Synthesis and crystal structure of two manganese-based 12-metallacrown-4 complexes: Na2(3-chloro­benzoate)2[12-MCMn(III)N(shi)-4](DMF)6 and MnNa(3-chloro­benzoate)3[12-MCMn(III)N(shi)-4](DMF)(H2O)4·4DMF·0.72H2O

Zaleski, C.M.; Zeller, M.

doi:10.1107/S2056989020006362

Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

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Figure 2
The single-crystal X-ray structure of MnNa(3-chlorobenzoate)₃[12-MC_{Mn(III)N(shi)}-4](DMF)(H₂O)₄·4DMF·0.72H₂O, 2, with displacement ellipsoids at the 50% probability level. (a) side view with only the metal atoms and heteroatoms of the axial ligands labelled for clarity and (b) top view with the axial ligand atoms omitted for clarity. In addition, the lattice DMF molecules, partially occupied water molecule, hydrogen atoms, and disorder have been omitted for clarity. See Fig. 1

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CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 76| Part 6| June 2020| Pages 848-856

https://doi.org/10.1107/S2056989020006362

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