Figure 4
Molecular packing in (Ip): (a) a view of the unit-cell contents shown in projection down the c axis, (b) a view of the unit-cell contents shown in projection down the b axis and (c) a view of the supramolecular layer. Molecular packing in (Ic): (d) a view of the unit-cell contents shown in projection down the c axis, (e) a view of the unit-cell contents shown in projection down the b axis and (f) a view of the supramolecular layer. The thioamide-N—H⋯S(thione), C—H⋯π and π–π interactions are shown as orange, purple and blue dashed lines, respectively. |