Figure 9
Supramolecular aggregation in related carbothioamide structures: (a) linear supramolecular chain in the crystal of MeOC(=S)N(H)(4-C(=O)Me-phenyl) (VI) mediated by thioamide-N—H⋯O(carboxy) hydrogen bonding shown as orange dashed lines and (b) zigzag chain in the crystal of (4-pyridyl)CH2OC(=S)N(H)phenyl mediated by thioamide-N—H⋯N(pyridyl) hydrogen bonding shown as blue dashed lines. |