Figure 1
The single-crystal X-ray structure of the ionic pair cis-[Mn(H2O)2(DMF)4]{Cu[12-MCCu(II)N(shi)-4]}·DMF associated with Cu1 and with displacement ellipsoids at the 50% probability level [symmetry code: (i) 2 − x, −y, 1 − z]. For clarity, only non-carbon atoms have been labeled, and the MC associated with Cu4, the lattice DMF molecule, H atoms, and disorder have been omitted. Color scheme: yellow – CuII, green – MnII, red – oxygen, blue – nitrogen, and gray – carbon. All figures were generated with the program Mercury (Macrae et al., 2020). |