Synthesis and crystal structure of two manganese-based 12-metallacrown-4 complexes: Na2(3-chloro­benzoate)2[12-MCMn(III)N(shi)-4](DMF)6 and MnNa(3-chloro­benzoate)3[12-MCMn(III)N(shi)-4](DMF)(H2O)4·4DMF·0.72H2O

Zaleski, C.M.; Zeller, M.

doi:10.1107/S2056989020006362

Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

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Figure 4
Intermolecular C—H⋯Cl interactions in 1 between the hydrogen atoms (white) of the methyl groups of the DMF associated with O11 and the chlorine atom of the neighboring 3-chlorobenzoate anion [symmetry code: (ii) x + 1, y, z + 1]. The interactions result in a one-dimensional network. For clarity the disorder has been omitted and only the atoms involved in the interactions have been labeled.

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 76| Part 6| June 2020| Pages 848-856

https://doi.org/10.1107/S2056989020006362

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