(IUCr) Syntheses and crystal structures of [Ir<span class="sup"><sup>III</sup></span>{C(CHCO<span class="inf"><sub>2</sub></span>Et)(dppm)<span class="inf"><sub>2</sub></span>-<span class="symbol">κ</span><span class="sup"><sup>4</sup></span><span class="it"><i>P</i></span>,<span class="it"><i>C</i></span>,<span class="it"><i>C</i></span>′,<span class="it"><i>P</i></span>′}ClH]Cl·2.75CH<span class="inf"><sub>2</sub></span>Cl<span class="inf"><sub>2</sub></span> and its derivatives, [Ir<span class="sup"><sup>III</sup></span>{C(CHCO<span class="inf"><sub>2</sub></span>Et)(dppm)<span class="inf"><sub>2</sub></span>-<span class="symbol">κ</span><span class="sup"><sup>4</sup></span><span class="it"><i>P</i></span>,<span class="it"><i>C</i></span>,<span class="it"><i>C</i></span>′,<span class="it"><i>P</i></span>′}(CH<span class="inf"><sub>2</sub></span>CO<span class="inf"><sub>2</sub></span>Et)Cl]Cl·CH<span class="inf"><sub>3</sub></span>OH·0.5H<span class="inf"><sub>2</sub></span>O, [Ir<span class="sup"><sup>III</sup></span>{C(CHCO<span class="inf"><sub>2</sub></span>Et)(dppm)<span class="inf"><sub>2</sub></span>-<span class="symbol">κ</span><span class="sup"><sup>4</sup></span><span class="it"><i>P</i></span>,<span class="it"><i>C</i></span>,<span class="it"><i>C</i></span>′,<span class="it"><i>P</i></span>′}Cl<span class="inf"><sub>2</sub></span>]Cl·CH<span class="inf"><sub>3</sub></span>OH·2H<span class="inf"><sub>2</sub></span>O and [Ir<span class="sup"><sup>III</sup></span>{C(CHCO<span class="inf"><sub>2</sub></span>Et)(dppm)<span class="inf"><sub>2</sub></span>-<span class="symbol">κ</span><span class="sup"><sup>4</sup></span><span class="it"><i>P</i></span>,<span class="it"><i>C</i></span>,<span class="it"><i>C</i></span>′,<span class="it"><i>P</i></span>′}(CH<span class="inf"><sub>2</sub></span>CO<span class="inf"><sub>2</sub></span>Et)(CO)]Cl<span class="inf"><sub>2</sub></span>·2CH<span class="inf"><sub>2</sub></span>Cl<span class="inf"><sub>2</sub></span>·1.5H<span class="inf"><sub>2</sub></span>O

Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

IUCr IT WDC

home archive editors for authors for readers submit open access

[Figure 4]

view article

Figure 4
Molecular structure of the complex cation in 6 and the counter-anion. Displacement ellipsoids are drawn at the 30% probability level. For clarity, only the ipso carbon atoms of the phenyl groups are presented and the solvent molecules are omitted.

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 75| Part 1| January 2019| Pages 12-20

https://doi.org/10.1107/S2056989018017024

Open

Open Access

access

Follow Acta Cryst. E

Sign up for e-alerts

Follow Acta Cryst. on Twitter

Follow us on facebook

Sign up for RSS feeds