Investigation of solid-state photochemical nitro–nitrito linkage isomerization: crystal structures of trans-bis­(ethyl­enedi­amine)(iso­thio­cyanato)­nitritocobalt(III) salts: thio­cyanate, chloride monohydrate, and perchlorate–thio­cyanate­(0.75/0.25)

Ohba, S.; Tsuchimoto, M.; Kurachi, S.

doi:10.1107/S2056989018013634

Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

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Figure 6
The crystal structure of (III)

, projected along a. N—H⋯O/N and C—H⋯O hydrogen bonds are shown as blue dashed lines. Both possible orientations of the disordered thiocyanate (S7/C43/N32) and perchlorate (Cl4/O16–O19) ions are indicated.

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 74| Part 10| October 2018| Pages 1526-1531

https://doi.org/10.1107/S2056989018013634

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