Crystal structure and spectroscopic properties of aqua­dichlorido­{1,1′-[(pyridine-2,6-diyl-κN)bis(methyl­ene)]bis­(4-butyl-4,5-di­hydro-1H-1,2,4-triazole-5-thione-κN2)}cobalt(II)

Miecznikowski, J.R.; Jasinski, J.P.; Ostrowski, T.J.; Landy, K.R.; Bonitatibus, S.C.; Smolinsky, A.N.; Bertolotti, N.R.

doi:10.1107/S2056989020013547

Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

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Figure 3
A view of the molecular structure of C₁₉H₂₉Cl₂CoN₇OS₂, 8, showing the atom-labeling scheme and displacement ellipsoids drawn at the 30% probability level. The molecule crystallizes in the C2/c space group with a twofold rotation axis perpendicular to a c-glide plane along the center of the pincer ligand through to the metal ion transforming the two asymmetric units into the complete complex and containing four cobalt(II) complexes per unit cell. Atoms with the suffix A are generated by the symmetry operation 1 − x, y, −z + $[{1\over 2}]$ .

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 76| Part 11| November 2020| Pages 1757-1761

https://doi.org/10.1107/S2056989020013547

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