Crystal structures of the [IrIII{C(C4H6O2)(dppm)-κ3P,C,O}(dppm)H](CF3O3S)2 and [IrIII{C(C4H6O2)(dppm)-κ2P,C}(CO)(dppm)H](CF3O3S)2 phosphorus ylide complexes, generated by a Wittig-type carbon–carbon coupling reaction of a carbodiphospho­rane PCP ligand system

Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

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Figure 3
The sequence of ligand replacements and reorganizations accompanying the transformation of 2 into 3 and then 4.

CRYSTALLOGRAPHIC
COMMUNICATIONS

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