Investigation of nitro–nitrito photoisomerization: crystal structures of trans-{2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}(pyridine/4-methyl­pyridine)­nitro­cobalt(III)

Ohba, S.; Tsuchimoto, M.; Yamada, N.

doi:10.1107/S2056989018015487

Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

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Figure 7
The steric circumstance of the nitro group in (II)

. Only parts of the complex are shown for clarity. The C—H⋯O hydrogen bonds are shown as blue dashed lines. Symmetry codes: (i) −x + 1, −y + 1, −z + 1; (ii) −x + 1, y − $[{1\over 2}]$ , −z + $[{3\over 2}]$ ; (iii) x + 1, −y + $[{1\over 2}]$ , z + $[{1\over 2}]$ ; (iv) −x + 1, y + $[{1\over 2}]$ , −z + $[{3\over 2}]$ ; (v) x − 1, −y + $[{1\over 2}]$ , z − $[{1\over 2}]$ ; (vi) −x, 1 − y, 1 − z.

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 74| Part 12| December 2018| Pages 1759-1763

https://doi.org/10.1107/S2056989018015487

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