Crystal structure of La₂₄Ru₁₁

The compound La₂₄Ru₁₁ (tetra­cosa­lanthanum undeca­ruthenium) crystallizes in a Ce₂₄Co₁₁-type structure. The non-centrosymmetric crystal structure (space group P6₃mc) contains RuLa₆ trigonal prisms, La₆ octa­hedra and LaRu₄ tetra­hedra and is closely related to that of Ce₂₃Ni₇Mg₄. This communication highlights the crystal-chemical similarities and points out the differences between the two structures. All of the tested crystals were inversion twins.

1. Chemical context

The La–Ru system has been extensively studied (Palenzona & Cirafici, 1989). The phase diagram contains five binary phases: the Laves phase, LaRu₂ (Compton & Matthias, 1959), with the MgCu₂-type structure; La₅Ru₃ (Palenzona & Canepa, 1990a); La₇Ru₃ (Palenzona & Canepa, 1990b), with the Sr₇Pt₃-type structure; La₅Ru₂ (Palenzona, 1979), with the Mn₅C₂-type structure and La₃Ru (Palenzona, 1979), with the cementite-type structure. According to a recent study (Carlsson, 2015), the phase La₅Ru₃ is believed to be a part of an incommensurate-composite-structure family related to Y₄₄Ru₂₅.

During a systematic search for optimal crystal-growth conditions for La₅Ru₃, the new compound, La₂₄Ru₁₁, was obtained as a secondary product. It crystallizes with a hexa­gonal unit cell, space group P6₃mc (186), and with a Ce₂₄Co₁₁ structure type (Larson & Cromer, 1962).

According to the Pearson's Crystal Data (Villars & Cenzual, 2019), the composition ratio of 24:11 is not common and only a few binary compounds having this composition have been reported (Singh & Raman, 1968; Raevskaya et al., 1994). However, there are several ternary inter­metallics with a rare-earth content higher than 60 at.%, including Yb₉CuMg₄ (De Negri et al., 2016), La₄₃Ni₁₇Mg₅ (Solokha et al., 2009a) and Ce₂₃Ni₇Mg₄ (Solokha et al., 2009b), which share some structural features with the title compound, La₂₄Ru₁₁, described below.

2. Structural commentary

The hexa­gonal primitive structure of La₂₄Ru₁₁, containing 70 atoms per cell, was solved with data acquired by a single-crystal X-ray diffraction measurement using a charge-flipping algorithm (Oszlányi & Süto, 2004, 2005) in the SUPERFLIP program (Palatinus & Chapuis, 2007) implemented in the JANA2006 package (Petříček et al., 2014).

The structure is closely related to that of Ce₂₃Ni₇Mg₄ (Solokha et al., 2009b) and can be described in terms of stacking along (00z) of the three different slabs A, B and C shown in Fig. 1(a), 1(b) and 1(c), respectively.

Figure 1 (a),(b) Distribution of triads of RuLa6 trigonal prisms (red) within slab A and slab B, respectively; (c) distribution of RuLa6 trigonal prisms (red), La6 octa­hedra (blue) and LaRu4 tetra­hedra (green) within slab C.

Slabs A and B are formed from trigonal prisms (consisting of six lanthanum atoms coordinated to a central ruthenium atom), three of which are joined together by sharing common edges and a vertex, to form triads. The two slabs are very similar to each other: slab B may be generated simply by rotating slab A by a 60° angle around the sixfold rotation axis of the lattice and translating it by the vector (2/3,2/3,0).

Structures containing only A and B slabs have previously been reported; for example, Ru₇B₃ (Hyde et al., 1979) consists of an infinite packing of ABAB slabs in which the trigonal prisms are formed by ruthenium atoms coordinating to central boron atoms. About 50 isostructural binary compounds with general composition R₇T₃, formed by a transition metal (T) with a lanthanide/actinide (R), have been discovered up to now and include Th₇Fe₃, Th₇Co₃ and Th₇Ni₃ (Palenzona & Cirafici, 1989), Nd₇Pd₃ (Moreau & Parthé, 1973) and Pr₇Pd₃ (Moreau & Parthé, 1973).

Slab C shown in Fig. 1(c) consists of three polyhedra: isolated Ru-centred trigonal prisms of lanthanum atoms (red), joining slabs A and B and oriented along the (00z) direction, empty La₆ octa­hedra (blue) and La-centred ruthenium tetra­hedra (green). In both La₂₄Ru₁₁ and the related structure, Ce₂₃Ni₇Mg₄ (Solokha et al., 2009b), the empty octa­hedra are formed by the rare-earth component. The compositional difference between these two structures arises from the the presence of an additional atom of La inside each ruthenium tetra­hedron in the title compound.

The final stacking sequence is ABCA′B′C′ (Fig. 2) where A′, B′ and C′ are the slabs A, B and C, respectively, rotated by a 60° angle around the sixfold rotation axis of the lattice.

Figure 2 ABCA′B′C′ stacking of slabs formed by trigonal prisms (red), octa­hedra (blue) and tetra­hedra (green) in La24Ru11.

3. Synthesis and crystallization

A sample weighing 0.5001 g and with nominal composition La₆₅Ru₃₅ was prepared from powdered metal constituents in stoichiometric amounts (m_La = 0.3593 g and m_Ru = 0.1408 g). The powders were weighed in a glovebox, mixed together and pressed into a pellet. The pellet was then arc-melted (necessary to obtain total melting, since the Ru–La system contains high-melting inter­metallics) in a low-pressure Ar chamber to prevent oxidation and then annealed for 10 days at 800°C. The alloy was crushed and a number of crystals were extracted and analysed. In addition to the title compound, La₂₄Ru₁₁, a small qu­antity of the phase LaRu₂ (cF24-MgCu₂) was also present.

4. Refinement details

Crystal data, data collection and structure refinement details are summarized in Table 1. All of the tested crystals were twinnedby inversion, as confirmed by Flack-parameter refinement (Flack, 1983). In addition, a weak diffuse scattering in the diffraction pattern (probably due to stacking faults), is clearly visible in the (0kl) layer for fifth-order reflections (Fig. 3), which tend to overlap with their neighbours, forming streaks. This phenomenon is likely to be responsible for the slightly elevated values of residual electron density after the final refinement cycle. A B-C type 1 Gaussian isotropic extinction correction (Becker & Coppens, 1974a,b) was applied.

Table 1
Experimental details

Crystal data
Chemical formula	La24Ru11
Mr	4445.9
Crystal system, space group	Hexagonal, P63mc
Temperature (K)	298
a, c (Å)	10.0627 (18), 22.801 (3)
V (Å^3)	1999.5 (8)
Z	2
Radiation type	Mo Kα
μ (mm^−1)	29.00
Crystal size (mm)	0.23 × 0.2 × 0.2
Data collection
Diffractometer	Rigaku Oxford Diffraction Xcalibur, Eos
Absorption correction	Analytical (CrysAlis PRO, Rigaku OD, 2019) [Analytical numeric absorption correction using a multifaceted crystal model based on Clark & Reid (1995)]
Tmin, Tmax	0.014, 0.059
No. of measured, independent and observed [I > 3σ(I)] reflections	6801, 1699, 1069
Rint	0.094
(sin θ/λ)max (Å^−1)	0.646
Refinement
R[F^2 > 2σ(F^2)], wR(F), S	0.057, 0.049, 1.24
No. of reflections	1069
No. of parameters	76
Δρmax, Δρmin (e Å^−3)	3.36, −3.12
Absolute structure	Flack (1983), 429 Friedel pairs used in the refinement
Absolute structure parameter	0.35 (9)
Computer programs: CrysAlis PRO (Rigaku OD, 2019), JANA2006 (Petříček et al., 2014) and DIAMOND (Brandenburg & Putz, 2019).

Figure 3 Diffraction pattern of the (0kl) layer showing twinned peaks and weak diffuse scattering, especially for the fifth-order reflections.

Supporting information

Computing details

Data collection: CrysAlis PRO (Rigaku OD, 2019); cell refinement: CrysAlis PRO (Rigaku OD, 2019); data reduction: CrysAlis PRO (Rigaku OD, 2019); program(s) used to solve structure: Jana2006 (Petříček et al., 2014); program(s) used to refine structure: Jana2006 (Petříček et al., 2014); molecular graphics: DIAMOND (Brandenburg & Putz, 2019).

Tetracosalanthanum undecaruthenium

Crystal data

La24Ru11	Dx = 7.385 Mg m^−3
Mr = 4445.9	Mo Kα radiation, λ = 0.71073 Å
Hexagonal, P63mc	Cell parameters from 1576 reflections
Hall symbol: P 6c -2c	θ = 4.8–27.3°
a = 10.0627 (18) Å	µ = 29.00 mm^−1
c = 22.801 (3) Å	T = 298 K
V = 1999.5 (8) Å^3	Hexagonal, grey
Z = 2	0.23 × 0.2 × 0.2 mm
F(000) = 3704

Data collection

Rigaku Oxford Diffraction Xcalibur, Eos diffractometer	1699 independent reflections
Radiation source: X-ray tube	1069 reflections with I > 3σ(I)
Graphite monochromator	Rint = 0.094
Detector resolution: 8.0683 pixels mm^-1	θmax = 27.3°, θmin = 4.8°
ω scans	h = −6→11
Absorption correction: analytical (CrysAlisPro, Rigaku OD, 2019) [Analytical numeric absorption correction using a multifaceted crystal model based on Clark & Reid (1995)]	k = −13→10
Tmin = 0.014, Tmax = 0.059	l = −29→29
6801 measured reflections

Refinement

Refinement on F	Weighting scheme based on measured s.u.'s w = 1/(σ^2(F) + 0.0001F^2)
R[F^2 > 2σ(F^2)] = 0.057	(Δ/σ)max = 0.0003
wR(F^2) = 0.049	Δρmax = 3.36 e Å^−3
S = 1.24	Δρmin = −3.12 e Å^−3
1069 reflections	Extinction correction: B-C type 1 Gaussian isotropic (Becker & Coppens, 1974a,b)
76 parameters	Extinction coefficient: 100
0 restraints	Absolute structure: Flack (1983), 429 Friedel pairs used in the refinement
1 constraint	Absolute structure parameter: 0.35 (9)

Special details

Refinement. Data collection and reduction were performed with CrysAlis PRO (Rigaku OD, 2019) software. Structure solution and refinement were performed with JANA2006 (Petříček et al., 2014). During refinement, site occupation factors were checked, but no hints of disorder were found. In the final refinement cycles, all the atoms were refined with anisotropic thermal parameters. DIAMOND Version 4.6.3 (Brandenburg & Putz, 2019) was used for structure visualization and polyhedra construction.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
La1	1	1	0.6280 (3)	0.0285 (15)
La2	0.45874 (16)	0.9175 (3)	0.6059 (3)	0.0274 (12)
La3	0.5908 (4)	0.79539 (19)	0.4730 (3)	0.0270 (13)
La4	0.87616 (17)	0.7523 (3)	0.8272 (3)	0.0274 (11)
La5	0.4014 (3)	0.20071 (17)	0.2379 (3)	0.0300 (12)
La6	0.79826 (19)	0.5965 (4)	0.5186 (3)	0.0262 (13)
La7	0.20264 (16)	0.4053 (3)	0.1801 (3)	0.0298 (12)
La8	0.333333	0.666667	0.3124 (3)	0.0260 (15)
La9	0.9168 (3)	0.45838 (17)	0.3769 (3)	0.0274 (12)
La10	1	1	0.4706 (3)	0.0299 (17)
Ru1	0.8492 (3)	0.6983 (5)	0.4062 (3)	0.0301 (19)
Ru2	0.666667	0.333333	0.5929 (3)	0.030 (2)
Ru3	0.4838 (2)	0.5162 (2)	0.2522 (3)	0.0304 (17)
Ru4	0.6909 (5)	0.8455 (3)	0.5825 (3)	0.0342 (19)
Ru5	1	1	0.748776	0.039 (2)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
La1	0.031 (2)	0.031 (2)	0.0243 (17)	0.0153 (10)	0	0
La2	0.0274 (13)	0.0271 (19)	0.0276 (10)	0.0135 (9)	−0.0004 (6)	−0.0007 (12)
La3	0.029 (2)	0.0281 (15)	0.0241 (11)	0.0145 (10)	0.0004 (12)	0.0002 (6)
La4	0.0293 (13)	0.0287 (18)	0.0240 (9)	0.0144 (9)	0.0000 (6)	0.0000 (12)
La5	0.0307 (19)	0.0300 (13)	0.0296 (12)	0.0153 (9)	0.0067 (12)	0.0033 (6)
La6	0.0249 (15)	0.031 (2)	0.0245 (11)	0.0156 (11)	0.0007 (6)	0.0013 (11)
La7	0.0325 (15)	0.0271 (19)	0.0280 (11)	0.0136 (10)	0.0016 (6)	0.0032 (12)
La8	0.0189 (19)	0.0189 (19)	0.040 (2)	0.0095 (10)	0	0
La9	0.0267 (19)	0.0272 (14)	0.0281 (10)	0.0133 (10)	−0.0018 (12)	−0.0009 (6)
La10	0.031 (2)	0.031 (2)	0.0286 (19)	0.0153 (12)	0	0
Ru1	0.030 (2)	0.036 (3)	0.0264 (16)	0.0181 (15)	0.0007 (9)	0.0013 (17)
Ru2	0.030 (3)	0.030 (3)	0.028 (3)	0.0152 (15)	0	0
Ru3	0.034 (2)	0.034 (2)	0.0303 (16)	0.022 (2)	−0.0001 (8)	0.0001 (8)
Ru4	0.021 (3)	0.033 (3)	0.045 (2)	0.0104 (13)	−0.0056 (18)	−0.0028 (9)
Ru5	0.046 (3)	0.046 (3)	0.025 (3)	0.0228 (16)	0	0

Geometric parameters (Å, º)

La1—La7^i	3.727 (5)	La4—La10^xii	3.918 (8)
La1—La7^ii	3.727 (5)	La4—Ru1^viii	3.023 (8)
La1—La7^iii	3.727 (5)	La4—Ru1^xiii	3.023 (7)
La1—La10	3.587 (11)	La4—Ru5	2.803 (5)
La1—Ru4	2.886 (6)	La5—La7	3.754 (5)
La1—Ru4^iv	2.886 (6)	La5—La7^xiv	3.754 (4)
La1—Ru4^v	2.886 (6)	La5—La9^x	3.885 (8)
La1—Ru5	2.755 (8)	La5—La9^xv	3.885 (8)
La2—La2^vi	3.786 (4)	La5—Ru3	2.871 (3)
La2—La2^vii	3.786 (4)	La5—Ru3^x	2.871 (5)
La2—La3	3.754 (8)	La6—La7^i	3.683 (9)
La2—La3^vi	3.754 (8)	La6—La9	3.932 (8)
La2—La5^i	3.758 (8)	La6—La9^x	3.932 (8)
La2—La5^viii	3.758 (8)	La6—La10	3.682 (5)
La2—La6^vi	3.748 (7)	La6—Ru1	2.713 (9)
La2—La6^v	3.748 (6)	La6—Ru2	2.852 (7)
La2—La7^viii	3.596 (7)	La7—La7^vi	3.945 (4)
La2—La7^iii	3.596 (5)	La7—La7^vii	3.945 (4)
La2—Ru4	2.822 (6)	La7—La8	3.780 (8)
La2—Ru4^vi	2.822 (4)	La7—Ru2^xvi	3.024 (7)
La3—La3^vi	3.886 (5)	La7—Ru3	2.965 (6)
La3—La3^vii	3.886 (4)	La7—Ru3^vii	2.965 (6)
La3—La4^ix	3.610 (9)	La8—La9^xvii	3.916 (5)
La3—La6	3.691 (6)	La8—La9^x	3.916 (5)
La3—La6^v	3.691 (4)	La8—La9^v	3.916 (5)
La3—La9^x	3.856 (6)	La8—Ru3	2.960 (5)
La3—La9^v	3.856 (7)	La8—Ru3^vi	2.960 (5)
La3—La10	3.567 (4)	La8—Ru3^vii	2.960 (5)
La3—Ru4	2.644 (9)	La9—La9^x	3.775 (5)
La4—La4^iv	3.738 (4)	La9—La9^xv	3.775 (4)
La4—La4^v	3.738 (5)	La9—Ru1	2.895 (6)
La4—La5^i	3.673 (6)	La9—Ru1^xv	2.895 (4)
La4—La5^ii	3.673 (6)	La9—Ru3^xv	3.016 (9)
La4—La7^i	3.623 (9)	La10—Ru1	3.012 (6)
La4—La8^i	3.667 (4)	La10—Ru1^iv	3.012 (6)
La4—La9^xi	3.813 (5)	La10—Ru1^v	3.012 (7)
La4—La9^viii	3.813 (4)
La7^i—La1—La7^ii	110.31 (14)	La2^xviii—La7—La7^vi	56.73 (9)
La7^i—La1—La7^iii	110.31 (14)	La2^xviii—La7—La7^vii	108.92 (11)
La7^i—La1—La10	108.62 (15)	La2^xviii—La7—La8	107.30 (10)
La7^i—La1—Ru4	70.89 (10)	La2^xviii—La7—Ru2^xvi	65.98 (11)
La7^i—La1—Ru4^iv	70.89 (11)	La2^xviii—La7—Ru3	63.25 (15)
La7^i—La1—Ru4^v	177.6 (3)	La2^xviii—La7—Ru3^vii	152.50 (10)
La7^i—La1—Ru5	71.38 (15)	La4^xvi—La7—La5	59.68 (13)
La7^ii—La1—La7^iii	110.31 (14)	La4^xvi—La7—La5^xxi	59.68 (12)
La7^ii—La1—La10	108.62 (15)	La4^xvi—La7—La6^xvi	157.48 (12)
La7^ii—La1—Ru4	177.6 (3)	La4^xvi—La7—La7^vi	109.16 (17)
La7^ii—La1—Ru4^iv	70.89 (11)	La4^xvi—La7—La7^vii	109.16 (18)
La7^ii—La1—Ru4^v	70.89 (14)	La4^xvi—La7—La8	59.33 (13)
La7^ii—La1—Ru5	71.38 (15)	La4^xvi—La7—Ru2^xvi	153.4 (2)
La7^iii—La1—La10	108.62 (15)	La4^xvi—La7—Ru3	67.10 (16)
La7^iii—La1—Ru4	70.89 (12)	La4^xvi—La7—Ru3^vii	67.10 (17)
La7^iii—La1—Ru4^iv	177.6 (3)	La5—La7—La5^xxi	107.61 (15)
La7^iii—La1—Ru4^v	70.89 (15)	La5—La7—La6^xvi	110.42 (16)
La7^iii—La1—Ru5	71.38 (15)	La5—La7—La7^vi	90.45 (9)
La10—La1—Ru4	68.94 (19)	La5—La7—La7^vii	144.57 (14)
La10—La1—Ru4^iv	68.9 (2)	La5—La7—La8	90.35 (15)
La10—La1—Ru4^v	68.94 (19)	La5—La7—Ru2^xvi	126.05 (10)
La10—La1—Ru5	180	La5—La7—Ru3	48.87 (9)
Ru4—La1—Ru4^iv	107.8 (2)	La5—La7—Ru3^vii	125.3 (2)
Ru4—La1—Ru4^v	107.8 (2)	La5^xxi—La7—La6^xvi	110.42 (14)
Ru4—La1—Ru5	111.06 (19)	La5^xxi—La7—La7^vi	144.57 (17)
Ru4^iv—La1—Ru4^v	107.8 (2)	La5^xxi—La7—La7^vii	90.45 (11)
Ru4^iv—La1—Ru5	111.1 (2)	La5^xxi—La7—La8	90.35 (15)
Ru4^v—La1—Ru5	111.06 (19)	La5^xxi—La7—Ru2^xvi	126.05 (13)
La2^vi—La2—La2^vii	60.00 (9)	La5^xxi—La7—Ru3	125.3 (2)
La2^vi—La2—La3	90.76 (14)	La5^xxi—La7—Ru3^vii	48.87 (9)
La2^vi—La2—La3^vi	59.72 (13)	La6^xvi—La7—La7^vi	90.21 (14)
La2^vi—La2—La5^i	91.66 (14)	La6^xvi—La7—La7^vii	90.21 (16)
La2^vi—La2—La5^viii	59.76 (12)	La6^xvi—La7—La8	143.19 (13)
La2^vi—La2—La6^vi	107.90 (12)	La6^xvi—La7—Ru2^xvi	49.12 (15)
La2^vi—La2—La6^v	146.9 (2)	La6^xvi—La7—Ru3	123.75 (16)
La2^vi—La2—La7^viii	108.92 (12)	La6^xvi—La7—Ru3^vii	123.75 (18)
La2^vi—La2—La7^iii	150.8 (2)	La7^vi—La7—La7^vii	60.00 (9)
La2^vi—La2—Ru4	106.59 (12)	La7^vi—La7—La8	58.54 (12)
La2^vi—La2—Ru4^vi	47.87 (14)	La7^vi—La7—Ru2^xvi	49.28 (13)
La2^vii—La2—La3	59.72 (13)	La7^vi—La7—Ru3	48.29 (11)
La2^vii—La2—La3^vi	90.76 (15)	La7^vi—La7—Ru3^vii	95.77 (13)
La2^vii—La2—La5^i	59.76 (13)	La7^vii—La7—La8	58.54 (12)
La2^vii—La2—La5^viii	91.66 (14)	La7^vii—La7—Ru2^xvi	49.28 (13)
La2^vii—La2—La6^vi	146.9 (2)	La7^vii—La7—Ru3	95.77 (12)
La2^vii—La2—La6^v	107.90 (13)	La7^vii—La7—Ru3^vii	48.29 (12)
La2^vii—La2—La7^viii	150.8 (2)	La8—La7—Ru2^xvi	94.06 (15)
La2^vii—La2—La7^iii	108.92 (12)	La8—La7—Ru3	50.31 (12)
La2^vii—La2—Ru4	47.87 (9)	La8—La7—Ru3^vii	50.31 (12)
La2^vii—La2—Ru4^vi	106.59 (14)	Ru2^xvi—La7—Ru3	96.82 (12)
La3—La2—La3^vi	62.33 (14)	Ru2^xvi—La7—Ru3^vii	96.82 (15)
La3—La2—La5^i	107.05 (13)	Ru3—La7—Ru3^vii	100.0 (2)
La3—La2—La5^viii	147.62 (11)	La4^xvi—La8—La4^ix	119.17 (9)
La3—La2—La6^vi	91.87 (18)	La4^xvi—La8—La4^xxii	119.17 (7)
La3—La2—La6^v	58.94 (11)	La4^xvi—La8—La7	58.21 (13)
La3—La2—La7^viii	149.28 (18)	La4^xvi—La8—La7^vi	111.92 (15)
La3—La2—La7^iii	106.97 (12)	La4^xvi—La8—La7^vii	111.92 (14)
La3—La2—Ru4	44.68 (17)	La4^xvi—La8—La9^xvii	60.27 (7)
La3—La2—Ru4^vi	106.2 (2)	La4^xvi—La8—La9^x	60.27 (7)
La3^vi—La2—La5^i	147.62 (11)	La4^xvi—La8—La9^v	152.7 (2)
La3^vi—La2—La5^viii	107.05 (10)	La4^xvi—La8—Ru3	66.52 (8)
La3^vi—La2—La6^vi	58.94 (13)	La4^xvi—La8—Ru3^vi	157.6 (3)
La3^vi—La2—La6^v	91.87 (18)	La4^xvi—La8—Ru3^vii	66.52 (9)
La3^vi—La2—La7^viii	106.97 (14)	La4^ix—La8—La4^xxii	119.17 (9)
La3^vi—La2—La7^iii	149.28 (18)	La4^ix—La8—La7	111.92 (15)
La3^vi—La2—Ru4	106.2 (2)	La4^ix—La8—La7^vi	58.21 (13)
La3^vi—La2—Ru4^vi	44.68 (17)	La4^ix—La8—La7^vii	111.92 (15)
La5^i—La2—La5^viii	64.37 (14)	La4^ix—La8—La9^xvii	152.7 (2)
La5^i—La2—La6^vi	152.73 (16)	La4^ix—La8—La9^x	60.27 (8)
La5^i—La2—La6^v	108.92 (11)	La4^ix—La8—La9^v	60.27 (10)
La5^i—La2—La7^viii	96.02 (19)	La4^ix—La8—Ru3	66.52 (10)
La5^i—La2—La7^iii	61.34 (11)	La4^ix—La8—Ru3^vi	66.52 (10)
La5^i—La2—Ru4	65.26 (18)	La4^ix—La8—Ru3^vii	157.6 (3)
La5^i—La2—Ru4^vi	126.9 (2)	La4^xxii—La8—La7	111.92 (15)
La5^viii—La2—La6^vi	108.92 (13)	La4^xxii—La8—La7^vi	111.92 (15)
La5^viii—La2—La6^v	152.73 (16)	La4^xxii—La8—La7^vii	58.21 (13)
La5^viii—La2—La7^viii	61.34 (13)	La4^xxii—La8—La9^xvii	60.27 (7)
La5^viii—La2—La7^iii	96.02 (19)	La4^xxii—La8—La9^x	152.7 (2)
La5^viii—La2—Ru4	126.9 (2)	La4^xxii—La8—La9^v	60.27 (9)
La5^viii—La2—Ru4^vi	65.26 (17)	La4^xxii—La8—Ru3	157.6 (3)
La6^vi—La2—La6^v	64.01 (12)	La4^xxii—La8—Ru3^vi	66.52 (9)
La6^vi—La2—La7^viii	60.16 (15)	La4^xxii—La8—Ru3^vii	66.52 (10)
La6^vi—La2—La7^iii	94.82 (11)	La7—La8—La7^vi	62.92 (13)
La6^vi—La2—Ru4	123.6 (2)	La7—La8—La7^vii	62.92 (13)
La6^vi—La2—Ru4^vi	62.57 (15)	La7—La8—La9^xvii	91.15 (10)
La6^v—La2—La7^viii	94.82 (11)	La7—La8—La9^x	91.15 (11)
La6^v—La2—La7^iii	60.16 (13)	La7—La8—La9^v	149.09 (19)
La6^v—La2—Ru4	62.57 (12)	La7—La8—Ru3	50.42 (12)
La6^v—La2—Ru4^vi	123.6 (2)	La7—La8—Ru3^vi	99.4 (2)
La7^viii—La2—La7^iii	66.54 (11)	La7—La8—Ru3^vii	50.42 (13)
La7^viii—La2—Ru4	140.14 (15)	La7^vi—La8—La7^vii	62.92 (14)
La7^viii—La2—Ru4^vi	73.63 (16)	La7^vi—La8—La9^xvii	149.09 (19)
La7^iii—La2—Ru4	73.63 (12)	La7^vi—La8—La9^x	91.15 (11)
La7^iii—La2—Ru4^vi	140.1 (2)	La7^vi—La8—La9^v	91.15 (11)
Ru4—La2—Ru4^vi	146.0 (2)	La7^vi—La8—Ru3	50.42 (13)
La2—La3—La2^vii	60.56 (13)	La7^vi—La8—Ru3^vi	50.42 (14)
La2—La3—La3^vi	58.83 (13)	La7^vi—La8—Ru3^vii	99.4 (2)
La2—La3—La3^vii	89.24 (13)	La7^vii—La8—La9^xvii	91.15 (11)
La2—La3—La4^ix	149.65 (12)	La7^vii—La8—La9^x	149.09 (19)
La2—La3—La6	109.8 (2)	La7^vii—La8—La9^v	91.15 (10)
La2—La3—La6^v	60.44 (12)	La7^vii—La8—Ru3	99.4 (2)
La2—La3—La9^x	146.71 (12)	La7^vii—La8—Ru3^vi	50.42 (12)
La2—La3—La9^v	90.79 (13)	La7^vii—La8—Ru3^vii	50.42 (12)
La2—La3—La10	108.59 (16)	La9^xvii—La8—La9^x	106.79 (13)
La2—La3—Ru4	48.63 (17)	La9^xvii—La8—La9^v	106.79 (13)
La2^vii—La3—La3^vi	89.24 (14)	La9^xvii—La8—Ru3	125.78 (6)
La2^vii—La3—La3^vii	58.83 (12)	La9^xvii—La8—Ru3^vi	125.78 (8)
La2^vii—La3—La4^ix	149.65 (13)	La9^xvii—La8—Ru3^vii	49.67 (15)
La2^vii—La3—La6	60.44 (12)	La9^x—La8—La9^v	106.79 (14)
La2^vii—La3—La6^v	109.79 (19)	La9^x—La8—Ru3	49.67 (15)
La2^vii—La3—La9^x	90.79 (12)	La9^x—La8—Ru3^vi	125.78 (7)
La2^vii—La3—La9^v	146.71 (16)	La9^x—La8—Ru3^vii	125.78 (7)
La2^vii—La3—La10	108.59 (18)	La9^v—La8—Ru3	125.78 (7)
La2^vii—La3—Ru4	48.63 (12)	La9^v—La8—Ru3^vi	49.67 (15)
La3^vi—La3—La3^vii	60.00 (10)	La9^v—La8—Ru3^vii	125.78 (9)
La3^vi—La3—La4^ix	109.74 (18)	Ru3—La8—Ru3^vi	100.20 (19)
La3^vi—La3—La6	146.80 (13)	Ru3—La8—Ru3^vii	100.20 (19)
La3^vi—La3—La6^v	90.67 (12)	Ru3^vi—La8—Ru3^vii	100.20 (18)
La3^vi—La3—La9^x	108.14 (12)	La3^iv—La9—La3^xv	60.51 (11)
La3^vi—La3—La9^v	59.75 (11)	La3^iv—La9—La4^xxiii	106.19 (11)
La3^vi—La3—La10	149.99 (8)	La3^iv—La9—La4^xviii	56.16 (12)
La3^vi—La3—Ru4	106.6 (2)	La3^iv—La9—La5^x	153.45 (15)
La3^vii—La3—La4^ix	109.74 (17)	La3^iv—La9—La5^xv	112.04 (11)
La3^vii—La3—La6	90.67 (10)	La3^iv—La9—La6	56.57 (10)
La3^vii—La3—La6^v	146.80 (17)	La3^iv—La9—La6^xv	87.60 (17)
La3^vii—La3—La9^x	59.75 (10)	La3^iv—La9—La8^xxiv	67.06 (11)
La3^vii—La3—La9^v	108.14 (14)	La3^iv—La9—La9^x	108.14 (13)
La3^vii—La3—La10	149.99 (12)	La3^iv—La9—La9^xv	144.6 (2)
La3^vii—La3—Ru4	106.61 (18)	La3^iv—La9—Ru1	61.43 (12)
La4^ix—La3—La6	93.92 (16)	La3^iv—La9—Ru1^xv	118.7 (2)
La4^ix—La3—La6^v	93.92 (13)	La3^iv—La9—Ru3^xv	108.56 (12)
La4^ix—La3—La9^x	61.31 (13)	La3^xv—La9—La4^xxiii	56.16 (13)
La4^ix—La3—La9^v	61.31 (14)	La3^xv—La9—La4^xviii	106.19 (11)
La4^ix—La3—La10	66.18 (15)	La3^xv—La9—La5^x	112.04 (13)
La4^ix—La3—Ru4	137.77 (17)	La3^xv—La9—La5^xv	153.45 (16)
La6—La3—La6^v	111.18 (14)	La3^xv—La9—La6	87.60 (17)
La6—La3—La9^x	62.74 (12)	La3^xv—La9—La6^xv	56.57 (12)
La6—La3—La9^v	152.51 (17)	La3^xv—La9—La8^xxiv	67.06 (12)
La6—La3—La10	60.95 (8)	La3^xv—La9—La9^x	144.6 (2)
La6—La3—Ru4	64.68 (17)	La3^xv—La9—La9^xv	108.14 (13)
La6^v—La3—La9^x	152.51 (17)	La3^xv—La9—Ru1	118.7 (2)
La6^v—La3—La9^v	62.74 (12)	La3^xv—La9—Ru1^xv	61.43 (15)
La6^v—La3—La10	60.95 (9)	La3^xv—La9—Ru3^xv	108.56 (15)
La6^v—La3—Ru4	64.68 (14)	La4^xxiii—La9—La4^xviii	112.06 (14)
La9^x—La3—La9^v	109.2 (2)	La4^xxiii—La9—La5^x	56.99 (11)
La9^x—La3—La10	95.88 (13)	La4^xxiii—La9—La5^xv	108.06 (19)
La9^x—La3—Ru4	124.98 (17)	La4^xxiii—La9—La6	141.9 (2)
La9^v—La3—La10	95.88 (11)	La4^xxiii—La9—La6^xv	87.10 (13)
La9^v—La3—Ru4	124.98 (14)	La4^xxiii—La9—La8^xxiv	56.63 (7)
La10—La3—Ru4	71.60 (18)	La4^xxiii—La9—La9^x	145.54 (13)
La3^xiii—La4—La4^iv	109.74 (17)	La4^xxiii—La9—La9^xv	89.72 (9)
La3^xiii—La4—La4^v	109.74 (19)	La4^xxiii—La9—Ru1	162.55 (11)
La3^xiii—La4—La5^i	123.63 (14)	La4^xxiii—La9—Ru1^xv	51.37 (15)
La3^xiii—La4—La5^ii	123.63 (15)	La4^xxiii—La9—Ru3^xv	64.02 (14)
La3^xiii—La4—La7^i	134.77 (12)	La4^xviii—La9—La5^x	108.06 (19)
La3^xiii—La4—La8^i	72.32 (14)	La4^xviii—La9—La5^xv	56.99 (11)
La3^xiii—La4—La9^xi	62.53 (15)	La4^xviii—La9—La6	87.10 (12)
La3^xiii—La4—La9^viii	62.53 (13)	La4^xviii—La9—La6^xv	141.95 (19)
La3^xiii—La4—La10^xii	56.38 (13)	La4^xviii—La9—La8^xxiv	56.63 (8)
La3^xiii—La4—Ru1^viii	63.92 (19)	La4^xviii—La9—La9^x	89.72 (11)
La3^xiii—La4—Ru1^xiii	63.92 (16)	La4^xviii—La9—La9^xv	145.54 (16)
La3^xiii—La4—Ru5	152.59 (18)	La4^xviii—La9—Ru1	51.37 (12)
La4^iv—La4—La4^v	60.00 (10)	La4^xviii—La9—Ru1^xv	162.55 (18)
La4^iv—La4—La5^i	108.42 (14)	La4^xviii—La9—Ru3^xv	64.02 (13)
La4^iv—La4—La5^ii	59.41 (11)	La5^x—La9—La5^xv	62.04 (14)
La4^iv—La4—La7^i	109.16 (17)	La5^x—La9—La6	149.48 (9)
La4^iv—La4—La8^i	149.58 (12)	La5^x—La9—La6^xv	109.92 (10)
La4^iv—La4—La9^xi	90.28 (9)	La5^x—La9—La8^xxiv	86.47 (14)
La4^iv—La4—La9^viii	146.03 (17)	La5^x—La9—La9^x	91.69 (14)
La4^iv—La4—La10^xii	61.51 (12)	La5^x—La9—La9^xv	60.93 (12)
La4^iv—La4—Ru1^viii	97.75 (15)	La5^x—La9—Ru1	128.7 (2)
La4^iv—La4—Ru1^xiii	51.80 (12)	La5^x—La9—Ru1^xv	69.16 (16)
La4^iv—La4—Ru5	48.17 (10)	La5^x—La9—Ru3^xv	47.12 (11)
La4^v—La4—La5^i	59.41 (10)	La5^xv—La9—La6	109.92 (13)
La4^v—La4—La5^ii	108.42 (13)	La5^xv—La9—La6^xv	149.48 (12)
La4^v—La4—La7^i	109.16 (18)	La5^xv—La9—La8^xxiv	86.47 (15)
La4^v—La4—La8^i	149.58 (9)	La5^xv—La9—La9^x	60.93 (13)
La4^v—La4—La9^xi	146.03 (13)	La5^xv—La9—La9^xv	91.69 (14)
La4^v—La4—La9^viii	90.28 (11)	La5^xv—La9—Ru1	69.16 (17)
La4^v—La4—La10^xii	61.51 (13)	La5^xv—La9—Ru1^xv	128.7 (2)
La4^v—La4—Ru1^viii	51.80 (15)	La5^xv—La9—Ru3^xv	47.12 (13)
La4^v—La4—Ru1^xiii	97.75 (14)	La6—La9—La6^xv	60.69 (13)
La4^v—La4—Ru5	48.17 (11)	La6—La9—La8^xxiv	123.49 (12)
La5^i—La4—La5^ii	111.1 (2)	La6—La9—La9^x	61.31 (13)
La5^i—La4—La7^i	61.92 (13)	La6—La9—La9^xv	91.44 (14)
La5^i—La4—La8^i	93.44 (10)	La6—La9—Ru1	43.62 (16)
La5^i—La4—La9^xi	153.95 (16)	La6—La9—Ru1^xv	103.7 (2)
La5^i—La4—La9^viii	62.49 (11)	La6—La9—Ru3^xv	149.61 (12)
La5^i—La4—La10^xii	113.65 (12)	La6^xv—La9—La8^xxiv	123.49 (15)
La5^i—La4—Ru1^viii	71.20 (16)	La6^xv—La9—La9^x	91.44 (15)
La5^i—La4—Ru1^xiii	156.97 (13)	La6^xv—La9—La9^xv	61.31 (12)
La5^i—La4—Ru5	63.93 (11)	La6^xv—La9—Ru1	103.7 (2)
La5^ii—La4—La7^i	61.92 (13)	La6^xv—La9—Ru1^xv	43.62 (16)
La5^ii—La4—La8^i	93.44 (13)	La6^xv—La9—Ru3^xv	149.61 (13)
La5^ii—La4—La9^xi	62.49 (12)	La8^xxiv—La9—La9^x	143.40 (15)
La5^ii—La4—La9^viii	153.95 (16)	La8^xxiv—La9—La9^xv	143.40 (16)
La5^ii—La4—La10^xii	113.65 (10)	La8^xxiv—La9—Ru1	105.97 (8)
La5^ii—La4—Ru1^viii	156.97 (13)	La8^xxiv—La9—Ru1^xv	105.97 (16)
La5^ii—La4—Ru1^xiii	71.20 (15)	La8^xxiv—La9—Ru3^xv	48.44 (13)
La5^ii—La4—Ru5	63.93 (11)	La9^x—La9—La9^xv	60.00 (10)
La7^i—La4—La8^i	62.46 (14)	La9^x—La9—Ru1	49.31 (9)
La7^i—La4—La9^xi	95.29 (14)	La9^x—La9—Ru1^xv	107.43 (15)
La7^i—La4—La9^viii	95.29 (12)	La9^x—La9—Ru3^xv	106.82 (19)
La7^i—La4—La10^xii	168.85 (15)	La9^xv—La9—Ru1	107.43 (13)
La7^i—La4—Ru1^viii	131.07 (16)	La9^xv—La9—Ru1^xv	49.31 (14)
La7^i—La4—Ru1^xiii	131.07 (17)	La9^xv—La9—Ru3^xv	106.82 (18)
La7^i—La4—Ru5	72.63 (15)	Ru1—La9—Ru1^xv	144.2 (3)
La8^i—La4—La9^xi	63.11 (8)	Ru1—La9—Ru3^xv	106.59 (19)
La8^i—La4—La9^viii	63.11 (8)	Ru1^xv—La9—Ru3^xv	106.6 (2)
La8^i—La4—La10^xii	128.7 (2)	La1—La10—La3	89.13 (16)
La8^i—La4—Ru1^viii	109.43 (14)	La1—La10—La3^iv	89.13 (16)
La8^i—La4—Ru1^xiii	109.43 (15)	La1—La10—La3^v	89.13 (16)
La8^i—La4—Ru5	135.1 (2)	La1—La10—La4^xxv	146.57 (9)
La9^xi—La4—La9^viii	111.09 (14)	La1—La10—La4^ix	146.57 (9)
La9^xi—La4—La10^xii	91.00 (15)	La1—La10—La4^xviii	146.57 (9)
La9^xi—La4—Ru1^viii	125.4 (2)	La1—La10—La6	72.72 (14)
La9^xi—La4—Ru1^xiii	48.44 (11)	La1—La10—La6^iv	72.72 (14)
La9^xi—La4—Ru5	124.08 (11)	La1—La10—La6^v	72.72 (15)
La9^viii—La4—La10^xii	91.00 (15)	La1—La10—Ru1	119.21 (17)
La9^viii—La4—Ru1^viii	48.44 (11)	La1—La10—Ru1^iv	119.21 (17)
La9^viii—La4—Ru1^xiii	125.4 (2)	La1—La10—Ru1^v	119.21 (17)
La9^viii—La4—Ru5	124.08 (13)	La3—La10—La3^iv	119.98 (6)
La10^xii—La4—Ru1^viii	49.39 (13)	La3—La10—La3^v	119.98 (9)
La10^xii—La4—Ru1^xiii	49.39 (14)	La3—La10—La4^xxv	106.74 (16)
La10^xii—La4—Ru5	96.21 (11)	La3—La10—La4^ix	57.45 (14)
Ru1^viii—La4—Ru1^xiii	97.7 (2)	La3—La10—La4^xviii	106.74 (16)
Ru1^viii—La4—Ru5	99.50 (16)	La3—La10—La6	61.19 (7)
Ru1^xiii—La4—Ru5	99.50 (9)	La3—La10—La6^iv	161.8 (3)
La2^xvi—La5—La2^xviii	60.49 (13)	La3—La10—La6^v	61.19 (7)
La2^xvi—La5—La4^xvi	156.03 (16)	La3—La10—Ru1	64.60 (10)
La2^xvi—La5—La4^xix	113.64 (11)	La3—La10—Ru1^iv	151.7 (3)
La2^xvi—La5—La7	106.2 (2)	La3—La10—Ru1^v	64.60 (11)
La2^xvi—La5—La7^xiv	57.20 (11)	La3^iv—La10—La3^v	119.98 (8)
La2^xvi—La5—La9^x	142.72 (10)	La3^iv—La10—La4^xxv	106.74 (16)
La2^xvi—La5—La9^xv	107.83 (13)	La3^iv—La10—La4^ix	106.74 (17)
La2^xvi—La5—Ru3	119.61 (19)	La3^iv—La10—La4^xviii	57.45 (14)
La2^xvi—La5—Ru3^x	61.67 (17)	La3^iv—La10—La6	61.19 (7)
La2^xviii—La5—La4^xvi	113.64 (13)	La3^iv—La10—La6^iv	61.19 (9)
La2^xviii—La5—La4^xix	156.03 (17)	La3^iv—La10—La6^v	161.8 (3)
La2^xviii—La5—La7	57.20 (12)	La3^iv—La10—Ru1	64.60 (11)
La2^xviii—La5—La7^xiv	106.20 (19)	La3^iv—La10—Ru1^iv	64.60 (15)
La2^xviii—La5—La9^x	107.83 (10)	La3^iv—La10—Ru1^v	151.7 (3)
La2^xviii—La5—La9^xv	142.72 (11)	La3^v—La10—La4^xxv	57.45 (14)
La2^xviii—La5—Ru3	61.67 (16)	La3^v—La10—La4^ix	106.74 (17)
La2^xviii—La5—Ru3^x	119.6 (2)	La3^v—La10—La4^xviii	106.74 (16)
La4^xvi—La5—La4^xix	61.19 (11)	La3^v—La10—La6	161.8 (3)
La4^xvi—La5—La7	58.39 (13)	La3^v—La10—La6^iv	61.19 (11)
La4^xvi—La5—La7^xiv	107.78 (11)	La3^v—La10—La6^v	61.19 (9)
La4^xvi—La5—La9^x	60.52 (11)	La3^v—La10—Ru1	151.7 (3)
La4^xvi—La5—La9^xv	90.14 (18)	La3^v—La10—Ru1^iv	64.60 (15)
La4^xvi—La5—Ru3	67.20 (13)	La3^v—La10—Ru1^v	64.60 (11)
La4^xvi—La5—Ru3^x	126.2 (2)	La4^xxv—La10—La4^ix	56.99 (12)
La4^xix—La5—La7	107.78 (12)	La4^xxv—La10—La4^xviii	56.99 (13)
La4^xix—La5—La7^xiv	58.39 (12)	La4^xxv—La10—La6	140.7 (2)
La4^xix—La5—La9^x	90.14 (17)	La4^xxv—La10—La6^iv	89.14 (12)
La4^xix—La5—La9^xv	60.52 (12)	La4^xxv—La10—La6^v	89.14 (12)
La4^xix—La5—Ru3	126.2 (2)	La4^xxv—La10—Ru1	94.2 (2)
La4^xix—La5—Ru3^x	67.20 (12)	La4^xxv—La10—Ru1^iv	49.63 (16)
La7—La5—La7^xiv	109.14 (15)	La4^xxv—La10—Ru1^v	49.63 (15)
La7—La5—La9^x	92.03 (13)	La4^ix—La10—La4^xviii	56.99 (14)
La7—La5—La9^xv	145.8 (2)	La4^ix—La10—La6	89.14 (12)
La7—La5—Ru3	51.08 (11)	La4^ix—La10—La6^iv	140.7 (2)
La7—La5—Ru3^x	159.8 (2)	La4^ix—La10—La6^v	89.14 (13)
La7^xiv—La5—La9^x	145.81 (19)	La4^ix—La10—Ru1	49.63 (15)
La7^xiv—La5—La9^xv	92.03 (12)	La4^ix—La10—Ru1^iv	94.2 (2)
La7^xiv—La5—Ru3	159.8 (2)	La4^ix—La10—Ru1^v	49.63 (14)
La7^xiv—La5—Ru3^x	51.08 (11)	La4^xviii—La10—La6	89.14 (12)
La9^x—La5—La9^xv	58.14 (13)	La4^xviii—La10—La6^iv	89.14 (13)
La9^x—La5—Ru3	50.33 (16)	La4^xviii—La10—La6^v	140.7 (2)
La9^x—La5—Ru3^x	107.2 (2)	La4^xviii—La10—Ru1	49.63 (13)
La9^xv—La5—Ru3	107.2 (2)	La4^xviii—La10—Ru1^iv	49.63 (15)
La9^xv—La5—Ru3^x	50.33 (17)	La4^xviii—La10—Ru1^v	94.2 (2)
Ru3—La5—Ru3^x	148.13 (17)	La6—La10—La6^iv	111.57 (14)
La2^iv—La6—La2^vii	113.7 (2)	La6—La10—La6^v	111.57 (13)
La2^iv—La6—La3	155.60 (17)	La6—La10—Ru1	46.49 (15)
La2^iv—La6—La3^iv	60.62 (12)	La6—La10—Ru1^iv	124.17 (15)
La2^iv—La6—La7^i	57.87 (13)	La6—La10—Ru1^v	124.17 (9)
La2^iv—La6—La9	89.74 (14)	La6^iv—La10—La6^v	111.57 (14)
La2^iv—La6—La9^x	143.08 (16)	La6^iv—La10—Ru1	124.17 (12)
La2^iv—La6—La10	106.29 (9)	La6^iv—La10—Ru1^iv	46.49 (15)
La2^iv—La6—Ru1	122.97 (15)	La6^iv—La10—Ru1^v	124.17 (11)
La2^iv—La6—Ru2	65.22 (12)	La6^v—La10—Ru1	124.17 (10)
La2^vii—La6—La3	60.62 (12)	La6^v—La10—Ru1^iv	124.17 (14)
La2^vii—La6—La3^iv	155.60 (17)	La6^v—La10—Ru1^v	46.49 (16)
La2^vii—La6—La7^i	57.87 (13)	Ru1—La10—Ru1^iv	98.2 (2)
La2^vii—La6—La9	143.08 (13)	Ru1—La10—Ru1^v	98.2 (2)
La2^vii—La6—La9^x	89.74 (12)	Ru1^iv—La10—Ru1^v	98.2 (2)
La2^vii—La6—La10	106.29 (12)	La4^ix—Ru1—La4^xviii	76.40 (18)
La2^vii—La6—Ru1	122.97 (17)	La4^ix—Ru1—La6	136.9 (2)
La2^vii—La6—Ru2	65.22 (11)	La4^ix—Ru1—La9	129.5 (3)
La3—La6—La3^iv	113.60 (15)	La4^ix—Ru1—La9^x	80.19 (16)
La3—La6—La7^i	106.48 (16)	La4^ix—Ru1—La10	80.98 (19)
La3—La6—La9	108.29 (19)	La4^xviii—Ru1—La6	136.93 (18)
La3—La6—La9^x	60.69 (12)	La4^xviii—Ru1—La9	80.19 (16)
La3—La6—La10	57.86 (8)	La4^xviii—Ru1—La9^x	129.5 (3)
La3—La6—Ru1	65.18 (17)	La4^xviii—Ru1—La10	80.98 (15)
La3—La6—Ru2	123.03 (11)	La6—Ru1—La9	89.0 (2)
La3^iv—La6—La7^i	106.48 (14)	La6—Ru1—La9^x	88.96 (18)
La3^iv—La6—La9	60.69 (12)	La6—Ru1—La10	79.9 (2)
La3^iv—La6—La9^x	108.29 (19)	La9—Ru1—La9^x	81.38 (16)
La3^iv—La6—La10	57.86 (8)	La9—Ru1—La10	137.99 (16)
La3^iv—La6—Ru1	65.18 (14)	La9^x—Ru1—La10	138.0 (2)
La3^iv—La6—Ru2	123.03 (14)	La6—Ru2—La6^x	88.3 (2)
La7^i—La6—La9	145.16 (14)	La6—Ru2—La6^xv	88.3 (2)
La7^i—La6—La9^x	145.16 (9)	La6—Ru2—La7^i	77.58 (15)
La7^i—La6—La10	107.53 (17)	La6—Ru2—La7^xxvi	133.93 (12)
La7^i—La6—Ru1	161.16 (17)	La6—Ru2—La7^xiii	133.93 (8)
La7^i—La6—Ru2	53.30 (17)	La6^x—Ru2—La6^xv	88.3 (2)
La9—La6—La9^x	57.38 (12)	La6^x—Ru2—La7^i	133.93 (12)
La9—La6—La10	92.76 (16)	La6^x—Ru2—La7^xxvi	77.58 (15)
La9—La6—Ru1	47.41 (16)	La6^x—Ru2—La7^xiii	133.93 (10)
La9—La6—Ru2	104.02 (16)	La6^xv—Ru2—La7^i	133.93 (9)
La9^x—La6—La10	92.76 (17)	La6^xv—Ru2—La7^xxvi	133.93 (10)
La9^x—La6—Ru1	47.41 (12)	La6^xv—Ru2—La7^xiii	77.58 (16)
La9^x—La6—Ru2	104.02 (14)	La7^i—Ru2—La7^xxvi	81.4 (2)
La10—La6—Ru1	53.63 (17)	La7^i—Ru2—La7^xiii	81.4 (2)
La10—La6—Ru2	160.8 (3)	La7^xxvi—Ru2—La7^xiii	81.4 (2)
Ru1—La6—Ru2	145.5 (2)	La5—Ru3—La5^xv	88.43 (13)
La1^xvi—La7—La2^xx	88.43 (12)	La5—Ru3—La7	80.05 (14)
La1^xvi—La7—La2^xviii	88.43 (12)	La5—Ru3—La7^vi	139.0 (3)
La1^xvi—La7—La4^xvi	86.35 (15)	La5—Ru3—La8	132.81 (15)
La1^xvi—La7—La5	70.25 (10)	La5—Ru3—La9^x	82.55 (18)
La1^xvi—La7—La5^xxi	70.25 (10)	La5^xv—Ru3—La7	139.0 (3)
La1^xvi—La7—La6^xvi	71.13 (16)	La5^xv—Ru3—La7^vi	80.05 (14)
La1^xvi—La7—La7^vi	145.15 (15)	La5^xv—Ru3—La8	132.81 (15)
La1^xvi—La7—La7^vii	145.15 (14)	La5^xv—Ru3—La9^x	82.55 (17)
La1^xvi—La7—La8	145.7 (2)	La7—Ru3—La7^vi	83.41 (17)
La1^xvi—La7—Ru2^xvi	120.3 (2)	La7—Ru3—La8	79.27 (14)
La1^xvi—La7—Ru3	119.07 (13)	La7—Ru3—La9^x	133.59 (16)
La1^xvi—La7—Ru3^vii	119.07 (9)	La7^vi—Ru3—La8	79.27 (15)
La2^xx—La7—La2^xviii	121.6 (2)	La7^vi—Ru3—La9^x	133.59 (17)
La2^xx—La7—La4^xvi	118.98 (13)	La8—Ru3—La9^x	81.9 (2)
La2^xx—La7—La5	158.60 (12)	La1—Ru4—La2	126.9 (2)
La2^xx—La7—La5^xxi	61.46 (12)	La1—Ru4—La2^vii	126.9 (2)
La2^xx—La7—La6^xvi	61.97 (15)	La1—Ru4—La3	130.3 (3)
La2^xx—La7—La7^vi	108.92 (13)	La2—Ru4—La2^vii	84.25 (16)
La2^xx—La7—La7^vii	56.73 (10)	La2—Ru4—La3	86.7 (2)
La2^xx—La7—La8	107.30 (13)	La2^vii—Ru4—La3	86.69 (18)
La2^xx—La7—Ru2^xvi	65.98 (12)	La1—Ru5—La4	129.64 (11)
La2^xx—La7—Ru3	152.50 (14)	La1—Ru5—La4^iv	129.64 (11)
La2^xx—La7—Ru3^vii	63.25 (15)	La1—Ru5—La4^v	129.64 (11)
La2^xviii—La7—La4^xvi	118.98 (15)	La4—Ru5—La4^iv	83.65 (12)
La2^xviii—La7—La5	61.46 (12)	La4—Ru5—La4^v	83.65 (13)
La2^xviii—La7—La5^xxi	158.60 (14)	La4^iv—Ru5—La4^v	83.65 (14)
La2^xviii—La7—La6^xvi	61.97 (14)

Symmetry codes: (i) −x+1, −y+1, z+1/2; (ii) y+1, −x+y+1, z+1/2; (iii) x−y+1, x+1, z+1/2; (iv) −y+2, x−y+1, z; (v) −x+y+1, −x+2, z; (vi) −y+1, x−y+1, z; (vii) −x+y, −x+1, z; (viii) y, −x+y+1, z+1/2; (ix) y, −x+y+1, z−1/2; (x) −y+1, x−y, z; (xi) −x+2, −y+1, z+1/2; (xii) −x+2, −y+2, z+1/2; (xiii) x−y+1, x, z+1/2; (xiv) −x+y, −x, z; (xv) −x+y+1, −x+1, z; (xvi) −x+1, −y+1, z−1/2; (xvii) x−1, y, z; (xviii) x−y+1, x, z−1/2; (xix) x−y, x−1, z−1/2; (xx) y−1, −x+y, z−1/2; (xxi) −y, x−y, z; (xxii) x−y, x, z−1/2; (xxiii) −x+2, −y+1, z−1/2; (xxiv) x+1, y, z; (xxv) −x+2, −y+2, z−1/2; (xxvi) y, −x+y, z+1/2.