Crystal structure of the BaII-based CoII-containing one-dimensional coordination polymer poly[[aqua{μ4-2,2′-[(4,10-dimethyl-1,4,7,10-tetra­aza­cyclo­dodecane-1,7-di­yl)bis(methylidene)]bis­(4-oxo-4H-pyran-3-olato)}­perchloratocobaltbarium] perchlorate]

Paoli, P.; Macedi, E.; Rossi, P.; Giorgi, L.; Formica, M.; Fusi, V.

doi:10.1107/S2056989017015638

Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

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Figure 6
Crystal packing of the title compound as viewed along the a axis. The non-coordinating ClO₄⁻ anions are depicted in ball and stick mode. Hydrogen bonds involving the non-coordinating ClO₄⁻ anion and two {Ba[Co(H_–2L1)](ClO₄)(H₂O)}⁺ cationic fragments on the same plane are depicted in light-blue dotted lines. Hydrogen bonds involving the non-coordinating ClO₄⁻ anion and a {Ba[Co(H_–2L1)](ClO₄)(H₂O)}⁺ cationic fragment out of plane (symmetry operation x − 1, y, z) are depicted in grey dotted lines. Only H atoms involved in the C—H⋯O interactions and only one component of the disordered perchlorate anion and water molecule are shown.

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 73| Part 12| December 2017| Pages 1806-1811

https://doi.org/10.1107/S2056989017015638

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