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Figure 5
Views of the Hirshfeld surfaces mapped over (a) dnorm, (b) curvedness and (c) shape-index, and (d) the fingerprint plot for the title complex. The red circles in (b) indicate patches of the same shape corresponding to contact areas of neighbouring complexes. The central ellipse in (c) indicates the ππ overlap of the central phenyl rings, and the two circles at both ends of the surface the overlap of the pyridine ring and the phenyl ring of the benzo­thia­zol part of neighbouring centrosymmetrically related NNbz ligands. In (d), de and di are the distances to the nearest atom centre exterior and inter­ior to the surface. A1 and A4 stand for the acceptor atoms in O1W—H201⋯N3 and C⋯H inter­actions. A2, B2 indicate the acceptor atom and the H-donated atom in the C5—H5⋯O2 inter­action, B1 the H101 atom in the O1W—H101⋯O1M inter­action, and B3, C and D the H⋯F, H⋯H and C⋯C inter­actions, respectively.

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