)
H671.25830.49380.68140.037*
C851.1591 (8)0.4688 (5)0.6156 (5)0.032 (2)
H681.20760.49430.57830.038*
C861.0577 (8)0.4322 (5)0.6092 (4)0.0268 (18)
H691.03670.43280.56720.032*
C870.8699 (7)0.3309 (4)0.5843 (4)0.0189 (16)
C880.9687 (8)0.2832 (5)0.5841 (4)0.0252 (18)
H701.02450.26410.62090.030*
C890.9870 (8)0.2634 (5)0.5320 (4)0.0266 (18)
H711.05460.23070.53280.032*
C900.9049 (9)0.2917 (5)0.4772 (4)0.033 (2)
H720.91760.27900.44050.039*
C910.8061 (9)0.3379 (5)0.4773 (4)0.033 (2)
H730.74950.35600.44090.039*
C920.7887 (9)0.3582 (5)0.5301 (4)0.0275 (19)
H740.72100.39080.52930.033*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ru10.0100 (3)0.0136 (3)0.0100 (3)0.0008 (2)0.0009 (2)0.0056 (2)
Ru20.0106 (3)0.0204 (3)0.0123 (3)0.0038 (2)0.0026 (2)0.0075 (2)
Ru30.0132 (3)0.0146 (3)0.0143 (3)0.0020 (2)0.0007 (2)0.0077 (2)
P10.0149 (9)0.0120 (8)0.0115 (8)0.0022 (7)0.0023 (7)0.0045 (7)
P20.0106 (9)0.0128 (8)0.0127 (8)0.0010 (7)0.0004 (7)0.0053 (7)
P30.0115 (9)0.0160 (9)0.0119 (8)0.0004 (7)0.0006 (7)0.0066 (7)
O10.030 (3)0.034 (3)0.025 (3)0.000 (3)0.001 (3)0.022 (3)
O20.015 (3)0.062 (4)0.033 (3)0.006 (3)0.001 (3)0.025 (3)
O30.035 (4)0.033 (4)0.023 (3)0.015 (3)0.007 (3)0.007 (3)
O40.036 (4)0.070 (5)0.037 (4)0.006 (3)0.004 (3)0.038 (4)
O50.030 (3)0.030 (3)0.028 (3)0.003 (3)0.009 (3)0.013 (3)
O60.036 (4)0.018 (3)0.035 (3)0.004 (2)0.001 (3)0.007 (3)
O70.035 (4)0.044 (4)0.039 (4)0.005 (3)0.017 (3)0.028 (3)
C10.019 (4)0.021 (4)0.013 (3)0.005 (3)0.001 (3)0.007 (3)
C20.017 (4)0.029 (4)0.021 (4)0.003 (3)0.014 (3)0.016 (3)
C30.018 (4)0.031 (5)0.017 (4)0.008 (3)0.004 (3)0.011 (4)
C40.013 (4)0.039 (5)0.023 (4)0.003 (3)0.000 (3)0.010 (4)
C50.018 (4)0.020 (4)0.017 (4)0.006 (3)0.013 (3)0.008 (3)
C60.016 (4)0.021 (4)0.016 (4)0.004 (3)0.000 (3)0.010 (3)
C70.029 (4)0.018 (4)0.017 (4)0.001 (3)0.004 (3)0.008 (3)
C80.018 (4)0.016 (4)0.017 (4)0.006 (3)0.007 (3)0.004 (3)
C90.018 (4)0.011 (3)0.021 (4)0.001 (3)0.002 (3)0.006 (3)
C100.015 (4)0.023 (4)0.026 (4)0.001 (3)0.002 (3)0.004 (3)
C110.024 (4)0.011 (3)0.025 (4)0.008 (3)0.009 (3)0.002 (3)
C120.027 (5)0.023 (4)0.018 (4)0.009 (3)0.005 (3)0.006 (3)
C130.022 (4)0.014 (4)0.016 (4)0.004 (3)0.002 (3)0.003 (3)
C140.013 (4)0.029 (4)0.028 (4)0.001 (3)0.000 (3)0.014 (4)
C150.023 (5)0.029 (5)0.043 (5)0.003 (4)0.014 (4)0.007 (4)
C160.027 (5)0.036 (5)0.021 (4)0.003 (4)0.003 (4)0.015 (4)
C170.015 (4)0.019 (4)0.016 (3)0.010 (3)0.003 (3)0.010 (3)
C180.019 (4)0.016 (4)0.022 (4)0.002 (3)0.005 (3)0.008 (3)
C190.017 (4)0.026 (4)0.024 (4)0.005 (3)0.001 (3)0.010 (3)
C200.018 (4)0.032 (4)0.021 (4)0.004 (3)0.005 (3)0.010 (3)
C210.029 (5)0.034 (5)0.024 (4)0.009 (4)0.003 (4)0.024 (4)
C220.012 (4)0.024 (4)0.028 (4)0.002 (3)0.001 (3)0.012 (3)
C230.014 (4)0.014 (3)0.013 (3)0.001 (3)0.003 (3)0.005 (3)
C240.017 (4)0.026 (4)0.016 (4)0.006 (3)0.002 (3)0.009 (3)
C250.020 (4)0.033 (5)0.020 (4)0.003 (3)0.006 (3)0.007 (4)
C260.027 (4)0.029 (4)0.017 (4)0.003 (3)0.008 (3)0.013 (3)
C270.026 (4)0.030 (4)0.020 (4)0.007 (3)0.004 (3)0.015 (4)
C280.019 (4)0.026 (4)0.020 (4)0.008 (3)0.005 (3)0.010 (3)
C290.016 (4)0.015 (3)0.013 (3)0.001 (3)0.003 (3)0.006 (3)
C300.017 (4)0.027 (4)0.028 (4)0.002 (3)0.006 (3)0.009 (4)
C310.028 (5)0.018 (4)0.029 (4)0.003 (3)0.002 (4)0.007 (3)
C320.029 (4)0.014 (4)0.020 (4)0.000 (3)0.003 (3)0.005 (3)
C330.019 (4)0.017 (4)0.021 (4)0.001 (3)0.005 (3)0.008 (3)
C340.014 (4)0.018 (4)0.011 (3)0.002 (3)0.003 (3)0.008 (3)
C350.015 (4)0.007 (3)0.022 (4)0.002 (3)0.003 (3)0.003 (3)
C360.018 (4)0.034 (5)0.025 (4)0.006 (3)0.001 (3)0.013 (4)
C370.020 (4)0.042 (5)0.040 (5)0.004 (4)0.004 (4)0.033 (4)
C380.024 (4)0.021 (4)0.041 (5)0.002 (3)0.010 (4)0.014 (4)
C390.020 (4)0.024 (4)0.032 (5)0.004 (3)0.009 (4)0.003 (4)
C400.022 (4)0.017 (4)0.021 (4)0.003 (3)0.003 (3)0.006 (3)
C410.015 (4)0.021 (4)0.011 (3)0.003 (3)0.005 (3)0.006 (3)
C420.019 (4)0.021 (4)0.024 (4)0.001 (3)0.008 (3)0.010 (3)
C430.020 (4)0.021 (4)0.031 (4)0.004 (3)0.011 (4)0.014 (4)
C440.038 (5)0.023 (4)0.016 (4)0.010 (3)0.006 (4)0.013 (3)
C450.031 (5)0.028 (4)0.013 (4)0.003 (3)0.004 (3)0.007 (3)
C460.024 (4)0.027 (4)0.020 (4)0.005 (3)0.002 (3)0.013 (3)
Ru40.0126 (3)0.0127 (3)0.0111 (3)0.0000 (2)0.0016 (2)0.0058 (2)
Ru50.0115 (3)0.0191 (3)0.0125 (3)0.0007 (2)0.0012 (2)0.0077 (2)
Ru60.0132 (3)0.0149 (3)0.0143 (3)0.0004 (2)0.0016 (2)0.0083 (2)
P40.0135 (9)0.0140 (9)0.0118 (8)0.0007 (7)0.0037 (7)0.0050 (7)
P50.0135 (9)0.0163 (9)0.0144 (9)0.0009 (7)0.0008 (7)0.0070 (7)
P60.0138 (9)0.0161 (9)0.0133 (9)0.0006 (7)0.0028 (7)0.0063 (7)
O80.037 (4)0.031 (3)0.027 (3)0.006 (3)0.003 (3)0.024 (3)
O90.018 (3)0.066 (5)0.041 (4)0.002 (3)0.013 (3)0.033 (4)
O100.031 (3)0.025 (3)0.024 (3)0.007 (3)0.004 (3)0.001 (3)
O110.030 (4)0.058 (4)0.041 (4)0.008 (3)0.000 (3)0.038 (4)
O120.037 (4)0.028 (3)0.032 (3)0.004 (3)0.021 (3)0.015 (3)
O130.034 (3)0.017 (3)0.032 (3)0.002 (2)0.001 (3)0.006 (3)
O140.037 (4)0.040 (4)0.045 (4)0.003 (3)0.012 (3)0.030 (3)
C470.016 (4)0.019 (4)0.020 (4)0.005 (3)0.001 (3)0.009 (3)
C480.014 (4)0.029 (4)0.026 (4)0.004 (3)0.002 (4)0.013 (4)
C490.011 (4)0.030 (5)0.021 (4)0.006 (3)0.002 (3)0.016 (4)
C500.008 (4)0.037 (5)0.012 (3)0.000 (3)0.006 (3)0.008 (3)
C510.025 (4)0.014 (4)0.019 (4)0.002 (3)0.007 (4)0.010 (3)
C520.016 (4)0.032 (5)0.022 (4)0.000 (3)0.001 (3)0.016 (4)
C530.029 (4)0.015 (4)0.023 (4)0.002 (3)0.001 (4)0.008 (3)
C540.015 (4)0.012 (3)0.013 (3)0.000 (3)0.006 (3)0.006 (3)
C550.022 (4)0.018 (4)0.022 (4)0.002 (3)0.001 (3)0.010 (3)
C560.022 (4)0.017 (4)0.033 (5)0.001 (3)0.006 (4)0.009 (3)
C570.026 (4)0.015 (4)0.026 (4)0.001 (3)0.015 (4)0.004 (3)
C580.024 (4)0.021 (4)0.014 (4)0.005 (3)0.012 (3)0.008 (3)
C590.028 (5)0.019 (4)0.020 (4)0.002 (3)0.000 (3)0.007 (3)
C600.015 (4)0.028 (4)0.030 (4)0.001 (3)0.005 (3)0.017 (4)
C610.024 (4)0.030 (5)0.023 (4)0.004 (3)0.016 (4)0.002 (4)
C620.033 (5)0.028 (4)0.015 (4)0.002 (4)0.007 (3)0.011 (3)
C630.010 (4)0.022 (4)0.018 (4)0.005 (3)0.001 (3)0.009 (3)
C640.025 (4)0.023 (4)0.021 (4)0.002 (3)0.003 (3)0.013 (3)
C650.025 (5)0.027 (4)0.020 (4)0.007 (3)0.011 (4)0.000 (3)
C660.021 (4)0.041 (5)0.019 (4)0.013 (4)0.001 (3)0.012 (4)
C670.031 (5)0.033 (5)0.028 (4)0.006 (4)0.003 (4)0.023 (4)
C680.016 (4)0.031 (4)0.028 (4)0.001 (3)0.003 (3)0.015 (4)
C690.023 (4)0.023 (4)0.016 (4)0.000 (3)0.001 (3)0.010 (3)
C700.023 (4)0.026 (4)0.019 (4)0.002 (3)0.004 (3)0.006 (3)
C710.016 (4)0.045 (5)0.029 (4)0.002 (4)0.003 (4)0.021 (4)
C720.027 (5)0.028 (4)0.024 (4)0.008 (3)0.004 (4)0.013 (4)
C730.031 (5)0.031 (4)0.015 (4)0.007 (4)0.001 (3)0.014 (3)
C740.024 (4)0.024 (4)0.023 (4)0.005 (3)0.006 (3)0.011 (3)
C750.016 (4)0.020 (4)0.022 (4)0.001 (3)0.001 (3)0.012 (3)
C760.023 (4)0.023 (4)0.032 (5)0.005 (3)0.000 (4)0.007 (4)
C770.032 (5)0.025 (5)0.045 (6)0.005 (4)0.004 (4)0.008 (4)
C780.035 (5)0.013 (4)0.031 (5)0.004 (3)0.003 (4)0.001 (3)
C790.022 (4)0.026 (4)0.025 (4)0.004 (3)0.001 (3)0.006 (4)
C800.024 (4)0.017 (4)0.013 (3)0.003 (3)0.002 (3)0.007 (3)
C810.007 (3)0.019 (4)0.019 (4)0.002 (3)0.006 (3)0.005 (3)
C820.022 (4)0.025 (4)0.023 (4)0.004 (3)0.002 (3)0.011 (3)
C830.028 (5)0.031 (5)0.036 (5)0.002 (4)0.006 (4)0.021 (4)
C840.018 (4)0.024 (4)0.051 (6)0.004 (3)0.002 (4)0.017 (4)
C850.024 (5)0.022 (4)0.048 (6)0.004 (3)0.008 (4)0.013 (4)
C860.029 (5)0.026 (4)0.029 (4)0.000 (3)0.007 (4)0.014 (4)
C870.019 (4)0.016 (4)0.019 (4)0.005 (3)0.009 (3)0.004 (3)
C880.026 (4)0.027 (4)0.024 (4)0.009 (3)0.005 (4)0.011 (4)
C890.028 (5)0.028 (4)0.032 (5)0.007 (3)0.018 (4)0.019 (4)
C900.048 (6)0.036 (5)0.021 (4)0.017 (4)0.014 (4)0.017 (4)
C910.052 (6)0.029 (5)0.018 (4)0.004 (4)0.003 (4)0.011 (4)
C920.038 (5)0.025 (4)0.018 (4)0.009 (4)0.001 (4)0.008 (3)
Geometric parameters (Å, º) top
Ru1—C11.853 (7)Ru4—C471.871 (8)
Ru1—P22.3115 (19)Ru4—P52.3126 (19)
Ru1—P12.3252 (18)Ru4—P62.3187 (19)
Ru1—P32.3267 (19)Ru4—P42.3221 (19)
Ru1—Ru22.9297 (8)Ru4—Ru52.9220 (8)
Ru1—Ru33.0089 (8)Ru4—Ru63.0018 (8)
Ru1—H11.85 (8)Ru4—H381.77 (10)
Ru1—H21.82 (10)Ru4—H391.71 (8)
Ru2—C31.909 (8)Ru5—C501.914 (8)
Ru2—C41.915 (9)Ru5—C491.920 (8)
Ru2—C21.935 (8)Ru5—C481.942 (9)
Ru2—P12.3332 (19)Ru5—P42.3419 (19)
Ru2—Ru32.7945 (8)Ru5—Ru62.7902 (8)
Ru2—H11.93 (7)Ru5—H381.78 (5)
Ru3—C61.908 (8)Ru6—C521.906 (9)
Ru3—C71.926 (8)Ru6—C531.918 (8)
Ru3—C51.943 (8)Ru6—C511.948 (8)
Ru3—P12.3259 (18)Ru6—P42.3331 (19)
Ru3—H21.67 (10)Ru6—H391.77 (8)
P1—C81.833 (7)P4—C541.823 (7)
P2—C171.826 (7)P5—C631.828 (8)
P2—C231.830 (7)P5—C691.829 (8)
P2—C291.845 (7)P5—C751.847 (8)
P3—C341.824 (7)P6—C801.815 (8)
P3—C411.828 (7)P6—C871.821 (8)
P3—C351.835 (8)P6—C811.834 (7)
O1—C11.150 (9)O8—C471.135 (9)
O2—C21.144 (10)O9—C481.136 (10)
O3—C31.148 (10)O10—C491.138 (10)
O4—C41.155 (11)O11—C501.137 (10)
O5—C51.130 (10)O12—C511.125 (10)
O6—C61.130 (9)O13—C521.138 (10)
O7—C71.136 (10)O14—C531.134 (10)
C8—C91.403 (11)C54—C551.415 (10)
C8—C131.418 (11)C54—C591.420 (11)
C9—C101.394 (11)C55—C561.381 (12)
C9—C141.502 (11)C55—C601.517 (11)
C10—C111.393 (12)C56—C571.390 (12)
C10—H30.9500C56—H400.9500
C11—C121.387 (13)C57—C581.366 (12)
C11—C151.508 (11)C57—C611.521 (11)
C12—C131.411 (11)C58—C591.404 (12)
C12—H40.9500C58—H410.9500
C13—C161.490 (12)C59—C621.512 (11)
C14—H50.9800C60—H420.9800
C14—H60.9800C60—H430.9800
C14—H70.9800C60—H440.9800
C15—H80.9800C61—H450.9800
C15—H90.9800C61—H460.9800
C15—H100.9800C61—H470.9800
C16—H110.9800C62—H480.9800
C16—H120.9800C62—H490.9800
C16—H130.9800C62—H500.9800
C17—C181.393 (11)C63—C641.394 (11)
C17—C221.394 (11)C63—C681.398 (11)
C18—C191.388 (11)C64—C651.404 (12)
C18—H140.9500C64—H510.9500
C19—C201.373 (12)C65—C661.369 (13)
C19—H150.9500C65—H520.9500
C20—C211.383 (12)C66—C671.388 (13)
C20—H160.9500C66—H530.9500
C21—C221.387 (11)C67—C681.381 (12)
C21—H170.9500C67—H540.9500
C22—H180.9500C68—H550.9500
C23—C281.372 (11)C69—C741.380 (11)
C23—C241.418 (10)C69—C701.396 (11)
C24—C251.385 (12)C70—C711.387 (11)
C24—H190.9500C70—H560.9500
C25—C261.373 (12)C71—C721.379 (12)
C25—H200.9500C71—H570.9500
C26—C271.389 (12)C72—C731.390 (12)
C26—H210.9500C72—H580.9500
C27—C281.398 (11)C73—C741.386 (11)
C27—H220.9500C73—H590.9500
C28—H230.9500C74—H600.9500
C29—C301.390 (11)C75—C761.401 (11)
C29—C341.412 (10)C75—C801.405 (11)
C30—C311.388 (12)C76—C771.391 (13)
C30—H240.9500C76—H610.9500
C31—C321.392 (12)C77—C781.381 (13)
C31—H250.9500C77—H620.9500
C32—C331.385 (11)C78—C791.378 (12)
C32—H260.9500C78—H630.9500
C33—C341.392 (10)C79—C801.412 (11)
C33—H270.9500C79—H640.9500
C35—C361.385 (11)C81—C861.380 (11)
C35—C401.411 (10)C81—C821.411 (11)
C36—C371.392 (12)C82—C831.389 (11)
C36—H280.9500C82—H650.9500
C37—C381.384 (13)C83—C841.358 (13)
C37—H290.9500C83—H660.9500
C38—C391.365 (13)C84—C851.391 (14)
C38—H300.9500C84—H670.9500
C39—C401.382 (12)C85—C861.384 (12)
C39—H310.9500C85—H680.9500
C40—H320.9500C86—H690.9500
C41—C461.378 (11)C87—C921.394 (11)
C41—C421.410 (11)C87—C881.395 (12)
C42—C431.373 (11)C88—C891.369 (12)
C42—H330.9500C88—H700.9500
C43—C441.379 (12)C89—C901.408 (13)
C43—H340.9500C89—H710.9500
C44—C451.388 (12)C90—C911.375 (14)
C44—H350.9500C90—H720.9500
C45—C461.404 (11)C91—C921.389 (12)
C45—H360.9500C91—H730.9500
C46—H370.9500C92—H740.9500
C1—Ru1—P287.6 (2)C47—Ru4—P587.9 (2)
C1—Ru1—P197.1 (2)C47—Ru4—P696.1 (2)
P2—Ru1—P1106.74 (7)P5—Ru4—P683.67 (7)
C1—Ru1—P396.2 (2)C47—Ru4—P496.6 (2)
P2—Ru1—P384.03 (7)P5—Ru4—P4106.98 (7)
P1—Ru1—P3163.17 (7)P6—Ru4—P4163.70 (7)
C1—Ru1—Ru294.3 (2)C47—Ru4—Ru593.6 (2)
P2—Ru1—Ru2157.89 (5)P5—Ru4—Ru5158.48 (5)
P1—Ru1—Ru251.15 (5)P6—Ru4—Ru5117.43 (5)
P3—Ru1—Ru2117.56 (5)P4—Ru4—Ru551.51 (5)
C1—Ru1—Ru3144.2 (2)C47—Ru4—Ru6143.8 (2)
P2—Ru1—Ru3112.36 (5)P5—Ru4—Ru6112.95 (5)
P1—Ru1—Ru349.70 (5)P6—Ru4—Ru6114.79 (5)
P3—Ru1—Ru3114.56 (5)P4—Ru4—Ru650.01 (5)
Ru2—Ru1—Ru356.123 (19)Ru5—Ru4—Ru656.180 (19)
C1—Ru1—H189 (2)C47—Ru4—H3892 (3)
P2—Ru1—H1162 (2)P5—Ru4—H38166.7 (19)
P1—Ru1—H191 (2)P6—Ru4—H3883 (2)
P3—Ru1—H179 (2)P4—Ru4—H3886.2 (16)
Ru2—Ru1—H140 (2)Ru5—Ru4—H3834.8 (18)
Ru3—Ru1—H180 (2)Ru6—Ru4—H3874.1 (16)
C1—Ru1—H2169 (3)C47—Ru4—H39174 (3)
P2—Ru1—H2103 (3)P5—Ru4—H3998 (3)
P1—Ru1—H278 (3)P6—Ru4—H3987 (3)
P3—Ru1—H287 (3)P4—Ru4—H3979 (3)
Ru2—Ru1—H275 (3)Ru5—Ru4—H3980 (3)
Ru3—Ru1—H229 (3)Ru6—Ru4—H3931 (3)
H1—Ru1—H282 (4)H38—Ru4—H3983 (4)
C3—Ru2—C495.3 (4)C50—Ru5—C4995.8 (3)
C3—Ru2—C296.4 (3)C50—Ru5—C48100.4 (3)
C4—Ru2—C2100.8 (3)C49—Ru5—C4895.9 (3)
C3—Ru2—P198.0 (2)C50—Ru5—P4109.9 (2)
C4—Ru2—P1110.0 (2)C49—Ru5—P498.4 (2)
C2—Ru2—P1144.4 (2)C48—Ru5—P4144.8 (2)
C3—Ru2—Ru396.4 (2)C50—Ru5—Ru6160.7 (2)
C4—Ru2—Ru3160.7 (2)C49—Ru5—Ru696.2 (2)
C2—Ru2—Ru393.2 (2)C48—Ru5—Ru693.4 (2)
P1—Ru2—Ru353.03 (5)P4—Ru5—Ru653.21 (5)
C3—Ru2—Ru1148.7 (2)C50—Ru5—Ru499.2 (2)
C4—Ru2—Ru199.3 (3)C49—Ru5—Ru4148.9 (2)
C2—Ru2—Ru1107.8 (2)C48—Ru5—Ru4107.8 (2)
P1—Ru2—Ru150.91 (5)P4—Ru5—Ru450.90 (5)
Ru3—Ru2—Ru163.37 (2)Ru6—Ru5—Ru463.36 (2)
C3—Ru2—H1172 (2)C50—Ru5—H3890 (3)
C4—Ru2—H186 (2)C49—Ru5—H38172 (3)
C2—Ru2—H176 (2)C48—Ru5—H3877 (3)
P1—Ru2—H189 (2)P4—Ru5—H3885 (3)
Ru3—Ru2—H185 (2)Ru6—Ru5—H3880 (3)
Ru1—Ru2—H138 (2)Ru4—Ru5—H3834 (3)
C6—Ru3—C790.6 (3)C52—Ru6—C5390.5 (3)
C6—Ru3—C595.2 (3)C52—Ru6—C5195.2 (3)
C7—Ru3—C599.7 (3)C53—Ru6—C5198.8 (3)
C6—Ru3—P195.1 (2)C52—Ru6—P496.2 (2)
C7—Ru3—P1113.9 (2)C53—Ru6—P4113.5 (3)
C5—Ru3—P1144.7 (2)C51—Ru6—P4145.6 (2)
C6—Ru3—Ru292.4 (2)C52—Ru6—Ru591.8 (2)
C7—Ru3—Ru2167.0 (2)C53—Ru6—Ru5166.9 (3)
C5—Ru3—Ru292.6 (2)C51—Ru6—Ru593.8 (2)
P1—Ru3—Ru253.27 (5)P4—Ru6—Ru553.50 (5)
C6—Ru3—Ru1143.5 (2)C52—Ru6—Ru4144.0 (2)
C7—Ru3—Ru1110.9 (2)C53—Ru6—Ru4111.7 (2)
C5—Ru3—Ru1109.1 (2)C51—Ru6—Ru4108.1 (2)
P1—Ru3—Ru149.68 (5)P4—Ru6—Ru449.69 (5)
Ru2—Ru3—Ru160.50 (2)Ru5—Ru6—Ru460.465 (19)
C6—Ru3—H2174 (3)C52—Ru6—H39174 (3)
C7—Ru3—H295 (3)C53—Ru6—H3994 (3)
C5—Ru3—H285 (3)C51—Ru6—H3989 (3)
P1—Ru3—H281 (3)P4—Ru6—H3978 (3)
Ru2—Ru3—H281 (3)Ru5—Ru6—H3983 (3)
Ru1—Ru3—H232 (3)Ru4—Ru6—H3930 (3)
C8—P1—Ru1127.4 (2)C54—P4—Ru4126.8 (2)
C8—P1—Ru3135.9 (3)C54—P4—Ru6137.3 (2)
Ru1—P1—Ru380.62 (6)Ru4—P4—Ru680.31 (6)
C8—P1—Ru2138.0 (3)C54—P4—Ru5138.0 (2)
Ru1—P1—Ru277.94 (6)Ru4—P4—Ru577.58 (6)
Ru3—P1—Ru273.71 (5)Ru6—P4—Ru573.28 (6)
C17—P2—C23105.4 (3)C63—P5—C69104.9 (4)
C17—P2—C29103.7 (3)C63—P5—C75102.8 (3)
C23—P2—C2999.4 (3)C69—P5—C75101.0 (3)
C17—P2—Ru1116.4 (2)C63—P5—Ru4115.9 (2)
C23—P2—Ru1121.6 (2)C69—P5—Ru4122.5 (3)
C29—P2—Ru1107.6 (2)C75—P5—Ru4107.0 (2)
C34—P3—C41102.6 (3)C80—P6—C87102.3 (3)
C34—P3—C35103.6 (3)C80—P6—C81104.3 (3)
C41—P3—C35104.2 (3)C87—P6—C81102.2 (3)
C34—P3—Ru1107.8 (2)C80—P6—Ru4107.7 (3)
C41—P3—Ru1115.6 (2)C87—P6—Ru4116.3 (2)
C35—P3—Ru1120.9 (2)C81—P6—Ru4121.8 (2)
O1—C1—Ru1177.8 (7)O8—C47—Ru4176.6 (7)
O2—C2—Ru2179.1 (7)O9—C48—Ru5178.8 (8)
O3—C3—Ru2179.1 (7)O10—C49—Ru5179.1 (7)
O4—C4—Ru2175.9 (8)O11—C50—Ru5176.8 (7)
O5—C5—Ru3177.2 (7)O12—C51—Ru6179.3 (8)
O6—C6—Ru3178.4 (7)O13—C52—Ru6178.7 (7)
O7—C7—Ru3172.6 (7)O14—C53—Ru6173.2 (7)
C9—C8—C13119.7 (7)C55—C54—C59118.2 (7)
C9—C8—P1120.0 (6)C55—C54—P4120.1 (6)
C13—C8—P1120.2 (6)C59—C54—P4121.6 (6)
C10—C9—C8120.0 (7)C56—C55—C54119.6 (7)
C10—C9—C14116.9 (7)C56—C55—C60118.0 (7)
C8—C9—C14123.0 (7)C54—C55—C60122.3 (7)
C11—C10—C9121.5 (8)C55—C56—C57122.6 (8)
C11—C10—H3119.3C55—C56—H40118.7
C9—C10—H3119.3C57—C56—H40118.7
C12—C11—C10118.2 (7)C58—C57—C56117.9 (7)
C12—C11—C15121.1 (8)C58—C57—C61121.0 (8)
C10—C11—C15120.7 (8)C56—C57—C61121.1 (8)
C11—C12—C13122.5 (8)C57—C58—C59122.5 (7)
C11—C12—H4118.7C57—C58—H41118.8
C13—C12—H4118.7C59—C58—H41118.8
C12—C13—C8118.0 (7)C58—C59—C54119.1 (7)
C12—C13—C16118.6 (7)C58—C59—C62118.8 (7)
C8—C13—C16123.5 (7)C54—C59—C62122.1 (7)
C9—C14—H5109.5C55—C60—H42109.5
C9—C14—H6109.5C55—C60—H43109.5
H5—C14—H6109.5H42—C60—H43109.5
C9—C14—H7109.5C55—C60—H44109.5
H5—C14—H7109.5H42—C60—H44109.5
H6—C14—H7109.5H43—C60—H44109.5
C11—C15—H8109.5C57—C61—H45109.5
C11—C15—H9109.5C57—C61—H46109.5
H8—C15—H9109.5H45—C61—H46109.5
C11—C15—H10109.5C57—C61—H47109.5
H8—C15—H10109.5H45—C61—H47109.5
H9—C15—H10109.5H46—C61—H47109.5
C13—C16—H11109.5C59—C62—H48109.5
C13—C16—H12109.5C59—C62—H49109.5
H11—C16—H12109.5H48—C62—H49109.5
C13—C16—H13109.5C59—C62—H50109.5
H11—C16—H13109.5H48—C62—H50109.5
H12—C16—H13109.5H49—C62—H50109.5
C18—C17—C22119.1 (7)C64—C63—C68119.0 (7)
C18—C17—P2119.5 (5)C64—C63—P5119.7 (6)
C22—C17—P2121.1 (6)C68—C63—P5120.9 (6)
C19—C18—C17119.7 (7)C63—C64—C65119.8 (7)
C19—C18—H14120.1C63—C64—H51120.1
C17—C18—H14120.1C65—C64—H51120.1
C20—C19—C18120.9 (8)C66—C65—C64120.3 (8)
C20—C19—H15119.6C66—C65—H52119.9
C18—C19—H15119.6C64—C65—H52119.9
C19—C20—C21119.8 (7)C65—C66—C67120.2 (8)
C19—C20—H16120.1C65—C66—H53119.9
C21—C20—H16120.1C67—C66—H53119.9
C20—C21—C22120.0 (7)C68—C67—C66120.1 (8)
C20—C21—H17120.0C68—C67—H54120.0
C22—C21—H17120.0C66—C67—H54120.0
C21—C22—C17120.4 (7)C67—C68—C63120.5 (8)
C21—C22—H18119.8C67—C68—H55119.7
C17—C22—H18119.8C63—C68—H55119.7
C28—C23—C24119.1 (7)C74—C69—C70118.8 (7)
C28—C23—P2118.6 (6)C74—C69—P5119.0 (6)
C24—C23—P2121.8 (5)C70—C69—P5122.0 (6)
C25—C24—C23118.8 (7)C71—C70—C69119.3 (8)
C25—C24—H19120.6C71—C70—H56120.3
C23—C24—H19120.6C69—C70—H56120.3
C26—C25—C24121.8 (8)C72—C71—C70121.0 (8)
C26—C25—H20119.1C72—C71—H57119.5
C24—C25—H20119.1C70—C71—H57119.5
C25—C26—C27119.6 (7)C71—C72—C73120.4 (7)
C25—C26—H21120.2C71—C72—H58119.8
C27—C26—H21120.2C73—C72—H58119.8
C26—C27—C28119.4 (7)C74—C73—C72118.1 (8)
C26—C27—H22120.3C74—C73—H59120.9
C28—C27—H22120.3C72—C73—H59120.9
C23—C28—C27121.3 (7)C69—C74—C73122.4 (8)
C23—C28—H23119.4C69—C74—H60118.8
C27—C28—H23119.4C73—C74—H60118.8
C30—C29—C34119.5 (7)C76—C75—C80120.3 (7)
C30—C29—P2122.5 (6)C76—C75—P5121.8 (6)
C34—C29—P2117.9 (5)C80—C75—P5117.8 (6)
C31—C30—C29121.3 (7)C77—C76—C75119.5 (8)
C31—C30—H24119.4C77—C76—H61120.3
C29—C30—H24119.4C75—C76—H61120.3
C30—C31—C32118.9 (8)C78—C77—C76120.5 (8)
C30—C31—H25120.5C78—C77—H62119.8
C32—C31—H25120.5C76—C77—H62119.8
C33—C32—C31120.5 (7)C79—C78—C77120.8 (8)
C33—C32—H26119.7C79—C78—H63119.6
C31—C32—H26119.7C77—C78—H63119.6
C32—C33—C34120.9 (7)C78—C79—C80120.2 (8)
C32—C33—H27119.6C78—C79—H64119.9
C34—C33—H27119.6C80—C79—H64119.9
C33—C34—C29118.8 (7)C75—C80—C79118.7 (7)
C33—C34—P3123.7 (6)C75—C80—P6116.8 (6)
C29—C34—P3117.0 (5)C79—C80—P6124.4 (6)
C36—C35—C40118.7 (7)C86—C81—C82119.0 (7)
C36—C35—P3119.7 (6)C86—C81—P6123.4 (6)
C40—C35—P3121.6 (6)C82—C81—P6117.5 (6)
C35—C36—C37120.3 (8)C83—C82—C81119.6 (8)
C35—C36—H28119.8C83—C82—H65120.2
C37—C36—H28119.8C81—C82—H65120.2
C38—C37—C36120.6 (8)C84—C83—C82120.5 (8)
C38—C37—H29119.7C84—C83—H66119.7
C36—C37—H29119.7C82—C83—H66119.7
C39—C38—C37119.2 (8)C83—C84—C85120.5 (8)
C39—C38—H30120.4C83—C84—H67119.7
C37—C38—H30120.4C85—C84—H67119.7
C38—C39—C40121.6 (8)C86—C85—C84119.6 (9)
C38—C39—H31119.2C86—C85—H68120.2
C40—C39—H31119.2C84—C85—H68120.2
C39—C40—C35119.6 (8)C81—C86—C85120.7 (8)
C39—C40—H32120.2C81—C86—H69119.6
C35—C40—H32120.2C85—C86—H69119.6
C46—C41—C42119.2 (7)C92—C87—C88118.5 (7)
C46—C41—P3122.8 (6)C92—C87—P6122.4 (6)
C42—C41—P3117.8 (6)C88—C87—P6118.9 (6)
C43—C42—C41120.2 (8)C89—C88—C87121.5 (8)
C43—C42—H33119.9C89—C88—H70119.3
C41—C42—H33119.9C87—C88—H70119.3
C42—C43—C44120.6 (8)C88—C89—C90119.6 (8)
C42—C43—H34119.7C88—C89—H71120.2
C44—C43—H34119.7C90—C89—H71120.2
C43—C44—C45120.3 (7)C91—C90—C89119.5 (8)
C43—C44—H35119.9C91—C90—H72120.2
C45—C44—H35119.9C89—C90—H72120.2
C44—C45—C46119.4 (8)C90—C91—C92120.5 (8)
C44—C45—H36120.3C90—C91—H73119.7
C46—C45—H36120.3C92—C91—H73119.7
C41—C46—C45120.3 (7)C91—C92—C87120.3 (8)
C41—C46—H37119.8C91—C92—H74119.8
C45—C46—H37119.8C87—C92—H74119.8
C1—Ru1—Ru2—C3104.0 (5)C47—Ru4—Ru5—C5012.6 (3)
P2—Ru1—Ru2—C39.8 (5)P5—Ru4—Ru5—C50106.0 (3)
P1—Ru1—Ru2—C38.3 (4)P6—Ru4—Ru5—C5086.1 (2)
P3—Ru1—Ru2—C3156.7 (4)P4—Ru4—Ru5—C50108.3 (2)
Ru3—Ru1—Ru2—C354.4 (4)Ru6—Ru4—Ru5—C50171.2 (2)
C1—Ru1—Ru2—C412.6 (3)C47—Ru4—Ru5—C49105.3 (5)
P2—Ru1—Ru2—C4106.8 (3)P5—Ru4—Ru5—C4912.0 (5)
P1—Ru1—Ru2—C4108.3 (2)P6—Ru4—Ru5—C49156.0 (4)
P3—Ru1—Ru2—C486.6 (2)P4—Ru4—Ru5—C499.7 (4)
Ru3—Ru1—Ru2—C4171.0 (2)Ru6—Ru4—Ru5—C4953.2 (4)
C1—Ru1—Ru2—C2117.2 (3)C47—Ru4—Ru5—C48116.8 (3)
P2—Ru1—Ru2—C2148.7 (3)P5—Ru4—Ru5—C48149.9 (3)
P1—Ru1—Ru2—C2147.1 (2)P6—Ru4—Ru5—C4818.0 (2)
P3—Ru1—Ru2—C217.9 (2)P4—Ru4—Ru5—C48147.6 (2)
Ru3—Ru1—Ru2—C284.5 (2)Ru6—Ru4—Ru5—C4884.7 (2)
C1—Ru1—Ru2—P195.7 (2)C47—Ru4—Ru5—P495.6 (2)
P2—Ru1—Ru2—P11.57 (14)P5—Ru4—Ru5—P42.30 (15)
P3—Ru1—Ru2—P1165.02 (8)P6—Ru4—Ru5—P4165.66 (8)
Ru3—Ru1—Ru2—P162.64 (6)Ru6—Ru4—Ru5—P462.90 (6)
C1—Ru1—Ru2—Ru3158.4 (2)C47—Ru4—Ru5—Ru6158.5 (2)
P2—Ru1—Ru2—Ru364.21 (14)P5—Ru4—Ru5—Ru665.19 (15)
P1—Ru1—Ru2—Ru362.64 (6)P6—Ru4—Ru5—Ru6102.76 (6)
P3—Ru1—Ru2—Ru3102.38 (6)P4—Ru4—Ru5—Ru662.90 (6)
C3—Ru2—Ru3—C60.7 (3)C50—Ru5—Ru6—C52128.6 (7)
C4—Ru2—Ru3—C6126.3 (8)C49—Ru5—Ru6—C520.5 (3)
C2—Ru2—Ru3—C697.4 (3)C48—Ru5—Ru6—C5295.8 (3)
P1—Ru2—Ru3—C694.5 (2)P4—Ru5—Ru6—C5296.3 (2)
Ru1—Ru2—Ru3—C6154.2 (2)Ru4—Ru5—Ru6—C52155.9 (2)
C3—Ru2—Ru3—C7104.1 (10)C50—Ru5—Ru6—C5328.6 (12)
C4—Ru2—Ru3—C722.9 (13)C49—Ru5—Ru6—C5399.5 (10)
C2—Ru2—Ru3—C7159.1 (10)C48—Ru5—Ru6—C53164.2 (10)
P1—Ru2—Ru3—C78.9 (10)P4—Ru5—Ru6—C533.7 (10)
Ru1—Ru2—Ru3—C750.7 (10)Ru4—Ru5—Ru6—C5355.9 (10)
C3—Ru2—Ru3—C594.6 (3)C50—Ru5—Ru6—C51136.0 (7)
C4—Ru2—Ru3—C5138.4 (8)C49—Ru5—Ru6—C5195.8 (3)
C2—Ru2—Ru3—C52.1 (3)C48—Ru5—Ru6—C510.5 (3)
P1—Ru2—Ru3—C5170.2 (2)P4—Ru5—Ru6—C51168.3 (2)
Ru1—Ru2—Ru3—C5110.5 (2)Ru4—Ru5—Ru6—C51108.7 (2)
C3—Ru2—Ru3—P195.2 (2)C50—Ru5—Ru6—P432.3 (7)
C4—Ru2—Ru3—P131.8 (8)C49—Ru5—Ru6—P495.8 (2)
C2—Ru2—Ru3—P1168.0 (2)C48—Ru5—Ru6—P4167.9 (2)
Ru1—Ru2—Ru3—P159.64 (6)Ru4—Ru5—Ru6—P459.61 (6)
C3—Ru2—Ru3—Ru1154.8 (2)C50—Ru5—Ru6—Ru427.3 (7)
C4—Ru2—Ru3—Ru127.8 (7)C49—Ru5—Ru6—Ru4155.4 (2)
C2—Ru2—Ru3—Ru1108.4 (2)C48—Ru5—Ru6—Ru4108.3 (2)
P1—Ru2—Ru3—Ru159.64 (6)P4—Ru5—Ru6—Ru459.61 (6)
C1—Ru1—Ru3—C68.1 (6)C47—Ru4—Ru6—C525.7 (6)
P2—Ru1—Ru3—C6111.5 (4)P5—Ru4—Ru6—C52114.9 (4)
P1—Ru1—Ru3—C618.1 (4)P6—Ru4—Ru6—C52151.5 (4)
P3—Ru1—Ru3—C6154.8 (4)P4—Ru4—Ru6—C5221.5 (4)
Ru2—Ru1—Ru3—C647.0 (4)Ru5—Ru4—Ru6—C5243.9 (4)
C1—Ru1—Ru3—C7130.4 (5)C47—Ru4—Ru6—C53130.2 (5)
P2—Ru1—Ru3—C710.8 (3)P5—Ru4—Ru6—C539.6 (3)
P1—Ru1—Ru3—C7104.2 (3)P6—Ru4—Ru6—C5384.1 (3)
P3—Ru1—Ru3—C782.9 (3)P4—Ru4—Ru6—C53102.9 (3)
Ru2—Ru1—Ru3—C7169.3 (3)Ru5—Ru4—Ru6—C53168.4 (3)
C1—Ru1—Ru3—C5120.8 (5)C47—Ru4—Ru6—C51122.2 (5)
P2—Ru1—Ru3—C5119.6 (2)P5—Ru4—Ru6—C51117.2 (2)
P1—Ru1—Ru3—C5147.0 (2)P6—Ru4—Ru6—C5123.6 (2)
P3—Ru1—Ru3—C525.9 (2)P4—Ru4—Ru6—C51149.4 (3)
Ru2—Ru1—Ru3—C581.9 (2)Ru5—Ru4—Ru6—C5184.0 (2)
C1—Ru1—Ru3—P126.2 (4)C47—Ru4—Ru6—P427.2 (4)
P2—Ru1—Ru3—P193.41 (8)P5—Ru4—Ru6—P493.37 (8)
P3—Ru1—Ru3—P1172.90 (8)P6—Ru4—Ru6—P4172.97 (8)
Ru2—Ru1—Ru3—P165.09 (6)Ru5—Ru4—Ru6—P465.43 (6)
C1—Ru1—Ru3—Ru238.9 (4)C47—Ru4—Ru6—Ru538.2 (4)
P2—Ru1—Ru3—Ru2158.50 (5)P5—Ru4—Ru6—Ru5158.80 (6)
P1—Ru1—Ru3—Ru265.09 (6)P6—Ru4—Ru6—Ru5107.54 (6)
P3—Ru1—Ru3—Ru2107.81 (6)P4—Ru4—Ru6—Ru565.43 (6)
C1—Ru1—P1—C852.8 (4)C47—Ru4—P4—C5452.5 (4)
P2—Ru1—P1—C836.8 (4)P5—Ru4—P4—C5437.3 (3)
P3—Ru1—P1—C8165.1 (4)P6—Ru4—P4—C54166.7 (3)
Ru2—Ru1—P1—C8142.6 (4)Ru5—Ru4—P4—C54141.8 (3)
Ru3—Ru1—P1—C8142.2 (4)Ru6—Ru4—P4—C54143.4 (3)
C1—Ru1—P1—Ru3164.9 (2)C47—Ru4—P4—Ru6164.2 (2)
P2—Ru1—P1—Ru3105.42 (6)P5—Ru4—P4—Ru6106.02 (7)
P3—Ru1—P1—Ru322.9 (3)P6—Ru4—P4—Ru623.3 (3)
Ru2—Ru1—P1—Ru375.20 (5)Ru5—Ru4—P4—Ru674.86 (5)
C1—Ru1—P1—Ru289.7 (2)C47—Ru4—P4—Ru589.3 (2)
P2—Ru1—P1—Ru2179.38 (6)P5—Ru4—P4—Ru5179.12 (6)
P3—Ru1—P1—Ru252.3 (3)P6—Ru4—P4—Ru551.6 (3)
Ru3—Ru1—P1—Ru275.20 (5)Ru6—Ru4—P4—Ru574.86 (5)
C6—Ru3—P1—C855.0 (4)C52—Ru6—P4—C5457.3 (4)
C7—Ru3—P1—C837.9 (4)C53—Ru6—P4—C5436.0 (4)
C5—Ru3—P1—C8161.4 (5)C51—Ru6—P4—C54165.9 (5)
Ru2—Ru3—P1—C8144.3 (4)Ru5—Ru6—P4—C54144.9 (4)
Ru1—Ru3—P1—C8135.7 (4)Ru4—Ru6—P4—C54135.2 (4)
C6—Ru3—P1—Ru1169.3 (2)C52—Ru6—P4—Ru4167.5 (2)
C7—Ru3—P1—Ru197.7 (3)C53—Ru6—P4—Ru499.3 (3)
C5—Ru3—P1—Ru162.9 (4)C51—Ru6—P4—Ru458.9 (4)
Ru2—Ru3—P1—Ru180.07 (5)Ru5—Ru6—P4—Ru479.84 (5)
C6—Ru3—P1—Ru289.2 (2)C52—Ru6—P4—Ru587.7 (2)
C7—Ru3—P1—Ru2177.8 (2)C53—Ru6—P4—Ru5179.1 (2)
C5—Ru3—P1—Ru217.2 (4)C51—Ru6—P4—Ru520.9 (4)
Ru1—Ru3—P1—Ru280.07 (5)Ru4—Ru6—P4—Ru579.84 (5)
C3—Ru2—P1—C850.5 (4)C50—Ru5—P4—C5446.5 (4)
C4—Ru2—P1—C848.1 (5)C49—Ru5—P4—C5452.8 (4)
C2—Ru2—P1—C8163.4 (5)C48—Ru5—P4—C54165.7 (5)
Ru3—Ru2—P1—C8142.6 (4)Ru6—Ru5—P4—C54144.3 (4)
Ru1—Ru2—P1—C8133.8 (4)Ru4—Ru5—P4—C54132.2 (4)
C3—Ru2—P1—Ru1175.7 (2)C50—Ru5—P4—Ru485.7 (3)
C4—Ru2—P1—Ru185.7 (3)C49—Ru5—P4—Ru4175.0 (2)
C2—Ru2—P1—Ru162.8 (4)C48—Ru5—P4—Ru462.1 (4)
Ru3—Ru2—P1—Ru183.62 (5)Ru6—Ru5—P4—Ru483.46 (5)
C3—Ru2—P1—Ru392.0 (2)C50—Ru5—P4—Ru6169.2 (3)
C4—Ru2—P1—Ru3169.3 (3)C49—Ru5—P4—Ru691.5 (2)
C2—Ru2—P1—Ru320.9 (4)C48—Ru5—P4—Ru621.3 (4)
Ru1—Ru2—P1—Ru383.62 (5)Ru4—Ru5—P4—Ru683.46 (5)
C1—Ru1—P2—C1738.4 (4)C47—Ru4—P5—C6338.4 (4)
P1—Ru1—P2—C1758.3 (3)P6—Ru4—P5—C63134.7 (3)
P3—Ru1—P2—C17134.9 (3)P4—Ru4—P5—C6357.9 (3)
Ru2—Ru1—P2—C1757.0 (3)Ru5—Ru4—P5—C6356.0 (3)
Ru3—Ru1—P2—C17111.0 (3)Ru6—Ru4—P5—C63111.0 (3)
C1—Ru1—P2—C23169.3 (4)C47—Ru4—P5—C69168.9 (4)
P1—Ru1—P2—C2372.6 (3)P6—Ru4—P5—C6994.8 (3)
P3—Ru1—P2—C2394.2 (3)P4—Ru4—P5—C6972.6 (3)
Ru2—Ru1—P2—C2373.8 (3)Ru5—Ru4—P5—C6974.5 (3)
Ru3—Ru1—P2—C2319.9 (3)Ru6—Ru4—P5—C6919.5 (3)
C1—Ru1—P2—C2977.3 (3)C47—Ru4—P5—C7575.5 (3)
P1—Ru1—P2—C29174.1 (2)P6—Ru4—P5—C7520.8 (3)
P3—Ru1—P2—C2919.2 (2)P4—Ru4—P5—C75171.8 (3)
Ru2—Ru1—P2—C29172.8 (2)Ru5—Ru4—P5—C75169.9 (3)
Ru3—Ru1—P2—C29133.3 (2)Ru6—Ru4—P5—C75135.1 (3)
C1—Ru1—P3—C3466.0 (3)C47—Ru4—P6—C8064.0 (3)
P2—Ru1—P3—C3420.9 (2)P5—Ru4—P6—C8023.2 (3)
P1—Ru1—P3—C34151.8 (3)P4—Ru4—P6—C80155.0 (3)
Ru2—Ru1—P3—C34164.1 (2)Ru5—Ru4—P6—C80161.3 (2)
Ru3—Ru1—P3—C34132.8 (2)Ru6—Ru4—P6—C80135.5 (2)
C1—Ru1—P3—C41179.9 (4)C47—Ru4—P6—C87178.0 (4)
P2—Ru1—P3—C4193.2 (3)P5—Ru4—P6—C8790.9 (3)
P1—Ru1—P3—C4137.7 (4)P4—Ru4—P6—C8741.0 (4)
Ru2—Ru1—P3—C4181.8 (3)Ru5—Ru4—P6—C8784.7 (3)
Ru3—Ru1—P3—C4118.7 (3)Ru6—Ru4—P6—C8721.5 (3)
C1—Ru1—P3—C3552.7 (4)C47—Ru4—P6—C8156.2 (4)
P2—Ru1—P3—C35139.6 (3)P5—Ru4—P6—C81143.4 (3)
P1—Ru1—P3—C3589.5 (4)P4—Ru4—P6—C8184.7 (4)
Ru2—Ru1—P3—C3545.4 (3)Ru5—Ru4—P6—C8141.0 (3)
Ru3—Ru1—P3—C35108.5 (3)Ru6—Ru4—P6—C81104.2 (3)
Ru1—P1—C8—C988.1 (6)Ru4—P4—C54—C5589.1 (6)
Ru3—P1—C8—C931.6 (8)Ru6—P4—C54—C5530.8 (8)
Ru2—P1—C8—C9154.7 (4)Ru5—P4—C54—C55155.4 (5)
Ru1—P1—C8—C1389.2 (6)Ru4—P4—C54—C5987.6 (6)
Ru3—P1—C8—C13151.1 (5)Ru6—P4—C54—C59152.5 (5)
Ru2—P1—C8—C1328.0 (8)Ru5—P4—C54—C5927.8 (8)
C13—C8—C9—C103.2 (11)C59—C54—C55—C562.3 (11)
P1—C8—C9—C10174.1 (6)P4—C54—C55—C56174.5 (6)
C13—C8—C9—C14178.4 (7)C59—C54—C55—C60178.7 (7)
P1—C8—C9—C144.3 (10)P4—C54—C55—C604.4 (10)
C8—C9—C10—C110.9 (11)C54—C55—C56—C570.3 (12)
C14—C9—C10—C11179.4 (7)C60—C55—C56—C57179.3 (7)
C9—C10—C11—C121.3 (11)C55—C56—C57—C582.0 (12)
C9—C10—C11—C15177.7 (7)C55—C56—C57—C61177.0 (8)
C10—C11—C12—C131.1 (11)C56—C57—C58—C592.2 (12)
C15—C11—C12—C13177.8 (7)C61—C57—C58—C59176.8 (7)
C11—C12—C13—C81.1 (11)C57—C58—C59—C540.2 (12)
C11—C12—C13—C16179.5 (7)C57—C58—C59—C62179.8 (7)
C9—C8—C13—C123.3 (10)C55—C54—C59—C582.1 (11)
P1—C8—C13—C12174.0 (5)P4—C54—C59—C58174.7 (6)
C9—C8—C13—C16177.4 (7)C55—C54—C59—C62177.6 (7)
P1—C8—C13—C165.3 (10)P4—C54—C59—C625.7 (10)
C23—P2—C17—C1846.7 (7)C69—P5—C63—C6446.0 (7)
C29—P2—C17—C18150.8 (6)C75—P5—C63—C64151.2 (6)
Ru1—P2—C17—C1891.4 (6)Ru4—P5—C63—C6492.4 (6)
C23—P2—C17—C22138.4 (6)C69—P5—C63—C68140.6 (6)
C29—P2—C17—C2234.4 (7)C75—P5—C63—C6835.3 (7)
Ru1—P2—C17—C2283.5 (6)Ru4—P5—C63—C6881.0 (6)
C22—C17—C18—C191.1 (12)C68—C63—C64—C650.9 (11)
P2—C17—C18—C19176.0 (6)P5—C63—C64—C65174.5 (6)
C17—C18—C19—C200.7 (12)C63—C64—C65—C660.2 (12)
C18—C19—C20—C210.9 (13)C64—C65—C66—C670.4 (12)
C19—C20—C21—C221.5 (13)C65—C66—C67—C680.6 (13)
C20—C21—C22—C172.0 (12)C66—C67—C68—C631.7 (12)
C18—C17—C22—C211.8 (12)C64—C63—C68—C671.9 (12)
P2—C17—C22—C21176.6 (6)P5—C63—C68—C67175.3 (6)
C17—P2—C23—C28166.0 (6)C63—P5—C69—C74160.6 (6)
C29—P2—C23—C2886.8 (6)C75—P5—C69—C7492.9 (7)
Ru1—P2—C23—C2830.6 (7)Ru4—P5—C69—C7425.7 (8)
C17—P2—C23—C2421.2 (7)C63—P5—C69—C7024.7 (7)
C29—P2—C23—C2485.9 (6)C75—P5—C69—C7081.8 (7)
Ru1—P2—C23—C24156.6 (5)Ru4—P5—C69—C70159.6 (5)
C28—C23—C24—C251.4 (11)C74—C69—C70—C711.8 (12)
P2—C23—C24—C25174.1 (6)P5—C69—C70—C71176.6 (6)
C23—C24—C25—C261.4 (12)C69—C70—C71—C721.7 (13)
C24—C25—C26—C270.4 (13)C70—C71—C72—C730.5 (13)
C25—C26—C27—C280.7 (12)C71—C72—C73—C740.6 (13)
C24—C23—C28—C270.3 (12)C70—C69—C74—C730.8 (12)
P2—C23—C28—C27173.3 (6)P5—C69—C74—C73175.6 (6)
C26—C27—C28—C230.8 (12)C72—C73—C74—C690.4 (13)
C17—P2—C29—C3044.8 (7)C63—P5—C75—C7645.1 (7)
C23—P2—C29—C3063.8 (7)C69—P5—C75—C7663.2 (7)
Ru1—P2—C29—C30168.6 (6)Ru4—P5—C75—C76167.6 (6)
C17—P2—C29—C34137.8 (6)C63—P5—C75—C80137.2 (6)
C23—P2—C29—C34113.7 (6)C69—P5—C75—C80114.5 (6)
Ru1—P2—C29—C3413.9 (6)Ru4—P5—C75—C8014.7 (6)
C34—C29—C30—C311.7 (12)C80—C75—C76—C773.0 (13)
P2—C29—C30—C31175.8 (7)P5—C75—C76—C77179.4 (7)
C29—C30—C31—C322.4 (13)C75—C76—C77—C781.2 (14)
C30—C31—C32—C332.9 (13)C76—C77—C78—C790.2 (15)
C31—C32—C33—C342.6 (12)C77—C78—C79—C800.3 (14)
C32—C33—C34—C291.8 (11)C76—C75—C80—C793.4 (11)
C32—C33—C34—P3173.9 (6)P5—C75—C80—C79178.8 (6)
C30—C29—C34—C331.3 (11)C76—C75—C80—P6173.1 (6)
P2—C29—C34—C33176.2 (6)P5—C75—C80—P64.6 (8)
C30—C29—C34—P3173.9 (6)C78—C79—C80—C752.1 (12)
P2—C29—C34—P33.6 (8)C78—C79—C80—P6174.1 (7)
C41—P3—C34—C3369.1 (7)C87—P6—C80—C75101.2 (6)
C35—P3—C34—C3339.2 (7)C81—P6—C80—C75152.6 (6)
Ru1—P3—C34—C33168.4 (6)Ru4—P6—C80—C7521.8 (6)
C41—P3—C34—C29103.1 (6)C87—P6—C80—C7975.1 (7)
C35—P3—C34—C29148.6 (6)C81—P6—C80—C7931.1 (7)
Ru1—P3—C34—C2919.4 (6)Ru4—P6—C80—C79161.8 (6)
C34—P3—C35—C3688.0 (7)C80—P6—C81—C8681.7 (7)
C41—P3—C35—C36164.9 (6)C87—P6—C81—C8624.5 (7)
Ru1—P3—C35—C3632.7 (7)Ru4—P6—C81—C86156.4 (6)
C34—P3—C35—C4090.3 (6)C80—P6—C81—C8295.2 (6)
C41—P3—C35—C4016.7 (7)C87—P6—C81—C82158.5 (6)
Ru1—P3—C35—C40148.9 (5)Ru4—P6—C81—C8226.6 (7)
C40—C35—C36—C370.4 (12)C86—C81—C82—C830.7 (12)
P3—C35—C36—C37178.0 (7)P6—C81—C82—C83176.4 (6)
C35—C36—C37—C380.9 (13)C81—C82—C83—C840.1 (13)
C36—C37—C38—C390.1 (13)C82—C83—C84—C851.0 (13)
C37—C38—C39—C401.6 (13)C83—C84—C85—C861.0 (13)
C38—C39—C40—C352.1 (12)C82—C81—C86—C850.6 (12)
C36—C35—C40—C391.1 (11)P6—C81—C86—C85176.2 (6)
P3—C35—C40—C39179.4 (6)C84—C85—C86—C810.2 (13)
C34—P3—C41—C468.9 (7)C80—P6—C87—C9215.4 (7)
C35—P3—C41—C46116.6 (7)C81—P6—C87—C92123.3 (7)
Ru1—P3—C41—C46108.2 (6)Ru4—P6—C87—C92101.6 (7)
C34—P3—C41—C42176.2 (6)C80—P6—C87—C88169.0 (6)
C35—P3—C41—C4268.4 (6)C81—P6—C87—C8861.1 (7)
Ru1—P3—C41—C4266.8 (6)Ru4—P6—C87—C8873.9 (6)
C46—C41—C42—C430.5 (11)C92—C87—C88—C890.2 (12)
P3—C41—C42—C43174.7 (6)P6—C87—C88—C89176.0 (6)
C41—C42—C43—C441.4 (12)C87—C88—C89—C900.2 (12)
C42—C43—C44—C452.0 (12)C88—C89—C90—C911.1 (13)
C43—C44—C45—C460.7 (12)C89—C90—C91—C921.6 (14)
C42—C41—C46—C451.7 (12)C90—C91—C92—C871.1 (14)
P3—C41—C46—C45173.2 (6)C88—C87—C92—C910.2 (12)
C44—C45—C46—C411.2 (13)P6—C87—C92—C91175.4 (7)
 

Acknowledgements

This work was supported in part by a Waseda University Grant for Special Research Projects (project number 2017 K-199). The author thanks Dr H. Hashimoto and Professor H. Tobita for their helpful assistance.

References

First citationBunten, K. A., Farrar, D. H., Poë, A. J. & Lough, A. J. (2000). Organometallics, 19, 3674–3682.  Web of Science CSD CrossRef CAS Google Scholar
First citationGamble, A. J., Lynam, J. M., Thatcher, R. J., Walton, P. H. & Whitwood, A. C. (2013). Inorg. Chem. 52, 4517–4527.  Web of Science CSD CrossRef CAS PubMed Google Scholar
First citationGuan, H., Iimura, M., Magee, M. P., Norton, J. R. & Janak, K. E. (2003). Organometallics, 22, 4084–4089.  Web of Science CSD CrossRef CAS Google Scholar
First citationHigashi, T. (1999). NUMABS. Rigaku Corporation, Tokyo, Japan.  Google Scholar
First citationKakizawa, T., Hashimoto, H. & Tobita, H. (2006). J. Organomet. Chem. 691, 726–736.  Web of Science CSD CrossRef CAS Google Scholar
First citationKakizawa, T., Hashimoto, H. & Tobita, H. (2015). Inorg. Chim. Acta, 425, 7–10.  Web of Science CSD CrossRef CAS Google Scholar
First citationMacrae, C. F., Bruno, I. J., Chisholm, J. A., Edgington, P. R., McCabe, P., Pidcock, E., Rodriguez-Monge, L., Taylor, R., van de Streek, J. & Wood, P. A. (2008). J. Appl. Cryst. 41, 466–470.  Web of Science CSD CrossRef CAS IUCr Journals Google Scholar
First citationMashima, K., Komura, N., Yamagata, T., Tani, K. & Haga, M. (1997). Inorg. Chem. 36, 2908–2912.  CSD CrossRef PubMed CAS Web of Science Google Scholar
First citationMolecular Structure Corporation & Rigaku (2000). TEXSAN. MSC, The Woodlands, Texas, USA, and Rigaku Corporation, Tokyo, Japan.  Google Scholar
First citationNakamura, G., Kondo, M., Crisalli, M., Lee, S. K., Shibata, A., Ford, P. C. & Masaoka, S. (2015). Dalton Trans. 44, 17189–17200.  Web of Science CSD CrossRef CAS PubMed Google Scholar
First citationNakamura, G., Okamura, M., Yoshida, M., Suzuki, T., Takagi, H. D., Kondo, M. & Masaoka, S. (2014). Inorg. Chem. 53, 7214–7226.  Web of Science CSD CrossRef CAS PubMed Google Scholar
First citationNesterov, V. N., Watson, W. H., Kandala, S. & Richmond, M. G. (2007). Polyhedron, 26, 3602–3608.  Web of Science CSD CrossRef CAS Google Scholar
First citationRigaku (1998). PROCESS-AUTO. Rigaku Corporation, Tokyo, Japan.  Google Scholar
First citationSheldrick, G. M. (2008). Acta Cryst. A64, 112–122.  Web of Science CrossRef CAS IUCr Journals Google Scholar
First citationSues, P. E., Lough, A. J. & Morris, R. H. (2014). J. Am. Chem. Soc. 136, 4746–4760.  Web of Science CSD CrossRef CAS PubMed Google Scholar
First citationWatson, W. H., Kandala, S. & Richmond, M. G. (2007). J. Organomet. Chem. 692, 1648–1652.  Web of Science CSD CrossRef CAS Google Scholar

This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.

Journal logoCRYSTALLOGRAPHIC
COMMUNICATIONS
ISSN: 2056-9890
Follow Acta Cryst. E
Sign up for e-alerts
Follow Acta Cryst. on Twitter
Follow us on facebook
Sign up for RSS feeds