research communications
Na+[Me3NB12Cl11]−·SO2: a rare example of a sodium–SO2 complex
aAnorganische Chemie, Fakultät für Mathematik und Naturwissenschaften, Bergische Universität Wuppertal, Gaussstr. 20, 42119 Wuppertal, Germany
*Correspondence e-mail: carsten.jenne@uni-wuppertal.de
In the title compound, Na+[Me3NB12Cl11]−·SO2 [systematic name: sodium 1-(trimethylammonio)undecachloro-closo-dodecaborate sulfur dioxide], the SO2 molecule is η1-O-coordinated to the Na+ cation. Surprisingly, the SO2 molecule is more weakly bound to sodium than is found in other sodium–SO2 complexes and the SO2 molecule is essentially undistorted compared to the structure of free SO2. The Na+ cation has a of eight in a distorted twofold-capped trigonal prism and makes contacts to three individual boron cluster anions, resulting in an overall three-dimensional network. Although the number of known η1-O-coordinated SO2 complexes is growing, sodium-SO2 complexes are still rare.
Keywords: boron cluster; crystal structure; sodium; sulfur dioxide; weakly coordinating anion.
CCDC reference: 1908217
1. Chemical context
Liquid sulfur dioxide is a polar but only very weakly coordinating solvent (Waddington, 1965), which is frequently used in organic and inorganic synthesis. The coordination chemistry in and of sulfur dioxide has been the topic of various reviews (Mingos, 1978; Ryan et al., 1981; Mews et al., 2000). Initially, only S- and η2-S,O-coordination of SO2 with soft transition-metal centers were investigated, but it was subsequently shown that η1-O-coordination of SO2 is preferred with hard main-group and transition-metal cations. Theoretical studies established that the oxygen–metal cation bonds are purely ionic (Decken et al., 2009; Derendorf et al., 2010). Mews and co-workers crystallized metal hexafluoro arsenates M[AsF6] (M = alkaline-earth and transition-metal cations) from liquid sulfur dioxide to obtain their SO2 complexes (Mews et al., 2000). Unfortunately, the alkali-metal hexafluoro arsenates, M[AsF6] (M = Li, Na, K), are almost insoluble in liquid sulfur dioxide and the corresponding SO2 complexes remained elusive. Until recently, only two examples of alkali-metal–SO2 complexes were known; namely, the η2-O,O bridged coordination complexes, [Li(OSO)6/2][AlCl4] (Simon et al., 1980) and [Na(OSO)1.5][AlCl4] (Peters et al., 1982), crystallized in the presence of the [AlCl4]− anion. Only after the introduction of modern weakly coordinating anions into sulfur dioxide coordination chemistry could alkali-metal sulfur dioxide complexes be studied intentionally. By using a large fluorinated aluminate anion, the of [(OSO)2Li{AlF(Al(OR)3}Li{Al(OR)4}] [R = C(CF3)3] (Cameron et al., 2010) was determined. In addition, use of halogenated closo-dodecaborates [B12X12]2− (X = F–I) led to a systematic study of alkali-metal sulfur dioxide complexes (Derendorf et al., 2010). Halogenated closo-dodecaborates belong to the growing class of modern weakly coordinating anions (Knapp, 2013). The [Me3NB12Cl11]− anion represents a recent modification of the halogenated closo-dodecaborates and possesses a reduced charge of −1 (Bolli et al., 2014). This anion has been utilized very recently to stabilize a variety of reactive cations in the solid state (e.g. Bertocco et al., 2016) and has been applied in silver-free gold catalysis (Wegener et al., 2015). From a failed attempt to prepare [Et3SiOS(H)OSiEt3][Me3NB12Cl11]−, we obtained single crystals of the title compound as a by-product. Na+[Me3NB12Cl11]−·SO2 is a rare example of a sodium–SO2 complex, and its is discussed herein.
2. Structural commentary
The title salt crystallizes with one SO2 molecule per formula unit (Fig. 1). The SO2 molecule is η1-O-bonded to the Na+ cation, as is expected for SO2 coordination to hard-metal centers. The Na+—O distance of 2.428 (4) Å is about 0.1 Å longer than the average Na+⋯O distance (of 2.34 Å) found in the Na2[B12X12]·nSO2 (X = H, Cl–I) complexes, which indicates weaker coordination. The S—O bonds are essentially of equal length [1.428 (3) and 1.412 (4) Å; Table 1] and very close to the values found in a free SO2 molecule in either the solid state [1.4299 (3) Å; Grabowsky et al., 2012] or in the gas phase [1.4343 (3) Å; Holder & Fink, 1981]. This behaviour is in contrast to that observed in other coordination compounds with η1-O-coordinated terminal SO2 ligands (e.g. Mews et al., 2000) where lengthening of the S—Oc bond and shortening of the S—Ot bond occurs, as predicted by theoretical concepts (Decken et al., 2009; Derendorf et al., 2010). Thus, the current finding is in accord with weaker coordination of the SO2 molecule to Na+ than is found in other SO2 complexes of hard metal cations. In addition to coordinating to the SO2 molecule, each sodium cation coordinates to seven of the eleven chlorine atoms of the boron cluster (Fig. 1).
In the packed structure, two sodium cations are coordinated in an η2-fashion to two chlorine atoms, while a third sodium cation is coordinated in an η3-manner to three chlorine atoms (Fig. 2). The Cl⋯Na+ distances range from 2.870 (2) to 3.209 (2) Å, and are, on average, longer than those in Na2[B12Cl12]·4SO2 (i.e. 3.052 vs 2.929 Å) (Derendorf et al., 2010), and are in accord with the sum of the van der Waals radius of chlorine (1.75 Å; Mantina et al., 2009) and the ionic radius of sodium (1.18 Å; Shannon, 1976) of 2.93 Å. However, when anisotropy of the van der Waals radius (Batsanov, 2001) is taken into account, the intermolecular distances are still in the expected range. The B—Cl bond lengths of the chlorine atoms coordinating to Na+ lie in the range 1.796 (5) to 1.803 (4) Å (av. 1.799 Å) and are only slightly longer than those of the non-coordinating chlorine atoms [1.779 (5) to 1.797 (4) Å, av. 1.786 Å]. It has previously been noted that the presence of strong Lewis acids, such as Me+ or R3Si+, leads to a significant elongation of the B—Cl bonds by up to 0.1 Å (Bolli et al., 2010, 2014; Kessler et al., 2010). Therefore, in the title compound, the Cl⋯Na+ interaction can be classified as weak and the singly charged [Me3NB12Cl11]− anion is more weakly coordinating towards Na+ than the doubly charged [B12Cl12]2− anion.
3. Supramolecular features
The Na+ cation is surrounded by seven chlorine atoms from three different boron clusters and one oxygen atom from a SO2 molecule, resulting in a total of 8 (Fig. 1) and giving rise to a three-dimensional network. The polyhedron around Na+ may be best described as a distorted twofold-capped trigonal prism (Fig. 3). The structure of the title compound is reminiscent of that of Ag[Me3NB12Cl11]·SO2 (Jenne & Wegener, 2018), although the coordination sphere around the metal cations is different in the two structures. The Na+⋯Cl contacts are weaker than the Ag+⋯Cl contacts and there is also only one SO2 molecule per cation present in the title compound. The [Me3NB12Cl11]− anions are placed in a body-centered cubic arrangement (Fig. 4) with some of the intermolecular Cl⋯Cl distances being shorter than the sum of the van Waals radii (3.50 Å; Mantina et al., 2009). The [Me3NB12Cl11]− anions pack quite efficiently in the solid state and unlike in Na2[B12Cl12]·4SO2, where the structure contains two molecules of SO2 per sodium cation to separate the doubly charged anions, only one SO2 molecule is required in this case.
4. Database survey
The [Me3NB12Cl11]− anion was first reported in 2014 (Bolli et al., 2014) and a variety of crystal structures containing this anion have been published (e.g. Saleh et al., 2016; Bertocco et al., 2016; Bolli et al., 2017; Jenne & Wegener, 2018), in which the [Me3NB12Cl11]− anion is essentially identical to that reported in this study. Sodium complexes of fluorinated closo-dodecaborates were studied recently by Strauss and co-workers (Bukovsky et al., 2017a,b). Sodium–SO2 complexes are still rare. Only the complex [Na(OSO)1.5][AlCl4] (Peters et al., 1982) and four complexes of the type Na2[B12X12]·nSO2 (X = H, Cl–I) (Derendorf et al., 2010) are known. The number of η1-O-bonded SO2 complexes is growing, although there is still some terra incognita in the Periodic Table. Structures published before the year 2000 are compiled in a review (Mews et al., 2000). Recent examples include alkali-metal (Cameron et al., 2010; Derendorf et al., 2010; Malischewski et al., 2016) and transition-metal complexes (Knapp & Mews, 2005; Akkuş et al., 2006; Decken et al., 2009; Aris et al., 2011; Malischewski et al., 2016, Jenne & Wegener, 2018).
5. Synthesis and crystallization
The crystals were obtained as a by-product from a reaction of [CPh3][Me3NB12Cl11] with Et3SiH and SO2 in 1,2-difluorobenzene designed to give [Et3SiOS(H)OSiEt3][Me3NB12Cl11]− in analogy to a published procedure (Kessler et al., 2010). Crystallization of the red–brown product from 1,2-difluorobenzene/n-pentane yielded the title compound as colorless crystals. The source of the sodium cation remains uncertain, but it may arise from an incomplete conversion of Na[Me3NB12Cl11] to [CPh3][Me3NB12Cl11] (Bolli et al., 2014).
6. Refinement
Crystal data, data collection and structure . H atoms were placed in calculated positions and refined as riding with C—H = 0.96 Å and Uiso(H) = 1.5Ueq(C).
details are summarized in Table 2
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Supporting information
CCDC reference: 1908217
https://doi.org/10.1107/S2056989019004663/cq2030sup1.cif
contains datablock I. DOI:Structure factors: contains datablock I. DOI: https://doi.org/10.1107/S2056989019004663/cq2030Isup2.hkl
Data collection: CrysAlis PRO (Rigaku OD, 2015); cell
CrysAlis PRO (Rigaku OD, 2015); data reduction: CrysAlis PRO (Rigaku OD, 2015); program(s) used to solve structure: ShelXT (Sheldrick, 2015a); program(s) used to refine structure: SHELXL (Sheldrick, 2015b); molecular graphics: DIAMOND (Brandenburg & Putz, 1999); software used to prepare material for publication: OLEX2 (Dolomanov et al., 2009).Na+·C3H9B12Cl11N−·SO2 | Dx = 1.916 Mg m−3 |
Mr = 665.83 | Mo Kα radiation, λ = 0.71073 Å |
Orthorhombic, P212121 | Cell parameters from 4780 reflections |
a = 9.1943 (3) Å | θ = 2.6–28.9° |
b = 12.9081 (4) Å | µ = 1.44 mm−1 |
c = 19.4486 (5) Å | T = 150 K |
V = 2308.19 (11) Å3 | Block, colourless |
Z = 4 | 0.06 × 0.05 × 0.05 mm |
F(000) = 1296 |
Rigaku Oxford Diffraction Xcalibur, Eos, Gemini ultra diffractometer | 4967 independent reflections |
Radiation source: fine-focus sealed X-ray tube, Enhance (Mo) X-ray Source | 4560 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.032 |
Detector resolution: 16.2705 pixels mm-1 | θmax = 27.0°, θmin = 1.9° |
ω scans | h = −11→8 |
Absorption correction: multi-scan (CrysAlisPro; Rigaku OD, 2015) | k = −16→12 |
Tmin = 0.984, Tmax = 1.000 | l = −24→24 |
10389 measured reflections |
Refinement on F2 | Hydrogen site location: inferred from neighbouring sites |
Least-squares matrix: full | H-atom parameters constrained |
R[F2 > 2σ(F2)] = 0.031 | w = 1/[σ2(Fo2) + (0.026P)2] where P = (Fo2 + 2Fc2)/3 |
wR(F2) = 0.064 | (Δ/σ)max < 0.001 |
S = 1.04 | Δρmax = 0.32 e Å−3 |
4967 reflections | Δρmin = −0.44 e Å−3 |
283 parameters | Absolute structure: Flack x determined using 1789 quotients [(I+)-(I-)]/[(I+)+(I-)] (Parsons et al., 2013). |
0 restraints | Absolute structure parameter: −0.09 (5) |
Primary atom site location: structure-invariant direct methods |
Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. |
x | y | z | Uiso*/Ueq | ||
Cl3 | 0.54490 (10) | 0.60120 (8) | 0.50279 (5) | 0.0174 (2) | |
Cl6 | 1.01248 (10) | 0.32550 (8) | 0.37747 (5) | 0.0167 (2) | |
Cl5 | 1.06356 (11) | 0.58650 (8) | 0.30581 (5) | 0.0194 (2) | |
Cl8 | 0.43371 (11) | 0.66888 (8) | 0.33691 (5) | 0.0183 (2) | |
Cl2 | 0.68060 (11) | 0.32798 (8) | 0.49788 (5) | 0.0183 (2) | |
Cl4 | 0.79016 (11) | 0.76099 (7) | 0.38771 (5) | 0.0181 (2) | |
Cl10 | 0.88045 (11) | 0.39211 (9) | 0.21212 (5) | 0.0189 (2) | |
Cl11 | 0.65146 (11) | 0.23842 (8) | 0.32551 (5) | 0.0171 (2) | |
Cl12 | 0.49042 (11) | 0.44663 (8) | 0.22120 (5) | 0.0186 (2) | |
Cl9 | 0.74597 (11) | 0.66169 (8) | 0.21672 (5) | 0.0197 (2) | |
Cl7 | 0.37526 (11) | 0.40537 (8) | 0.39531 (5) | 0.0172 (2) | |
S1 | 0.11196 (13) | 0.57107 (9) | 0.11604 (6) | 0.0263 (3) | |
Na1 | 0.19934 (19) | 0.38485 (15) | 0.25524 (9) | 0.0273 (4) | |
O1 | 0.1870 (3) | 0.4912 (2) | 0.15243 (16) | 0.0274 (8) | |
N1 | 0.9459 (4) | 0.5473 (3) | 0.49125 (17) | 0.0160 (7) | |
B1 | 0.8383 (5) | 0.5239 (4) | 0.4285 (2) | 0.0108 (9) | |
B6 | 0.8625 (5) | 0.4148 (4) | 0.3718 (2) | 0.0112 (9) | |
B10 | 0.7980 (5) | 0.4478 (4) | 0.2875 (2) | 0.0127 (9) | |
B7 | 0.5540 (5) | 0.4545 (3) | 0.3782 (2) | 0.0122 (9) | |
B2 | 0.7093 (5) | 0.4170 (4) | 0.4290 (2) | 0.0118 (9) | |
C1 | 0.8866 (5) | 0.6276 (4) | 0.5402 (2) | 0.0263 (11) | |
H1A | 0.860583 | 0.688810 | 0.515050 | 0.039* | |
H1B | 0.959336 | 0.644482 | 0.573805 | 0.039* | |
H1C | 0.802058 | 0.600510 | 0.562979 | 0.039* | |
B5 | 0.8909 (5) | 0.5418 (4) | 0.3378 (2) | 0.0123 (9) | |
B4 | 0.7569 (5) | 0.6247 (3) | 0.3761 (2) | 0.0128 (9) | |
B9 | 0.7332 (5) | 0.5772 (3) | 0.2902 (2) | 0.0122 (9) | |
B11 | 0.6889 (5) | 0.3712 (4) | 0.3426 (2) | 0.0130 (10) | |
B3 | 0.6441 (4) | 0.5479 (4) | 0.4315 (2) | 0.0106 (9) | |
C2 | 1.0899 (5) | 0.5885 (4) | 0.4670 (2) | 0.0314 (12) | |
H2A | 1.134523 | 0.539081 | 0.436710 | 0.047* | |
H2B | 1.152153 | 0.600198 | 0.505865 | 0.047* | |
H2C | 1.075159 | 0.652549 | 0.442895 | 0.047* | |
B8 | 0.5822 (5) | 0.5814 (4) | 0.3473 (2) | 0.0117 (9) | |
C3 | 0.9774 (6) | 0.4535 (4) | 0.5346 (3) | 0.0359 (13) | |
H3A | 0.889899 | 0.431478 | 0.557199 | 0.054* | |
H3B | 1.049605 | 0.470500 | 0.568433 | 0.054* | |
H3C | 1.012930 | 0.398568 | 0.505844 | 0.054* | |
B12 | 0.6101 (5) | 0.4728 (3) | 0.2921 (2) | 0.0120 (9) | |
O2 | 0.1730 (4) | 0.6032 (3) | 0.05292 (16) | 0.0382 (9) |
U11 | U22 | U33 | U12 | U13 | U23 | |
Cl3 | 0.0191 (5) | 0.0190 (5) | 0.0140 (5) | 0.0024 (4) | 0.0047 (4) | −0.0039 (4) |
Cl6 | 0.0121 (5) | 0.0151 (5) | 0.0231 (5) | 0.0039 (4) | −0.0010 (4) | −0.0001 (4) |
Cl5 | 0.0131 (5) | 0.0220 (6) | 0.0231 (5) | −0.0063 (4) | 0.0040 (4) | −0.0007 (4) |
Cl8 | 0.0164 (5) | 0.0185 (5) | 0.0200 (5) | 0.0073 (4) | −0.0030 (4) | 0.0016 (4) |
Cl2 | 0.0239 (5) | 0.0172 (5) | 0.0138 (5) | −0.0002 (4) | 0.0010 (4) | 0.0054 (4) |
Cl4 | 0.0229 (6) | 0.0098 (5) | 0.0217 (5) | −0.0018 (4) | 0.0002 (4) | −0.0018 (4) |
Cl10 | 0.0191 (5) | 0.0234 (6) | 0.0141 (5) | −0.0009 (4) | 0.0052 (4) | −0.0054 (4) |
Cl11 | 0.0212 (5) | 0.0117 (5) | 0.0183 (5) | −0.0027 (4) | −0.0042 (4) | −0.0031 (4) |
Cl12 | 0.0170 (5) | 0.0256 (6) | 0.0131 (5) | −0.0022 (4) | −0.0049 (4) | −0.0010 (4) |
Cl9 | 0.0252 (5) | 0.0191 (6) | 0.0149 (5) | −0.0024 (4) | 0.0008 (4) | 0.0070 (4) |
Cl7 | 0.0099 (5) | 0.0225 (5) | 0.0193 (5) | −0.0037 (4) | 0.0022 (4) | 0.0002 (5) |
S1 | 0.0254 (6) | 0.0214 (6) | 0.0322 (7) | 0.0024 (5) | −0.0012 (5) | 0.0017 (5) |
Na1 | 0.0230 (9) | 0.0285 (11) | 0.0303 (10) | 0.0011 (8) | 0.0057 (8) | 0.0049 (8) |
O1 | 0.0253 (17) | 0.0265 (19) | 0.0303 (19) | −0.0009 (15) | −0.0034 (15) | 0.0026 (15) |
N1 | 0.0158 (17) | 0.0180 (19) | 0.0140 (18) | 0.0008 (15) | −0.0060 (15) | −0.0035 (15) |
B1 | 0.011 (2) | 0.009 (2) | 0.012 (2) | 0.0009 (17) | −0.0018 (19) | −0.0025 (18) |
B6 | 0.010 (2) | 0.013 (2) | 0.010 (2) | 0.0026 (18) | 0.0006 (18) | −0.0012 (18) |
B10 | 0.009 (2) | 0.016 (2) | 0.013 (2) | −0.0010 (18) | −0.0003 (18) | −0.0010 (19) |
B7 | 0.008 (2) | 0.015 (2) | 0.014 (2) | −0.0011 (18) | −0.0003 (19) | 0.0004 (18) |
B2 | 0.013 (2) | 0.013 (2) | 0.009 (2) | −0.0019 (18) | −0.0010 (18) | 0.0008 (18) |
C1 | 0.027 (2) | 0.032 (3) | 0.020 (2) | 0.005 (2) | −0.008 (2) | −0.012 (2) |
B5 | 0.011 (2) | 0.014 (2) | 0.012 (2) | −0.0023 (18) | 0.0009 (19) | −0.0007 (18) |
B4 | 0.015 (2) | 0.009 (2) | 0.015 (2) | −0.0027 (18) | 0.0004 (19) | 0.0014 (17) |
B9 | 0.013 (2) | 0.014 (2) | 0.009 (2) | −0.0013 (19) | 0.0012 (18) | 0.0028 (18) |
B11 | 0.013 (2) | 0.015 (2) | 0.011 (2) | −0.0015 (18) | −0.0022 (18) | −0.0028 (18) |
B3 | 0.009 (2) | 0.012 (2) | 0.011 (2) | 0.0011 (18) | 0.0007 (18) | 0.0003 (18) |
C2 | 0.017 (2) | 0.049 (4) | 0.029 (3) | −0.007 (2) | −0.005 (2) | −0.012 (2) |
B8 | 0.011 (2) | 0.011 (2) | 0.013 (2) | −0.0001 (18) | −0.0029 (18) | 0.0032 (18) |
C3 | 0.054 (4) | 0.026 (3) | 0.028 (3) | 0.001 (2) | −0.028 (2) | 0.004 (2) |
B12 | 0.013 (2) | 0.014 (2) | 0.009 (2) | −0.0008 (18) | −0.0004 (19) | 0.0007 (18) |
O2 | 0.049 (2) | 0.041 (2) | 0.0248 (19) | −0.0089 (19) | −0.0077 (16) | 0.0012 (17) |
Cl4—Na1i | 3.209 (2) | B6—B5 | 1.787 (6) |
Cl5—Na1ii | 3.050 (2) | B6—B11 | 1.785 (6) |
Cl6—Na1ii | 3.031 (2) | B10—B5 | 1.777 (6) |
Cl7—Na1 | 3.179 (2) | B10—B9 | 1.774 (6) |
Cl9—Na1i | 2.975 (2) | B10—B11 | 1.770 (6) |
Cl10—Na1ii | 3.051 (2) | B10—B12 | 1.760 (6) |
Cl12—Na1 | 2.870 (2) | B7—B2 | 1.802 (6) |
S1—O1 | 1.428 (3) | B7—B11 | 1.782 (6) |
S1—O2 | 1.412 (4) | B7—B3 | 1.792 (6) |
Na1—O1 | 2.428 (4) | B7—B8 | 1.764 (6) |
Cl2—B2 | 1.785 (5) | B7—B12 | 1.769 (6) |
Cl3—B3 | 1.797 (4) | B2—B11 | 1.791 (6) |
Cl4—B4 | 1.800 (5) | B2—B3 | 1.794 (7) |
Cl5—B5 | 1.800 (5) | C1—H1A | 0.9600 |
Cl6—B6 | 1.801 (4) | C1—H1B | 0.9600 |
Cl7—B7 | 1.792 (5) | C1—H1C | 0.9600 |
Cl8—B8 | 1.783 (4) | B5—B4 | 1.794 (6) |
Cl9—B9 | 1.803 (4) | B5—B9 | 1.779 (6) |
Cl10—B10 | 1.800 (5) | B4—B9 | 1.792 (6) |
Cl11—B11 | 1.779 (5) | B4—B3 | 1.794 (6) |
Cl12—B12 | 1.796 (5) | B4—B8 | 1.791 (6) |
N1—B1 | 1.600 (5) | B9—B8 | 1.779 (6) |
N1—C1 | 1.510 (5) | B9—B12 | 1.760 (6) |
N1—C2 | 1.503 (5) | B11—B12 | 1.792 (7) |
N1—C3 | 1.503 (6) | B3—B8 | 1.785 (6) |
B1—B6 | 1.803 (6) | C2—H2A | 0.9600 |
B1—B2 | 1.820 (6) | C2—H2B | 0.9600 |
B1—B5 | 1.844 (7) | C2—H2C | 0.9600 |
B1—B4 | 1.813 (6) | B8—B12 | 1.785 (6) |
B1—B3 | 1.813 (6) | C3—H3A | 0.9600 |
B6—B10 | 1.794 (6) | C3—H3B | 0.9600 |
B6—B2 | 1.795 (6) | C3—H3C | 0.9600 |
B6—Cl6—Na1ii | 102.94 (15) | H1A—C1—H1B | 109.5 |
B5—Cl5—Na1ii | 101.48 (16) | H1A—C1—H1C | 109.5 |
B4—Cl4—Na1i | 112.56 (16) | H1B—C1—H1C | 109.5 |
B10—Cl10—Na1ii | 101.13 (15) | Cl5—B5—B1 | 127.0 (3) |
B12—Cl12—Na1 | 116.54 (15) | B6—B5—Cl5 | 123.4 (3) |
B9—Cl9—Na1i | 116.86 (15) | B6—B5—B1 | 59.5 (2) |
B7—Cl7—Na1 | 109.68 (16) | B6—B5—B4 | 107.0 (3) |
O1—S1—O2 | 116.8 (2) | B10—B5—Cl5 | 116.9 (3) |
Cl6iii—Na1—Cl5iii | 74.39 (5) | B10—B5—B1 | 108.3 (3) |
Cl6iii—Na1—Cl4iv | 124.79 (7) | B10—B5—B6 | 60.4 (2) |
Cl6iii—Na1—Cl10iii | 71.26 (5) | B10—B5—B4 | 107.8 (3) |
Cl6iii—Na1—Cl7 | 68.74 (4) | B10—B5—B9 | 59.8 (2) |
Cl5iii—Na1—Cl4iv | 135.81 (7) | B4—B5—Cl5 | 123.9 (3) |
Cl5iii—Na1—Cl10iii | 70.67 (5) | B4—B5—B1 | 59.8 (2) |
Cl5iii—Na1—Cl7 | 82.00 (5) | B9—B5—Cl5 | 117.2 (3) |
Cl10iii—Na1—Cl4iv | 78.81 (5) | B9—B5—B1 | 108.4 (3) |
Cl10iii—Na1—Cl7 | 136.21 (6) | B9—B5—B6 | 108.0 (3) |
Cl12—Na1—Cl6iii | 141.23 (7) | B9—B5—B4 | 60.2 (3) |
Cl12—Na1—Cl5iii | 102.65 (6) | Cl4—B4—B1 | 124.1 (3) |
Cl12—Na1—Cl4iv | 84.87 (5) | B5—B4—Cl4 | 121.2 (3) |
Cl12—Na1—Cl10iii | 145.50 (7) | B5—B4—B1 | 61.5 (3) |
Cl12—Na1—Cl9iv | 98.84 (6) | B5—B4—B3 | 108.5 (3) |
Cl12—Na1—Cl7 | 72.55 (5) | B9—B4—Cl4 | 118.1 (3) |
Cl9iv—Na1—Cl6iii | 72.98 (5) | B9—B4—B1 | 109.1 (3) |
Cl9iv—Na1—Cl5iii | 146.78 (7) | B9—B4—B5 | 59.5 (3) |
Cl9iv—Na1—Cl4iv | 70.81 (5) | B9—B4—B3 | 107.4 (3) |
Cl9iv—Na1—Cl10iii | 104.04 (6) | B3—B4—Cl4 | 124.3 (3) |
Cl9iv—Na1—Cl7 | 80.65 (5) | B3—B4—B1 | 60.3 (2) |
Cl7—Na1—Cl4iv | 140.24 (6) | B8—B4—Cl4 | 119.8 (3) |
O1—Na1—Cl6iii | 139.66 (10) | B8—B4—B1 | 108.8 (3) |
O1—Na1—Cl5iii | 76.35 (9) | B8—B4—B5 | 107.5 (3) |
O1—Na1—Cl4iv | 64.50 (9) | B8—B4—B9 | 59.5 (2) |
O1—Na1—Cl10iii | 73.23 (9) | B8—B4—B3 | 59.8 (2) |
O1—Na1—Cl12 | 72.33 (9) | B10—B9—Cl9 | 121.6 (3) |
O1—Na1—Cl9iv | 134.94 (10) | B10—B9—B5 | 60.0 (3) |
O1—Na1—Cl7 | 133.02 (10) | B10—B9—B4 | 108.0 (3) |
S1—O1—Na1 | 147.0 (2) | B10—B9—B8 | 108.1 (3) |
C1—N1—B1 | 112.8 (3) | B5—B9—Cl9 | 121.0 (3) |
C2—N1—B1 | 111.8 (3) | B5—B9—B4 | 60.3 (3) |
C2—N1—C1 | 105.9 (3) | B5—B9—B8 | 108.6 (3) |
C2—N1—C3 | 106.9 (4) | B4—B9—Cl9 | 121.6 (3) |
C3—N1—B1 | 113.3 (3) | B8—B9—Cl9 | 121.8 (3) |
C3—N1—C1 | 105.6 (4) | B8—B9—B4 | 60.2 (2) |
N1—B1—B6 | 122.5 (3) | B12—B9—Cl9 | 121.4 (3) |
N1—B1—B2 | 122.8 (3) | B12—B9—B10 | 59.7 (2) |
N1—B1—B5 | 123.0 (3) | B12—B9—B5 | 108.5 (3) |
N1—B1—B4 | 123.3 (3) | B12—B9—B4 | 108.7 (3) |
N1—B1—B3 | 123.5 (3) | B12—B9—B8 | 60.6 (2) |
B6—B1—B2 | 59.4 (2) | Cl11—B11—B6 | 122.4 (3) |
B6—B1—B5 | 58.7 (2) | Cl11—B11—B7 | 121.3 (3) |
B6—B1—B4 | 105.5 (3) | Cl11—B11—B2 | 120.9 (3) |
B6—B1—B3 | 105.9 (3) | Cl11—B11—B12 | 121.7 (3) |
B2—B1—B5 | 105.7 (3) | B6—B11—B2 | 60.3 (2) |
B4—B1—B2 | 106.2 (3) | B6—B11—B12 | 107.7 (3) |
B4—B1—B5 | 58.7 (2) | B10—B11—Cl11 | 122.4 (3) |
B3—B1—B2 | 59.2 (2) | B10—B11—B6 | 60.6 (2) |
B3—B1—B5 | 105.5 (3) | B10—B11—B7 | 107.0 (3) |
B3—B1—B4 | 59.3 (2) | B10—B11—B2 | 108.9 (3) |
Cl6—B6—B1 | 123.8 (3) | B10—B11—B12 | 59.2 (2) |
B10—B6—Cl6 | 117.5 (3) | B7—B11—B6 | 108.0 (3) |
B10—B6—B1 | 109.4 (3) | B7—B11—B2 | 60.6 (3) |
B10—B6—B2 | 107.7 (3) | B7—B11—B12 | 59.3 (3) |
B2—B6—Cl6 | 124.9 (3) | B2—B11—B12 | 108.4 (3) |
B2—B6—B1 | 60.8 (2) | Cl3—B3—B1 | 126.1 (3) |
B5—B6—Cl6 | 119.9 (3) | B7—B3—Cl3 | 118.0 (3) |
B5—B6—B1 | 61.8 (3) | B7—B3—B1 | 108.8 (3) |
B5—B6—B10 | 59.5 (3) | B7—B3—B2 | 60.3 (2) |
B5—B6—B2 | 109.2 (3) | B7—B3—B4 | 107.0 (3) |
B11—B6—Cl6 | 120.2 (3) | B2—B3—Cl3 | 123.5 (3) |
B11—B6—B1 | 109.3 (3) | B2—B3—B1 | 60.6 (2) |
B11—B6—B10 | 59.3 (2) | B2—B3—B4 | 108.1 (3) |
B11—B6—B2 | 60.1 (2) | B4—B3—Cl3 | 123.0 (3) |
B11—B6—B5 | 107.6 (3) | B4—B3—B1 | 60.4 (2) |
B6—B10—Cl10 | 120.7 (3) | B8—B3—Cl3 | 116.9 (3) |
B5—B10—Cl10 | 121.2 (3) | B8—B3—B1 | 109.0 (3) |
B5—B10—B6 | 60.1 (3) | B8—B3—B7 | 59.1 (3) |
B9—B10—Cl10 | 122.8 (3) | B8—B3—B2 | 108.1 (3) |
B9—B10—B6 | 107.9 (3) | B8—B3—B4 | 60.0 (2) |
B9—B10—B5 | 60.1 (3) | N1—C2—H2A | 109.5 |
B11—B10—Cl10 | 120.6 (3) | N1—C2—H2B | 109.5 |
B11—B10—B6 | 60.1 (3) | N1—C2—H2C | 109.5 |
B11—B10—B5 | 108.7 (3) | H2A—C2—H2B | 109.5 |
B11—B10—B9 | 108.5 (3) | H2A—C2—H2C | 109.5 |
B12—B10—Cl10 | 121.9 (3) | H2B—C2—H2C | 109.5 |
B12—B10—B6 | 108.8 (3) | Cl8—B8—B4 | 121.7 (3) |
B12—B10—B5 | 108.6 (3) | Cl8—B8—B3 | 120.1 (3) |
B12—B10—B9 | 59.7 (3) | Cl8—B8—B12 | 122.6 (3) |
B12—B10—B11 | 61.0 (3) | B7—B8—Cl8 | 121.0 (3) |
Cl7—B7—B2 | 122.0 (3) | B7—B8—B4 | 108.4 (3) |
B11—B7—Cl7 | 119.8 (3) | B7—B8—B9 | 107.4 (3) |
B11—B7—B2 | 60.0 (3) | B7—B8—B3 | 60.6 (2) |
B11—B7—B3 | 108.0 (3) | B7—B8—B12 | 59.8 (3) |
B3—B7—Cl7 | 123.7 (3) | B9—B8—Cl8 | 123.1 (3) |
B3—B7—B2 | 59.9 (2) | B9—B8—B4 | 60.3 (2) |
B8—B7—Cl7 | 121.7 (3) | B9—B8—B3 | 108.4 (3) |
B8—B7—B2 | 108.6 (3) | B9—B8—B12 | 59.2 (2) |
B8—B7—B11 | 109.0 (3) | B3—B8—B4 | 60.2 (2) |
B8—B7—B3 | 60.3 (2) | B12—B8—B4 | 107.7 (3) |
B8—B7—B12 | 60.7 (3) | B12—B8—B3 | 108.4 (3) |
B12—B7—Cl7 | 119.4 (3) | N1—C3—H3A | 109.5 |
B12—B7—B2 | 108.9 (3) | N1—C3—H3B | 109.5 |
B12—B7—B11 | 60.6 (3) | N1—C3—H3C | 109.5 |
B12—B7—B3 | 108.8 (3) | H3A—C3—H3B | 109.5 |
Cl2—B2—B1 | 126.1 (3) | H3A—C3—H3C | 109.5 |
Cl2—B2—B6 | 124.9 (3) | H3B—C3—H3C | 109.5 |
Cl2—B2—B7 | 117.8 (3) | B10—B12—Cl12 | 121.9 (3) |
Cl2—B2—B11 | 118.5 (3) | B10—B12—B7 | 108.0 (3) |
Cl2—B2—B3 | 122.5 (3) | B10—B12—B9 | 60.5 (3) |
B6—B2—B1 | 59.8 (2) | B10—B12—B11 | 59.8 (3) |
B6—B2—B7 | 106.6 (3) | B10—B12—B8 | 108.4 (3) |
B7—B2—B1 | 108.0 (3) | B7—B12—Cl12 | 121.5 (3) |
B11—B2—B1 | 108.3 (3) | B7—B12—B11 | 60.1 (3) |
B11—B2—B6 | 59.7 (2) | B7—B12—B8 | 59.5 (3) |
B11—B2—B7 | 59.5 (3) | B9—B12—Cl12 | 121.5 (3) |
B11—B2—B3 | 107.5 (3) | B9—B12—B7 | 108.0 (3) |
B3—B2—B1 | 60.2 (2) | B9—B12—B11 | 108.2 (3) |
B3—B2—B6 | 107.1 (3) | B9—B12—B8 | 60.2 (3) |
B3—B2—B7 | 59.8 (2) | B11—B12—Cl12 | 122.0 (3) |
N1—C1—H1A | 109.5 | B8—B12—Cl12 | 121.4 (3) |
N1—C1—H1B | 109.5 | B8—B12—B11 | 107.6 (3) |
N1—C1—H1C | 109.5 | ||
Cl3—B3—B8—Cl8 | 2.8 (5) | B2—B1—B3—B4 | −137.0 (3) |
Cl3—B3—B8—B7 | −108.0 (3) | B2—B1—B3—B8 | −100.5 (3) |
Cl3—B3—B8—B4 | 114.4 (3) | B2—B6—B10—Cl10 | −146.9 (3) |
Cl3—B3—B8—B9 | 152.0 (3) | B2—B6—B10—B5 | 102.3 (3) |
Cl3—B3—B8—B12 | −145.3 (3) | B2—B6—B10—B9 | 64.5 (4) |
Cl6—B6—B10—Cl10 | 0.6 (5) | B2—B6—B10—B11 | −37.0 (3) |
Cl6—B6—B10—B5 | −110.2 (3) | B2—B6—B10—B12 | 1.2 (4) |
Cl6—B6—B10—B9 | −148.0 (3) | B2—B6—B5—Cl5 | 155.9 (3) |
Cl6—B6—B10—B11 | 110.5 (3) | B2—B6—B5—B1 | 39.3 (3) |
Cl6—B6—B10—B12 | 148.7 (3) | B2—B6—B5—B10 | −99.6 (3) |
Cl6—B6—B2—Cl2 | −2.3 (5) | B2—B6—B5—B4 | 1.5 (4) |
Cl6—B6—B2—B1 | 112.8 (4) | B2—B6—B5—B9 | −61.9 (4) |
Cl6—B6—B2—B7 | −145.7 (3) | B2—B6—B11—Cl11 | −109.7 (4) |
Cl6—B6—B2—B11 | −107.8 (4) | B2—B6—B11—B10 | 138.6 (3) |
Cl6—B6—B2—B3 | 151.6 (3) | B2—B6—B11—B7 | 38.8 (3) |
Cl6—B6—B5—Cl5 | 1.8 (5) | B2—B6—B11—B12 | 101.4 (3) |
Cl6—B6—B5—B1 | −114.9 (3) | B2—B7—B11—Cl11 | 110.3 (4) |
Cl6—B6—B5—B10 | 106.2 (3) | B2—B7—B11—B6 | −38.6 (3) |
Cl6—B6—B5—B4 | −152.6 (3) | B2—B7—B11—B10 | −102.5 (3) |
Cl6—B6—B5—B9 | 143.9 (3) | B2—B7—B11—B12 | −139.0 (3) |
Cl6—B6—B11—Cl11 | 5.7 (5) | B2—B7—B3—Cl3 | −114.6 (3) |
Cl6—B6—B11—B10 | −106.0 (3) | B2—B7—B3—B1 | 37.8 (3) |
Cl6—B6—B11—B7 | 154.2 (3) | B2—B7—B3—B4 | 101.6 (3) |
Cl6—B6—B11—B2 | 115.4 (3) | B2—B7—B3—B8 | 139.2 (3) |
Cl6—B6—B11—B12 | −143.1 (3) | B2—B7—B8—Cl8 | −146.1 (3) |
Cl5—B5—B4—Cl4 | −2.0 (5) | B2—B7—B8—B4 | 1.5 (4) |
Cl5—B5—B4—B1 | −116.6 (4) | B2—B7—B8—B9 | 65.1 (4) |
Cl5—B5—B4—B9 | 104.5 (4) | B2—B7—B8—B3 | −36.6 (3) |
Cl5—B5—B4—B3 | −155.8 (3) | B2—B7—B8—B12 | 101.7 (3) |
Cl5—B5—B4—B8 | 141.1 (3) | B2—B7—B12—Cl12 | 148.3 (3) |
Cl5—B5—B9—Cl9 | −4.2 (5) | B2—B7—B12—B10 | −0.1 (4) |
Cl5—B5—B9—B10 | 106.8 (3) | B2—B7—B12—B9 | −64.1 (4) |
Cl5—B5—B9—B4 | −115.4 (3) | B2—B7—B12—B11 | 36.9 (3) |
Cl5—B5—B9—B8 | −152.6 (3) | B2—B7—B12—B8 | −101.3 (3) |
Cl5—B5—B9—B12 | 143.1 (3) | B2—B11—B12—Cl12 | −147.6 (3) |
Cl8—B8—B12—Cl12 | 1.0 (5) | B2—B11—B12—B10 | 101.5 (3) |
Cl8—B8—B12—B10 | 149.9 (3) | B2—B11—B12—B7 | −37.0 (3) |
Cl8—B8—B12—B7 | −109.5 (4) | B2—B11—B12—B9 | 63.7 (4) |
Cl8—B8—B12—B9 | 111.9 (4) | B2—B11—B12—B8 | 0.1 (4) |
Cl8—B8—B12—B11 | −146.9 (3) | B2—B3—B8—Cl8 | 147.5 (3) |
Cl2—B2—B11—Cl11 | −3.7 (5) | B2—B3—B8—B7 | 36.7 (3) |
Cl2—B2—B11—B6 | −115.9 (3) | B2—B3—B8—B4 | −100.9 (3) |
Cl2—B2—B11—B10 | −153.4 (3) | B2—B3—B8—B9 | −63.3 (4) |
Cl2—B2—B11—B7 | 107.3 (3) | B2—B3—B8—B12 | −0.6 (4) |
Cl2—B2—B11—B12 | 143.8 (3) | C1—N1—B1—B6 | −167.5 (4) |
Cl2—B2—B3—Cl3 | 0.1 (5) | C1—N1—B1—B2 | −95.3 (4) |
Cl2—B2—B3—B1 | 116.1 (4) | C1—N1—B1—B5 | 121.3 (4) |
Cl2—B2—B3—B7 | −105.7 (4) | C1—N1—B1—B4 | 49.6 (5) |
Cl2—B2—B3—B4 | 154.7 (3) | C1—N1—B1—B3 | −23.1 (5) |
Cl2—B2—B3—B8 | −141.8 (3) | B5—B1—B6—Cl6 | 108.7 (4) |
Cl4—B4—B9—Cl9 | 1.4 (5) | B5—B1—B6—B10 | −36.9 (3) |
Cl4—B4—B9—B10 | 149.3 (3) | B5—B1—B6—B2 | −136.8 (3) |
Cl4—B4—B9—B5 | 111.5 (3) | B5—B1—B6—B11 | −100.1 (3) |
Cl4—B4—B9—B8 | −109.8 (3) | B5—B1—B2—Cl2 | 150.7 (3) |
Cl4—B4—B9—B12 | −147.4 (3) | B5—B1—B2—B6 | 37.4 (3) |
Cl4—B4—B3—Cl3 | 2.9 (5) | B5—B1—B2—B7 | −61.7 (4) |
Cl4—B4—B3—B1 | −113.1 (4) | B5—B1—B2—B11 | 1.2 (4) |
Cl4—B4—B3—B7 | 144.6 (3) | B5—B1—B2—B3 | −99.0 (3) |
Cl4—B4—B3—B2 | −151.8 (3) | B5—B1—B4—Cl4 | −110.1 (4) |
Cl4—B4—B3—B8 | 107.3 (4) | B5—B1—B4—B9 | 36.8 (3) |
Cl4—B4—B8—Cl8 | −5.6 (5) | B5—B1—B4—B3 | 136.5 (3) |
Cl4—B4—B8—B7 | −153.0 (3) | B5—B1—B4—B8 | 100.2 (3) |
Cl4—B4—B8—B9 | 107.1 (3) | B5—B1—B3—Cl3 | −148.8 (3) |
Cl4—B4—B8—B3 | −114.7 (4) | B5—B1—B3—B7 | 61.6 (4) |
Cl4—B4—B8—B12 | 143.8 (3) | B5—B1—B3—B2 | 99.3 (3) |
Cl10—B10—B5—Cl5 | 5.2 (5) | B5—B1—B3—B4 | −37.7 (3) |
Cl10—B10—B5—B1 | −146.4 (3) | B5—B1—B3—B8 | −1.2 (4) |
Cl10—B10—B5—B6 | −109.8 (4) | B5—B6—B10—Cl10 | 110.7 (3) |
Cl10—B10—B5—B4 | 150.3 (3) | B5—B6—B10—B9 | −37.8 (3) |
Cl10—B10—B5—B9 | 112.5 (4) | B5—B6—B10—B11 | −139.3 (3) |
Cl10—B10—B9—Cl9 | 0.1 (5) | B5—B6—B10—B12 | −101.1 (3) |
Cl10—B10—B9—B5 | −109.9 (4) | B5—B6—B2—Cl2 | −154.9 (3) |
Cl10—B10—B9—B4 | −147.8 (3) | B5—B6—B2—B1 | −39.7 (3) |
Cl10—B10—B9—B8 | 148.5 (3) | B5—B6—B2—B7 | 61.8 (4) |
Cl10—B10—B9—B12 | 110.5 (4) | B5—B6—B2—B11 | 99.7 (3) |
Cl10—B10—B11—Cl11 | −1.7 (5) | B5—B6—B2—B3 | −1.0 (4) |
Cl10—B10—B11—B6 | 110.1 (3) | B5—B6—B11—Cl11 | 147.8 (3) |
Cl10—B10—B11—B7 | −148.5 (3) | B5—B6—B11—B10 | 36.1 (3) |
Cl10—B10—B11—B2 | 147.5 (3) | B5—B6—B11—B7 | −63.7 (4) |
Cl10—B10—B11—B12 | −111.9 (4) | B5—B6—B11—B2 | −102.5 (3) |
Cl10—B10—B12—Cl12 | −1.3 (5) | B5—B6—B11—B12 | −1.1 (4) |
Cl10—B10—B12—B7 | 147.0 (3) | B5—B10—B9—Cl9 | 110.0 (4) |
Cl10—B10—B12—B9 | −112.1 (4) | B5—B10—B9—B4 | −37.9 (3) |
Cl10—B10—B12—B11 | 109.9 (4) | B5—B10—B9—B8 | −101.6 (3) |
Cl10—B10—B12—B8 | −150.0 (3) | B5—B10—B9—B12 | −139.5 (3) |
Cl11—B11—B12—Cl12 | −0.5 (5) | B5—B10—B11—Cl11 | −148.4 (3) |
Cl11—B11—B12—B10 | −111.4 (4) | B5—B10—B11—B6 | −36.6 (3) |
Cl11—B11—B12—B7 | 110.1 (4) | B5—B10—B11—B7 | 64.8 (4) |
Cl11—B11—B12—B9 | −149.2 (3) | B5—B10—B11—B2 | 0.8 (4) |
Cl11—B11—B12—B8 | 147.2 (3) | B5—B10—B11—B12 | 101.3 (3) |
Cl9—B9—B8—Cl8 | −0.4 (5) | B5—B10—B12—Cl12 | 147.3 (3) |
Cl9—B9—B8—B7 | 147.6 (3) | B5—B10—B12—B7 | −64.5 (4) |
Cl9—B9—B8—B4 | −110.8 (4) | B5—B10—B12—B9 | 36.4 (3) |
Cl9—B9—B8—B3 | −148.4 (3) | B5—B10—B12—B11 | −101.6 (3) |
Cl9—B9—B8—B12 | 110.7 (4) | B5—B10—B12—B8 | −1.5 (4) |
Cl9—B9—B12—Cl12 | −0.7 (5) | B5—B4—B9—Cl9 | −110.2 (4) |
Cl9—B9—B12—B10 | 110.8 (4) | B5—B4—B9—B10 | 37.8 (3) |
Cl9—B9—B12—B7 | −148.2 (3) | B5—B4—B9—B8 | 138.7 (3) |
Cl9—B9—B12—B11 | 148.2 (3) | B5—B4—B9—B12 | 101.1 (3) |
Cl9—B9—B12—B8 | −111.4 (4) | B5—B4—B3—Cl3 | 155.7 (3) |
Cl7—B7—B2—Cl2 | 0.1 (5) | B5—B4—B3—B1 | 39.7 (3) |
Cl7—B7—B2—B1 | −150.6 (3) | B5—B4—B3—B7 | −62.7 (4) |
Cl7—B7—B2—B6 | 146.4 (3) | B5—B4—B3—B2 | 1.0 (4) |
Cl7—B7—B2—B11 | 108.4 (4) | B5—B4—B3—B8 | −99.9 (3) |
Cl7—B7—B2—B3 | −113.1 (4) | B5—B4—B8—Cl8 | −149.3 (3) |
Cl7—B7—B11—Cl11 | −1.7 (5) | B5—B4—B8—B7 | 63.3 (4) |
Cl7—B7—B11—B6 | −150.6 (3) | B5—B4—B8—B9 | −36.6 (3) |
Cl7—B7—B11—B10 | 145.5 (3) | B5—B4—B8—B3 | 101.6 (3) |
Cl7—B7—B11—B2 | −112.0 (4) | B5—B4—B8—B12 | 0.1 (4) |
Cl7—B7—B11—B12 | 109.0 (4) | B5—B9—B8—Cl8 | 147.7 (3) |
Cl7—B7—B3—Cl3 | −4.1 (5) | B5—B9—B8—B7 | −64.4 (4) |
Cl7—B7—B3—B1 | 148.3 (3) | B5—B9—B8—B4 | 37.2 (3) |
Cl7—B7—B3—B2 | 110.5 (4) | B5—B9—B8—B3 | −0.3 (4) |
Cl7—B7—B3—B4 | −148.0 (3) | B5—B9—B8—B12 | −101.2 (3) |
Cl7—B7—B3—B8 | −110.3 (4) | B5—B9—B12—Cl12 | −147.8 (3) |
Cl7—B7—B8—Cl8 | 3.9 (5) | B5—B9—B12—B10 | −36.4 (3) |
Cl7—B7—B8—B4 | 151.5 (3) | B5—B9—B12—B7 | 64.6 (4) |
Cl7—B7—B8—B9 | −144.9 (3) | B5—B9—B12—B11 | 1.1 (4) |
Cl7—B7—B8—B3 | 113.4 (4) | B5—B9—B12—B8 | 101.4 (3) |
Cl7—B7—B8—B12 | −108.3 (4) | B4—B1—B6—Cl6 | 145.6 (3) |
Cl7—B7—B12—Cl12 | 1.7 (5) | B4—B1—B6—B10 | 0.0 (4) |
Cl7—B7—B12—B10 | −146.7 (3) | B4—B1—B6—B2 | −99.9 (3) |
Cl7—B7—B12—B9 | 149.3 (3) | B4—B1—B6—B5 | 36.9 (3) |
Cl7—B7—B12—B11 | −109.7 (4) | B4—B1—B6—B11 | −63.2 (4) |
Cl7—B7—B12—B8 | 112.1 (3) | B4—B1—B2—Cl2 | −148.0 (3) |
Na1ii—Cl6—B6—B1 | −106.3 (3) | B4—B1—B2—B6 | 98.8 (3) |
Na1ii—Cl6—B6—B10 | 36.8 (3) | B4—B1—B2—B7 | −0.4 (4) |
Na1ii—Cl6—B6—B2 | 178.1 (3) | B4—B1—B2—B11 | 62.5 (4) |
Na1ii—Cl6—B6—B5 | −32.1 (3) | B4—B1—B2—B3 | −37.6 (3) |
Na1ii—Cl6—B6—B11 | 105.4 (3) | B4—B1—B5—Cl5 | 111.7 (4) |
Na1ii—Cl5—B5—B1 | 104.0 (3) | B4—B1—B5—B6 | −137.4 (3) |
Na1ii—Cl5—B5—B6 | 29.3 (4) | B4—B1—B5—B10 | −100.4 (3) |
Na1ii—Cl5—B5—B10 | −41.6 (3) | B4—B1—B5—B9 | −37.0 (3) |
Na1ii—Cl5—B5—B4 | 179.4 (3) | B4—B1—B3—Cl3 | −111.1 (4) |
Na1ii—Cl5—B5—B9 | −109.7 (3) | B4—B1—B3—B7 | 99.3 (3) |
Na1i—Cl4—B4—B1 | 143.7 (3) | B4—B1—B3—B2 | 137.0 (3) |
Na1i—Cl4—B4—B5 | 69.0 (3) | B4—B1—B3—B8 | 36.5 (3) |
Na1i—Cl4—B4—B9 | −0.5 (3) | B4—B5—B9—Cl9 | 111.2 (4) |
Na1i—Cl4—B4—B3 | −141.4 (3) | B4—B5—B9—B10 | −137.7 (3) |
Na1i—Cl4—B4—B8 | −69.6 (3) | B4—B5—B9—B8 | −37.2 (3) |
Na1ii—Cl10—B10—B6 | −37.0 (3) | B4—B5—B9—B12 | −101.5 (3) |
Na1ii—Cl10—B10—B5 | 34.4 (3) | B4—B9—B8—Cl8 | 110.4 (4) |
Na1ii—Cl10—B10—B9 | 106.8 (3) | B4—B9—B8—B7 | −101.6 (3) |
Na1ii—Cl10—B10—B11 | −108.1 (3) | B4—B9—B8—B3 | −37.6 (3) |
Na1ii—Cl10—B10—B12 | 179.1 (3) | B4—B9—B8—B12 | −138.4 (3) |
Na1—Cl12—B12—B10 | 147.4 (3) | B4—B9—B12—Cl12 | 148.2 (3) |
Na1—Cl12—B12—B7 | 3.4 (4) | B4—B9—B12—B10 | −100.4 (3) |
Na1—Cl12—B12—B9 | −139.9 (3) | B4—B9—B12—B7 | 0.6 (4) |
Na1—Cl12—B12—B11 | 75.5 (3) | B4—B9—B12—B11 | −62.9 (4) |
Na1—Cl12—B12—B8 | −67.8 (3) | B4—B9—B12—B8 | 37.4 (3) |
Na1i—Cl9—B9—B10 | −145.2 (3) | B4—B3—B8—Cl8 | −111.5 (4) |
Na1i—Cl9—B9—B5 | −73.5 (3) | B4—B3—B8—B7 | 137.6 (3) |
Na1i—Cl9—B9—B4 | −1.5 (4) | B4—B3—B8—B9 | 37.6 (3) |
Na1i—Cl9—B9—B8 | 70.7 (3) | B4—B3—B8—B12 | 100.3 (3) |
Na1i—Cl9—B9—B12 | 143.3 (3) | B4—B8—B12—Cl12 | −148.1 (3) |
Na1—Cl7—B7—B2 | −147.3 (3) | B4—B8—B12—B10 | 0.8 (4) |
Na1—Cl7—B7—B11 | −76.1 (3) | B4—B8—B12—B7 | 101.4 (3) |
Na1—Cl7—B7—B3 | 139.9 (3) | B4—B8—B12—B9 | −37.2 (3) |
Na1—Cl7—B7—B8 | 66.7 (3) | B4—B8—B12—B11 | 64.0 (4) |
Na1—Cl7—B7—B12 | −5.1 (3) | B9—B10—B5—Cl5 | −107.3 (3) |
N1—B1—B6—Cl6 | −2.8 (6) | B9—B10—B5—B1 | 101.1 (3) |
N1—B1—B6—B10 | −148.5 (3) | B9—B10—B5—B6 | 137.7 (3) |
N1—B1—B6—B2 | 111.7 (4) | B9—B10—B5—B4 | 37.8 (3) |
N1—B1—B6—B5 | −111.5 (4) | B9—B10—B11—Cl11 | 147.8 (3) |
N1—B1—B6—B11 | 148.3 (4) | B9—B10—B11—B6 | −100.4 (3) |
N1—B1—B2—Cl2 | 2.0 (5) | B9—B10—B11—B7 | 1.0 (4) |
N1—B1—B2—B6 | −111.2 (4) | B9—B10—B11—B2 | −63.0 (4) |
N1—B1—B2—B7 | 149.6 (3) | B9—B10—B11—B12 | 37.5 (3) |
N1—B1—B2—B11 | −147.5 (3) | B9—B10—B12—Cl12 | 110.8 (4) |
N1—B1—B2—B3 | 112.4 (4) | B9—B10—B12—B7 | −100.9 (3) |
N1—B1—B5—Cl5 | 0.0 (6) | B9—B10—B12—B11 | −138.0 (3) |
N1—B1—B5—B6 | 110.8 (4) | B9—B10—B12—B8 | −37.9 (3) |
N1—B1—B5—B10 | 147.9 (3) | B9—B5—B4—Cl4 | −106.4 (4) |
N1—B1—B5—B4 | −111.8 (4) | B9—B5—B4—B1 | 138.9 (3) |
N1—B1—B5—B9 | −148.7 (3) | B9—B5—B4—B3 | 99.8 (3) |
N1—B1—B4—Cl4 | 1.1 (5) | B9—B5—B4—B8 | 36.6 (3) |
N1—B1—B4—B5 | 111.3 (4) | B9—B4—B3—Cl3 | −141.4 (3) |
N1—B1—B4—B9 | 148.1 (4) | B9—B4—B3—B1 | 102.5 (3) |
N1—B1—B4—B3 | −112.3 (4) | B9—B4—B3—B7 | 0.2 (4) |
N1—B1—B4—B8 | −148.6 (4) | B9—B4—B3—B2 | 63.8 (4) |
N1—B1—B3—Cl3 | 0.7 (6) | B9—B4—B3—B8 | −37.0 (3) |
N1—B1—B3—B7 | −148.9 (4) | B9—B4—B8—Cl8 | −112.8 (4) |
N1—B1—B3—B2 | −111.2 (4) | B9—B4—B8—B7 | 99.9 (3) |
N1—B1—B3—B4 | 111.8 (4) | B9—B4—B8—B3 | 138.2 (3) |
N1—B1—B3—B8 | 148.3 (4) | B9—B4—B8—B12 | 36.7 (3) |
B1—B6—B10—Cl10 | 148.6 (3) | B9—B8—B12—Cl12 | −110.9 (4) |
B1—B6—B10—B5 | 37.9 (3) | B9—B8—B12—B10 | 38.0 (3) |
B1—B6—B10—B9 | 0.1 (4) | B9—B8—B12—B7 | 138.6 (3) |
B1—B6—B10—B11 | −101.4 (3) | B9—B8—B12—B11 | 101.2 (3) |
B1—B6—B10—B12 | −63.2 (4) | B11—B6—B10—Cl10 | −109.9 (4) |
B1—B6—B2—Cl2 | −115.1 (4) | B11—B6—B10—B5 | 139.3 (3) |
B1—B6—B2—B7 | 101.5 (3) | B11—B6—B10—B9 | 101.5 (3) |
B1—B6—B2—B11 | 139.4 (3) | B11—B6—B10—B12 | 38.2 (3) |
B1—B6—B2—B3 | 38.8 (3) | B11—B6—B2—Cl2 | 105.4 (4) |
B1—B6—B5—Cl5 | 116.7 (4) | B11—B6—B2—B1 | −139.4 (3) |
B1—B6—B5—B10 | −138.9 (3) | B11—B6—B2—B7 | −37.9 (3) |
B1—B6—B5—B4 | −37.7 (3) | B11—B6—B2—B3 | −100.7 (3) |
B1—B6—B5—B9 | −101.2 (3) | B11—B6—B5—Cl5 | −140.4 (3) |
B1—B6—B11—Cl11 | −146.7 (3) | B11—B6—B5—B1 | 102.9 (3) |
B1—B6—B11—B10 | 101.6 (3) | B11—B6—B5—B10 | −36.0 (3) |
B1—B6—B11—B7 | 1.8 (4) | B11—B6—B5—B4 | 65.2 (4) |
B1—B6—B11—B2 | −37.0 (3) | B11—B6—B5—B9 | 1.7 (4) |
B1—B6—B11—B12 | 64.5 (4) | B11—B10—B5—Cl5 | 151.6 (3) |
B1—B2—B11—Cl11 | 148.5 (3) | B11—B10—B5—B1 | 0.0 (4) |
B1—B2—B11—B6 | 36.3 (3) | B11—B10—B5—B6 | 36.6 (3) |
B1—B2—B11—B10 | −1.3 (4) | B11—B10—B5—B4 | −63.2 (4) |
B1—B2—B11—B7 | −100.6 (3) | B11—B10—B5—B9 | −101.1 (3) |
B1—B2—B11—B12 | −64.1 (4) | B11—B10—B9—Cl9 | −148.5 (3) |
B1—B2—B3—Cl3 | −116.0 (4) | B11—B10—B9—B5 | 101.4 (3) |
B1—B2—B3—B7 | 138.2 (3) | B11—B10—B9—B4 | 63.5 (4) |
B1—B2—B3—B4 | 38.6 (3) | B11—B10—B9—B8 | −0.1 (4) |
B1—B2—B3—B8 | 102.1 (3) | B11—B10—B9—B12 | −38.1 (3) |
B1—B5—B4—Cl4 | 114.6 (4) | B11—B10—B12—Cl12 | −111.1 (4) |
B1—B5—B4—B9 | −138.9 (3) | B11—B10—B12—B7 | 37.1 (3) |
B1—B5—B4—B3 | −39.1 (3) | B11—B10—B12—B9 | 138.0 (3) |
B1—B5—B4—B8 | −102.3 (3) | B11—B10—B12—B8 | 100.1 (3) |
B1—B5—B9—Cl9 | 148.0 (3) | B11—B7—B2—Cl2 | −108.3 (3) |
B1—B5—B9—B10 | −101.0 (3) | B11—B7—B2—B1 | 101.0 (3) |
B1—B5—B9—B4 | 36.8 (3) | B11—B7—B2—B6 | 38.0 (3) |
B1—B5—B9—B8 | −0.4 (4) | B11—B7—B2—B3 | 138.4 (3) |
B1—B5—B9—B12 | −64.7 (4) | B11—B7—B3—Cl3 | −151.7 (3) |
B1—B4—B9—Cl9 | −147.8 (3) | B11—B7—B3—B1 | 0.7 (4) |
B1—B4—B9—B10 | 0.1 (4) | B11—B7—B3—B2 | −37.1 (3) |
B1—B4—B9—B5 | −37.7 (3) | B11—B7—B3—B4 | 64.4 (4) |
B1—B4—B9—B8 | 101.0 (3) | B11—B7—B3—B8 | 102.1 (3) |
B1—B4—B9—B12 | 63.4 (4) | B11—B7—B8—Cl8 | 150.1 (3) |
B1—B4—B3—Cl3 | 116.1 (4) | B11—B7—B8—B4 | −62.3 (4) |
B1—B4—B3—B7 | −102.3 (3) | B11—B7—B8—B9 | 1.4 (4) |
B1—B4—B3—B2 | −38.7 (3) | B11—B7—B8—B3 | −100.3 (3) |
B1—B4—B3—B8 | −139.5 (3) | B11—B7—B8—B12 | 37.9 (3) |
B1—B4—B8—Cl8 | 145.6 (3) | B11—B7—B12—Cl12 | 111.4 (4) |
B1—B4—B8—B7 | −1.7 (4) | B11—B7—B12—B10 | −37.0 (3) |
B1—B4—B8—B9 | −101.6 (3) | B11—B7—B12—B9 | −101.0 (3) |
B1—B4—B8—B3 | 36.6 (3) | B11—B7—B12—B8 | −138.2 (3) |
B1—B4—B8—B12 | −64.9 (4) | B11—B2—B3—Cl3 | 142.5 (3) |
B1—B3—B8—Cl8 | −148.2 (3) | B11—B2—B3—B1 | −101.4 (3) |
B1—B3—B8—B7 | 101.0 (3) | B11—B2—B3—B7 | 36.8 (3) |
B1—B3—B8—B4 | −36.6 (3) | B11—B2—B3—B4 | −62.8 (4) |
B1—B3—B8—B9 | 1.0 (4) | B11—B2—B3—B8 | 0.7 (4) |
B1—B3—B8—B12 | 63.7 (4) | B3—B1—B6—Cl6 | −152.5 (3) |
B6—B1—B2—Cl2 | 113.2 (4) | B3—B1—B6—B10 | 61.9 (4) |
B6—B1—B2—B7 | −99.1 (3) | B3—B1—B6—B2 | −38.0 (3) |
B6—B1—B2—B11 | −36.2 (3) | B3—B1—B6—B5 | 98.8 (3) |
B6—B1—B2—B3 | −136.4 (3) | B3—B1—B6—B11 | −1.4 (4) |
B6—B1—B5—Cl5 | −110.9 (4) | B3—B1—B2—Cl2 | −110.4 (4) |
B6—B1—B5—B10 | 37.0 (3) | B3—B1—B2—B6 | 136.4 (3) |
B6—B1—B5—B4 | 137.4 (3) | B3—B1—B2—B7 | 37.3 (3) |
B6—B1—B5—B9 | 100.4 (3) | B3—B1—B2—B11 | 100.2 (3) |
B6—B1—B4—Cl4 | −147.0 (3) | B3—B1—B5—Cl5 | 149.7 (3) |
B6—B1—B4—B5 | −36.9 (3) | B3—B1—B5—B6 | −99.5 (3) |
B6—B1—B4—B9 | −0.1 (4) | B3—B1—B5—B10 | −62.4 (4) |
B6—B1—B4—B3 | 99.6 (3) | B3—B1—B5—B4 | 37.9 (3) |
B6—B1—B4—B8 | 63.3 (4) | B3—B1—B5—B9 | 1.0 (4) |
B6—B1—B3—Cl3 | 150.0 (3) | B3—B1—B4—Cl4 | 113.4 (4) |
B6—B1—B3—B7 | 0.4 (4) | B3—B1—B4—B5 | −136.5 (3) |
B6—B1—B3—B2 | 38.1 (3) | B3—B1—B4—B9 | −99.6 (3) |
B6—B1—B3—B4 | −98.9 (3) | B3—B1—B4—B8 | −36.3 (3) |
B6—B1—B3—B8 | −62.4 (4) | B3—B7—B2—Cl2 | 113.2 (3) |
B6—B10—B5—Cl5 | 115.0 (3) | B3—B7—B2—B1 | −37.4 (3) |
B6—B10—B5—B1 | −36.6 (3) | B3—B7—B2—B6 | −100.4 (3) |
B6—B10—B5—B4 | −99.9 (3) | B3—B7—B2—B11 | −138.4 (3) |
B6—B10—B5—B9 | −137.7 (3) | B3—B7—B11—Cl11 | 147.4 (3) |
B6—B10—B9—Cl9 | 147.8 (3) | B3—B7—B11—B6 | −1.5 (4) |
B6—B10—B9—B5 | 37.8 (3) | B3—B7—B11—B10 | −65.4 (4) |
B6—B10—B9—B4 | −0.1 (4) | B3—B7—B11—B2 | 37.1 (3) |
B6—B10—B9—B8 | −63.8 (4) | B3—B7—B11—B12 | −101.9 (3) |
B6—B10—B9—B12 | −101.7 (3) | B3—B7—B8—Cl8 | −109.5 (3) |
B6—B10—B11—Cl11 | −111.8 (4) | B3—B7—B8—B4 | 38.1 (3) |
B6—B10—B11—B7 | 101.4 (3) | B3—B7—B8—B9 | 101.7 (3) |
B6—B10—B11—B2 | 37.4 (3) | B3—B7—B8—B12 | 138.3 (3) |
B6—B10—B11—B12 | 138.0 (3) | B3—B7—B12—Cl12 | −148.1 (3) |
B6—B10—B12—Cl12 | −149.0 (3) | B3—B7—B12—B10 | 63.6 (4) |
B6—B10—B12—B7 | −0.7 (4) | B3—B7—B12—B9 | −0.5 (4) |
B6—B10—B12—B9 | 100.2 (3) | B3—B7—B12—B11 | 100.5 (3) |
B6—B10—B12—B11 | −37.8 (3) | B3—B7—B12—B8 | −37.6 (3) |
B6—B10—B12—B8 | 62.3 (4) | B3—B2—B11—Cl11 | −147.9 (3) |
B6—B2—B11—Cl11 | 112.2 (4) | B3—B2—B11—B6 | 99.9 (3) |
B6—B2—B11—B10 | −37.5 (3) | B3—B2—B11—B10 | 62.4 (4) |
B6—B2—B11—B7 | −136.9 (3) | B3—B2—B11—B7 | −37.0 (3) |
B6—B2—B11—B12 | −100.4 (3) | B3—B2—B11—B12 | −0.5 (4) |
B6—B2—B3—Cl3 | −154.6 (3) | B3—B4—B9—Cl9 | 148.3 (3) |
B6—B2—B3—B1 | −38.6 (3) | B3—B4—B9—B10 | −63.8 (4) |
B6—B2—B3—B7 | 99.6 (3) | B3—B4—B9—B5 | −101.6 (3) |
B6—B2—B3—B4 | 0.0 (4) | B3—B4—B9—B8 | 37.1 (3) |
B6—B2—B3—B8 | 63.5 (4) | B3—B4—B9—B12 | −0.5 (4) |
B6—B5—B4—Cl4 | 152.2 (3) | B3—B4—B8—Cl8 | 109.0 (4) |
B6—B5—B4—B1 | 37.6 (3) | B3—B4—B8—B7 | −38.3 (3) |
B6—B5—B4—B9 | −101.3 (3) | B3—B4—B8—B9 | −138.2 (3) |
B6—B5—B4—B3 | −1.5 (4) | B3—B4—B8—B12 | −101.5 (3) |
B6—B5—B4—B8 | −64.7 (4) | B3—B8—B12—Cl12 | 148.2 (3) |
B6—B5—B9—Cl9 | −149.1 (3) | B3—B8—B12—B10 | −62.8 (4) |
B6—B5—B9—B10 | −38.0 (3) | B3—B8—B12—B7 | 37.7 (3) |
B6—B5—B9—B4 | 99.7 (3) | B3—B8—B12—B9 | −100.9 (3) |
B6—B5—B9—B8 | 62.6 (4) | B3—B8—B12—B11 | 0.4 (4) |
B6—B5—B9—B12 | −1.7 (4) | C2—N1—B1—B6 | 73.4 (5) |
B6—B11—B12—Cl12 | 148.7 (3) | C2—N1—B1—B2 | 145.5 (4) |
B6—B11—B12—B10 | 37.8 (3) | C2—N1—B1—B5 | 2.1 (5) |
B6—B11—B12—B7 | −100.8 (3) | C2—N1—B1—B4 | −69.6 (5) |
B6—B11—B12—B9 | 0.0 (4) | C2—N1—B1—B3 | −142.2 (4) |
B6—B11—B12—B8 | −63.7 (4) | B8—B7—B2—Cl2 | 150.0 (3) |
B10—B6—B2—Cl2 | 142.1 (3) | B8—B7—B2—B1 | −0.7 (4) |
B10—B6—B2—B1 | −102.8 (3) | B8—B7—B2—B6 | −63.7 (4) |
B10—B6—B2—B7 | −1.3 (4) | B8—B7—B2—B11 | −101.7 (3) |
B10—B6—B2—B11 | 36.6 (3) | B8—B7—B2—B3 | 36.8 (3) |
B10—B6—B2—B3 | −64.0 (4) | B8—B7—B11—Cl11 | −148.7 (3) |
B10—B6—B5—Cl5 | −104.4 (4) | B8—B7—B11—B6 | 62.4 (4) |
B10—B6—B5—B1 | 138.9 (3) | B8—B7—B11—B10 | −1.5 (4) |
B10—B6—B5—B4 | 101.2 (3) | B8—B7—B11—B2 | 101.0 (3) |
B10—B6—B5—B9 | 37.7 (3) | B8—B7—B11—B12 | −38.0 (3) |
B10—B6—B11—Cl11 | 111.7 (4) | B8—B7—B3—Cl3 | 106.2 (3) |
B10—B6—B11—B7 | −99.8 (3) | B8—B7—B3—B1 | −101.4 (3) |
B10—B6—B11—B2 | −138.6 (3) | B8—B7—B3—B2 | −139.2 (3) |
B10—B6—B11—B12 | −37.2 (3) | B8—B7—B3—B4 | −37.7 (3) |
B10—B5—B4—Cl4 | −144.1 (3) | B8—B7—B12—Cl12 | −110.4 (4) |
B10—B5—B4—B1 | 101.3 (3) | B8—B7—B12—B10 | 101.2 (3) |
B10—B5—B4—B9 | −37.6 (3) | B8—B7—B12—B9 | 37.2 (3) |
B10—B5—B4—B3 | 62.1 (4) | B8—B7—B12—B11 | 138.2 (3) |
B10—B5—B4—B8 | −1.0 (4) | B8—B4—B9—Cl9 | 111.1 (3) |
B10—B5—B9—Cl9 | −111.1 (4) | B8—B4—B9—B10 | −100.9 (3) |
B10—B5—B9—B4 | 137.7 (3) | B8—B4—B9—B5 | −138.7 (3) |
B10—B5—B9—B8 | 100.6 (3) | B8—B4—B9—B12 | −37.6 (3) |
B10—B5—B9—B12 | 36.3 (3) | B8—B4—B3—Cl3 | −104.4 (4) |
B10—B9—B8—Cl8 | −148.7 (3) | B8—B4—B3—B1 | 139.5 (3) |
B10—B9—B8—B7 | −0.8 (4) | B8—B4—B3—B7 | 37.2 (3) |
B10—B9—B8—B4 | 100.8 (3) | B8—B4—B3—B2 | 100.9 (3) |
B10—B9—B8—B3 | 63.3 (4) | B8—B9—B12—Cl12 | 110.7 (4) |
B10—B9—B8—B12 | −37.6 (3) | B8—B9—B12—B10 | −137.8 (3) |
B10—B9—B12—Cl12 | −111.4 (4) | B8—B9—B12—B7 | −36.8 (3) |
B10—B9—B12—B7 | 101.0 (3) | B8—B9—B12—B11 | −100.4 (3) |
B10—B9—B12—B11 | 37.5 (3) | C3—N1—B1—B6 | −47.6 (5) |
B10—B9—B12—B8 | 137.8 (3) | C3—N1—B1—B2 | 24.5 (5) |
B10—B11—B12—Cl12 | 110.9 (4) | C3—N1—B1—B5 | −118.9 (4) |
B10—B11—B12—B7 | −138.5 (3) | C3—N1—B1—B4 | 169.5 (4) |
B10—B11—B12—B9 | −37.8 (3) | C3—N1—B1—B3 | 96.8 (5) |
B10—B11—B12—B8 | −101.4 (3) | B12—B10—B5—Cl5 | −143.6 (3) |
B7—B2—B11—Cl11 | −110.9 (4) | B12—B10—B5—B1 | 64.8 (4) |
B7—B2—B11—B6 | 136.9 (3) | B12—B10—B5—B6 | 101.4 (3) |
B7—B2—B11—B10 | 99.3 (4) | B12—B10—B5—B4 | 1.6 (4) |
B7—B2—B11—B12 | 36.5 (3) | B12—B10—B5—B9 | −36.3 (3) |
B7—B2—B3—Cl3 | 105.7 (3) | B12—B10—B9—Cl9 | −110.4 (4) |
B7—B2—B3—B1 | −138.2 (3) | B12—B10—B9—B5 | 139.5 (3) |
B7—B2—B3—B4 | −99.7 (3) | B12—B10—B9—B4 | 101.6 (3) |
B7—B2—B3—B8 | −36.1 (3) | B12—B10—B9—B8 | 38.0 (3) |
B7—B11—B12—Cl12 | −110.6 (4) | B12—B10—B11—Cl11 | 110.2 (4) |
B7—B11—B12—B10 | 138.5 (3) | B12—B10—B11—B6 | −138.0 (3) |
B7—B11—B12—B9 | 100.8 (3) | B12—B10—B11—B7 | −36.6 (3) |
B7—B11—B12—B8 | 37.1 (3) | B12—B10—B11—B2 | −100.6 (4) |
B7—B3—B8—Cl8 | 110.9 (3) | B12—B7—B2—Cl2 | −145.5 (3) |
B7—B3—B8—B4 | −137.6 (3) | B12—B7—B2—B1 | 63.8 (4) |
B7—B3—B8—B9 | −100.0 (3) | B12—B7—B2—B6 | 0.8 (4) |
B7—B3—B8—B12 | −37.3 (3) | B12—B7—B2—B11 | −37.2 (3) |
B7—B8—B12—Cl12 | 110.6 (4) | B12—B7—B2—B3 | 101.3 (3) |
B7—B8—B12—B10 | −100.5 (3) | B12—B7—B11—Cl11 | −110.7 (4) |
B7—B8—B12—B9 | −138.6 (3) | B12—B7—B11—B6 | 100.4 (3) |
B7—B8—B12—B11 | −37.3 (3) | B12—B7—B11—B10 | 36.5 (3) |
B2—B1—B6—Cl6 | −114.5 (4) | B12—B7—B11—B2 | 139.0 (3) |
B2—B1—B6—B10 | 99.9 (3) | B12—B7—B3—Cl3 | 144.0 (3) |
B2—B1—B6—B5 | 136.8 (3) | B12—B7—B3—B1 | −63.6 (4) |
B2—B1—B6—B11 | 36.7 (3) | B12—B7—B3—B2 | −101.4 (3) |
B2—B1—B5—Cl5 | −148.7 (3) | B12—B7—B3—B4 | 0.2 (4) |
B2—B1—B5—B6 | −37.8 (3) | B12—B7—B3—B8 | 37.8 (3) |
B2—B1—B5—B10 | −0.7 (4) | B12—B7—B8—Cl8 | 112.2 (4) |
B2—B1—B5—B4 | 99.6 (3) | B12—B7—B8—B4 | −100.2 (3) |
B2—B1—B5—B9 | 62.7 (4) | B12—B7—B8—B9 | −36.5 (3) |
B2—B1—B4—Cl4 | 151.0 (3) | B12—B7—B8—B3 | −138.3 (3) |
B2—B1—B4—B5 | −98.9 (3) | B12—B9—B8—Cl8 | −111.1 (4) |
B2—B1—B4—B9 | −62.1 (4) | B12—B9—B8—B7 | 36.8 (3) |
B2—B1—B4—B3 | 37.6 (3) | B12—B9—B8—B4 | 138.4 (3) |
B2—B1—B4—B8 | 1.3 (4) | B12—B9—B8—B3 | 100.9 (3) |
B2—B1—B3—Cl3 | 111.8 (4) | O2—S1—O1—Na1 | 176.9 (3) |
B2—B1—B3—B7 | −37.7 (3) |
Symmetry codes: (i) −x+1, y+1/2, −z+1/2; (ii) x+1, y, z; (iii) x−1, y, z; (iv) −x+1, y−1/2, −z+1/2. |
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