Figure 5
The molecular packing in (II): (a) linear, supramolecular tube along [901] sustained by charge-assisted amine-N—H⋯O(carboxylate) and hydroxy-O—H⋯O(carboxylate) hydrogen-bonding interactions shown as blue and orange dashed lines, respectively; intramolecular amine-N—H⋯O(carboxylate) hydrogen bonds are represented by pink dashed lines, (b) end-on view of the supramolecular tube and (c) a view of the unit-cell contents in projection down the c axis. The methylene-, methyl-C—H⋯O(nitro) and π–π interactions are shown as green and purple dashed lines, respectively. In each of (a) and (b), non-participating H atoms are omitted. |