Crystal structure and characterization of a new copper(II) chloride dimer with meth­yl(pyridin-2-yl­methyl­idene)amine

Vassilyeva, O.Y.; Buvaylo, E.A.; Kokozay, V.N.; Melnyk, A.K.; Skelton, B.W.

doi:10.1107/S2056989020005903

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Volume 76| Part 6| June 2020| Pages 790-793

https://doi.org/10.1107/S2056989020005903

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Crystal structure and characterization of a new copper(II) chloride dimer with methyl(pyridin-2-ylmethylidene)amine

Olga Yu. Vassilyeva,^a ^* Elena A. Buvaylo,^a Vladimir N. Kokozay,^a Andrii K. Melnyk ^b and Brian W. Skelton ^c

^aDepartment of Chemistry, Taras Shevchenko National University of Kyiv, 64/13 Volodymyrska str., Kyiv 01601, Ukraine, ^bInstitute for Sorption and Problems of Endoecology, The National Academy of Sciences of Ukraine, 13 General Naumova str., Kyiv 03164, Ukraine, and ^cSchool of Molecular Sciences, M310, University of Western Australia, Perth, WA 6009, Australia
^*Correspondence e-mail: vassilyeva@univ.kiev.ua

Edited by S. Parkin, University of Kentucky, USA (Received 15 April 2020; accepted 29 April 2020; online 5 May 2020)

The new copper(II) complex, namely, di-μ-chlorido-bis{chlorido[methyl(pyridin-2-ylmethylidene)amine-κ²N,N′]copper(II)}, [Cu₂Cl₄(C₇H₈N₂)₂], (I), with the ligand 2-pyridylmethyl-N-methylimine (L, a product of Schiff base condensation between methylamine and 2-pyridinecarbaldehyde) is built of discrete centrosymmetric dimers. The coordination about the Cu^II ion can be described as distorted square pyramidal. The base of the pyramid consists of two nitrogen atoms from the bidentate chelate L [Cu—N = 2.0241 (9), 2.0374 (8) Å] and two chlorine atoms [Cu—Cl = 2.2500 (3), 2.2835 (3) Å]. The apical position is occupied by another Cl atom with the apical bond being significantly elongated at 2.6112 (3) Å. The trans angles of the base are 155.16 (3) and 173.79 (2)°. The Cu⋯Cu separation in the dimer is 3.4346 (3) Å. In the crystal structure, the loosely packed dimers are arranged in stacks propagating along the a axis. The X-band polycrystalline 77 K EPR spectrum of (I) demonstrates a typical axial pattern characteristic of mononuclear Cu^II complexes. Compound (I) is redox active and shows a cyclic voltammetric response with E_1/2 = −0.037 V versus silver–silver chloride electrode (SSCE) assignable to the reduction peak of Cu^II/Cu^I in methanol as solvent.

Keywords: crystal structure; Cu^II dimer; Schiff base ligand; 2-pyridinecarbaldehyde; methylamine.

CCDC reference: 1981381

1. Chemical context

The crystal structure of the title compound was determined as part of our ongoing research focused on the design and synthesis of the organic–inorganic halometallates with substituted imidazo[1,5-a]pyridinium cations. The first cation in the series, 2-methyl-3-(pyridin-2-yl)imidazo[1,5-a]pyridinium, was obtained by the replacement of a conventional aqueous solution of methylamine with its solid hydrochloride salt in the reaction with 2-pyridinecarbaldehyde (2-PCA) in methanol (Buvaylo et al., 2015 ). The cation is a result of the acid-catalysed oxidative condensation–cyclization between two molecules of 2-PCA and one molecule of CH₃NH₂ with the acid added as an adduct of the amine. The prepared in situ organic cation forms a halometallate salt in the subsequent interaction with divalent metal halides (M = Mn, Co, Zn, Cd) or can be isolated in salt form with Cl⁻/NO₃⁻ anions (Buvaylo et al., 2015; Vassilyeva et al., 2019a ,b , 2020 ).

The burgeoning research in the field of organic–inorganic halometallate-based hybrids in search of new applications (Wheaton et al., 2018 ; Yangui et al., 2019 ; Szklarz et al., 2020 ) prompted us to extend the developed reaction to the possible preparation of a mixed-metal hybrid halometallate by combining two different metals with the organic precursors:

Cu – NiCl₂·6H₂O – CH₃NH₂·HCl – 2-PCA – CH₃OH in air

Adhering to the direct synthesis approach (Kokozay et al., 2018 ), one of the metals was introduced in a zerovalent state. Our earlier studies showed that a metal powder was oxidized in solution to form a coordination compound in the presence of a proton-donating agent and dioxygen from the air, this being reduced to give H₂O.

Such a complication of the reaction system had an adverse effect, precluding formation of the desired heterocycle with the imidazo[1,5-a]pyridinium skeleton but afforded the Schiff base 2-pyridylmethyl-N-methylimine (L) instead. The latter is a pale-yellow liquid usually accessible by a straightforward interaction of 2-PCA with a 40% aqueous solution of methylamine (Schulz et al., 2009 ). In the present work, the imine L was isolated as the copper(II) complex [CuLCl₂]₂, (I), the dimeric structure of which has been established by X-ray crystallography. The title compound was characterized by elemental analysis, IR and EPR spectroscopy as well as cyclic voltammetry.

2. Structural commentary

The title complex crystallizes in the triclinic space group, P $[\overline{1}]$ ; the dimeric molecule is situated on a crystallographic inversion centre. The coordination about the Cu atom can be described as distorted square pyramidal. The angular structural index parameter, τ = (β − α)/60, evaluated from the two largest angles (α < β) in the five-coordinated geometry, which has ideal values of 1 for an equilateral bipyramid and 0 for a square pyramid, is equal to 0.31 (Table 1). The base of the pyramid consists of the two nitrogen atoms, N1, N22 from the bidentate chelate ligand L and the two chlorine atoms, Cl2 and the centrosymmetrically related Cl1 of the dimer (Fig. 1). Bond parameters are unexceptional (Table 1). The apical position is occupied by the Cl1 atom with the apical bond being significantly elongated at 2.6112 (3) Å compared to the Cu1—Cl1ⁱ bond length of 2.2835 (3) Å [symmetry code: (i) 1 − x, 1 − y, 1 − z]. The trans angles of the base are N22—Cu1—Cl2 = 155.16 (3)° and N1—Cu1—Cl1ⁱ = 173.79 (2)°. The cis angles at the copper atom vary from 80.20 (3) to 108.803 (10)°. The Cu⋯Cuⁱ separation in the dimer is 3.4346 (3) Å.

Table 1
Selected geometric parameters (Å, °)

Cu1—N1	2.0241 (9)	Cu1—Cl1ⁱ	2.2835 (3)
Cu1—N22	2.0374 (8)	Cu1—Cl1	2.6112 (3)
Cu1—Cl2	2.2500 (3)

N1—Cu1—N22	80.20 (3)	N1—Cu1—Cl1	88.81 (3)
N1—Cu1—Cl2	92.29 (2)	N22—Cu1—Cl1	94.79 (3)
N22—Cu1—Cl2	155.16 (3)	Cl2—Cu1—Cl1	108.803 (10)
N1—Cu1—Cl1ⁱ	173.79 (2)	Cl1ⁱ—Cu1—Cl1	91.137 (10)
N22—Cu1—Cl1ⁱ	93.61 (3)	Cu1ⁱ—Cl1—Cu1	88.864 (11)
Cl2—Cu1—Cl1ⁱ	93.600 (11)
Symmetry code: (i) -x+1, -y+1, -z+1.

Figure 1
Molecular structure and principal labelling of [CuLCl₂]₂ (I)

with ellipsoids at the 50% probability level.

3. Supramolecular features

In the crystal structure, the dimers are arranged in stacks propagating along the a-axis direction and demonstrate loose packing (Fig. 2). The shortest distance between the Cl atoms of adjacent molecules is 4.4204 (5) Å for Cl2⋯Cl2ⁱⁱ [symmetry code: (ii) 1 − x, 2 − y, 2 − z] and the minimum separation between Cu atoms inside the stack is as long as 7.1550 (5) Å for Cu1⋯Cu1ⁱⁱⁱ [symmetry code: (iii) −x, 1 − y, 1 − z]. The neighbouring pyridyl rings along the stack are coplanar, with the ring centroid distance being equal to the a-axis length [7.7054 (5) Å], which is too great for π–overlap.

Figure 2
Fragment of crystal packing of [CuLCl₂]₂ (I)

viewed along the c-axis direction.

4. Database survey

A survey of the Cambridge Structural Database (CSD, Version 5.40, October 2019; Groom et al., 2016 ) reveals that crystal structures containing L as a ligand comprise seven examples of divalent Mn, Ni, Zn and Pd as well as tetravalent Sn compounds. Among these metal complexes, the ligand demonstrates the same coordination mode as in compound (I) both in monomeric Ni [CSD refcode ADIQOV (Bai et al., 2012 ); NEKYOT (Pioquinto-Mendoza et al., 2013 )], Zn (BULSUX; Schulz et al., 2009), Pd (NEKYUZ; Pioquinto-Mendoza et al., 2013) and Sn coordination compounds (NELKAS and NELKEW; Guzmán-Percástegui et al., 2013 ) and Zn (BULSUX; Schulz et al., 2009) and Mn (VECDAJ; Bai et al., 2006 ) dimers. Out of all the L complexes, only the nickel ones accommodate two ligands in the coordination sphere of the metal ion.

5. IR and EPR spectroscopy measurements

A broad band centred at about 3440 cm⁻¹ in the IR spectrum of (I) could be due to adsorbed water molecules (see supporting information). Several bands arising above and below 3000 cm⁻¹ are assigned to aromatic =CH and alkyl –CH stretching, respectively. The characteristic ν(C=N) absorption of the Schiff base, which appears at 1652 cm⁻¹ as a sharp and rather intense band in the IR spectrum of L (Schulz et al., 2009), is detected at 1648 cm⁻¹ in the spectrum of (I). A number of sharp and intense absorptions are observed in the aromatic ring stretching (1600–1400 cm⁻¹) and C—H out-of-plane bending regions (800–700 cm⁻¹).

The X-band polycrystalline EPR spectra of (I) (Fig. 3) show a typical axial pattern characteristic for the mononuclear Cu^II complexes with no visible hyperfine structure. The spectra are almost temperature independent with a subtle change of their shapes seen between 295 and 77 K. The axial symmetry characteristics of (I), g_|| = 2.26 and g_⊥ = 2.06, with a g_|| > g_⊥ > 2.02 relation confirm a square-pyramidal coordination geometry for the metal centre suggested by the structural data. The additional low intensity lines at g_eff = 2.18, 2.16 and 2.12 may indicate exchange interactions between copper(II) ions in the dimer that are probably very weak.

Figure 3
X-band EPR spectra of [CuLCl₂]₂ (I)

in the solid state at 293 (red) and 77 K (black).

6. Cyclic voltammetry

Compound (I) is redox active and shows a cyclic voltammetric response in the potential range of −0.12 – 0.047 V (E_1/2 = −0.037 V vs SSCE), which is assignable to the reduction peak of Cu^II/Cu^I (Fig. 4). The complex exhibits quasi-reversible behaviour as indicated by the non-equivalent current intensity of cathodic and anodic peaks (i_c/i_a = 0.422) and a large separation between them (167 mV) (Crutchley et al., 1990 ). Since Cu^I prefers to be four-coordinate, the irreversibility of the Cu^II/Cu^I couple may be due to the dissociation of the dimers in solution. Reduction of copper(I) to copper(0) is associated with the irreversible peak II at −0.36 V vs SSCE. The latter process causes removal of the metal centre from the complex molecule. The resulting free ligand undergoes reduction at about −0.8 V, which is superimposed with the reduction peak of the solvent, as is evident from the comparison between the cyclic voltammograms of (I) and supporting electrolyte methanol solutions.

Figure 4
Cyclic voltammogram of [CuLCl₂]₂ (I)

, 0.1 mM in methanol mixed with 0.1 M acetate buffer (pH 4) and NaClO₄ (70:28:2) as supporting electrolyte at a glassy carbon electrode and Ag/AgCl as reference electrode (scan rate: 100 mV s⁻¹; T = 298 K).

7. Synthesis and crystallization

2-PCA (0.19 ml, 2 mmol) was magnetically stirred with CH₃NH₂·HCl (0.27 g, 4 mmol) in 20 ml methanol in a 50 ml Erlenmeyer flask at room temperature (r.t.) for an hour. Dry NiCl₂·6H₂O (0.23 g, 1 mmol) and Cu powder (0.06 g, 1.0 mmol) were added to the resulting yellow solution of the preformed Schiff base. The mixture immediately turned green and was magnetically stirred at 323 K in open air to achieve dissolution of the metallic copper (4 h). The resulting solution was filtered and left to evaporate at r.t. Green plate-like crystals of (I) suitable for X-ray analysis deposited over two days. They were filtered off, washed with diethyl ether and finally dried in air. Yield (based on Cu): 71%. Analysis calculated for C₁₄H₁₆Cl₄Cu₂N₄ (509.19): C 33.02, H 3.17, N 11.00%. Found: C 33.29, H 3.30, N 10.74%. IR (ν, cm⁻¹, KBr): 3438br, 3092, 3068, 3022, 2992, 2922, 1648, 1598vs, 1568, 1474, 1434, 1364, 1300s, 1272, 1224, 1156s, 1108, 1050, 1024vs, 980, 946, 882, 782vs, 646, 514, 476, 420.

8. Refinement

Crystal data, data collection and structure refinement details are summarized in Table 2. Anisotropic displacement parameters were employed for the non-hydrogen atoms. All hydrogen atoms were added at calculated positions and refined by use of a riding model with isotropic displacement parameters based on those of the parent atom (C—H = 0.95 Å, U_iso(H) = 1.2U_eqC for CH, C—H = 0.98 Å, U_iso(H) = 1.5U_eqC for CH₃).

Table 2
Experimental details

Crystal data
Chemical formula	[Cu₂Cl₄(C₇H₈N₂)₂]
M_r	509.19
Crystal system, space group	Triclinic, P $[\overline{1}]$
Temperature (K)	100
a, b, c (Å)	7.7054 (5), 7.7240 (5), 8.5606 (5)
α, β, γ (°)	103.659 (5), 98.803 (5), 110.273 (5)
V (Å³)	448.74 (5)
Z	1
Radiation type	Mo Kα
μ (mm⁻¹)	2.97
Crystal size (mm)	0.56 × 0.41 × 0.16

Data collection
Diffractometer	Oxford Diffraction Gemini diffractometer
Absorption correction	Analytical (CrysAlis PRO; Rigaku OD, 2016 $[Rigaku OD (2016). CrysAlis PRO. Rigaku Oxford Diffraction Ltd, Yarnton, England.]$ )
T_min, T_max	0.367, 0.669
No. of measured, independent and observed [I > 2σ(I)] reflections	13153, 4238, 3866
R_int	0.024
(sin θ/λ)_max (Å⁻¹)	0.827

Refinement
R[F² > 2σ(F²)], wR(F²), S	0.021, 0.054, 1.08
No. of reflections	4238
No. of parameters	111
H-atom treatment	H-atom parameters constrained
Δρ_max, Δρ_min (e Å⁻³)	0.68, −0.52
Computer programs: CrysAlis PRO (Rigaku OD, 2016 $[Rigaku OD (2016). CrysAlis PRO. Rigaku Oxford Diffraction Ltd, Yarnton, England.]$ ), SHELXT (Sheldrick, 2015a ), SHELXL2017 (Sheldrick, 2015b ), DIAMOND (Brandenburg, 1999 ), Mercury (Macrae, 2020 ) and WinGX (Farrugia, 2012 ).

Supporting information

CCDC reference: 1981381

Crystal structure: contains datablocks I, global. DOI: https://doi.org/10.1107/S2056989020005903/pk2625sup1.cif

Structure factors: contains datablock I. DOI: https://doi.org/10.1107/S2056989020005903/pk2625Isup2.hkl

IR spectrum. DOI: https://doi.org/10.1107/S2056989020005903/pk2625sup3.pdf

checkCIF report

Computing details top

Data collection: CrysAlis PRO (Rigaku OD, 2016); cell refinement: CrysAlis PRO (Rigaku OD, 2016); data reduction: CrysAlis PRO (Rigaku OD, 2016); program(s) used to solve structure: SHELXT (Sheldrick, 2015a); program(s) used to refine structure: SHELXL2017 (Sheldrick, 2015b); molecular graphics: DIAMOND (Brandenburg, 1999), Mercury (Macrae, 2020); software used to prepare material for publication: WinGX (Farrugia, 2012).

Di-µ-chlorido-bis{chlorido[methyl(pyridin-2-ylmethylidene)amine-κ²N,N']copper(II)} top

Crystal data top

[Cu₂Cl₄(C₇H₈N₂)₂]	Z = 1
M_r = 509.19	F(000) = 254
Triclinic, P1	D_x = 1.884 Mg m⁻³
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 7.7054 (5) Å	Cell parameters from 7922 reflections
b = 7.7240 (5) Å	θ = 4.0–37.5°
c = 8.5606 (5) Å	µ = 2.97 mm⁻¹
α = 103.659 (5)°	T = 100 K
β = 98.803 (5)°	Plate, green
γ = 110.273 (5)°	0.56 × 0.41 × 0.16 mm
V = 448.74 (5) Å³

Data collection top

Oxford Diffraction Gemini diffractometer	4238 independent reflections
Graphite monochromator	3866 reflections with I > 2σ(I)
Detector resolution: 10.4738 pixels mm^-1	R_int = 0.024
ω scans	θ_max = 36.0°, θ_min = 4.2°
Absorption correction: analytical (CrysAlis Pro; Rigaku OD, 2016)	h = −12→12
T_min = 0.367, T_max = 0.669	k = −12→12
13153 measured reflections	l = −14→14

Refinement top

Refinement on F²	Hydrogen site location: inferred from neighbouring sites
Least-squares matrix: full	H-atom parameters constrained
R[F² > 2σ(F²)] = 0.021	w = 1/[σ²(F_o²) + (0.0232P)² + 0.1399P] where P = (F_o² + 2F_c²)/3
wR(F²) = 0.054	(Δ/σ)_max = 0.002
S = 1.08	Δρ_max = 0.68 e Å⁻³
4238 reflections	Δρ_min = −0.52 e Å⁻³
111 parameters	Extinction correction: SHELXL-2017/1 (Sheldrick 2015b), Fc^*=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4
0 restraints	Extinction coefficient: 0.018 (2)

Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. One low theta reflection was omitted from the refinement.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Cu1	0.50923 (2)	0.72999 (2)	0.57914 (2)	0.01020 (4)
Cl1	0.73459 (3)	0.54548 (3)	0.59992 (3)	0.01344 (5)
Cl2	0.36774 (3)	0.72631 (3)	0.79030 (3)	0.01500 (5)
N1	0.73406 (12)	0.98020 (12)	0.71584 (10)	0.01113 (13)
C2	0.82713 (14)	1.08198 (14)	0.62321 (12)	0.01197 (15)
C21	0.74454 (15)	0.99108 (15)	0.44328 (12)	0.01362 (16)
H21	0.797176	1.050864	0.36667	0.016*
N22	0.59926 (13)	0.82859 (13)	0.39284 (10)	0.01293 (14)
C23	0.51841 (17)	0.72996 (17)	0.21469 (12)	0.01786 (18)
H23A	0.580724	0.81486	0.153155	0.027*
H23B	0.380672	0.699047	0.18678	0.027*
H23C	0.539512	0.609696	0.184401	0.027*
C3	0.98700 (15)	1.25492 (15)	0.69291 (13)	0.01513 (17)
H3	1.047781	1.324625	0.625083	0.018*
C4	1.05621 (15)	1.32381 (15)	0.86576 (14)	0.01670 (18)
H4	1.166445	1.441282	0.917816	0.02*
C5	0.96252 (15)	1.21913 (15)	0.96081 (13)	0.01547 (17)
H5	1.008301	1.263236	1.078576	0.019*
C6	0.79997 (14)	1.04805 (14)	0.88085 (12)	0.01344 (16)
H6	0.734271	0.977774	0.946118	0.016*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Cu1	0.01109 (6)	0.00923 (6)	0.00822 (5)	0.00253 (4)	0.00183 (4)	0.00182 (4)
Cl1	0.01209 (9)	0.01174 (9)	0.01270 (9)	0.00393 (7)	−0.00076 (7)	0.00086 (7)
Cl2	0.01607 (10)	0.01358 (10)	0.01276 (9)	0.00224 (8)	0.00631 (8)	0.00342 (7)
N1	0.0127 (3)	0.0098 (3)	0.0105 (3)	0.0037 (3)	0.0030 (3)	0.0034 (2)
C2	0.0132 (4)	0.0110 (4)	0.0128 (4)	0.0046 (3)	0.0050 (3)	0.0049 (3)
C21	0.0170 (4)	0.0150 (4)	0.0125 (4)	0.0082 (3)	0.0061 (3)	0.0065 (3)
N22	0.0162 (4)	0.0142 (4)	0.0094 (3)	0.0075 (3)	0.0029 (3)	0.0037 (3)
C23	0.0238 (5)	0.0209 (5)	0.0087 (4)	0.0100 (4)	0.0027 (3)	0.0037 (3)
C3	0.0143 (4)	0.0118 (4)	0.0188 (4)	0.0034 (3)	0.0063 (3)	0.0052 (3)
C4	0.0136 (4)	0.0119 (4)	0.0200 (4)	0.0021 (3)	0.0033 (3)	0.0020 (3)
C5	0.0149 (4)	0.0130 (4)	0.0135 (4)	0.0032 (3)	0.0008 (3)	0.0009 (3)
C6	0.0148 (4)	0.0120 (4)	0.0102 (3)	0.0029 (3)	0.0015 (3)	0.0024 (3)

Geometric parameters (Å, º) top

Cu1—N1	2.0241 (9)	N22—C23	1.4580 (13)
Cu1—N22	2.0374 (8)	C23—H23A	0.98
Cu1—Cl2	2.2500 (3)	C23—H23B	0.98
Cu1—Cl1ⁱ	2.2835 (3)	C23—H23C	0.98
Cu1—Cl1	2.6112 (3)	C3—C4	1.3953 (15)
N1—C6	1.3320 (12)	C3—H3	0.95
N1—C2	1.3561 (12)	C4—C5	1.3867 (15)
C2—C3	1.3842 (14)	C4—H4	0.95
C2—C21	1.4663 (14)	C5—C6	1.3953 (14)
C21—N22	1.2796 (13)	C5—H5	0.95
C21—H21	0.95	C6—H6	0.95

N1—Cu1—N22	80.20 (3)	C21—N22—Cu1	114.21 (7)
N1—Cu1—Cl2	92.29 (2)	C23—N22—Cu1	126.45 (7)
N22—Cu1—Cl2	155.16 (3)	N22—C23—H23A	109.5
N1—Cu1—Cl1ⁱ	173.79 (2)	N22—C23—H23B	109.5
N22—Cu1—Cl1ⁱ	93.61 (3)	H23A—C23—H23B	109.5
Cl2—Cu1—Cl1ⁱ	93.600 (11)	N22—C23—H23C	109.5
N1—Cu1—Cl1	88.81 (3)	H23A—C23—H23C	109.5
N22—Cu1—Cl1	94.79 (3)	H23B—C23—H23C	109.5
Cl2—Cu1—Cl1	108.803 (10)	C2—C3—C4	118.02 (9)
Cl1ⁱ—Cu1—Cl1	91.137 (10)	C2—C3—H3	121
Cu1ⁱ—Cl1—Cu1	88.864 (11)	C4—C3—H3	121
C6—N1—C2	118.79 (8)	C5—C4—C3	119.36 (9)
C6—N1—Cu1	127.36 (7)	C5—C4—H4	120.3
C2—N1—Cu1	113.81 (6)	C3—C4—H4	120.3
N1—C2—C3	122.78 (9)	C4—C5—C6	118.99 (10)
N1—C2—C21	113.95 (8)	C4—C5—H5	120.5
C3—C2—C21	123.26 (9)	C6—C5—H5	120.5
N22—C21—C2	117.82 (8)	N1—C6—C5	122.05 (9)
N22—C21—H21	121.1	N1—C6—H6	119
C2—C21—H21	121.1	C5—C6—H6	119
C21—N22—C23	119.31 (9)

C6—N1—C2—C3	−0.69 (15)	N1—C2—C3—C4	1.35 (16)
Cu1—N1—C2—C3	−178.63 (8)	C21—C2—C3—C4	−177.87 (10)
C6—N1—C2—C21	178.59 (9)	C2—C3—C4—C5	−0.67 (16)
Cu1—N1—C2—C21	0.66 (11)	C3—C4—C5—C6	−0.57 (17)
N1—C2—C21—N22	−0.97 (14)	C2—N1—C6—C5	−0.66 (15)
C3—C2—C21—N22	178.31 (10)	Cu1—N1—C6—C5	176.97 (8)
C2—C21—N22—C23	−177.41 (9)	C4—C5—C6—N1	1.29 (17)
C2—C21—N22—Cu1	0.77 (12)

Symmetry code: (i) −x+1, −y+1, −z+1.

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
C6—H6···Cl2	0.95	2.71	3.2301 (10)	115

Funding information

Funding for this research was provided by: Ministry of Education and Science of Ukraine (project No. 19BF037-05).

References

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