research communications
κ2N2,N2′](1,10-phenanthroline-κ2N,N′)zinc(II)
of bis[dihydrobis(pyrazol-1-yl)borato-aInstitut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth Str. 2, D-24118 Kiel, Germany
*Correspondence e-mail: ftuczek@ac.uni-kiel.de
The 6H8N4B)2(C12H8N2)], comprises one half of a ZnII cation (site symmetry 2), one dihydrobis(pyrazol-1-yl)borate ligand in a general position, and one half of a phenanthroline ligand, the other half being completed by twofold rotation symmetry. The ZnII cation is coordinated in form of a slightly distorted octahedron by the N atoms of a phenanthroline ligand and by two pairs of N atoms of symmetry-related dihydrobis(pyrazol-1-yl)borate ligands. The discrete complexes are arranged into columns that elongate in the c-axis direction with a parallel alignment of the phenanthroline ligands, indicating weak π–π interactions.
of the title compound, [Zn(CKeywords: crystal structure; model substance for FeII dihydrobis(pyrazol-1-yl)borate phenanthroline; ZnII.
CCDC reference: 1937083
1. Chemical context
Spin-crossover transition-metal complexes (3d4–3d7) continue to be a fascinating class of functional materials in the field of coordination chemistry and have the potential to play a significant role in electronic data storage or in spintronics (Gütlich et al., 2013; Halcrow, 2013). Transitions between the diamagnetic low spin state (S = 0 for FeII) and the paramagnetic high-spin state (S = 2 for FeII) of such complexes can be induced by stimuli such as temperature or light. In most cases, spin-crossover complexes are based on octahedral [FeIIN6] coordination environments with chelating or mono-coordinating nitrogen donor ligands. From all metal ions and ligands leading to spin-crossover complexes, the FeII/nitrogen ligand combination leads to the greatest changes in metal–ligand bond lengths between the two spin states and so far to the longest-lived photochemical excited spin state (Halcrow, 2007). Since the beginning of this research area some several decades ago, this field has been directed towards applications using the change of the magnetic and electronic properties of the spin-crossover compounds associated with the spin transition. Regarding applications, it might be advantageous to deposit spin-crossover complexes as thin films on substrates. This can be achieved by different methods of which physical vapour deposition is the most practicable because the formation of solvates can be ruled out. In this context, we have deposited various complexes with organoborate ligands mainly based on dihydrobis(pyrazol-1-yl)borate on different substrates (Naggert et al., 2011, 2015; Ossinger et al., 2017; Gopakumar et al., 2012; Kipgen et al., 2018).
In the course of this project we became interested in the well-known iron spin-crossover complex [Fe(H2B(pz)2)2(phen)] ((H2B(pz)2)2 = bis(dihydrobis(pyrazol-1-yl)borate); phen = 1,10-phenanthroline). To make conclusions regarding the behaviour of [Fe(H2B(pz)2)2(phen)] on substrates such as, for example, graphene, quantum-chemical calculations using the xTB program (Grimme et al., 2017; Bannwarth et al., 2019) are useful. We are especially interested in structural details of the high-spin state, but unfortunately for iron(II) complexes the geometry optimization always leads to the low-spin state. To overcome this problem, corresponding compounds with ZnII can be used in the calculation, because their geometry is close to that of FeII compounds in the high-spin state. This approach is beneficial because the calculation of diamagnetic compounds is simpler and, in addition, diamagnetic compounds can easily be investigated by NMR spectroscopy. Therefore, ZnII complexes are often used as model systems for high-spin iron(II) complexes (Seredyuk et al., 2007; Schenker et al., 2001). The ionic radii (Shannon, 1976) for ZnII cations (3d10, 1S) are nearly the same as for FeII cations in the high-spin state (3d6, 5T2), frequently leading to the formation of isotypic compounds.
With these consideration in mind, [Zn(H2B(pz)2)2(phen)] was synthesized, crystallized and investigated by single crystal X-ray diffraction. The X-ray powder pattern revealed that a pure compound was obtained (see Fig. S1 in the supporting information) that is suitable for physical vapour deposition, in analogy to the FeII analogue (Naggert et al., 2011, 2015; Ossinger et al., 2017). Comparison of the infrared spectra from the bulk and vacuum-deposited ZnII compound shows identical vibrational modes, proving that no decomposition takes place during deposition (Fig. S2).
2. Structural commentary
[Zn(H2B(pz)2)2(phen)] is isotypic with the FeII analogue (Real et al., 1997). The of the title compound consists of one dihydrobis(pyrazol-1-yl)borate ligand, one half of a ZnII cation located on a twofold rotation axis and one half of a phenanthroline ligand, the other half being completed by application of twofold rotation symmetry. The ZnII cation is coordinated by the N atoms of the chelating phenanthroline ligand and by two pairs of N atoms of two symmetry-related dihydrobis(pyrazol-1-yl)borate ligands, leading to a slightly distorted octahedral coordination environment (Fig. 1), as shown by the different bond lengths and angles deviating from ideal values (Table 1). The Zn—N bond lengths involving the dihydrobis(pyrazol-1-yl)borate ligand are 2.1454 (18) and 2.1705 (18) Å and thus are significantly shorter than those to the phenanthroline ligand of 2.2101 (19) Å. The planes of the five-membered rings of the dihydrobis(pyrazol-1-yl)borate ligand are rotated with respect to each other by 44.4 (2)°.
3. Supramolecular features
In the c-axis direction (Fig. 2). Within these columns, the phenanthroline ligands are parallel but shifted relative to each other (Fig. 3). The shortest distance between two parallel phenanthroline planes amounts to 3.9341 (11) Å, indicative of weak π–π interactions.
of the title compound, the discrete complexes are arranged into columns that elongate in the4. Database survey
There are already 17 crystal structures of iron complexes with dihydrobis(pyrazol-1-yl)borate and different co-ligands reported in the literature, which includes [Fe(H2B(pz)2)2(phen)] and [Fe(H2B(pz)2)2(2,2′-bipy)] (Real et al., 1997; Thompson, et al., 2004) as the most well-known complexes. In the others, the co-ligand is exchanged by annelated bipyridyl ligands (Kulmaczewski et al., 2014), various modified diarylethene ligands (Nihei et al., 2013; Milek et al., 2013; Mörtel et al., 2017), 4,7-dimethyl-phenanthroline (Naggert et al., 2015), dimethylbipyridine derivatives substituted in the 5,5′ position (Xue et al., 2018), diaminobipyridine (Luo et al., 2016) and chiral (R)/(S)-4,5-pinenepyridyl-2-pyrazine ligands (Ru et al., 2017). In all of these complexes, the FeII cations are coordinated by three bidentate chelate ligands in an octahedral environment and show spin-crossover behaviour. Moreover, the structure of the synthetic intermediate used for the preparation of the Fe phenanthroline complex, [Fe(H2B(pz)2)2(MeOH)2], has also been published (Ossinger et al., 2016).
To the best of our knowledge, no zinc complex with the dihydrobis(pyrazol-1-yl)borate ligand and additional co-ligands has been reported in the literature. So far only the complex [Zn(H2B(pz)2)2] (Reger et al., 2000) and four related compounds with dihydrobis(pyrazol-1-yl)borate modified by different substituents at the pyrazole unit have been reported (Rheingold et al., 2000; Agrifoglio & Capparelli, 2005; Dias & Gorden, 1996). In all of these complexes, the ZnII cations are tetrahedrally coordinated by two bidentate organoborate ligands based on dihydrobis(pyrazol-1-yl)borate. There are other zinc complexes supported by the tripodal hydrotris(pyrazol-1-yl)borate ligand (Nakata et al., 1995) with various substituents at the pyrazole unit forming different solvates (Reger et al., 2000; Kitano et al., 2003; Lobbia et al., 1997; Yang et al., 1997; Calvo & Vahrenkamp, 2006; Janiak et al., 2000; Looney et al., 1995; Bats & Guo, 2014). In the zinc complexes, the metal cations are in each case coordinated by two tripodal ligands in an octahedral coordination environment.
5. Synthesis and crystallization
1H-pyrazole, potassium tetrahydroborate, zinc perchlorate hexahydrate and 1,10-phenanthroline were purchased and used without further purification. Solvents were purchased and purified by distilling over conventional drying agents. K[H2B(pz)2] and [Zn(H2B(pz)2)2(phen)] were synthesized according to previously reported procedures (Naggert et al., 2011, 2015; Ossinger et al., 2016, 2017).
Synthesis of [Zn(H2B(pz)2)2(phen)]: To a solution of Zn(ClO4)2·6H2O (746 mg, 2.00 mmol) in methanol (10 ml) a solution of K[H2B(pz)2] (744 mg, 4.00 mmol) in methanol (10 ml) was added. After 15 min of stirring, precipitated KClO4 was removed by filtration. To the filtrate a solution of 1,10-phenanthroline (361 mg, 2.00 mmol) in methanol (10 ml) was added dropwise, leading to the formation of a colourless precipitate. The mixture was stirred for another hour at room temperature and the precipitate was filtered off, washed with methanol (5 ml) and filtered again by suction filtration (30 min). Yield: 142 mg (263 µmol, 13% based on Zn(ClO4)2·6H2O).
Elemental analysis calculated for C24H24B2ZnN10: C 53.42, H 4.48, N 25.96%, found: C 53.39, H 4.47, N 25.98%.
HRESI–MS(+)(CHCl3 + MeOH): m/z (%) = [M − H2B(pz)2]+ calculated 391.08155, found 391.08061 (5).
1H NMR (400 MHz, CDCl3): δ (ppm) = 9.21 (dd, J = 4.3Hz, 1.7Hz, 2H, phen-H4), 8.27 (dd, J = 8.1Hz, 1.7Hz, 2H, phen-H4), 7.81 (s, 2H, phen-H7), 7.73 (dd, J = 2.2Hz, 0.5Hz, 4H, pyrazolyl-H5), 7.65 (dd, J = 8.1Hz, 4.3Hz, 2H, phen-H3), 7.57 (d, J = 1.9Hz, 4H, pyrazolyl-H3), 6.28 (t, J = 2.1Hz, 4H, pyrazolyl-H4), 3.78 (br. d, J = 127.9Hz, 4H, B-H).
13C{1H} NMR (100 MHz, CDCl3): δ/ppm = 150.5 (CH, phen-C2), 146.39 (Cq, phen-C6), 140.31 (CH, pyrazolyl-C3), 136.93 (CH, pyrazolyl-C5), 136.14 (CH, phen-C4), 128.8 (Cq, phen-C5), 126.68 (CH, phen-C7), 123.24 (CH, phen-C3), 105.13 (CH, pyrazolyl-C4).
1B NMR (128 MHz, CDCl3): δ/ppm = −8.43 (br. s (t), 1B).
IR (ATR, 298 K): ν/cm−1 = 3134, 3118, 3073, 3060 [w, ν (=C—H)], 2464, 2438, 2397, 2356 [m, νasym. (–BH2)], 2309, 2295 [m, νsym. (–BH2)], 1719 (w), 1625 (w), 1595 (w), 1578 (w), 1515 (m). 1494 (m), 1425 (m), 1399 (m), 1347 (w), 1321 (w), 1294 (m), 1266 (w), 1213 (m), 1200 (m), 1186 (m), 1172 (m), 1160 (s), 1137 (w), 1098 (w), 1090 (w), 1064 (m), 1049 (s), 1011 (w), 978 (m), 960 (w), 921 (w), 900 (w), 882 (m), 866 (w), 843 (m), 806 (w), 782 (s), 747 (s), 727 (s), 717 (m), 678 (m), 649 (m), 637 (s), 623 (m), 480 (w), 437 (w), 421 (w).
Raman (Bulk, 298 K): ν (cm−1) = 3134, 3115, 3088, 3074, 3061, 3028, 2997 [m, ν (=C—H)], 2472, 2447, 2397, 2359 [w, νasym. (–BH2)], 2310, 2297 [w, νsym. (–BH2)], 1626 (w), 1605 (w), 1589 (w), 1516 (w), 1452 (m), 1419 (s), 1408 (m), 1350 (w), 1308 (m), 1296 (m), 1213 (m), 1163 (w), 1138 (w), 1097 (w), 1057 (w), 1045 (m), 1012 (w), 980 (w), 924 (w), 727 (m), 559 (w), 422 (w), 411 (w).
UV/Vis (KBr, 298 K): λmax (nm) = 204, 230, 274, 298, 332, 448–600 (br), 600–650 (br).
Crystallization: Single crystals of [Zn(H2B(pz)2)2(phen)] were obtained under synthetic conditions as described above. After the precipitate was filtered off and washed with methanol, the mother liquor was stored at 278 K. After a few days colourless block-like single crystals had formed.
Experimental details: NMR spectra were recorded in deuterated solvents with a Bruker Avance 400 spectrometer operating at a 1H frequency of 400 MHz, a 13C frequency of 100 MHz and a 11B frequency of 128 MHz. They were referenced to the residual protonated solvent signal [1H: δ(CDCl3) = 7.26 ppm], the solvent signal [13C: δ(CDCl3) = 77.16 ppm] or an (11B:BF3·Et2O) (Gottlieb et al., 1997; Fulmer et al., 2010). Signals were assigned with the help of DEPT-135 and two-dimensional correlation spectra (1H,1H-COSY, 1H,13C-HSQC, 1H,13C-HMBC). Signal multiplicities are abbreviated as s (singlet), d (doublet), t (triplet), m (multiplet) and br. (broad signal). Elemental analyses were performed using a vario MICRO cube CHNS element analyser from Elementar. Samples were burned in sealed tin containers by a stream of oxygen. High-resolution ESI mass spectra were recorded on a ThermoFisher Orbitrap spectrometer. IR spectra were recorded on a Bruker Alpha-P ATR-IR Spectrometer. Signal intensities are marked as s (strong), m (medium), w (weak) and br. (broad). For FT–Raman spectroscopy, a Bruker RAM II −1064 FT–Raman Module, a R510-N/R Nd:YAG-laser (1046 nm, up to 500 mW) and a D418-T/R liquid-nitrogen-cooled, highly sensitive Ge detector or a Bruker IFS 66 with a FRA 106 unit and a 35mW NdYAG-LASER (1064 nm) was used. XRPD experiments were performed with a Stoe Transmission Powder Diffraction System (STADI P) with Cu Kα radiation (λ = 1.5406 Å) that is equipped with position-sensitive detectors (Mythen-K1). UV/vis spectra were recorded with a Cary 5000 spectrometer in transmission geometry.
6. Refinement
Crystal data, data collection and structure . The H atoms were positioned with idealized geometry (C—H = 0.93 Å) and were refined with Uiso(H) = 1.2Ueq(C) using a riding model. The B—H hydrogen atoms were located in a difference-Fourier map. Their bond lengths were set to ideal values (B—H = 0.97 Å) and finally they were refined with Uiso(H) = 1.5Ueq(B) using a riding model.
details are summarized in Table 2Supporting information
CCDC reference: 1937083
https://doi.org/10.1107/S2056989019009289/wm5509sup1.cif
contains datablock I. DOI:Structure factors: contains datablock I. DOI: https://doi.org/10.1107/S2056989019009289/wm5509Isup2.hkl
Figure S1. Experimental XRPD pattern of [Zn(H2B(pz)2)2(phen)] measuered at rt (a) as well as simulated XRPD pattern calculated from the single https://doi.org/10.1107/S2056989019009289/wm5509sup3.jpg
(b) (293 K) in comparison with the calculated pattern for the isostructural high-spin complex [Fe(H2B(pz)2)2(phen)] (c) retrieved from literature (Real et al., 1997). DOI:Figure S2. Fourier transform infrared (FT-IR) spectra of bulk material (black line) and vacuum-deposited material (red line) of the zinc complex at rt. DOI: https://doi.org/10.1107/S2056989019009289/wm5509sup4.jpg
Data collection: X-AREA (Stoe & Cie, 2008); cell
X-AREA (Stoe & Cie, 2008); data reduction: X-AREA (Stoe & Cie, 2008); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL2014 (Sheldrick, 2015); molecular graphics: DIAMOND (Brandenburg, 1999); software used to prepare material for publication: publCIF (Westrip, 2010).[Zn(C6H8BN4)2(C12H8N2)] | F(000) = 1112 |
Mr = 539.52 | Dx = 1.410 Mg m−3 |
Monoclinic, C2/c | Mo Kα radiation, λ = 0.71073 Å |
a = 17.4591 (10) Å | Cell parameters from 10361 reflections |
b = 16.0990 (7) Å | θ = 2.3–27.0° |
c = 10.6076 (6) Å | µ = 1.00 mm−1 |
β = 121.533 (4)° | T = 293 K |
V = 2541.3 (3) Å3 | Block, colourless |
Z = 4 | 0.13 × 0.10 × 0.06 mm |
Stoe IPDS-2 diffractometer | 2359 reflections with I > 2σ(I) |
ω scans | Rint = 0.031 |
Absorption correction: numerical (X-RED and X-SHAPE; Stoe & Cie, 2008) | θmax = 27.0°, θmin = 2.3° |
Tmin = 0.805, Tmax = 0.911 | h = −21→22 |
10361 measured reflections | k = −20→16 |
2765 independent reflections | l = −13→13 |
Refinement on F2 | 0 restraints |
Least-squares matrix: full | Hydrogen site location: inferred from neighbouring sites |
R[F2 > 2σ(F2)] = 0.039 | H-atom parameters constrained |
wR(F2) = 0.089 | w = 1/[σ2(Fo2) + (0.0445P)2 + 0.6977P] where P = (Fo2 + 2Fc2)/3 |
S = 1.08 | (Δ/σ)max < 0.001 |
2765 reflections | Δρmax = 0.22 e Å−3 |
168 parameters | Δρmin = −0.22 e Å−3 |
Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. |
x | y | z | Uiso*/Ueq | ||
Zn1 | 0.5000 | 0.75993 (2) | 0.7500 | 0.04673 (13) | |
N1 | 0.42976 (13) | 0.86884 (12) | 0.6097 (2) | 0.0560 (5) | |
C1 | 0.36392 (18) | 0.86814 (18) | 0.4692 (3) | 0.0689 (7) | |
H1 | 0.3393 | 0.8173 | 0.4246 | 0.083* | |
C2 | 0.3299 (2) | 0.9403 (2) | 0.3851 (4) | 0.0835 (9) | |
H2 | 0.2851 | 0.9372 | 0.2855 | 0.100* | |
C3 | 0.3626 (2) | 1.0144 (2) | 0.4497 (4) | 0.0912 (10) | |
H3 | 0.3399 | 1.0630 | 0.3950 | 0.109* | |
C4 | 0.4307 (2) | 1.01866 (16) | 0.5991 (4) | 0.0762 (8) | |
C5 | 0.46363 (16) | 0.94306 (13) | 0.6741 (3) | 0.0556 (5) | |
C6 | 0.4676 (3) | 1.09407 (18) | 0.6787 (5) | 0.1086 (14) | |
H6 | 0.4458 | 1.1445 | 0.6300 | 0.130* | |
N11 | 0.43035 (14) | 0.63487 (13) | 0.4888 (2) | 0.0595 (5) | |
N12 | 0.41630 (13) | 0.66673 (11) | 0.5937 (2) | 0.0518 (4) | |
C11 | 0.37140 (18) | 0.60880 (16) | 0.6182 (3) | 0.0642 (6) | |
H11 | 0.3534 | 0.6138 | 0.6863 | 0.077* | |
C12 | 0.3549 (2) | 0.54065 (19) | 0.5298 (4) | 0.0870 (9) | |
H12 | 0.3241 | 0.4925 | 0.5248 | 0.104* | |
C13 | 0.3939 (2) | 0.55958 (19) | 0.4513 (4) | 0.0830 (9) | |
H13 | 0.3950 | 0.5251 | 0.3819 | 0.100* | |
B1 | 0.4746 (2) | 0.6851 (2) | 0.4199 (3) | 0.0690 (8) | |
H1A | 0.4381 | 0.7334 | 0.3693 | 0.083* | |
H1B | 0.4782 | 0.6511 | 0.3476 | 0.083* | |
N13 | 0.57014 (14) | 0.71333 (13) | 0.5411 (2) | 0.0580 (5) | |
N14 | 0.58774 (13) | 0.75821 (12) | 0.6621 (2) | 0.0546 (4) | |
C14 | 0.67425 (17) | 0.78014 (16) | 0.7300 (3) | 0.0631 (6) | |
H24 | 0.7046 | 0.8106 | 0.8173 | 0.076* | |
C15 | 0.71221 (18) | 0.75136 (19) | 0.6524 (3) | 0.0732 (7) | |
H15 | 0.7710 | 0.7589 | 0.6753 | 0.088* | |
C16 | 0.64476 (18) | 0.70945 (19) | 0.5346 (3) | 0.0695 (7) | |
H16 | 0.6497 | 0.6825 | 0.4617 | 0.083* |
U11 | U22 | U33 | U12 | U13 | U23 | |
Zn1 | 0.0499 (2) | 0.0432 (2) | 0.04314 (19) | 0.000 | 0.02155 (15) | 0.000 |
N1 | 0.0552 (11) | 0.0514 (11) | 0.0531 (11) | 0.0032 (9) | 0.0225 (9) | 0.0053 (8) |
C1 | 0.0653 (16) | 0.0721 (16) | 0.0568 (15) | 0.0089 (13) | 0.0232 (13) | 0.0111 (12) |
C2 | 0.0744 (19) | 0.099 (2) | 0.0705 (18) | 0.0207 (17) | 0.0335 (16) | 0.0335 (17) |
C3 | 0.081 (2) | 0.079 (2) | 0.115 (3) | 0.0242 (17) | 0.052 (2) | 0.051 (2) |
C4 | 0.0742 (18) | 0.0522 (14) | 0.112 (2) | 0.0121 (13) | 0.0552 (18) | 0.0250 (14) |
C5 | 0.0550 (13) | 0.0459 (12) | 0.0735 (15) | 0.0046 (10) | 0.0390 (12) | 0.0063 (10) |
C6 | 0.104 (3) | 0.0439 (14) | 0.174 (4) | 0.0090 (15) | 0.070 (3) | 0.0195 (17) |
N11 | 0.0640 (12) | 0.0682 (12) | 0.0513 (11) | −0.0061 (10) | 0.0338 (10) | −0.0125 (9) |
N12 | 0.0583 (11) | 0.0524 (10) | 0.0486 (10) | −0.0039 (8) | 0.0307 (9) | −0.0052 (8) |
C11 | 0.0742 (17) | 0.0613 (14) | 0.0657 (15) | −0.0147 (12) | 0.0425 (14) | −0.0092 (11) |
C12 | 0.110 (3) | 0.0628 (16) | 0.108 (2) | −0.0286 (17) | 0.070 (2) | −0.0235 (16) |
C13 | 0.094 (2) | 0.0747 (18) | 0.088 (2) | −0.0200 (16) | 0.0525 (19) | −0.0387 (16) |
B1 | 0.0674 (18) | 0.098 (2) | 0.0443 (14) | −0.0064 (16) | 0.0308 (14) | −0.0032 (14) |
N13 | 0.0588 (11) | 0.0716 (12) | 0.0495 (10) | 0.0034 (9) | 0.0324 (9) | 0.0081 (9) |
N14 | 0.0524 (10) | 0.0625 (11) | 0.0484 (9) | −0.0004 (9) | 0.0260 (8) | 0.0083 (8) |
C14 | 0.0559 (13) | 0.0688 (15) | 0.0584 (13) | −0.0027 (11) | 0.0256 (12) | 0.0166 (11) |
C15 | 0.0540 (13) | 0.095 (2) | 0.0748 (16) | 0.0067 (14) | 0.0365 (13) | 0.0276 (15) |
C16 | 0.0663 (16) | 0.0879 (18) | 0.0663 (16) | 0.0139 (14) | 0.0430 (15) | 0.0181 (13) |
Zn1—N12 | 2.1454 (18) | N11—N12 | 1.358 (2) |
Zn1—N12i | 2.1454 (18) | N11—B1 | 1.541 (4) |
Zn1—N14 | 2.1704 (18) | N12—C11 | 1.328 (3) |
Zn1—N14i | 2.1705 (18) | C11—C12 | 1.372 (4) |
Zn1—N1 | 2.2101 (19) | C11—H11 | 0.9300 |
Zn1—N1i | 2.2101 (19) | C12—C13 | 1.356 (4) |
N1—C1 | 1.323 (3) | C12—H12 | 0.9300 |
N1—C5 | 1.350 (3) | C13—H13 | 0.9300 |
C1—C2 | 1.394 (4) | B1—N13 | 1.549 (4) |
C1—H1 | 0.9300 | B1—H1A | 0.9700 |
C2—C3 | 1.347 (5) | B1—H1B | 0.9700 |
C2—H2 | 0.9300 | N13—C16 | 1.341 (3) |
C3—C4 | 1.399 (5) | N13—N14 | 1.361 (3) |
C3—H3 | 0.9300 | N14—C14 | 1.337 (3) |
C4—C5 | 1.402 (3) | C14—C15 | 1.379 (4) |
C4—C6 | 1.426 (5) | C14—H24 | 0.9300 |
C5—C5i | 1.438 (5) | C15—C16 | 1.365 (4) |
C6—C6i | 1.334 (8) | C15—H15 | 0.9300 |
C6—H6 | 0.9300 | C16—H16 | 0.9300 |
N11—C13 | 1.329 (3) | ||
N12—Zn1—N12i | 91.24 (10) | C13—N11—N12 | 109.0 (2) |
N12—Zn1—N14 | 90.43 (7) | C13—N11—B1 | 128.0 (2) |
N12i—Zn1—N14 | 88.55 (7) | N12—N11—B1 | 122.7 (2) |
N12—Zn1—N14i | 88.55 (7) | C11—N12—N11 | 105.83 (19) |
N12i—Zn1—N14i | 90.43 (7) | C11—N12—Zn1 | 124.95 (15) |
N14—Zn1—N14i | 178.54 (11) | N11—N12—Zn1 | 123.73 (14) |
N12—Zn1—N1 | 96.92 (7) | N12—C11—C12 | 111.2 (2) |
N12i—Zn1—N1 | 171.59 (8) | N12—C11—H11 | 124.4 |
N14—Zn1—N1 | 89.34 (7) | C12—C11—H11 | 124.4 |
N14i—Zn1—N1 | 91.83 (7) | C13—C12—C11 | 104.3 (2) |
N12—Zn1—N1i | 171.59 (7) | C13—C12—H12 | 127.9 |
N12i—Zn1—N1i | 96.92 (7) | C11—C12—H12 | 127.9 |
N14—Zn1—N1i | 91.83 (7) | N11—C13—C12 | 109.6 (2) |
N14i—Zn1—N1i | 89.34 (7) | N11—C13—H13 | 125.2 |
N1—Zn1—N1i | 75.01 (11) | C12—C13—H13 | 125.2 |
C1—N1—C5 | 118.1 (2) | N11—B1—N13 | 110.5 (2) |
C1—N1—Zn1 | 126.95 (18) | N11—B1—H1A | 109.6 |
C5—N1—Zn1 | 114.81 (16) | N13—B1—H1A | 109.6 |
N1—C1—C2 | 122.8 (3) | N11—B1—H1B | 109.6 |
N1—C1—H1 | 118.6 | N13—B1—H1B | 109.6 |
C2—C1—H1 | 118.6 | H1A—B1—H1B | 108.1 |
C3—C2—C1 | 119.2 (3) | C16—N13—N14 | 109.1 (2) |
C3—C2—H2 | 120.4 | C16—N13—B1 | 126.7 (2) |
C1—C2—H2 | 120.4 | N14—N13—B1 | 123.6 (2) |
C2—C3—C4 | 120.2 (3) | C14—N14—N13 | 106.4 (2) |
C2—C3—H3 | 119.9 | C14—N14—Zn1 | 128.16 (17) |
C4—C3—H3 | 119.9 | N13—N14—Zn1 | 123.37 (14) |
C3—C4—C5 | 117.0 (3) | N14—C14—C15 | 110.5 (2) |
C3—C4—C6 | 124.4 (3) | N14—C14—H24 | 124.8 |
C5—C4—C6 | 118.6 (3) | C15—C14—H24 | 124.8 |
N1—C5—C4 | 122.7 (3) | C16—C15—C14 | 105.0 (2) |
N1—C5—C5i | 117.61 (13) | C16—C15—H15 | 127.5 |
C4—C5—C5i | 119.68 (18) | C14—C15—H15 | 127.5 |
C6i—C6—C4 | 121.61 (19) | N13—C16—C15 | 109.0 (2) |
C6i—C6—H6 | 119.2 | N13—C16—H16 | 125.5 |
C4—C6—H6 | 119.2 | C15—C16—H16 | 125.5 |
Symmetry code: (i) −x+1, y, −z+3/2. |
Acknowledgements
This project was supported by the DFG (SFB 677 Function by Switching) and the State of Schleswig-Holstein. We thank Professor Dr Wolfgang Bensch for access to his experimental facilities.
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