Two salts of the 6,6-di­fluoro-6H-dibenzo[c,e][1,2]oxaborinin-6-ide anion with different cations

Budanow, A.; Lerner, H.-W.; Bolte, M.

doi:10.1107/S2056989020015066

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Volume 76| Part 12| December 2020| Pages 1837-1840

https://doi.org/10.1107/S2056989020015066

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Two salts of the 6,6-difluoro-6H-dibenzo[c,e][1,2]oxaborinin-6-ide anion with different cations

Alexandra Budanow,^a Hans-Wolfram Lerner ^a and Michael Bolte ^a ^*

^aInstitut für Anorganische und Analytische Chemie, Goethe-Universität Frankfurt, Max-von-Laue-Strasse 7, 60438 Frankfurt am Main, Germany
^*Correspondence e-mail: bolte@chemie.uni-frankfurt.de

Edited by W. T. A. Harrison, University of Aberdeen, Scotland (Received 6 November 2020; accepted 12 November 2020; online 17 November 2020)

The crystal structures are reported of the 6,6-difluoro-6H-dibenzo[c,e][1,2]oxaborinin-6-ide (or 9,9-difluoro-10-oxa-9-boraphenanthren-9-ide) anion with two different cations, namely, potassium 6,6-difluoro-6H-dibenzo[c,e][1,2]oxaborinin-6-ide, K⁺·C₁₂H₈BF₂O⁻, (II), featuring a polymeric structure, and bis(tetraphenylphosphonium) bis(6,6-difluoro-6H-dibenzo[c,e][1,2]oxaborinin-6-ide) acetonitrile trisolvate, 2C₂₄H₂₀P⁺·2C₁₂H₈BF₂O⁻·3CH₃CN, (III), which is composed of discrete cations, anions and acetonitrile solvent molecules linked by C—H⋯O, C—H⋯N and C—H⋯F hydrogen bonds. There are only minor differences in the geometrical parameters of the anions in these structures.

Keywords: crystal structure; boron; fluorine; potassium.

CCDC references: 2043934; 2043933

1. Chemical context

Oxaboraphenanthrenes are interesting building blocks for organic optoelectronic materials. Recently, we have prepared various 9-substituted oxaboraphenanthrene derivatives and investigated their stability and luminescence behavior (Budanow et al., 2016 ). The starting material for our approach was 9-chloro-10,9-oxaboraphenanthrene (Budanow et al., 2014 ), which is, however, an air-sensitive compound. Therefore we were now interested in air-stable precursors for oxaboraphenanthrene preparation.

Because certain borinic acids are readily fluorinated with KHF₂, we tested whether (I) (Fig. 1) could be transformed into a fluoroborane upon treatment with KHF₂. Indeed, by stirring a solution of (I) in the presence of KHF₂ in methanol, a clean and quantitative OH/F exchange was established and 9,9-difluorido-10,9-oxaboraphenanthrene potassium (II) was obtained (Fig. 1). Subsequent treatment of (II) with Ph₄PBr gave the 9,9-difluorido-10,9-oxaboraphenanthrene salt as an acetonitrile solvate (III). The crystal structures of (II) and (III) are now described.

Figure 1
Synthesis of the 9,9-difluorido-10,9-oxaboraphenanthrene salts (II) and (III).

2. Structural commentary

The anion in (II) has an almost planar skeleton (r.m.s. deviation 0.103 Å for the C, B and O atoms) (Fig. 2) and the bond lengths of the B and O atoms are in their usual ranges [B1—C1 = 1.591 (2); B1—O1 = 1.4564 (19), C11—O1 = 1.3678 (17) Å]. The B atom is substituted by two F ligands with bond lengths B1—F1 = 1.4483 (18) and B1—F2 = 1.4325 (18) Å. The dihedral angle between the C1–C6 and C11–C16 aromatic rings in the anion of (II) is 11.09 (9) Å.

Figure 2
A perspective view of the asymmetric unit of (II). Displacement ellipsoids are drawn at the 50% probability level.

The asymmetric unit of (III) consists of two C₁₂H₈BF₂O⁻ anions (Figs. 3 and 4), two C₂₄H₂₀P⁺ tetraphenylphosphonium cations and three acetonitrile solvent molecules, one of which is disordered over two sets of sites. The oxaboraphenanthrene moieties of both the B1 and B1A anions are again essentially planar (r.m.s. deviations = 0.042 and 0.093 Å, respectively). The bond lengths involving B and O [B1—C1 = 1.603 (2); B1—O1 = 1.466 (2); B1—F1 = 1.412 (2); B1—F2 = 1.411 (2), C11—O1 = 1.3492 (19) Å and B1A—C1A = 1.601 (2), B1A—O1A = 1.475 (2); B1A—F1A = 1.417 (2); B1A—F2A = 1.415 (2); C11A—O1A = 1.3435 (19) Å] show some slight variations between (II) and (III). In (II), the B—F bonds are longer than in (III), which is presumably due to the F⋯K contacts.

Figure 3
A perspective view of the first of the two anions in the asymmetric unit of (III). Displacement ellipsoids are drawn at the 50% probability level.

Figure 4
A perspective view of the second of the two anions in the asymmetric unit of (III). Displacement ellipsoids are drawn at the 50% probability level.

3. Supramolecular features

The extended structure of (II) features a polymeric network forming layers lying parallel to (001) (Figs. 5, 6). K1 is bonded to four F atoms with K—F distances ranging from 2.6132 (9) to 2.7407 (10) Å and two O atoms with K—O distances of 2.7307 (10) and 2.9324 (11) Å. There is one relatively short K⋯C contact [K1⋯C11 = 3.3883 (14)Å] but there are no K⋯π interactions.

Figure 5
Packing diagram of (II) with a view onto the bc plane. H atoms are omitted for clarity.

Figure 6
Packing diagram of (II) viewed along the b-axis direction. H atoms are omitted for clarity.

In the extended structure of (III) (Fig. 7), the component species are linked by numerous C—H⋯O, C—H⋯N and C—H⋯F interactions (Table 1) into a three-dimensional network.

Table 1
Hydrogen-bond geometry (Å, °) for (III)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
C26A—H26A⋯O1A	0.95	2.58	3.322 (2)	135
C32A—H32A⋯F2ⁱ	0.95	2.40	3.069 (2)	127
C42A—H42A⋯F2ⁱ	0.95	2.51	3.378 (2)	152
C44A—H44A⋯F1Aⁱ	0.95	2.54	3.482 (2)	172
C53—H53⋯O1ⁱ	0.95	2.59	3.389 (2)	142
C54A—H54A⋯F2ⁱⁱ	0.95	2.55	3.436 (3)	156
C55A—H55A⋯N81′ⁱ	0.95	2.52	3.180 (8)	127
C63—H63A⋯N61ⁱⁱⁱ	0.98	2.58	3.365 (6)	137
C63—H63C⋯N71^iv	0.98	2.47	3.371 (7)	153
C73—H73A⋯F1	0.98	2.19	3.106 (4)	156
C73—H73B⋯N81ⁱⁱ	0.98	2.45	3.313 (10)	146
C83—H83A⋯F1	0.98	2.52	3.252 (4)	131
Symmetry codes: (i) x+1, y, z; (ii) ; (iii) ; (iv) x+1, y+1, z.

Figure 7
Packing diagram of (III) viewed along the a-axis direction. H atoms and the minor occupied sites of the disordered acetonitrile molecule are omitted for clarity.

4. Database survey

There are no structures in the Cambridge Structural Database (version 5.41 of November 2019 plus three updates; Groom et al., 2016 ) containing the 6,6′-difluoro-6H-dibenzo[c,e][1,2]oxaborinine anion. When the F ligands in the query are changed to any ligand, three structures are found, namely (6H-dibenzo[c,e][1,2]oxadihydridoborato-O)(tetrahydrofuran)(tetramethylethylenediamine)lithium (CSD refcode CADVIN; Knizek & Nöth, 2000 ), [6-phenyl-6-(phenyl)-6H-6-dibenzo[c,e][1,2]oxaborinine]bis(tetrahydrofuran)lithium benzene solvate (TUZTAL; Budanow et al., 2016) and (9-tert-butyl-9H-9-benzo[c][1,2]benzoxaborinino[4,3,2-ij][2,1]benzoxaborinine)bis(tetrahydrofuran)lithium (9-tert-butyl-9H-9-benzo[c][1,2]benzoxaborinino[4,3,2-ij][2,1]benzoxaborinine)tris(tetrahydrofuran)lithium (RUHZUS; Sato et al., 2020 ). Since in RUHZUS, the ligands at B are involved in a ring closure, this structure is excluded from the comparison with (II) and (III).

The bond lengths involving B and O in these structures are: CADVIN: B—C = 1.589, B—O = 1.534, C—O = 1.360 Å; TUZTAL: B—C = 1.611, B—O = 1.543, C—O = 1.358 Å. Whereas the B—C and the O—C bonds are in the same range as in (II) and (III), the B—O bond is significantly longer than in (II) and (III). It is notable that the oxaboraphenanthrene moieties in CADVIN and TUZTAL are far more distorted from planarity than in (II) and (III): the dihedral angles between the aromatic rings are 16.9° in CADVIN and 19.1° in TUZTAL. These dihedral angles are 11.09 (9)° in (II) and 4.53 (7) and 9.68 (8)° in (III).

5. Synthesis and crystallization

Synthesis of 9,9-difluorido-10,9-oxaboraphenanthrene potassium (II):

To a solution of 9-hydroxooxaboraphenanthrene (I) (1.556 g, 7.94 mmol) in methanol (70 ml) a solution of KHF₂ (2.669 g, 34.17 mmol) in methanol (30 ml) and water (30 ml) was added at room temperature and the resulting reacting mixture was stirred for 12 h. After removal of all volatiles in vacuo, the residue was extracted into acetonitrile (30 ml). The colorless suspension was filtered. All volatiles were removed in vacuo. The product was obtained as a colorless powder in a yield of 66% (1.34 g, 5.23 mmol). Slow evaporation of a saturated acetonitrile solution of (II) over Granopent led to colorless plates, which were suitable for an investigation by X-ray crystallography.

Synthesis of 9,9-difluorido-10,9-oxaboraphenanthrene tetraphenylphosphonium (III):

To a solution of (II) (0.511 g, 2.0 mmol) in acetonitrile (25 ml) Ph₄PBr (0.88 g, 2.10 mmol) was added at room temperature and the resulting reacting mixture was stirred for 12 h. The colorless suspension was filtered. After removal of all volatiles, the product was obtained as a colorless powder in a yield of 92% (0.221 g, 0.36 mmol). Slow evaporation of a saturated acetonitrile solution of (III) over Granopent led to colorless blocks, which were suitable for an investigation by X-ray crystallography.

6. Refinement

Crystal data, data collection and structure refinement details are summarized in Table 2. The H atoms for both structures were refined using a riding model with C—H = 0.95 Å and with U_iso(H) = 1.2U_eq(C) or with C_methyl—H = 0.98 Å and with U_iso(H) = 1.5U_eq(C). The methyl groups were allowed to rotate but not to tip. In (III), the C≡N group of one acetonitrile molecule is disordered over two sets of sites with a site occupation factor of 0.545 (5) for the major disorder component.

Table 2
Experimental details

	(II)	(III)
Crystal data
Chemical formula	K⁺·C₁₂H₈BF₂O⁻	2C₂₄H₂₀P⁺·2C₁₂H₈BF₂O⁻·3C₂H₃N
M_r	256.09	1235.89
Crystal system, space group	Monoclinic, P2₁/c	Triclinic, P $[\overline{1}]$
Temperature (K)	173	173
a, b, c (Å)	13.2962 (10), 6.2300 (4), 12.9294 (11)	10.3527 (4), 13.5958 (5), 23.4352 (9)
α, β, γ (°)	90, 97.226 (6), 90	86.218 (3), 78.916 (3), 87.104 (3)
V (Å³)	1062.50 (14)	3227.6 (2)
Z	4	2
Radiation type	Mo Kα	Mo Kα
μ (mm⁻¹)	0.50	0.13
Crystal size (mm)	0.48 × 0.46 × 0.23	0.42 × 0.38 × 0.29

Data collection
Diffractometer	Stoe IPDS II two-circle	Stoe IPDS II two-circle
Absorption correction	Multi-scan (X-AREA; Stoe & Cie, 2001 )	Multi-scan (X-AREA; Stoe & Cie, 2001)
T_min, T_max	0.794, 0.893	0.947, 0.963
No. of measured, independent and observed [I > 2σ(I)] reflections	6459, 1980, 1796	47827, 11854, 10863
R_int	0.050	0.040
(sin θ/λ)_max (Å⁻¹)	0.607	0.604

Refinement
R[F² > 2σ(F²)], wR(F²), S	0.030, 0.083, 1.06	0.041, 0.109, 1.05
No. of reflections	1980	11854
No. of parameters	154	842
H-atom treatment	H-atom parameters constrained	H-atom parameters constrained
Δρ_max, Δρ_min (e Å⁻³)	0.26, −0.43	0.48, −0.44
Computer programs: X-AREA (Stoe & Cie, 2001), SHELXT (Sheldrick, 2015a ), SHELXL (Sheldrick, 2015b ), XP (Sheldrick, 2015b), Mercury (Macrae et al., 2020 ) and publCIF (Westrip, 2010 ).

Supporting information

CCDC references: 2043934; 2043933

Crystal structure: contains datablocks II, III, global. DOI: https://doi.org/10.1107/S2056989020015066/hb7952sup1.cif

Structure factors: contains datablock II. DOI: https://doi.org/10.1107/S2056989020015066/hb7952IIsup2.hkl

Structure factors: contains datablock III. DOI: https://doi.org/10.1107/S2056989020015066/hb7952IIIsup3.hkl

Supporting information file. DOI: https://doi.org/10.1107/S2056989020015066/hb7952IIsup4.cml

Supporting information file. DOI: https://doi.org/10.1107/S2056989020015066/hb7952IIIsup5.cml

checkCIF report

Computing details top

For both structures, data collection: X-AREA (Stoe & Cie, 2001); cell refinement: X-AREA (Stoe & Cie, 2001); data reduction: X-AREA (Stoe & Cie, 2001); program(s) used to solve structure: ShelXT (Sheldrick, 2015a); program(s) used to refine structure: SHELXL (Sheldrick, 2015b); molecular graphics: XP (Sheldrick, 2015b) and Mercury (Macrae et al., 2020); software used to prepare material for publication: publCIF (Westrip, 2010).

Potassium 6,6-difluoro-6H-dibenzo[c,e][1,2]oxaborinin-6-ide (II) top

Crystal data top

K⁺·C₁₂H₈BF₂O⁻	F(000) = 520
M_r = 256.09	D_x = 1.601 Mg m⁻³
Monoclinic, P2₁/c	Mo Kα radiation, λ = 0.71073 Å
a = 13.2962 (10) Å	Cell parameters from 6730 reflections
b = 6.2300 (4) Å	θ = 3.6–26.0°
c = 12.9294 (11) Å	µ = 0.50 mm⁻¹
β = 97.226 (6)°	T = 173 K
V = 1062.50 (14) Å³	Plate, colourless
Z = 4	0.48 × 0.46 × 0.23 mm

Data collection top

STOE IPDS II two-circle diffractometer	1796 reflections with I > 2σ(I)
ω scans	R_int = 0.050
Absorption correction: multi-scan (X-Area; Stoe & Cie, 2001)	θ_max = 25.6°, θ_min = 3.6°
T_min = 0.794, T_max = 0.893	h = −16→16
6459 measured reflections	k = −7→7
1980 independent reflections	l = −15→13

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.030	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.083	H-atom parameters constrained
S = 1.06	w = 1/[σ²(F_o²) + (0.0507P)² + 0.1783P] where P = (F_o² + 2F_c²)/3
1980 reflections	(Δ/σ)_max < 0.001
154 parameters	Δρ_max = 0.26 e Å⁻³
0 restraints	Δρ_min = −0.43 e Å⁻³

Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
K1	0.47144 (2)	0.77289 (5)	0.38440 (2)	0.02252 (13)
B1	0.61842 (12)	0.3281 (3)	0.38931 (12)	0.0182 (3)
O1	0.62336 (7)	0.46771 (16)	0.48017 (7)	0.0201 (2)
F1	0.55034 (6)	0.42677 (15)	0.30658 (6)	0.0258 (2)
F2	0.56553 (6)	0.13979 (14)	0.41608 (7)	0.0246 (2)
C1	0.72587 (11)	0.2796 (2)	0.35252 (11)	0.0186 (3)
C2	0.80729 (11)	0.4170 (2)	0.38571 (11)	0.0195 (3)
C3	0.90255 (11)	0.3756 (3)	0.35387 (12)	0.0249 (3)
H3	0.958382	0.465504	0.377711	0.030*
C4	0.91617 (12)	0.2057 (3)	0.28830 (13)	0.0279 (4)
H4	0.980868	0.181458	0.266586	0.034*
C5	0.83640 (12)	0.0709 (3)	0.25411 (12)	0.0271 (3)
H5	0.845540	−0.044942	0.208452	0.033*
C6	0.74217 (12)	0.1076 (3)	0.28767 (11)	0.0226 (3)
H6	0.687666	0.012800	0.265759	0.027*
C11	0.70096 (11)	0.6112 (2)	0.50227 (11)	0.0177 (3)
C12	0.79123 (11)	0.5970 (2)	0.45628 (11)	0.0194 (3)
C13	0.86343 (12)	0.7582 (2)	0.48232 (13)	0.0253 (3)
H13	0.924129	0.756567	0.450636	0.030*
C14	0.84952 (12)	0.9195 (3)	0.55239 (13)	0.0285 (4)
H14	0.899937	1.026782	0.567981	0.034*
C15	0.76149 (12)	0.9244 (2)	0.60003 (12)	0.0263 (3)
H15	0.752271	1.032398	0.649848	0.032*
C16	0.68731 (12)	0.7707 (2)	0.57435 (12)	0.0221 (3)
H16	0.626722	0.774242	0.606210	0.027*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
K1	0.0320 (2)	0.01629 (19)	0.01999 (19)	−0.00165 (13)	0.00615 (13)	0.00069 (11)
B1	0.0191 (7)	0.0158 (7)	0.0197 (7)	−0.0023 (6)	0.0025 (6)	−0.0009 (6)
O1	0.0187 (5)	0.0208 (5)	0.0215 (5)	−0.0053 (4)	0.0048 (4)	−0.0038 (4)
F1	0.0269 (5)	0.0275 (5)	0.0218 (4)	0.0072 (4)	−0.0016 (3)	−0.0030 (3)
F2	0.0244 (4)	0.0189 (4)	0.0317 (5)	−0.0070 (4)	0.0085 (3)	−0.0034 (4)
C1	0.0210 (7)	0.0182 (7)	0.0166 (6)	0.0005 (6)	0.0028 (5)	0.0031 (5)
C2	0.0200 (7)	0.0206 (7)	0.0181 (6)	0.0001 (6)	0.0032 (5)	0.0038 (6)
C3	0.0197 (7)	0.0289 (8)	0.0266 (7)	−0.0015 (6)	0.0052 (6)	0.0014 (6)
C4	0.0222 (8)	0.0355 (9)	0.0275 (8)	0.0053 (7)	0.0084 (6)	0.0002 (7)
C5	0.0310 (8)	0.0262 (8)	0.0249 (7)	0.0066 (7)	0.0062 (6)	−0.0024 (6)
C6	0.0235 (7)	0.0212 (7)	0.0231 (7)	−0.0004 (6)	0.0029 (6)	−0.0001 (6)
C11	0.0174 (6)	0.0159 (6)	0.0188 (6)	−0.0017 (6)	−0.0013 (5)	0.0022 (5)
C12	0.0201 (7)	0.0191 (7)	0.0184 (6)	−0.0013 (6)	0.0002 (5)	0.0031 (5)
C13	0.0215 (7)	0.0253 (8)	0.0290 (8)	−0.0054 (6)	0.0028 (6)	0.0018 (6)
C14	0.0285 (8)	0.0217 (8)	0.0335 (8)	−0.0077 (7)	−0.0028 (6)	−0.0018 (6)
C15	0.0295 (8)	0.0189 (7)	0.0286 (8)	0.0013 (6)	−0.0038 (6)	−0.0037 (6)
C16	0.0224 (7)	0.0211 (7)	0.0222 (7)	0.0031 (6)	0.0002 (6)	−0.0008 (6)

Geometric parameters (Å, º) top

K1—F2ⁱ	2.6132 (9)	C2—C3	1.404 (2)
K1—F1ⁱⁱ	2.6307 (9)	C2—C12	1.478 (2)
K1—F1	2.6511 (9)	C3—C4	1.382 (2)
K1—O1ⁱⁱⁱ	2.7307 (10)	C3—H3	0.9500
K1—F2ⁱⁱⁱ	2.7407 (10)	C4—C5	1.381 (2)
K1—O1	2.9324 (11)	C4—H4	0.9500
K1—B1ⁱⁱⁱ	3.3560 (16)	C5—C6	1.395 (2)
K1—B1	3.3867 (17)	C5—H5	0.9500
K1—C11	3.3883 (14)	C6—H6	0.9500
K1—C6ⁱⁱ	3.5338 (16)	C11—C16	1.390 (2)
K1—C16	3.5351 (15)	C11—C12	1.408 (2)
K1—K1^iv	4.1169 (6)	C12—C13	1.401 (2)
B1—F2	1.4325 (18)	C13—C14	1.381 (2)
B1—F1	1.4483 (18)	C13—H13	0.9500
B1—O1	1.4564 (19)	C14—C15	1.390 (2)
B1—C1	1.591 (2)	C14—H14	0.9500
O1—C11	1.3678 (17)	C15—C16	1.385 (2)
C1—C6	1.395 (2)	C15—H15	0.9500
C1—C2	1.404 (2)	C16—H16	0.9500

F2ⁱ—K1—F1ⁱⁱ	79.77 (3)	F2—B1—C1	113.79 (12)
F2ⁱ—K1—F1	124.50 (3)	F1—B1—C1	111.18 (12)
F1ⁱⁱ—K1—F1	86.689 (19)	O1—B1—C1	113.80 (12)
F2ⁱ—K1—O1ⁱⁱⁱ	129.06 (3)	F2—B1—K1ⁱⁱⁱ	52.87 (6)
F1ⁱⁱ—K1—O1ⁱⁱⁱ	142.82 (3)	F1—B1—K1ⁱⁱⁱ	117.74 (9)
F1—K1—O1ⁱⁱⁱ	91.92 (3)	O1—B1—K1ⁱⁱⁱ	52.67 (6)
F2ⁱ—K1—F2ⁱⁱⁱ	79.51 (3)	C1—B1—K1ⁱⁱⁱ	131.05 (9)
F1ⁱⁱ—K1—F2ⁱⁱⁱ	143.09 (3)	F2—B1—K1	112.03 (9)
F1—K1—F2ⁱⁱⁱ	130.17 (3)	F1—B1—K1	48.20 (6)
O1ⁱⁱⁱ—K1—F2ⁱⁱⁱ	49.72 (3)	O1—B1—K1	59.60 (7)
F2ⁱ—K1—O1	102.13 (3)	C1—B1—K1	133.45 (9)
F1ⁱⁱ—K1—O1	128.41 (3)	K1ⁱⁱⁱ—B1—K1	84.37 (4)
F1—K1—O1	49.34 (3)	C11—O1—B1	121.00 (11)
O1ⁱⁱⁱ—K1—O1	73.88 (3)	C11—O1—K1ⁱⁱⁱ	128.44 (8)
F2ⁱⁱⁱ—K1—O1	85.80 (3)	B1—O1—K1ⁱⁱⁱ	102.23 (8)
F2ⁱ—K1—B1ⁱⁱⁱ	104.08 (3)	C11—O1—K1	97.24 (8)
F1ⁱⁱ—K1—B1ⁱⁱⁱ	151.33 (4)	B1—O1—K1	95.03 (8)
F1—K1—B1ⁱⁱⁱ	112.31 (4)	K1ⁱⁱⁱ—O1—K1	106.12 (3)
O1ⁱⁱⁱ—K1—B1ⁱⁱⁱ	25.09 (3)	B1—F1—K1^v	121.56 (8)
F2ⁱⁱⁱ—K1—B1ⁱⁱⁱ	24.63 (3)	B1—F1—K1	107.77 (8)
O1—K1—B1ⁱⁱⁱ	79.17 (3)	K1^v—F1—K1	130.59 (3)
F2ⁱ—K1—B1	116.68 (4)	B1—F2—K1^vi	156.70 (8)
F1ⁱⁱ—K1—B1	108.11 (4)	B1—F2—K1ⁱⁱⁱ	102.50 (8)
F1—K1—B1	24.03 (3)	K1^vi—F2—K1ⁱⁱⁱ	100.49 (3)
O1ⁱⁱⁱ—K1—B1	81.41 (4)	C6—C1—C2	118.68 (13)
F2ⁱⁱⁱ—K1—B1	108.43 (3)	C6—C1—B1	122.63 (13)
O1—K1—B1	25.37 (3)	C2—C1—B1	118.69 (13)
B1ⁱⁱⁱ—K1—B1	95.63 (4)	C1—C2—C3	119.20 (14)
F2ⁱ—K1—C11	78.65 (3)	C1—C2—C12	119.03 (13)
F1ⁱⁱ—K1—C11	121.14 (3)	C3—C2—C12	121.73 (14)
F1—K1—C11	63.37 (3)	C4—C3—C2	120.87 (15)
O1ⁱⁱⁱ—K1—C11	90.61 (3)	C4—C3—H3	119.6
F2ⁱⁱⁱ—K1—C11	83.90 (3)	C2—C3—H3	119.6
O1—K1—C11	23.61 (3)	C5—C4—C3	120.48 (14)
B1ⁱⁱⁱ—K1—C11	87.21 (4)	C5—C4—H4	119.8
B1—K1—C11	42.55 (4)	C3—C4—H4	119.8
F2ⁱ—K1—C6ⁱⁱ	133.20 (3)	C4—C5—C6	118.98 (14)
F1ⁱⁱ—K1—C6ⁱⁱ	61.99 (3)	C4—C5—H5	120.5
F1—K1—C6ⁱⁱ	81.32 (3)	C6—C5—H5	120.5
O1ⁱⁱⁱ—K1—C6ⁱⁱ	81.05 (3)	C1—C6—C5	121.75 (15)
F2ⁱⁱⁱ—K1—C6ⁱⁱ	115.17 (3)	C1—C6—K1^v	88.92 (9)
O1—K1—C6ⁱⁱ	122.23 (3)	C5—C6—K1^v	122.27 (10)
B1ⁱⁱⁱ—K1—C6ⁱⁱ	98.52 (4)	C1—C6—H6	119.1
B1—K1—C6ⁱⁱ	100.93 (4)	C5—C6—H6	119.1
C11—K1—C6ⁱⁱ	143.48 (4)	K1^v—C6—H6	58.0
F2ⁱ—K1—C16	64.13 (3)	O1—C11—C16	116.65 (13)
F1ⁱⁱ—K1—C16	129.60 (3)	O1—C11—C12	122.12 (13)
F1—K1—C16	86.27 (3)	C16—C11—C12	121.22 (14)
O1ⁱⁱⁱ—K1—C16	87.27 (3)	O1—C11—K1	59.16 (6)
F2ⁱⁱⁱ—K1—C16	64.72 (3)	C16—C11—K1	84.42 (9)
O1—K1—C16	41.25 (3)	C12—C11—K1	126.61 (9)
B1ⁱⁱⁱ—K1—C16	74.96 (4)	C13—C12—C11	116.64 (14)
B1—K1—C16	64.38 (4)	C13—C12—C2	123.00 (13)
C11—K1—C16	23.03 (3)	C11—C12—C2	120.35 (13)
C6ⁱⁱ—K1—C16	162.61 (4)	C14—C13—C12	122.36 (15)
F2ⁱ—K1—K1^iv	40.89 (2)	C14—C13—H13	118.8
F1ⁱⁱ—K1—K1^iv	114.80 (2)	C12—C13—H13	118.8
F1—K1—K1^iv	142.09 (2)	C13—C14—C15	119.76 (15)
O1ⁱⁱⁱ—K1—K1^iv	88.26 (2)	C13—C14—H14	120.1
F2ⁱⁱⁱ—K1—K1^iv	38.619 (19)	C15—C14—H14	120.1
O1—K1—K1^iv	94.86 (2)	C16—C15—C14	119.52 (14)
B1ⁱⁱⁱ—K1—K1^iv	63.21 (3)	C16—C15—H15	120.2
B1—K1—K1^iv	119.70 (3)	C14—C15—H15	120.2
C11—K1—K1^iv	78.72 (3)	C15—C16—C11	120.40 (15)
C6ⁱⁱ—K1—K1^iv	135.87 (3)	C15—C16—K1	130.95 (10)
C16—K1—K1^iv	55.86 (3)	C11—C16—K1	72.54 (8)
F2—B1—F1	104.23 (11)	C15—C16—H16	119.8
F2—B1—O1	105.54 (11)	C11—C16—H16	119.8
F1—B1—O1	107.63 (12)	K1—C16—H16	69.1

F2—B1—O1—C11	151.69 (11)	B1—C1—C2—C3	179.90 (13)
F1—B1—O1—C11	−97.45 (14)	C6—C1—C2—C12	−178.70 (13)
C1—B1—O1—C11	26.22 (18)	B1—C1—C2—C12	2.01 (19)
K1ⁱⁱⁱ—B1—O1—C11	150.72 (13)	C1—C2—C3—C4	1.8 (2)
K1—B1—O1—C11	−101.56 (11)	C12—C2—C3—C4	179.63 (14)
F2—B1—O1—K1ⁱⁱⁱ	0.97 (11)	C2—C3—C4—C5	−1.1 (2)
F1—B1—O1—K1ⁱⁱⁱ	111.83 (10)	C3—C4—C5—C6	−0.7 (2)
C1—B1—O1—K1ⁱⁱⁱ	−124.50 (10)	C2—C1—C6—C5	−0.9 (2)
K1—B1—O1—K1ⁱⁱⁱ	107.72 (5)	B1—C1—C6—C5	178.34 (14)
F2—B1—O1—K1	−106.75 (9)	C2—C1—C6—K1^v	−128.97 (12)
F1—B1—O1—K1	4.11 (11)	B1—C1—C6—K1^v	50.29 (13)
C1—B1—O1—K1	127.79 (11)	C4—C5—C6—C1	1.7 (2)
K1ⁱⁱⁱ—B1—O1—K1	−107.72 (5)	C4—C5—C6—K1^v	113.06 (15)
F2—B1—F1—K1^v	−76.01 (12)	B1—O1—C11—C16	165.10 (13)
O1—B1—F1—K1^v	172.24 (7)	K1ⁱⁱⁱ—O1—C11—C16	−52.50 (16)
C1—B1—F1—K1^v	46.99 (14)	K1—O1—C11—C16	64.76 (12)
K1ⁱⁱⁱ—B1—F1—K1^v	−131.24 (6)	B1—O1—C11—C12	−16.10 (19)
K1—B1—F1—K1^v	177.00 (10)	K1ⁱⁱⁱ—O1—C11—C12	126.30 (11)
F2—B1—F1—K1	106.99 (9)	K1—O1—C11—C12	−116.44 (12)
O1—B1—F1—K1	−4.76 (12)	B1—O1—C11—K1	100.34 (12)
C1—B1—F1—K1	−130.01 (10)	K1ⁱⁱⁱ—O1—C11—K1	−117.26 (9)
K1ⁱⁱⁱ—B1—F1—K1	51.76 (9)	O1—C11—C12—C13	177.69 (13)
F1—B1—F2—K1^vi	56.3 (3)	C16—C11—C12—C13	−3.6 (2)
O1—B1—F2—K1^vi	169.55 (14)	K1—C11—C12—C13	104.41 (13)
C1—B1—F2—K1^vi	−65.0 (3)	O1—C11—C12—C2	−3.2 (2)
K1ⁱⁱⁱ—B1—F2—K1^vi	170.5 (2)	C16—C11—C12—C2	175.51 (13)
K1—B1—F2—K1^vi	106.56 (19)	K1—C11—C12—C2	−76.51 (16)
F1—B1—F2—K1ⁱⁱⁱ	−114.22 (9)	C1—C2—C12—C13	−171.25 (13)
O1—B1—F2—K1ⁱⁱⁱ	−0.96 (11)	C3—C2—C12—C13	10.9 (2)
C1—B1—F2—K1ⁱⁱⁱ	124.51 (10)	C1—C2—C12—C11	9.7 (2)
K1—B1—F2—K1ⁱⁱⁱ	−63.96 (7)	C3—C2—C12—C11	−168.10 (13)
F2—B1—C1—C6	40.77 (19)	C11—C12—C13—C14	2.3 (2)
F1—B1—C1—C6	−76.55 (17)	C2—C12—C13—C14	−176.70 (14)
O1—B1—C1—C6	161.72 (13)	C12—C13—C14—C15	0.3 (2)
K1ⁱⁱⁱ—B1—C1—C6	101.37 (15)	C13—C14—C15—C16	−1.9 (2)
K1—B1—C1—C6	−128.40 (13)	C14—C15—C16—C11	0.6 (2)
F2—B1—C1—C2	−139.97 (13)	C14—C15—C16—K1	−92.15 (17)
F1—B1—C1—C2	102.71 (15)	O1—C11—C16—C15	−179.02 (13)
O1—B1—C1—C2	−19.02 (18)	C12—C11—C16—C15	2.2 (2)
K1ⁱⁱⁱ—B1—C1—C2	−79.37 (16)	K1—C11—C16—C15	−127.73 (13)
K1—B1—C1—C2	50.86 (18)	O1—C11—C16—K1	−51.29 (10)
C6—C1—C2—C3	−0.8 (2)	C12—C11—C16—K1	129.90 (13)

Symmetry codes: (i) x, y+1, z; (ii) −x+1, y+1/2, −z+1/2; (iii) −x+1, −y+1, −z+1; (iv) −x+1, −y+2, −z+1; (v) −x+1, y−1/2, −z+1/2; (vi) x, y−1, z.

Bis(tetraphenylphosphonium) 6,6-difluoro-6H-dibenzo[c,e][1,2]oxaborinin-6-ide acetonitrile trisolvate (III) top

Crystal data top

2C₂₄H₂₀P⁺·2C₁₂H₈BF₂O⁻·3C₂H₃N	Z = 2
M_r = 1235.89	F(000) = 1292
Triclinic, P1	D_x = 1.272 Mg m⁻³
a = 10.3527 (4) Å	Mo Kα radiation, λ = 0.71073 Å
b = 13.5958 (5) Å	Cell parameters from 61056 reflections
c = 23.4352 (9) Å	θ = 2.0–25.9°
α = 86.218 (3)°	µ = 0.13 mm⁻¹
β = 78.916 (3)°	T = 173 K
γ = 87.104 (3)°	Block, colourless
V = 3227.6 (2) Å³	0.42 × 0.38 × 0.29 mm

Data collection top

STOE IPDS II two-circle diffractometer	10863 reflections with I > 2σ(I)
ω scans	R_int = 0.040
Absorption correction: multi-scan (X-Area; Stoe & Cie, 2001)	θ_max = 25.4°, θ_min = 2.0°
T_min = 0.947, T_max = 0.963	h = −12→12
47827 measured reflections	k = −16→16
11854 independent reflections	l = −27→28

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F² > 2σ(F²)] = 0.041	H-atom parameters constrained
wR(F²) = 0.109	w = 1/[σ²(F_o²) + (0.0516P)² + 1.4271P] where P = (F_o² + 2F_c²)/3
S = 1.05	(Δ/σ)_max = 0.001
11854 reflections	Δρ_max = 0.48 e Å⁻³
842 parameters	Δρ_min = −0.44 e Å⁻³
0 restraints

Special details top

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
O1	0.12452 (13)	0.43049 (8)	0.25804 (5)	0.0398 (3)
B1	0.12323 (19)	0.37459 (13)	0.20674 (8)	0.0328 (4)
F1	0.22126 (13)	0.41208 (8)	0.16118 (5)	0.0551 (3)
F2	0.00205 (12)	0.39835 (8)	0.18908 (5)	0.0531 (3)
C1	0.14294 (14)	0.25805 (11)	0.21957 (7)	0.0292 (3)
C2	0.17145 (14)	0.21953 (11)	0.27317 (7)	0.0272 (3)
C3	0.18519 (15)	0.11698 (11)	0.28362 (7)	0.0315 (3)
H3	0.204651	0.091107	0.319803	0.038*
C4	0.17073 (16)	0.05318 (12)	0.24187 (8)	0.0354 (4)
H4	0.179876	−0.016049	0.249542	0.043*
C5	0.14293 (16)	0.09020 (12)	0.18890 (8)	0.0371 (4)
H5	0.133030	0.046587	0.160114	0.045*
C6	0.12967 (16)	0.19123 (12)	0.17818 (7)	0.0353 (4)
H6	0.111004	0.216017	0.141658	0.042*
C11	0.15851 (15)	0.39085 (11)	0.30763 (7)	0.0312 (3)
C12	0.18343 (14)	0.28890 (11)	0.31781 (7)	0.0268 (3)
C13	0.21755 (15)	0.25770 (12)	0.37135 (7)	0.0311 (3)
H13	0.235772	0.189468	0.379119	0.037*
C14	0.22553 (16)	0.32294 (13)	0.41318 (7)	0.0345 (3)
H14	0.247785	0.299361	0.449264	0.041*
C15	0.20102 (17)	0.42267 (13)	0.40237 (7)	0.0373 (4)
H15	0.206986	0.467925	0.430872	0.045*
C16	0.16792 (18)	0.45616 (12)	0.35008 (8)	0.0381 (4)
H16	0.151223	0.524744	0.342801	0.046*
P1	0.67556 (4)	0.15494 (3)	0.35037 (2)	0.02367 (9)
C21	0.67013 (15)	0.12421 (10)	0.27748 (6)	0.0272 (3)
C22	0.78659 (17)	0.10811 (12)	0.23759 (7)	0.0356 (4)
H22	0.869235	0.106773	0.249633	0.043*
C23	0.7804 (2)	0.09407 (14)	0.18009 (8)	0.0459 (4)
H23	0.859167	0.082089	0.152714	0.055*
C24	0.6604 (2)	0.09741 (15)	0.16243 (8)	0.0481 (5)
H24	0.657115	0.086850	0.123079	0.058*
C25	0.54518 (19)	0.11599 (13)	0.20154 (8)	0.0411 (4)
H25	0.463168	0.119617	0.188864	0.049*
C26	0.54918 (16)	0.12932 (11)	0.25924 (7)	0.0322 (3)
H26	0.470016	0.141883	0.286267	0.039*
C31	0.53405 (14)	0.10965 (10)	0.39992 (6)	0.0248 (3)
C32	0.47498 (15)	0.02422 (11)	0.38891 (7)	0.0281 (3)
H32	0.505119	−0.007380	0.353556	0.034*
C33	0.37240 (15)	−0.01386 (11)	0.42989 (7)	0.0318 (3)
H33	0.331854	−0.071696	0.422591	0.038*
C34	0.32868 (15)	0.03207 (11)	0.48147 (7)	0.0322 (3)
H34	0.256819	0.006415	0.508956	0.039*
C35	0.38893 (15)	0.11528 (11)	0.49337 (7)	0.0309 (3)
H35	0.359439	0.145623	0.529190	0.037*
C36	0.49214 (15)	0.15399 (11)	0.45292 (7)	0.0284 (3)
H36	0.534334	0.210452	0.461115	0.034*
C41	0.81841 (14)	0.09717 (11)	0.37314 (6)	0.0266 (3)
C42	0.85557 (16)	0.00071 (11)	0.35834 (7)	0.0335 (3)
H42	0.811375	−0.031069	0.333132	0.040*
C43	0.95702 (17)	−0.04846 (13)	0.38051 (8)	0.0400 (4)
H43	0.983616	−0.113748	0.369988	0.048*
C44	1.01967 (16)	−0.00275 (13)	0.41791 (8)	0.0402 (4)
H44	1.089368	−0.036748	0.433015	0.048*
C45	0.98160 (16)	0.09215 (13)	0.43351 (8)	0.0379 (4)
H45	1.024512	0.122775	0.459638	0.046*
C46	0.88125 (15)	0.14277 (12)	0.41124 (7)	0.0314 (3)
H46	0.855390	0.208128	0.421831	0.038*
C51	0.68050 (15)	0.28636 (10)	0.34950 (6)	0.0258 (3)
C52	0.79962 (15)	0.33163 (11)	0.32810 (7)	0.0309 (3)
H52	0.878918	0.292910	0.318517	0.037*
C53	0.80107 (17)	0.43362 (12)	0.32097 (7)	0.0351 (4)
H53	0.881769	0.465079	0.306699	0.042*
C54	0.68499 (17)	0.48980 (11)	0.33462 (7)	0.0346 (4)
H54	0.686732	0.559677	0.329805	0.041*
C55	0.56697 (17)	0.44518 (12)	0.35513 (7)	0.0345 (3)
H55	0.487928	0.484344	0.364219	0.041*
C56	0.56353 (15)	0.34322 (11)	0.36250 (7)	0.0301 (3)
H56	0.482246	0.312297	0.376277	0.036*
O1A	0.46591 (11)	0.79394 (8)	0.34012 (5)	0.0348 (2)
B1A	0.32951 (18)	0.76328 (13)	0.34453 (8)	0.0312 (4)
F1A	0.25501 (10)	0.84978 (7)	0.33229 (5)	0.0436 (2)
F2A	0.32692 (11)	0.69946 (7)	0.29946 (4)	0.0425 (2)
C1A	0.27336 (15)	0.71222 (11)	0.40733 (7)	0.0299 (3)
C2A	0.36027 (16)	0.67457 (11)	0.44359 (7)	0.0289 (3)
C3A	0.30921 (18)	0.62809 (12)	0.49817 (7)	0.0364 (4)
H3A	0.367670	0.602655	0.522687	0.044*
C4A	0.1751 (2)	0.61904 (13)	0.51648 (8)	0.0432 (4)
H4A	0.141895	0.587255	0.553332	0.052*
C5A	0.08914 (19)	0.65624 (14)	0.48120 (9)	0.0457 (4)
H5A	−0.003151	0.650298	0.493725	0.055*
C6A	0.13839 (17)	0.70203 (13)	0.42769 (8)	0.0390 (4)
H6A	0.078495	0.727520	0.403857	0.047*
C11A	0.54740 (16)	0.74683 (11)	0.37201 (7)	0.0307 (3)
C12A	0.50301 (16)	0.68660 (11)	0.42267 (7)	0.0296 (3)
C13A	0.59866 (18)	0.64043 (12)	0.45160 (8)	0.0376 (4)
H13A	0.570852	0.598894	0.485508	0.045*
C14A	0.73140 (18)	0.65331 (14)	0.43247 (9)	0.0452 (4)
H14A	0.793671	0.620652	0.452860	0.054*
C15A	0.77353 (18)	0.71413 (14)	0.38338 (9)	0.0463 (5)
H15A	0.864899	0.723935	0.370258	0.056*
C16A	0.68276 (17)	0.76060 (13)	0.35343 (8)	0.0388 (4)
H16A	0.712373	0.802395	0.319832	0.047*
P1A	0.74154 (4)	0.67262 (3)	0.14593 (2)	0.02748 (10)
C21A	0.61990 (15)	0.77059 (11)	0.14360 (7)	0.0290 (3)
C22A	0.58843 (18)	0.80677 (13)	0.09096 (8)	0.0389 (4)
H22A	0.633680	0.781568	0.055405	0.047*
C23A	0.4905 (2)	0.87989 (15)	0.09080 (9)	0.0495 (5)
H23A	0.469425	0.905880	0.054929	0.059*
C24A	0.42331 (19)	0.91521 (14)	0.14263 (9)	0.0466 (4)
H24A	0.355582	0.964914	0.142184	0.056*
C25A	0.45370 (18)	0.87892 (12)	0.19509 (8)	0.0394 (4)
H25A	0.406434	0.903138	0.230570	0.047*
C26A	0.55279 (16)	0.80746 (11)	0.19586 (7)	0.0334 (3)
H26A	0.575369	0.783373	0.231790	0.040*
C31A	0.66018 (16)	0.56238 (11)	0.17613 (7)	0.0322 (3)
C32A	0.72734 (19)	0.47093 (12)	0.16976 (9)	0.0419 (4)
H32A	0.816655	0.466797	0.150269	0.050*
C33A	0.6618 (2)	0.38587 (13)	0.19234 (10)	0.0514 (5)
H33A	0.707222	0.323427	0.188851	0.062*
C34A	0.5318 (2)	0.39153 (14)	0.21965 (9)	0.0518 (5)
H34A	0.487228	0.332857	0.233800	0.062*
C35A	0.4661 (2)	0.48134 (14)	0.22657 (9)	0.0487 (5)
H35A	0.376676	0.484745	0.245929	0.058*
C36A	0.52989 (18)	0.56706 (13)	0.20543 (8)	0.0388 (4)
H36A	0.484588	0.629246	0.210937	0.047*
C41A	0.85613 (15)	0.70925 (11)	0.18844 (7)	0.0294 (3)
C42A	0.93100 (18)	0.63853 (12)	0.21477 (8)	0.0374 (4)
H42A	0.917951	0.570346	0.212493	0.045*
C43A	1.0246 (2)	0.66824 (13)	0.24431 (9)	0.0457 (4)
H43A	1.075962	0.620113	0.262275	0.055*
C44A	1.04410 (19)	0.76758 (13)	0.24791 (9)	0.0437 (4)
H44A	1.108785	0.787400	0.268126	0.052*
C45A	0.96920 (18)	0.83766 (13)	0.22203 (8)	0.0417 (4)
H45A	0.981968	0.905736	0.224882	0.050*
C46A	0.87565 (17)	0.80948 (12)	0.19197 (8)	0.0353 (4)
H46A	0.825052	0.857948	0.173851	0.042*
C51A	0.82688 (17)	0.65247 (13)	0.07317 (7)	0.0368 (4)
C52A	0.7733 (2)	0.59274 (16)	0.03807 (9)	0.0542 (5)
H52A	0.695692	0.558136	0.053530	0.065*
C53A	0.8346 (3)	0.5845 (2)	−0.01946 (10)	0.0737 (8)
H53A	0.798253	0.544150	−0.043517	0.088*
C54A	0.9469 (3)	0.6338 (2)	−0.04215 (10)	0.0799 (9)
H54A	0.987884	0.627627	−0.081730	0.096*
C55A	1.0004 (3)	0.6921 (2)	−0.00771 (11)	0.0783 (8)
H55A	1.078704	0.725655	−0.023523	0.094*
C56A	0.9404 (2)	0.70232 (17)	0.05041 (9)	0.0543 (5)
H56A	0.977155	0.743069	0.074091	0.065*
N61	1.0162 (5)	0.9547 (3)	0.07570 (13)	0.1405 (15)
C62	1.1110 (4)	0.9774 (3)	0.04320 (13)	0.0991 (11)
C63	1.2218 (4)	1.0112 (5)	0.0041 (2)	0.156 (2)
H63A	1.195474	1.037192	−0.032195	0.235*
H63B	1.286666	0.956532	−0.004253	0.235*
H63C	1.260647	1.063580	0.021245	0.235*
N71	0.4432 (5)	0.1390 (3)	0.05427 (14)	0.1466 (16)
C72	0.4540 (4)	0.2169 (3)	0.06671 (11)	0.0886 (9)
C73	0.4630 (3)	0.3133 (3)	0.08298 (14)	0.0933 (10)
H73A	0.390831	0.327689	0.115388	0.140*
H73B	0.457012	0.359912	0.049792	0.140*
H73C	0.547505	0.319626	0.095136	0.140*
N81	0.4309 (7)	0.5722 (6)	0.0455 (4)	0.143 (3)	0.545 (5)
C82	0.3563 (6)	0.6043 (5)	0.0833 (4)	0.098 (2)	0.545 (5)
N81'	0.2713 (7)	0.7449 (6)	0.0256 (4)	0.118 (3)	0.455 (5)
C82'	0.2828 (6)	0.6973 (5)	0.0668 (4)	0.0790 (19)	0.455 (5)
C83	0.2753 (5)	0.6434 (3)	0.1246 (2)	0.1204 (14)
H83A	0.255574	0.595002	0.157706	0.181*	0.545 (5)
H83B	0.193732	0.664258	0.111112	0.181*	0.545 (5)
H83C	0.314423	0.700794	0.136783	0.181*	0.545 (5)
H83D	0.234341	0.580029	0.124309	0.181*	0.455 (5)
H83E	0.222277	0.682864	0.154807	0.181*	0.455 (5)
H83F	0.364246	0.631736	0.132872	0.181*	0.455 (5)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
O1	0.0612 (8)	0.0272 (6)	0.0336 (6)	0.0045 (5)	−0.0171 (6)	−0.0024 (5)
B1	0.0377 (9)	0.0315 (9)	0.0300 (9)	0.0016 (7)	−0.0090 (7)	−0.0014 (7)
F1	0.0722 (8)	0.0427 (6)	0.0432 (6)	−0.0100 (5)	0.0072 (5)	0.0038 (5)
F2	0.0583 (7)	0.0446 (6)	0.0648 (7)	0.0157 (5)	−0.0346 (6)	−0.0109 (5)
C1	0.0244 (7)	0.0316 (8)	0.0313 (8)	−0.0013 (6)	−0.0040 (6)	−0.0041 (6)
C2	0.0209 (7)	0.0284 (7)	0.0313 (8)	−0.0018 (5)	−0.0022 (6)	−0.0027 (6)
C3	0.0286 (8)	0.0294 (8)	0.0360 (8)	−0.0016 (6)	−0.0050 (6)	−0.0010 (6)
C4	0.0305 (8)	0.0279 (8)	0.0471 (10)	−0.0010 (6)	−0.0040 (7)	−0.0063 (7)
C5	0.0346 (8)	0.0357 (9)	0.0427 (10)	−0.0004 (7)	−0.0076 (7)	−0.0146 (7)
C6	0.0351 (8)	0.0387 (9)	0.0334 (9)	0.0001 (7)	−0.0086 (7)	−0.0068 (7)
C11	0.0319 (8)	0.0307 (8)	0.0314 (8)	−0.0008 (6)	−0.0067 (6)	−0.0019 (6)
C12	0.0208 (7)	0.0293 (7)	0.0295 (8)	−0.0024 (5)	−0.0024 (6)	−0.0018 (6)
C13	0.0279 (7)	0.0325 (8)	0.0326 (8)	−0.0001 (6)	−0.0055 (6)	−0.0003 (6)
C14	0.0310 (8)	0.0446 (9)	0.0284 (8)	0.0007 (7)	−0.0066 (6)	−0.0032 (7)
C15	0.0377 (9)	0.0415 (9)	0.0337 (9)	−0.0009 (7)	−0.0064 (7)	−0.0119 (7)
C16	0.0471 (10)	0.0299 (8)	0.0382 (9)	0.0008 (7)	−0.0089 (7)	−0.0065 (7)
P1	0.02439 (18)	0.02135 (18)	0.02522 (19)	−0.00115 (13)	−0.00411 (14)	−0.00261 (13)
C21	0.0320 (8)	0.0223 (7)	0.0270 (7)	−0.0013 (6)	−0.0051 (6)	−0.0019 (5)
C22	0.0360 (8)	0.0366 (8)	0.0334 (9)	0.0030 (7)	−0.0045 (7)	−0.0056 (7)
C23	0.0520 (11)	0.0497 (11)	0.0327 (9)	0.0048 (8)	0.0010 (8)	−0.0102 (8)
C24	0.0655 (13)	0.0507 (11)	0.0305 (9)	−0.0041 (9)	−0.0116 (9)	−0.0105 (8)
C25	0.0480 (10)	0.0427 (9)	0.0367 (9)	−0.0070 (8)	−0.0167 (8)	−0.0031 (7)
C26	0.0351 (8)	0.0298 (8)	0.0328 (8)	−0.0029 (6)	−0.0085 (7)	−0.0015 (6)
C31	0.0250 (7)	0.0228 (7)	0.0267 (7)	−0.0004 (5)	−0.0055 (6)	−0.0006 (5)
C32	0.0302 (7)	0.0243 (7)	0.0300 (8)	−0.0009 (6)	−0.0059 (6)	−0.0032 (6)
C33	0.0304 (8)	0.0265 (7)	0.0387 (9)	−0.0050 (6)	−0.0069 (7)	−0.0001 (6)
C34	0.0282 (7)	0.0319 (8)	0.0343 (8)	−0.0026 (6)	−0.0024 (6)	0.0038 (6)
C35	0.0327 (8)	0.0317 (8)	0.0269 (8)	0.0025 (6)	−0.0030 (6)	−0.0024 (6)
C36	0.0309 (8)	0.0251 (7)	0.0298 (8)	−0.0017 (6)	−0.0068 (6)	−0.0036 (6)
C41	0.0248 (7)	0.0259 (7)	0.0283 (7)	−0.0020 (6)	−0.0034 (6)	0.0006 (6)
C42	0.0341 (8)	0.0285 (8)	0.0381 (9)	0.0007 (6)	−0.0079 (7)	−0.0029 (6)
C43	0.0373 (9)	0.0323 (8)	0.0477 (10)	0.0078 (7)	−0.0054 (8)	0.0021 (7)
C44	0.0293 (8)	0.0461 (10)	0.0432 (10)	0.0018 (7)	−0.0080 (7)	0.0120 (8)
C45	0.0317 (8)	0.0474 (10)	0.0363 (9)	−0.0106 (7)	−0.0106 (7)	0.0058 (7)
C46	0.0322 (8)	0.0300 (8)	0.0322 (8)	−0.0062 (6)	−0.0055 (6)	−0.0001 (6)
C51	0.0300 (7)	0.0227 (7)	0.0250 (7)	−0.0019 (6)	−0.0059 (6)	−0.0019 (5)
C52	0.0297 (8)	0.0291 (8)	0.0331 (8)	−0.0018 (6)	−0.0042 (6)	−0.0003 (6)
C53	0.0395 (9)	0.0300 (8)	0.0365 (9)	−0.0104 (7)	−0.0078 (7)	0.0020 (6)
C54	0.0490 (10)	0.0229 (7)	0.0341 (8)	−0.0040 (7)	−0.0127 (7)	−0.0028 (6)
C55	0.0398 (9)	0.0273 (8)	0.0373 (9)	0.0045 (6)	−0.0097 (7)	−0.0065 (6)
C56	0.0299 (8)	0.0282 (7)	0.0324 (8)	−0.0013 (6)	−0.0059 (6)	−0.0039 (6)
O1A	0.0374 (6)	0.0347 (6)	0.0329 (6)	−0.0041 (5)	−0.0090 (5)	0.0023 (5)
B1A	0.0355 (9)	0.0288 (8)	0.0313 (9)	0.0030 (7)	−0.0116 (7)	−0.0043 (7)
F1A	0.0479 (6)	0.0391 (5)	0.0445 (6)	0.0096 (4)	−0.0151 (5)	0.0034 (4)
F2A	0.0525 (6)	0.0447 (6)	0.0326 (5)	−0.0058 (5)	−0.0103 (4)	−0.0106 (4)
C1A	0.0334 (8)	0.0255 (7)	0.0320 (8)	0.0011 (6)	−0.0080 (6)	−0.0071 (6)
C2A	0.0371 (8)	0.0233 (7)	0.0279 (8)	−0.0003 (6)	−0.0081 (6)	−0.0072 (6)
C3A	0.0514 (10)	0.0313 (8)	0.0287 (8)	−0.0047 (7)	−0.0117 (7)	−0.0048 (6)
C4A	0.0583 (11)	0.0386 (9)	0.0302 (9)	−0.0129 (8)	0.0026 (8)	−0.0069 (7)
C5A	0.0385 (9)	0.0481 (10)	0.0477 (11)	−0.0071 (8)	0.0033 (8)	−0.0126 (8)
C6A	0.0348 (9)	0.0384 (9)	0.0444 (10)	0.0019 (7)	−0.0082 (7)	−0.0065 (7)
C11A	0.0344 (8)	0.0278 (7)	0.0318 (8)	−0.0007 (6)	−0.0086 (6)	−0.0104 (6)
C12A	0.0359 (8)	0.0255 (7)	0.0304 (8)	0.0013 (6)	−0.0118 (6)	−0.0096 (6)
C13A	0.0447 (9)	0.0348 (8)	0.0383 (9)	0.0050 (7)	−0.0189 (8)	−0.0111 (7)
C14A	0.0422 (10)	0.0469 (10)	0.0543 (11)	0.0090 (8)	−0.0247 (9)	−0.0216 (9)
C15A	0.0319 (9)	0.0531 (11)	0.0588 (12)	−0.0012 (8)	−0.0126 (8)	−0.0290 (9)
C16A	0.0377 (9)	0.0399 (9)	0.0398 (9)	−0.0087 (7)	−0.0042 (7)	−0.0136 (7)
P1A	0.0303 (2)	0.02541 (19)	0.0278 (2)	0.00102 (15)	−0.00815 (15)	−0.00298 (15)
C21A	0.0310 (8)	0.0254 (7)	0.0314 (8)	−0.0003 (6)	−0.0079 (6)	−0.0017 (6)
C22A	0.0455 (10)	0.0404 (9)	0.0307 (9)	0.0091 (7)	−0.0093 (7)	−0.0040 (7)
C23A	0.0583 (12)	0.0509 (11)	0.0411 (10)	0.0184 (9)	−0.0198 (9)	−0.0010 (8)
C24A	0.0459 (10)	0.0419 (10)	0.0513 (11)	0.0160 (8)	−0.0116 (9)	−0.0055 (8)
C25A	0.0419 (9)	0.0347 (9)	0.0400 (9)	0.0045 (7)	−0.0032 (7)	−0.0075 (7)
C26A	0.0395 (9)	0.0297 (8)	0.0310 (8)	−0.0006 (6)	−0.0071 (7)	−0.0018 (6)
C31A	0.0386 (8)	0.0265 (7)	0.0353 (8)	−0.0017 (6)	−0.0162 (7)	−0.0022 (6)
C32A	0.0461 (10)	0.0307 (8)	0.0543 (11)	0.0032 (7)	−0.0227 (9)	−0.0073 (7)
C33A	0.0759 (14)	0.0244 (8)	0.0626 (13)	−0.0003 (8)	−0.0355 (11)	−0.0024 (8)
C34A	0.0721 (14)	0.0361 (10)	0.0525 (12)	−0.0190 (9)	−0.0242 (10)	0.0066 (8)
C35A	0.0535 (11)	0.0443 (10)	0.0489 (11)	−0.0154 (9)	−0.0101 (9)	0.0052 (8)
C36A	0.0427 (9)	0.0328 (8)	0.0413 (9)	−0.0048 (7)	−0.0089 (8)	0.0007 (7)
C41A	0.0321 (8)	0.0282 (7)	0.0287 (8)	−0.0029 (6)	−0.0072 (6)	−0.0013 (6)
C42A	0.0454 (9)	0.0273 (8)	0.0431 (10)	−0.0011 (7)	−0.0180 (8)	−0.0004 (7)
C43A	0.0519 (11)	0.0367 (9)	0.0557 (12)	0.0000 (8)	−0.0301 (9)	0.0020 (8)
C44A	0.0457 (10)	0.0421 (10)	0.0496 (11)	−0.0069 (8)	−0.0227 (8)	−0.0036 (8)
C45A	0.0459 (10)	0.0307 (8)	0.0524 (11)	−0.0079 (7)	−0.0170 (8)	−0.0031 (7)
C46A	0.0385 (9)	0.0272 (8)	0.0424 (9)	−0.0021 (6)	−0.0134 (7)	0.0003 (7)
C51A	0.0390 (9)	0.0409 (9)	0.0303 (8)	0.0125 (7)	−0.0087 (7)	−0.0054 (7)
C52A	0.0614 (13)	0.0625 (13)	0.0420 (11)	0.0127 (10)	−0.0167 (9)	−0.0194 (9)
C53A	0.093 (2)	0.0893 (18)	0.0426 (12)	0.0362 (16)	−0.0244 (13)	−0.0278 (12)
C54A	0.092 (2)	0.107 (2)	0.0323 (11)	0.0490 (17)	−0.0035 (12)	−0.0099 (13)
C55A	0.0646 (15)	0.108 (2)	0.0500 (14)	0.0099 (14)	0.0137 (12)	0.0074 (14)
C56A	0.0503 (11)	0.0681 (13)	0.0401 (11)	0.0011 (10)	0.0001 (9)	0.0005 (9)
N61	0.210 (4)	0.146 (3)	0.0611 (18)	−0.070 (3)	0.001 (2)	−0.0008 (18)
C62	0.147 (3)	0.099 (2)	0.0497 (16)	−0.032 (2)	−0.0075 (18)	−0.0033 (15)
C63	0.090 (3)	0.255 (6)	0.107 (3)	−0.002 (3)	0.003 (2)	0.050 (4)
N71	0.277 (5)	0.102 (2)	0.0662 (18)	0.009 (3)	−0.049 (2)	−0.0087 (17)
C72	0.125 (3)	0.101 (2)	0.0403 (13)	0.025 (2)	−0.0230 (15)	−0.0093 (14)
C73	0.096 (2)	0.109 (2)	0.079 (2)	0.0287 (18)	−0.0243 (17)	−0.0335 (18)
N81	0.101 (5)	0.151 (6)	0.160 (7)	−0.036 (4)	0.009 (4)	0.032 (5)
C82	0.061 (3)	0.083 (4)	0.143 (7)	−0.022 (3)	−0.010 (4)	0.034 (4)
N81'	0.081 (4)	0.140 (6)	0.139 (7)	−0.021 (4)	−0.039 (4)	0.003 (5)
C82'	0.050 (3)	0.087 (4)	0.103 (5)	−0.017 (3)	−0.019 (3)	−0.001 (4)
C83	0.114 (3)	0.096 (3)	0.154 (4)	−0.003 (2)	−0.041 (3)	0.013 (3)

Geometric parameters (Å, º) top

O1—C11	1.3492 (19)	C3A—H3A	0.9500
O1—B1	1.466 (2)	C4A—C5A	1.383 (3)
B1—F2	1.411 (2)	C4A—H4A	0.9500
B1—F1	1.412 (2)	C5A—C6A	1.380 (3)
B1—C1	1.603 (2)	C5A—H5A	0.9500
C1—C6	1.402 (2)	C6A—H6A	0.9500
C1—C2	1.407 (2)	C11A—C16A	1.403 (2)
C2—C3	1.404 (2)	C11A—C12A	1.411 (2)
C2—C12	1.480 (2)	C12A—C13A	1.405 (2)
C3—C4	1.383 (2)	C13A—C14A	1.377 (3)
C3—H3	0.9500	C13A—H13A	0.9500
C4—C5	1.385 (3)	C14A—C15A	1.384 (3)
C4—H4	0.9500	C14A—H14A	0.9500
C5—C6	1.385 (2)	C15A—C16A	1.382 (3)
C5—H5	0.9500	C15A—H15A	0.9500
C6—H6	0.9500	C16A—H16A	0.9500
C11—C16	1.397 (2)	P1A—C21A	1.7917 (15)
C11—C12	1.410 (2)	P1A—C31A	1.7930 (16)
C12—C13	1.401 (2)	P1A—C51A	1.7947 (17)
C13—C14	1.381 (2)	P1A—C41A	1.7966 (15)
C13—H13	0.9500	C21A—C22A	1.389 (2)
C14—C15	1.383 (2)	C21A—C26A	1.397 (2)
C14—H14	0.9500	C22A—C23A	1.384 (2)
C15—C16	1.378 (2)	C22A—H22A	0.9500
C15—H15	0.9500	C23A—C24A	1.381 (3)
C16—H16	0.9500	C23A—H23A	0.9500
P1—C51	1.7887 (14)	C24A—C25A	1.381 (3)
P1—C31	1.7935 (15)	C24A—H24A	0.9500
P1—C41	1.7944 (15)	C25A—C26A	1.379 (2)
P1—C21	1.7970 (15)	C25A—H25A	0.9500
C21—C22	1.394 (2)	C26A—H26A	0.9500
C21—C26	1.396 (2)	C31A—C36A	1.391 (2)
C22—C23	1.387 (2)	C31A—C32A	1.396 (2)
C22—H22	0.9500	C32A—C33A	1.392 (3)
C23—C24	1.380 (3)	C32A—H32A	0.9500
C23—H23	0.9500	C33A—C34A	1.376 (3)
C24—C25	1.381 (3)	C33A—H33A	0.9500
C24—H24	0.9500	C34A—C35A	1.371 (3)
C25—C26	1.385 (2)	C34A—H34A	0.9500
C25—H25	0.9500	C35A—C36A	1.384 (2)
C26—H26	0.9500	C35A—H35A	0.9500
C31—C36	1.400 (2)	C36A—H36A	0.9500
C31—C32	1.400 (2)	C41A—C42A	1.391 (2)
C32—C33	1.384 (2)	C41A—C46A	1.398 (2)
C32—H32	0.9500	C42A—C43A	1.384 (2)
C33—C34	1.384 (2)	C42A—H42A	0.9500
C33—H33	0.9500	C43A—C44A	1.386 (3)
C34—C35	1.388 (2)	C43A—H43A	0.9500
C34—H34	0.9500	C44A—C45A	1.381 (3)
C35—C36	1.385 (2)	C44A—H44A	0.9500
C35—H35	0.9500	C45A—C46A	1.385 (2)
C36—H36	0.9500	C45A—H45A	0.9500
C41—C46	1.393 (2)	C46A—H46A	0.9500
C41—C42	1.395 (2)	C51A—C56A	1.385 (3)
C42—C43	1.383 (2)	C51A—C52A	1.397 (3)
C42—H42	0.9500	C52A—C53A	1.384 (3)
C43—C44	1.381 (3)	C52A—H52A	0.9500
C43—H43	0.9500	C53A—C54A	1.371 (4)
C44—C45	1.382 (3)	C53A—H53A	0.9500
C44—H44	0.9500	C54A—C55A	1.373 (4)
C45—C46	1.384 (2)	C54A—H54A	0.9500
C45—H45	0.9500	C55A—C56A	1.397 (3)
C46—H46	0.9500	C55A—H55A	0.9500
C51—C52	1.396 (2)	C56A—H56A	0.9500
C51—C56	1.397 (2)	N61—C62	1.162 (5)
C52—C53	1.386 (2)	C62—C63	1.400 (5)
C52—H52	0.9500	C63—H63A	0.9800
C53—C54	1.386 (2)	C63—H63B	0.9800
C53—H53	0.9500	C63—H63C	0.9800
C54—C55	1.379 (2)	N71—C72	1.133 (4)
C54—H54	0.9500	C72—C73	1.401 (5)
C55—C56	1.387 (2)	C73—H73A	0.9800
C55—H55	0.9500	C73—H73B	0.9800
C56—H56	0.9500	C73—H73C	0.9800
O1A—C11A	1.3435 (19)	N81—C82	1.152 (11)
O1A—B1A	1.475 (2)	C82—C83	1.279 (9)
B1A—F2A	1.415 (2)	N81'—C82'	1.150 (10)
B1A—F1A	1.417 (2)	C82'—C83	1.488 (9)
B1A—C1A	1.601 (2)	C83—H83A	0.9800
C1A—C6A	1.398 (2)	C83—H83B	0.9800
C1A—C2A	1.408 (2)	C83—H83C	0.9800
C2A—C3A	1.408 (2)	C83—H83D	0.9800
C2A—C12A	1.479 (2)	C83—H83E	0.9800
C3A—C4A	1.381 (3)	C83—H83F	0.9800

C11—O1—B1	123.95 (13)	C4A—C3A—H3A	119.6
F2—B1—F1	105.79 (14)	C2A—C3A—H3A	119.6
F2—B1—O1	106.94 (14)	C3A—C4A—C5A	120.05 (17)
F1—B1—O1	107.56 (14)	C3A—C4A—H4A	120.0
F2—B1—C1	111.46 (14)	C5A—C4A—H4A	120.0
F1—B1—C1	112.30 (14)	C6A—C5A—C4A	119.53 (17)
O1—B1—C1	112.40 (13)	C6A—C5A—H5A	120.2
C6—C1—C2	117.90 (14)	C4A—C5A—H5A	120.2
C6—C1—B1	121.04 (14)	C5A—C6A—C1A	122.28 (17)
C2—C1—B1	121.05 (13)	C5A—C6A—H6A	118.9
C3—C2—C1	119.71 (14)	C1A—C6A—H6A	118.9
C3—C2—C12	121.62 (14)	O1A—C11A—C16A	117.06 (15)
C1—C2—C12	118.66 (13)	O1A—C11A—C12A	123.26 (14)
C4—C3—C2	120.81 (15)	C16A—C11A—C12A	119.67 (15)
C4—C3—H3	119.6	C13A—C12A—C11A	117.58 (15)
C2—C3—H3	119.6	C13A—C12A—C2A	122.52 (15)
C3—C4—C5	120.03 (15)	C11A—C12A—C2A	119.90 (14)
C3—C4—H4	120.0	C14A—C13A—C12A	122.25 (18)
C5—C4—H4	120.0	C14A—C13A—H13A	118.9
C6—C5—C4	119.52 (15)	C12A—C13A—H13A	118.9
C6—C5—H5	120.2	C13A—C14A—C15A	119.61 (17)
C4—C5—H5	120.2	C13A—C14A—H14A	120.2
C5—C6—C1	122.02 (16)	C15A—C14A—H14A	120.2
C5—C6—H6	119.0	C16A—C15A—C14A	120.04 (17)
C1—C6—H6	119.0	C16A—C15A—H15A	120.0
O1—C11—C16	116.71 (14)	C14A—C15A—H15A	120.0
O1—C11—C12	123.23 (14)	C15A—C16A—C11A	120.84 (18)
C16—C11—C12	120.06 (15)	C15A—C16A—H16A	119.6
C13—C12—C11	117.27 (14)	C11A—C16A—H16A	119.6
C13—C12—C2	122.68 (14)	C21A—P1A—C31A	108.71 (7)
C11—C12—C2	120.05 (14)	C21A—P1A—C51A	109.11 (7)
C14—C13—C12	122.13 (15)	C31A—P1A—C51A	108.93 (8)
C14—C13—H13	118.9	C21A—P1A—C41A	108.19 (7)
C12—C13—H13	118.9	C31A—P1A—C41A	112.38 (7)
C13—C14—C15	119.78 (15)	C51A—P1A—C41A	109.48 (8)
C13—C14—H14	120.1	C22A—C21A—C26A	120.21 (15)
C15—C14—H14	120.1	C22A—C21A—P1A	120.74 (12)
C16—C15—C14	119.73 (15)	C26A—C21A—P1A	119.00 (12)
C16—C15—H15	120.1	C23A—C22A—C21A	119.36 (16)
C14—C15—H15	120.1	C23A—C22A—H22A	120.3
C15—C16—C11	121.03 (16)	C21A—C22A—H22A	120.3
C15—C16—H16	119.5	C24A—C23A—C22A	120.20 (17)
C11—C16—H16	119.5	C24A—C23A—H23A	119.9
C51—P1—C31	111.54 (7)	C22A—C23A—H23A	119.9
C51—P1—C41	110.88 (7)	C25A—C24A—C23A	120.61 (16)
C31—P1—C41	107.22 (7)	C25A—C24A—H24A	119.7
C51—P1—C21	106.97 (7)	C23A—C24A—H24A	119.7
C31—P1—C21	110.05 (7)	C26A—C25A—C24A	119.84 (16)
C41—P1—C21	110.20 (7)	C26A—C25A—H25A	120.1
C22—C21—C26	120.23 (14)	C24A—C25A—H25A	120.1
C22—C21—P1	120.21 (12)	C25A—C26A—C21A	119.77 (15)
C26—C21—P1	119.04 (12)	C25A—C26A—H26A	120.1
C23—C22—C21	119.20 (16)	C21A—C26A—H26A	120.1
C23—C22—H22	120.4	C36A—C31A—C32A	119.58 (16)
C21—C22—H22	120.4	C36A—C31A—P1A	120.51 (12)
C24—C23—C22	120.38 (17)	C32A—C31A—P1A	119.90 (14)
C24—C23—H23	119.8	C33A—C32A—C31A	119.17 (19)
C22—C23—H23	119.8	C33A—C32A—H32A	120.4
C23—C24—C25	120.50 (17)	C31A—C32A—H32A	120.4
C23—C24—H24	119.8	C34A—C33A—C32A	120.51 (18)
C25—C24—H24	119.8	C34A—C33A—H33A	119.7
C24—C25—C26	120.00 (17)	C32A—C33A—H33A	119.7
C24—C25—H25	120.0	C35A—C34A—C33A	120.38 (18)
C26—C25—H25	120.0	C35A—C34A—H34A	119.8
C25—C26—C21	119.65 (16)	C33A—C34A—H34A	119.8
C25—C26—H26	120.2	C34A—C35A—C36A	120.1 (2)
C21—C26—H26	120.2	C34A—C35A—H35A	119.9
C36—C31—C32	119.94 (14)	C36A—C35A—H35A	119.9
C36—C31—P1	119.19 (11)	C35A—C36A—C31A	120.16 (17)
C32—C31—P1	120.49 (11)	C35A—C36A—H36A	119.9
C33—C32—C31	119.56 (14)	C31A—C36A—H36A	119.9
C33—C32—H32	120.2	C42A—C41A—C46A	120.00 (14)
C31—C32—H32	120.2	C42A—C41A—P1A	120.37 (12)
C32—C33—C34	120.22 (14)	C46A—C41A—P1A	119.52 (12)
C32—C33—H33	119.9	C43A—C42A—C41A	119.54 (15)
C34—C33—H33	119.9	C43A—C42A—H42A	120.2
C33—C34—C35	120.58 (15)	C41A—C42A—H42A	120.2
C33—C34—H34	119.7	C42A—C43A—C44A	120.58 (16)
C35—C34—H34	119.7	C42A—C43A—H43A	119.7
C36—C35—C34	119.87 (14)	C44A—C43A—H43A	119.7
C36—C35—H35	120.1	C45A—C44A—C43A	119.80 (16)
C34—C35—H35	120.1	C45A—C44A—H44A	120.1
C35—C36—C31	119.78 (14)	C43A—C44A—H44A	120.1
C35—C36—H36	120.1	C44A—C45A—C46A	120.52 (16)
C31—C36—H36	120.1	C44A—C45A—H45A	119.7
C46—C41—C42	120.02 (14)	C46A—C45A—H45A	119.7
C46—C41—P1	120.48 (12)	C45A—C46A—C41A	119.56 (15)
C42—C41—P1	118.99 (11)	C45A—C46A—H46A	120.2
C43—C42—C41	119.73 (15)	C41A—C46A—H46A	120.2
C43—C42—H42	120.1	C56A—C51A—C52A	120.02 (18)
C41—C42—H42	120.1	C56A—C51A—P1A	119.76 (14)
C44—C43—C42	120.06 (16)	C52A—C51A—P1A	120.03 (15)
C44—C43—H43	120.0	C53A—C52A—C51A	119.3 (2)
C42—C43—H43	120.0	C53A—C52A—H52A	120.3
C43—C44—C45	120.40 (15)	C51A—C52A—H52A	120.3
C43—C44—H44	119.8	C54A—C53A—C52A	120.8 (2)
C45—C44—H44	119.8	C54A—C53A—H53A	119.6
C44—C45—C46	120.28 (16)	C52A—C53A—H53A	119.6
C44—C45—H45	119.9	C53A—C54A—C55A	120.1 (2)
C46—C45—H45	119.9	C53A—C54A—H54A	120.0
C45—C46—C41	119.51 (15)	C55A—C54A—H54A	120.0
C45—C46—H46	120.2	C54A—C55A—C56A	120.5 (3)
C41—C46—H46	120.2	C54A—C55A—H55A	119.8
C52—C51—C56	120.30 (14)	C56A—C55A—H55A	119.8
C52—C51—P1	119.14 (11)	C51A—C56A—C55A	119.3 (2)
C56—C51—P1	119.98 (11)	C51A—C56A—H56A	120.3
C53—C52—C51	119.36 (15)	C55A—C56A—H56A	120.3
C53—C52—H52	120.3	N61—C62—C63	176.1 (5)
C51—C52—H52	120.3	C62—C63—H63A	109.5
C52—C53—C54	120.12 (15)	C62—C63—H63B	109.5
C52—C53—H53	119.9	H63A—C63—H63B	109.5
C54—C53—H53	119.9	C62—C63—H63C	109.5
C55—C54—C53	120.61 (14)	H63A—C63—H63C	109.5
C55—C54—H54	119.7	H63B—C63—H63C	109.5
C53—C54—H54	119.7	N71—C72—C73	178.1 (5)
C54—C55—C56	120.10 (15)	C72—C73—H73A	109.5
C54—C55—H55	119.9	C72—C73—H73B	109.5
C56—C55—H55	119.9	H73A—C73—H73B	109.5
C55—C56—C51	119.49 (14)	C72—C73—H73C	109.5
C55—C56—H56	120.3	H73A—C73—H73C	109.5
C51—C56—H56	120.3	H73B—C73—H73C	109.5
C11A—O1A—B1A	121.33 (13)	N81—C82—C83	177.7 (7)
F2A—B1A—F1A	106.56 (13)	N81'—C82'—C83	170.1 (8)
F2A—B1A—O1A	108.49 (14)	C82—C83—H83A	109.5
F1A—B1A—O1A	106.11 (13)	C82—C83—H83B	109.5
F2A—B1A—C1A	111.64 (13)	H83A—C83—H83B	109.5
F1A—B1A—C1A	112.18 (14)	C82—C83—H83C	109.5
O1A—B1A—C1A	111.55 (13)	H83A—C83—H83C	109.5
C6A—C1A—C2A	117.87 (15)	H83B—C83—H83C	109.5
C6A—C1A—B1A	121.82 (14)	C82'—C83—H83D	109.5
C2A—C1A—B1A	120.30 (14)	C82'—C83—H83E	109.5
C3A—C2A—C1A	119.49 (15)	H83D—C83—H83E	109.5
C3A—C2A—C12A	122.41 (14)	C82'—C83—H83F	109.5
C1A—C2A—C12A	118.10 (14)	H83D—C83—H83F	109.5
C4A—C3A—C2A	120.78 (16)	H83E—C83—H83F	109.5

C11—O1—B1—F2	132.26 (16)	C11A—O1A—B1A—F2A	−95.67 (16)
C11—O1—B1—F1	−114.49 (17)	C11A—O1A—B1A—F1A	150.16 (13)
C11—O1—B1—C1	9.6 (2)	C11A—O1A—B1A—C1A	27.71 (19)
F2—B1—C1—C6	52.6 (2)	F2A—B1A—C1A—C6A	−76.55 (19)
F1—B1—C1—C6	−65.9 (2)	F1A—B1A—C1A—C6A	43.0 (2)
O1—B1—C1—C6	172.65 (14)	O1A—B1A—C1A—C6A	161.88 (14)
F2—B1—C1—C2	−126.09 (15)	F2A—B1A—C1A—C2A	102.47 (16)
F1—B1—C1—C2	115.40 (16)	F1A—B1A—C1A—C2A	−138.00 (14)
O1—B1—C1—C2	−6.0 (2)	O1A—B1A—C1A—C2A	−19.10 (19)
C6—C1—C2—C3	−0.2 (2)	C6A—C1A—C2A—C3A	0.4 (2)
B1—C1—C2—C3	178.55 (14)	B1A—C1A—C2A—C3A	−178.69 (14)
C6—C1—C2—C12	−178.91 (13)	C6A—C1A—C2A—C12A	−179.02 (13)
B1—C1—C2—C12	−0.2 (2)	B1A—C1A—C2A—C12A	1.9 (2)
C1—C2—C3—C4	−0.1 (2)	C1A—C2A—C3A—C4A	0.0 (2)
C12—C2—C3—C4	178.53 (14)	C12A—C2A—C3A—C4A	179.37 (14)
C2—C3—C4—C5	0.3 (2)	C2A—C3A—C4A—C5A	−0.3 (2)
C3—C4—C5—C6	−0.1 (2)	C3A—C4A—C5A—C6A	0.2 (3)
C4—C5—C6—C1	−0.3 (3)	C4A—C5A—C6A—C1A	0.2 (3)
C2—C1—C6—C5	0.4 (2)	C2A—C1A—C6A—C5A	−0.5 (2)
B1—C1—C6—C5	−178.32 (15)	B1A—C1A—C6A—C5A	178.56 (16)
B1—O1—C11—C16	173.48 (16)	B1A—O1A—C11A—C16A	161.76 (14)
B1—O1—C11—C12	−6.8 (2)	B1A—O1A—C11A—C12A	−19.1 (2)
O1—C11—C12—C13	−179.84 (14)	O1A—C11A—C12A—C13A	179.16 (13)
C16—C11—C12—C13	−0.2 (2)	C16A—C11A—C12A—C13A	−1.7 (2)
O1—C11—C12—C2	−0.6 (2)	O1A—C11A—C12A—C2A	−1.2 (2)
C16—C11—C12—C2	179.06 (14)	C16A—C11A—C12A—C2A	177.91 (13)
C3—C2—C12—C13	4.3 (2)	C3A—C2A—C12A—C13A	9.5 (2)
C1—C2—C12—C13	−176.98 (14)	C1A—C2A—C12A—C13A	−171.16 (14)
C3—C2—C12—C11	−174.85 (14)	C3A—C2A—C12A—C11A	−170.15 (14)
C1—C2—C12—C11	3.8 (2)	C1A—C2A—C12A—C11A	9.2 (2)
C11—C12—C13—C14	0.7 (2)	C11A—C12A—C13A—C14A	0.8 (2)
C2—C12—C13—C14	−178.52 (14)	C2A—C12A—C13A—C14A	−178.82 (14)
C12—C13—C14—C15	−0.8 (2)	C12A—C13A—C14A—C15A	0.5 (2)
C13—C14—C15—C16	0.4 (3)	C13A—C14A—C15A—C16A	−0.8 (3)
C14—C15—C16—C11	0.1 (3)	C14A—C15A—C16A—C11A	−0.2 (2)
O1—C11—C16—C15	179.50 (16)	O1A—C11A—C16A—C15A	−179.37 (14)
C12—C11—C16—C15	−0.2 (3)	C12A—C11A—C16A—C15A	1.5 (2)
C51—P1—C21—C22	88.88 (14)	C31A—P1A—C21A—C22A	−107.92 (14)
C31—P1—C21—C22	−149.78 (12)	C51A—P1A—C21A—C22A	10.75 (16)
C41—P1—C21—C22	−31.74 (14)	C41A—P1A—C21A—C22A	129.78 (14)
C51—P1—C21—C26	−82.85 (13)	C31A—P1A—C21A—C26A	69.37 (14)
C31—P1—C21—C26	38.49 (14)	C51A—P1A—C21A—C26A	−171.96 (13)
C41—P1—C21—C26	156.53 (12)	C41A—P1A—C21A—C26A	−52.93 (14)
C26—C21—C22—C23	−2.1 (2)	C26A—C21A—C22A—C23A	0.3 (3)
P1—C21—C22—C23	−173.71 (13)	P1A—C21A—C22A—C23A	177.55 (15)
C21—C22—C23—C24	0.9 (3)	C21A—C22A—C23A—C24A	−1.1 (3)
C22—C23—C24—C25	0.8 (3)	C22A—C23A—C24A—C25A	0.7 (3)
C23—C24—C25—C26	−1.4 (3)	C23A—C24A—C25A—C26A	0.6 (3)
C24—C25—C26—C21	0.2 (3)	C24A—C25A—C26A—C21A	−1.4 (3)
C22—C21—C26—C25	1.5 (2)	C22A—C21A—C26A—C25A	1.0 (2)
P1—C21—C26—C25	173.25 (12)	P1A—C21A—C26A—C25A	−176.32 (13)
C51—P1—C31—C36	−38.09 (14)	C21A—P1A—C31A—C36A	−14.99 (16)
C41—P1—C31—C36	83.48 (13)	C51A—P1A—C31A—C36A	−133.78 (14)
C21—P1—C31—C36	−156.66 (11)	C41A—P1A—C31A—C36A	104.73 (14)
C51—P1—C31—C32	149.03 (12)	C21A—P1A—C31A—C32A	164.34 (13)
C41—P1—C31—C32	−89.40 (13)	C51A—P1A—C31A—C32A	45.56 (15)
C21—P1—C31—C32	30.46 (14)	C41A—P1A—C31A—C32A	−75.94 (15)
C36—C31—C32—C33	2.1 (2)	C36A—C31A—C32A—C33A	0.8 (3)
P1—C31—C32—C33	174.95 (12)	P1A—C31A—C32A—C33A	−178.57 (14)
C31—C32—C33—C34	−0.1 (2)	C31A—C32A—C33A—C34A	1.2 (3)
C32—C33—C34—C35	−1.5 (2)	C32A—C33A—C34A—C35A	−2.0 (3)
C33—C34—C35—C36	1.2 (2)	C33A—C34A—C35A—C36A	0.8 (3)
C34—C35—C36—C31	0.8 (2)	C34A—C35A—C36A—C31A	1.2 (3)
C32—C31—C36—C35	−2.4 (2)	C32A—C31A—C36A—C35A	−1.9 (3)
P1—C31—C36—C35	−175.36 (11)	P1A—C31A—C36A—C35A	177.39 (14)
C51—P1—C41—C46	29.64 (15)	C21A—P1A—C41A—C42A	157.16 (14)
C31—P1—C41—C46	−92.35 (13)	C31A—P1A—C41A—C42A	37.13 (16)
C21—P1—C41—C46	147.88 (12)	C51A—P1A—C41A—C42A	−84.04 (15)
C51—P1—C41—C42	−158.56 (12)	C21A—P1A—C41A—C46A	−26.78 (16)
C31—P1—C41—C42	79.45 (14)	C31A—P1A—C41A—C46A	−146.80 (13)
C21—P1—C41—C42	−40.32 (14)	C51A—P1A—C41A—C46A	92.02 (15)
C46—C41—C42—C43	−1.5 (2)	C46A—C41A—C42A—C43A	−0.1 (3)
P1—C41—C42—C43	−173.39 (13)	P1A—C41A—C42A—C43A	175.99 (15)
C41—C42—C43—C44	1.1 (3)	C41A—C42A—C43A—C44A	0.1 (3)
C42—C43—C44—C45	0.1 (3)	C42A—C43A—C44A—C45A	0.3 (3)
C43—C44—C45—C46	−0.8 (3)	C43A—C44A—C45A—C46A	−0.7 (3)
C44—C45—C46—C41	0.3 (2)	C44A—C45A—C46A—C41A	0.7 (3)
C42—C41—C46—C45	0.9 (2)	C42A—C41A—C46A—C45A	−0.4 (3)
P1—C41—C46—C45	172.58 (12)	P1A—C41A—C46A—C45A	−176.43 (14)
C31—P1—C51—C52	160.72 (12)	C21A—P1A—C51A—C56A	91.18 (16)
C41—P1—C51—C52	41.29 (14)	C31A—P1A—C51A—C56A	−150.29 (15)
C21—P1—C51—C52	−78.89 (13)	C41A—P1A—C51A—C56A	−27.04 (17)
C31—P1—C51—C56	−28.00 (14)	C21A—P1A—C51A—C52A	−83.80 (16)
C41—P1—C51—C56	−147.42 (12)	C31A—P1A—C51A—C52A	34.73 (17)
C21—P1—C51—C56	92.39 (13)	C41A—P1A—C51A—C52A	157.98 (14)
C56—C51—C52—C53	1.3 (2)	C56A—C51A—C52A—C53A	−0.3 (3)
P1—C51—C52—C53	172.52 (12)	P1A—C51A—C52A—C53A	174.66 (16)
C51—C52—C53—C54	−0.5 (2)	C51A—C52A—C53A—C54A	0.3 (3)
C52—C53—C54—C55	−0.3 (2)	C52A—C53A—C54A—C55A	0.2 (4)
C53—C54—C55—C56	0.2 (2)	C53A—C54A—C55A—C56A	−0.5 (4)
C54—C55—C56—C51	0.6 (2)	C52A—C51A—C56A—C55A	−0.1 (3)
C52—C51—C56—C55	−1.3 (2)	P1A—C51A—C56A—C55A	−175.04 (17)
P1—C51—C56—C55	−172.51 (12)	C54A—C55A—C56A—C51A	0.5 (4)

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
C26A—H26A···O1A	0.95	2.58	3.322 (2)	135
C32A—H32A···F2ⁱ	0.95	2.40	3.069 (2)	127
C42A—H42A···F2ⁱ	0.95	2.51	3.378 (2)	152
C44A—H44A···F1Aⁱ	0.95	2.54	3.482 (2)	172
C53—H53···O1ⁱ	0.95	2.59	3.389 (2)	142
C54A—H54A···F2ⁱⁱ	0.95	2.55	3.436 (3)	156
C55A—H55A···N81′ⁱ	0.95	2.52	3.180 (8)	127
C63—H63A···N61ⁱⁱⁱ	0.98	2.58	3.365 (6)	137
C63—H63C···N71^iv	0.98	2.47	3.371 (7)	153
C73—H73A···F1	0.98	2.19	3.106 (4)	156
C73—H73B···N81ⁱⁱ	0.98	2.45	3.313 (10)	146
C83—H83A···F1	0.98	2.52	3.252 (4)	131

Symmetry codes: (i) x+1, y, z; (ii) −x+1, −y+1, −z; (iii) −x+2, −y+2, −z; (iv) x+1, y+1, z.

References

Budanow, A., Sinke, T., Lerner, H.-W. & Bolte, M. (2014). Acta Cryst. C70, 662–667. CSD CrossRef IUCr Journals Google Scholar
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Volume 76| Part 12| December 2020| Pages 1837-1840

https://doi.org/10.1107/S2056989020015066

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research communications\(\def\hfill{\hskip 5em}\def\hfil{\hskip 3em}\def\eqno#1{\hfil {#1}}\)

Two salts of the 6,6-di­fluoro-6H-dibenzo[c,e][1,2]oxaborinin-6-ide anion with different cations

1. Chemical context

2. Structural commentary

3. Supra­molecular features

4. Database survey

5. Synthesis and crystallization

6. Refinement

Supporting information

References

research communications

Two salts of the 6,6-difluoro-6H-dibenzo[c,e][1,2]oxaborinin-6-ide anion with different cations

3. Supramolecular features