Figure 2
Dimers of complexes formed through π–π overlap between their coordinating NNbz ligands and intermolecular interactions between dimers with methanol solvent molecules and PF6− counter-anions. Colour code as in Fig. 1 with the additional O1M—H201⋯N3 interactions indicated by orange dashed lines. [Symmetry codes: (′) 1 − x, 1 − y, 1 − z; (′′) 2 − x, 1 − y, 1 − z; (′′′) −1 + x, y, z.] |