Crystal structure of silver carbonate iodide Ag10(CO3)3I4

Suzuki, R.; Watanabe, Y.; Yamane, H.; Kitaura, M.; Uchida, K.; Matsushima, Y.

doi:10.1107/S2056989021006022

research communications

CRYSTALLOGRAPHIC
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ISSN: 2056-9890

Volume 77| Part 7| July 2021| Pages 734-738

https://doi.org/10.1107/S2056989021006022

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Crystal structure of silver carbonate iodide Ag₁₀(CO₃)₃I₄

Ryoji Suzuki,^a Yuta Watanabe,^a Hisanori Yamane,^b Mamoru Kitaura,^c Kento Uchida ^a and Yuta Matsushima ^a ^*

^aChemistry and Chemical Engineering, Yamagata University, 4-3-16 Jonan, Yonezawa, 992-8510, Japan, ^bInstitute of Multidisciplinary Research for Advanced Materials, Tohoku, University, 2-1-1 Katahira, Aoba-ku, Sendai, 980- 8577, Japan, and ^cFaculty of Science, Yamagata University, 1-4-12 Kojirakawa-machi, Yamagata, 990-8560, Japan
^*Correspondence e-mail: ymatsush@yz.yamagata-u.ac.jp

Edited by M. Weil, Vienna University of Technology, Austria (Received 1 March 2021; accepted 9 June 2021; online 25 June 2021)

The title silver carbonate iodide, Ag₁₀(CO₃)₃I₄, decasilver(I) tris(carbonate) tetraiodide, was recently reported as a precursor of the new superionic conductor Ag₁₇(CO₃)₃I₁₁. Ag₁₀(CO₃)₃I₄, was prepared by heating a stoichiometric powder mixture of AgI and Ag₂CO₃ at 430 K. A single-crystal suitable for X-ray diffraction analysis was obtained by slow cooling of a melt with an AgI-rich composition down from 453 K. Ag₁₀(CO₃)₃I₄ exhibits a layered crystal structure packed along [10 $[\overline{1}]$ ], in which Ag atoms are intercalated between the layers of hexagonally close-packed I atoms, and CO₃ groups. Up to now, Cs₃Pb₂(CO₃)₃I is the only other compound containing carbonate groups and iodide ions registered in the Inorganic Crystal Structure Database.

Keywords: crystal structure; silver carbonate iodide; layered structure.

CCDC reference: 2088991

1. Chemical context

α-AgI is a representative superionic conductor of silver ions (Tubandt & Lorenz, 1914 ; Boyce & Huberman, 1979 ), which is synthesized at 420 K from wurzite-type β-AgI and is stable above the phase transition temperature. Many ternary and quaternary compounds containing Ag and I, such as β-Ag₃SI (Takahashi & Yamamoto, 1966 ), Ag₄RbI₅ (Owens & Argue, 1967 ,1970 ; Geller, 1967 ; Bradley & Greene, 1967a ,b ), Ag₄KI₅ (Owens & Argue, 1967; Bradley & Greene, 1966 ,1967b), Ag₃KI₄ (Takahashi et al., 1970 ), Ag₁₉I₁₅P₂O₇, Ag₇I₄PO₄ (Takahashi et al., 1972 ), Ag₆I₄WO₄ (Takahashi et al., 1973 ), and Ag₇(AsO₄)I₄ and Ag₇I₄VO₄ (Scrosati et al., 1975 ) have been synthesized and investigated as silver ion conductors. The crystal structures and Ag⁺ ionic conductivity of several silver compounds prepared by combining AgI and a silver oxyanion salt have also been reported (see Database survey). However, our recent report on the new superionic conductor Ag₁₇(CO₃)₃I₁₁ (Watanabe et al., 2021 ) was the first example of a compound in the AgI–Ag₂CO₃ pseudo-binary system. The superionic conductor Ag₁₇(CO₃)₃I₁₁ was prepared by a reaction between AgI and another silver carbonate iodide, i.e., Ag₁₀(CO₃)₃I₄. Herein, we report the crystal structure analysis of Ag₁₀(CO₃)₃I₄ by single-crystal X-ray diffraction (XRD). It should be noted that Cs₃Pb₂(CO₃)₃I (Liu et al., 2016 ) is the only other compound containing carbonate groups and an iodide ion in its chemical composition that can be currently found in the Inorganic Crystal Structure Database (ICSD; Zagorac et al., 2019 ).

A bulk Ag₁₀(CO₃)₃I₄ sample showed an ionic conductivity of 4.4×10⁻⁶ S cm⁻¹ at room temperature (RT) in the alternating-current impedance method using evaporated Au electrodes. This value is comparable with that of Ag₁₃(AsO₄)₃I₄ (6.4×10⁻⁶ S m⁻¹ at 303 K; Pitzschke et al., 2009a ) and Ag₄IPO₄ (3×10⁻⁶ S m⁻¹ at RT; Oleneva et al., 2008 ).

2. Structural commentary

Ag₁₀(CO₃)₃I₄ crystallizes in a monoclinic cell with the space group P2₁/c. The asymmetric unit of the structure comprises 40 sites for Ag, 16 for I, 12 for C, and 36 for O. The Ag atoms are aligned parallel to (10 $[\overline{1}]$ ), and an Ag layer is sandwiched between a CO₃ layer and the hexagonally aligned I layer, as shown in Fig. 1. The atomic arrangement of Ag and I atoms and CO₃ groups in the layers is projected on (10 $[\overline{1}]$ ) in Fig. 1, and along [101] and [010] in Fig. 2a and Fig. 2b, respectively. Reflecting the complexity of the crystal structure, there is a large variation in the interatomic distances. The shortest interatomic distance for each atom pair (Ag—O, Ag⋯Ag, Ag—I, etc.) is listed in Table 1.

Table 1
Shortest interatomic distances (Å) in the crystal structure of Ag₁₀(CO₃)₃I₄

Atom pair	Distance
Ag12—O23	2.252 (9)
Ag7—I6	2.7140 (14)
Ag26⋯Ag32 (in-layer)	2.9901 (15)
Ag13⋯Ag33 (out-of-layer; across CO₃ layer)	3.0620 (15)
Ag17⋯Ag27ⁱ (out-of-layer; across I layer)	2.9507 (15)
I10⋯I12ⁱⁱ	3.9564 (11)
C1—O1ⁱⁱⁱ (within a CO₃ group)	1.251 (15)
O25⋯O26 (within a CO₃ group)	2.206 (14)
O15⋯O25 (between different CO₃ groups)	2.816 (15)
Symmetry code: (i) x, −y + $[{1\over 2}]$ , z − $[{1\over 2}]$ ; (ii) −x, −y + 1, −z + 1; (iii) x + 1, y + $[{1\over 2}]$ , z + $[{1\over 2}]$ .

Figure 1
Arrangement of Ag and I atoms and CO₃ groups in the crystal structure of Ag₁₀(CO₃)₃I₄ projected on (10 $[\overline{1}]$ ). Displacement ellipsoids are drawn at the 99% probability level.

Figure 2
Projections of the crystal structure of Ag₁₀(CO₃)₃I₄ along [101] (a) and [010] (b).

Fundamental reflections in the XRD pattern were observed at every eight spots along the b* axis in the reciprocal space (Fig. S1 in the supporting information), and a period of b/8 = ∼4.43 Å corresponds to the average I⋯I distance in the layer of two-dimensionally closely packed I atoms along the b axis. The average I⋯I distance is slightly shorter than that of the close-packed I atom layer of β-AgI [4.5910 (11) Å; Yoshiasa et al., 1987 ]. The shortest I⋯I length of 3.9564 (11) Å for I10–I12 in Ag₁₀(CO₃)₃I₄ lies between the values observed in Ag₁₃(AsO₄)₃I₄ [3.9063 (9) Å; Pitzschke et al., 2009a] and Ag₂₆I₁₈(WO₄)₄ [4.03 (3) Å; Chan & Geller, 1977 ].

The CO₃ groups are aligned on approximately every b/4 period with the oxygen atoms oriented in different directions. The C—O bond lengths are in the range from 1.251 (15) Å for C1—O1 to 1.328 (15) Å for C1—O3, with the average length being 1.290 Å, which is longer than the C—O length in Ag₂CO₃ (1.274 Å; Norby et al., 2002 ) but close to those in CaCO₃ (1.282 Å; Maslen et al., 1995 ) and other calcite-type carbonates [1.2852 (4) Å in MgCO₃, 1.2867 (5) Å in MnCO₃, 1.2869 (5) Å in FeCO₃, 1.2859 (6) Å in ZnCO₃, and 1.2853 (4) Å in CaMg(CO₃)₂; Effenberger et al., 1981 ]. The short O⋯O distance of 2.816 (15) Å for O15⋯O25 belonging to different CO₃ groups is close to 2.85 Å as observed in MgCO₃ and ZnCO₃ (Effenberger et al., 1981).

The Ag atoms are coordinated by two or three I atoms, and two, three, or four O atoms of the CO₃ groups, with average distances of 3.20 Å for Ag—I and 2.85 Å for Ag—O. The shortest Ag—I bond length of 2.7140 (14) Å for Ag7—I6 is comparable with that found in Ag₁₃(AsO₄)₃I₄ [2.701 (1) Å; Pitzschke et al., 2009a] but shorter than the Ag—I bond lengths in β-AgI [2.8112 (10) and 2.819 (3) Å; Yoshiasa et al., 1987]. The shortest Ag—O length is 2.252 (9) Å for Ag12—O23, which is slightly longer than the shortest Ag—O length in Ag₂CO₃ (2.245 Å; Norby et al., 2002).

The shortest Ag⋯Ag distance of 2.9507 (15) Å is observed between Ag17 and Ag27 generated in another Ag layer across the I layer by the symmetry operation x, −y + $[{1\over 2}]$ , z − $[{1\over 2}]$ . The second shortest Ag⋯Ag distance is 2.9901 (15) Å and corresponds to Ag26⋯Ag32 in the same Ag layer. The shortest Ag⋯Ag distance across the CO₃ layer is 3.0620 (15) Å for Ag13⋯Ag33. These distances are comparable with the Ag⋯Ag distances reported for Ag₂CO₃ [2.8731 (10) Å; Norby et al., 2002], Ag₈(CrO₄)₃I₂ [2.8797 (8) Å; Pitzschke et al., 2009b ], and Ag₃I(NO₃)₂ [2.942 (8) Å; Birnstock & Britton, 1970 ]. Such short Ag⋯Ag distances are known to stem from the argentophilic d¹⁰⋯d¹⁰ interactions between Ag⁺ cations (Schmidbaur & Schier, 2015 ; Jansen, 1987 ).

3. Database survey

The crystal structures of quaternary inorganic compounds composed of silver and iodide ions and oxyanionic groups, such as Ag₂I(NO₃)₂ (Birnstock & Britton, 1970), Ag₁₆I₁₂P₂O₇ (Garrett et al., 1982 ), Ag₅IP₂O₇ (Adams & Preusser, 1999 ), Ag₄IPO₄ (Oleneva et al., 2008), Ag₈(CrO₄)₃I₂ (Pitzschke et al., 2009b), Ag₉(GeO₄)₂I (Pitzschke et al., 2009c ), Ag₈I₄V₂O₇ (Adams, 1996 ), Ag₁₃(AsO₄)₃I₄ (Pitzschke et al., 2009a), Ag₄I₂SeO₄ (Pitzschke et al., 2008a ), Ag₃ITeO₄ (Pitzschke et al., 2008a), Ag₉I₃(IO₃)₂(SeO₄)₂ (Pitzschke et al., 2008b ) and Ag₂₆I₁₈(WO₄)₄ (Chan & Geller, 1977) have been reported.

4. Synthesis and crystallization

As starting materials, powders of AgI and Ag₂CO₃ were prepared by precipitation from aqueous solutions containing AgNO₃ (99.8%, Kanto Chemical) and KI (99.5%, Kanto Chemical) at 323 K, and aqueous solutions of AgNO₃ and (NH₄)₂CO₃ (>30%_wt as NH₃, Kanto Chemical) at RT, respectively. The obtained polycrystalline solids were thoroughly mixed in an agate mortar at a molar ratio of 4:3 using a small amount of water as a mixing medium.

A bulk brownish sample was prepared at 430 K in a glass tube with one end open. The sample was then powdered with an agate mortar and subjected to powder XRD analysis using a Rigaku MiniFlex 600 powder X-ray diffractometer with Cu Kα radiation (λ = 1.54183 Å) and a 1D detector (Rigaku D/teX Ultra 250).

As for many other silver compounds, Ag₁₀(CO₃)₃I₄ is photo-sensitive. In contrast, Ag₁₀(CO₃)₃I₄ is thermally stable against heat treatment in air; no substantial mass change was observed up to 473 K in a thermogravimetric and differential thermal analysis (TG–DTA, Rigaku Thermo Evo) (Fig. S2), which was performed under a constant dry air flow of 100 sccm at a ramp rate of 3 K min⁻¹, indicating that neither a thermal decomposition nor oxidation occurred. An endothermic effect around 443 K, which can be attributed to the melting of Ag₁₀(CO₃)₃I₄, was observed in the TG–DTA analysis. A sample suitable for single-crystal XRD was prepared by subjecting a mixture of the starting powders containing a slight AgI excess composition (AgI:Ag₂CO₃ = 4.2:3) to the following heat treatment: after heating to 453 K at a ramp rate of 300 K h⁻¹, this temperature was held for 15 min, followed by cooling to 373 K at 1 K h⁻¹. The solidified sample was soft and easy to cut with a knife; however, all specimens obtained by cutting showed diffuse XRD spots and were not suitable for single-crystal XRD measurement. Relatively sharp XRD spots were observed from a fragment with a size of 252×245×78 µm, which was spontaneously and accidentally separated by cracking. The surface of the fragment was black and covered with polycrystalline Ag, which was presumably formed by photodegradation during handling. The fragment was fixed on a glass fiber with an epoxy resin and mounted on a goniometer under red light through a color filter from an LED lamp, and the XRD data were collected at 90 K with an open-flow nitrogen gas cooler (Oxford Cobra) in the dark.

5. Refinement

Crystal data, data collection and structure refinement details are summarized in Table 2. The initial structure model of the space group P2₁/c was obtained by intrinsic phasing in the APEX3 package (Bruker, 2017 ). Large positive and negative difference-Fourier peaks were observed, a feature that was probably caused by reflections overlapped with Debye–Scherrer rings from polycrystalline Ag metal on the surface of the crystal (Fig. S1). From the total independent 16240 reflections, 672 reflection data were excluded to lower the difference level within 2.6 e Å⁻³ with R1 = 0.0573 for 13157 [F_o > 4σ (F_o)] and 0.0689 for all 15568 data with GooF(S) = 1.140. The space groups P2₁, Pc, and P1 with twin models were also tested; however, neither further effective improvement of the R values nor reduction of the residual densities was achieved. The anisotropic displacement parameters of O2, O10, and O15 and the carbon sites were restrained with the ISOR command of SHELXL (Sheldrick, 2015b ) in the final refinement. A Rietveld analysis (Rigaku, 2018 $[Rigaku (2018). PDXL: Integrated X-ray Powder Diffraction Software. Rigaku Co., Tokyo, Japan.]$ ) based on the structural model determined by single-crystal XRD led to monoclinic unit-cell parameters of a = 14.2865 (7), b = 35.5959 (18), c = 17.0182 (8) Å, and β = 122.493 (2)° at RT with R_F/wR = 0.0294/0.0436 (Fig. S3), which validates the structural model determined by single-crystal XRD analysis.

Table 2
Experimental details

Crystal data
Chemical formula	Ag₁₀(CO₃)₃I₄
M_r	1766.33
Crystal system, space group	Monoclinic, P2₁/c
Temperature (K)	90
a, b, c (Å)	14.2342 (11), 35.421 (3), 16.9683 (12)
β (°)	122.725 (3)
V (Å³)	7197.3 (10)
Z	16
Radiation type	Mo Kα
μ (mm⁻¹)	17.53
Crystal size (mm)	0.25 × 0.25 × 0.08

Data collection
Diffractometer	Bruker D8 goniometer
Absorption correction	Multi-scan (SADABS; Krause et al., 2015 )
T_min, T_max	0.376, 0.746
No. of measured, independent and observed [I > 2σ(I)] reflections	75437, 15568, 13140
R_int	0.043
(sin θ/λ)_max (Å⁻¹)	0.649

Refinement
R[F² > 2σ(F²)], wR(F²), S	0.057, 0.126, 1.14
No. of reflections	15568
No. of parameters	937
No. of restraints	90
Δρ_max, Δρ_min (e Å⁻³)	2.22, −2.62
Computer programs: APEX3 (Bruker, 2017), SAINT (Bruker, 2017), SHELXT (Sheldrick, 2015a ), SHELXL (Sheldrick, 2015b), VESTA (Momma & Izumi, 2011 ), and pubCIF (Westrip, 2010 ).

Supporting information

CCDC reference: 2088991

Crystal structure: contains datablocks global, I. DOI: https://doi.org/10.1107/S2056989021006022/wm5603sup1.cif

Structure factors: contains datablock I. DOI: https://doi.org/10.1107/S2056989021006022/wm5603Isup2.hkl

Supplementary figures (Figs. S1-S3). DOI: https://doi.org/10.1107/S2056989021006022/wm5603sup3.pdf

Rietveld powder data: contains datablock I. DOI: https://doi.org/10.1107/S2056989021006022/wm5603Isup4.rtv

checkCIF report

Computing details top

Data collection: APEX3 (Bruker, 2017); cell refinement: SAINT (Bruker, 2017); data reduction: SAINT (Bruker, 2017); program(s) used to solve structure: SHELXT (Sheldrick, 2015a); program(s) used to refine structure: SHELXL (Sheldrick, 2015b); molecular graphics: VESTA (Momma & Izumi, 2011); software used to prepare material for publication: pubCIF (Westrip, 2010).

Decasilver(I) tris(carbonate) tetraidodide top

Crystal data top

Ag₁₀(CO₃)₃I₄	F(000) = 12352
M_r = 1766.33	D_x = 6.520 Mg m⁻³
Monoclinic, P2₁/c	Mo Kα radiation, λ = 0.71073 Å
a = 14.2342 (11) Å	Cell parameters from 4917 reflections
b = 35.421 (3) Å	θ = 2.7–35.6°
c = 16.9683 (12) Å	µ = 17.53 mm⁻¹
β = 122.725 (3)°	T = 90 K
V = 7197.3 (10) Å³	Platelet, brown transparent (black agi precipiated on the surface)
Z = 16	0.25 × 0.25 × 0.08 mm

Data collection top

Bruker D8 goniometer diffractometer	15568 independent reflections
Radiation source: micro focus sealed tube	13140 reflections with I > 2σ(I)
Detector resolution: 7.3910 pixels mm^-1	R_int = 0.043
ω scans	θ_max = 27.5°, θ_min = 2.1°
Absorption correction: multi-scan (SADABS; Krause et al., 2015)	h = −18→18
T_min = 0.376, T_max = 0.746	k = −45→46
75437 measured reflections	l = −22→22

Refinement top

Refinement on F²	90 restraints
Least-squares matrix: full	Primary atom site location: structure-invariant direct methods
R[F² > 2σ(F²)] = 0.057	w = 1/[σ²(F_o²) + (0.0103P)² + 615.6616P] where P = (F_o² + 2F_c²)/3
wR(F²) = 0.126	(Δ/σ)_max = 0.001
S = 1.14	Δρ_max = 2.22 e Å⁻³
15568 reflections	Δρ_min = −2.61 e Å⁻³
937 parameters

Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Ag1	0.08682 (9)	0.06634 (3)	0.20445 (7)	0.0138 (2)
Ag2	0.27633 (10)	0.03132 (3)	0.41983 (8)	0.0169 (2)
Ag3	0.55662 (9)	0.46648 (3)	0.19380 (7)	0.0150 (2)
Ag4	0.26078 (8)	0.57090 (3)	0.60251 (7)	0.01221 (19)
Ag5	0.03496 (8)	0.15772 (3)	0.17435 (7)	0.0125 (2)
Ag6	0.23310 (9)	0.18599 (3)	0.38229 (8)	0.0156 (2)
Ag7	0.43490 (10)	0.37201 (3)	0.05335 (8)	0.0184 (2)
Ag8	0.57487 (9)	0.31065 (3)	0.19823 (7)	0.0148 (2)
Ag9	0.25196 (9)	0.84280 (3)	0.09874 (7)	0.0160 (2)
Ag10	0.07104 (9)	0.75160 (3)	0.45762 (8)	0.0156 (2)
Ag11	0.07064 (9)	0.31349 (3)	0.19972 (7)	0.0156 (2)
Ag12	0.24584 (10)	0.27747 (3)	0.39764 (8)	0.0180 (2)
Ag13	0.55343 (9)	0.21817 (3)	0.18150 (8)	0.0157 (2)
Ag14	0.27216 (9)	0.67637 (3)	0.12176 (7)	0.0126 (2)
Ag15	0.05820 (8)	0.40832 (3)	0.19626 (7)	0.0130 (2)
Ag16	0.24072 (8)	0.44444 (3)	0.40286 (7)	0.0129 (2)
Ag17	0.42669 (9)	0.12869 (3)	0.03557 (7)	0.0136 (2)
Ag18	0.58339 (9)	0.05792 (3)	0.20303 (7)	0.0132 (2)
Ag19	0.22274 (9)	0.59037 (3)	0.06770 (8)	0.0181 (2)
Ag20	0.04730 (9)	0.00277 (3)	0.43913 (7)	0.0156 (2)
Ag21	0.08463 (9)	0.56456 (3)	0.20467 (7)	0.0129 (2)
Ag22	0.24736 (9)	0.53034 (3)	0.40259 (7)	0.0143 (2)
Ag23	0.46246 (8)	0.47035 (3)	0.32099 (7)	0.0122 (2)
Ag24	0.27468 (9)	0.42928 (3)	0.12342 (8)	0.0154 (2)
Ag25	0.04870 (8)	0.65006 (3)	0.19101 (7)	0.0132 (2)
Ag26	0.76530 (9)	0.19821 (3)	0.10542 (7)	0.0129 (2)
Ag27	0.57192 (9)	0.37693 (3)	0.46144 (7)	0.0137 (2)
Ag28	0.41143 (9)	0.30561 (3)	0.29182 (7)	0.0141 (2)
Ag29	0.22283 (10)	0.34487 (3)	0.07409 (8)	0.0178 (2)
Ag30	0.05501 (9)	0.24478 (3)	0.44679 (8)	0.0165 (2)
Ag31	0.08436 (9)	0.81768 (3)	0.20002 (7)	0.0131 (2)
Ag32	0.73211 (9)	0.28175 (3)	0.08057 (7)	0.0157 (2)
Ag33	0.45882 (8)	0.21862 (3)	0.30624 (7)	0.0128 (2)
Ag34	0.26225 (8)	0.18464 (3)	0.09611 (7)	0.0134 (2)
Ag35	0.03659 (8)	0.59658 (3)	0.67807 (7)	0.0125 (2)
Ag36	0.77018 (9)	0.44587 (3)	0.11381 (8)	0.0152 (2)
Ag37	0.54741 (9)	0.12430 (3)	0.44344 (7)	0.0145 (2)
Ag38	0.42942 (9)	0.05817 (3)	0.30366 (7)	0.0153 (2)
Ag39	0.24947 (9)	0.09758 (3)	0.10141 (7)	0.0145 (2)
Ag40	0.07517 (8)	0.49697 (3)	0.46486 (7)	0.0127 (2)
C1	0.1707 (10)	0.6132 (3)	0.4045 (9)	0.006 (2)
C2	0.1744 (11)	0.1016 (4)	0.4183 (10)	0.013 (3)
C3	0.5142 (11)	0.3904 (4)	0.2635 (9)	0.010 (2)
C4	0.0037 (11)	0.2318 (4)	0.2527 (9)	0.010 (2)
C5	0.3262 (9)	0.2685 (3)	0.0821 (8)	0.003 (2)
C6	0.6713 (12)	0.2601 (4)	0.3967 (10)	0.015 (3)
C7	0.8247 (11)	0.3606 (4)	0.0936 (9)	0.009 (2)
C8	0.1722 (11)	0.3591 (4)	0.4040 (10)	0.012 (2)
C9	0.4816 (11)	0.1403 (4)	0.2353 (9)	0.009 (2)
C10	0.0167 (10)	0.4843 (3)	0.2669 (9)	0.008 (2)
C11	0.3319 (11)	0.0134 (4)	0.0990 (9)	0.010 (2)
C12	0.3234 (12)	0.5137 (4)	0.0915 (10)	0.014 (3)
O1	0.7482 (8)	0.0913 (3)	0.0498 (6)	0.0107 (18)
O2	0.0858 (8)	0.6049 (3)	0.3234 (7)	0.0104 (18)
O3	0.1689 (8)	0.6468 (3)	0.4381 (6)	0.0117 (18)
O4	0.1132 (9)	0.0778 (3)	0.3555 (7)	0.016 (2)
O5	0.2745 (8)	0.0917 (3)	0.4871 (7)	0.018 (2)
O6	0.1392 (8)	0.1358 (3)	0.4168 (8)	0.017 (2)
O7	0.4765 (8)	0.4056 (3)	0.1825 (7)	0.0133 (19)
O8	0.5459 (8)	0.4123 (3)	0.3353 (7)	0.0127 (19)
O9	0.5252 (9)	0.3548 (3)	0.2765 (8)	0.019 (2)
O10	0.0376 (8)	0.7185 (3)	0.3300 (7)	0.0116 (18)
O11	0.0329 (8)	0.2081 (3)	0.3213 (7)	0.0116 (18)
O12	0.0199 (8)	0.2671 (3)	0.2713 (7)	0.0129 (19)
O13	0.2394 (9)	0.2290 (3)	0.4959 (7)	0.021 (2)
O14	0.3574 (9)	0.2988 (3)	0.1329 (7)	0.020 (2)
O15	0.3718 (10)	0.2370 (3)	0.1167 (8)	0.024 (2)
O16	0.5860 (8)	0.2710 (3)	0.3183 (7)	0.015 (2)
O17	0.2442 (8)	0.7812 (3)	0.0509 (7)	0.016 (2)
O18	0.3342 (8)	0.7264 (3)	0.0741 (7)	0.0137 (19)
O19	0.7387 (8)	0.3610 (3)	0.0068 (7)	0.016 (2)
O20	0.1418 (8)	0.8301 (3)	0.3600 (7)	0.0126 (19)
O21	0.8723 (8)	0.3927 (3)	0.1296 (7)	0.0128 (19)
O22	0.0857 (8)	0.3514 (3)	0.3222 (7)	0.0122 (19)
O23	0.2538 (8)	0.3370 (2)	0.4474 (7)	0.0122 (19)
O24	0.1684 (8)	0.3910 (3)	0.4422 (7)	0.015 (2)
O25	0.4524 (8)	0.1625 (3)	0.1640 (6)	0.0125 (19)
O26	0.5245 (8)	0.1561 (3)	0.3156 (6)	0.0116 (18)
O27	0.4623 (8)	0.1051 (3)	0.2223 (7)	0.0138 (19)
O28	0.0239 (8)	0.5311 (3)	0.8153 (6)	0.0119 (19)
O29	0.0494 (8)	0.4614 (3)	0.3380 (6)	0.0100 (18)
O30	0.0301 (8)	0.5192 (3)	0.2810 (7)	0.0135 (19)
O31	0.2471 (8)	0.0360 (3)	0.0549 (7)	0.0116 (18)
O32	0.4167 (8)	0.0220 (3)	0.1802 (7)	0.0128 (19)
O33	0.3297 (8)	0.5180 (3)	0.5604 (7)	0.015 (2)
O34	0.3586 (9)	0.5446 (3)	0.1375 (7)	0.017 (2)
O35	0.2370 (9)	0.5143 (4)	0.0050 (8)	0.026 (3)
O36	0.3710 (9)	0.4821 (3)	0.1274 (8)	0.023 (2)
I1	0.23839 (7)	0.50353 (2)	0.75382 (6)	0.01089 (16)
I2	0.02321 (7)	0.56825 (2)	0.49450 (6)	0.00922 (16)
I3	0.51853 (7)	0.05568 (2)	0.49871 (6)	0.01051 (16)
I4	0.02890 (7)	0.31583 (2)	0.49893 (6)	0.00977 (16)
I5	0.24870 (7)	0.12856 (2)	0.25332 (6)	0.01133 (17)
I6	0.48805 (7)	0.30683 (2)	0.00222 (6)	0.01024 (16)
I7	0.74654 (7)	0.37823 (2)	0.25684 (6)	0.01038 (16)
I8	0.24565 (7)	0.24507 (2)	0.24870 (6)	0.01053 (16)
I9	0.23835 (7)	0.74699 (2)	0.25736 (6)	0.01027 (16)
I10	0.01605 (7)	0.82021 (2)	0.49369 (6)	0.01008 (16)
I11	0.52303 (7)	0.30574 (2)	0.49127 (6)	0.00945 (16)
I12	0.00636 (7)	0.06869 (2)	0.49831 (6)	0.01186 (17)
I13	0.26024 (7)	0.37760 (2)	0.24425 (6)	0.01006 (16)
I14	0.26343 (7)	0.62687 (2)	0.24731 (6)	0.01021 (16)
I15	0.47596 (7)	0.05766 (2)	0.00446 (6)	0.00997 (16)
I16	0.24648 (7)	0.49627 (2)	0.25586 (6)	0.01117 (16)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Ag1	0.0155 (5)	0.0147 (5)	0.0103 (5)	−0.0023 (4)	0.0063 (4)	−0.0016 (4)
Ag2	0.0214 (5)	0.0133 (5)	0.0163 (5)	0.0022 (4)	0.0104 (4)	−0.0014 (4)
Ag3	0.0117 (5)	0.0200 (5)	0.0125 (5)	−0.0045 (4)	0.0060 (4)	−0.0011 (4)
Ag4	0.0085 (4)	0.0131 (5)	0.0127 (5)	0.0004 (3)	0.0041 (4)	−0.0010 (4)
Ag5	0.0108 (4)	0.0120 (5)	0.0137 (5)	0.0006 (3)	0.0060 (4)	−0.0007 (4)
Ag6	0.0137 (5)	0.0197 (5)	0.0153 (5)	−0.0005 (4)	0.0092 (4)	−0.0015 (4)
Ag7	0.0198 (5)	0.0203 (5)	0.0127 (5)	0.0083 (4)	0.0073 (4)	−0.0013 (4)
Ag8	0.0201 (5)	0.0124 (5)	0.0097 (5)	0.0007 (4)	0.0066 (4)	0.0005 (4)
Ag9	0.0224 (5)	0.0119 (5)	0.0095 (5)	0.0014 (4)	0.0060 (4)	−0.0018 (4)
Ag10	0.0169 (5)	0.0145 (5)	0.0146 (5)	0.0022 (4)	0.0080 (4)	−0.0036 (4)
Ag11	0.0204 (5)	0.0155 (5)	0.0095 (5)	0.0008 (4)	0.0073 (4)	0.0005 (4)
Ag12	0.0237 (6)	0.0148 (5)	0.0121 (5)	0.0031 (4)	0.0074 (4)	−0.0013 (4)
Ag13	0.0123 (5)	0.0210 (5)	0.0145 (5)	−0.0065 (4)	0.0076 (4)	−0.0026 (4)
Ag14	0.0134 (5)	0.0141 (5)	0.0109 (5)	−0.0013 (4)	0.0070 (4)	0.0019 (4)
Ag15	0.0089 (4)	0.0159 (5)	0.0133 (5)	0.0027 (4)	0.0053 (4)	0.0013 (4)
Ag16	0.0093 (4)	0.0139 (5)	0.0136 (5)	−0.0010 (4)	0.0050 (4)	0.0005 (4)
Ag17	0.0133 (5)	0.0155 (5)	0.0114 (5)	0.0023 (4)	0.0063 (4)	−0.0016 (4)
Ag18	0.0139 (5)	0.0148 (5)	0.0088 (5)	−0.0009 (4)	0.0048 (4)	−0.0010 (4)
Ag19	0.0187 (5)	0.0147 (5)	0.0185 (5)	0.0036 (4)	0.0085 (4)	0.0055 (4)
Ag20	0.0173 (5)	0.0161 (5)	0.0111 (5)	0.0035 (4)	0.0063 (4)	−0.0024 (4)
Ag21	0.0158 (5)	0.0117 (5)	0.0106 (5)	0.0003 (4)	0.0066 (4)	0.0006 (4)
Ag22	0.0182 (5)	0.0115 (5)	0.0082 (5)	0.0014 (4)	0.0038 (4)	−0.0006 (4)
Ag23	0.0084 (4)	0.0128 (5)	0.0138 (5)	−0.0004 (3)	0.0049 (4)	−0.0011 (4)
Ag24	0.0138 (5)	0.0197 (5)	0.0133 (5)	−0.0020 (4)	0.0077 (4)	0.0005 (4)
Ag25	0.0104 (5)	0.0155 (5)	0.0107 (5)	0.0027 (4)	0.0039 (4)	0.0023 (4)
Ag26	0.0112 (5)	0.0116 (4)	0.0144 (5)	0.0005 (3)	0.0060 (4)	−0.0025 (4)
Ag27	0.0142 (5)	0.0138 (5)	0.0125 (5)	−0.0017 (4)	0.0069 (4)	0.0019 (4)
Ag28	0.0154 (5)	0.0153 (5)	0.0095 (5)	−0.0011 (4)	0.0053 (4)	0.0002 (4)
Ag29	0.0236 (6)	0.0136 (5)	0.0159 (5)	0.0048 (4)	0.0105 (5)	0.0039 (4)
Ag30	0.0190 (5)	0.0178 (5)	0.0148 (5)	0.0010 (4)	0.0106 (4)	−0.0034 (4)
Ag31	0.0131 (5)	0.0140 (5)	0.0091 (5)	−0.0003 (4)	0.0040 (4)	0.0004 (4)
Ag32	0.0208 (5)	0.0124 (5)	0.0113 (5)	−0.0035 (4)	0.0071 (4)	−0.0011 (4)
Ag33	0.0106 (5)	0.0134 (5)	0.0147 (5)	0.0006 (4)	0.0069 (4)	−0.0015 (4)
Ag34	0.0085 (4)	0.0161 (5)	0.0132 (5)	−0.0008 (4)	0.0043 (4)	−0.0014 (4)
Ag35	0.0087 (4)	0.0123 (5)	0.0142 (5)	−0.0008 (3)	0.0047 (4)	0.0003 (4)
Ag36	0.0128 (5)	0.0136 (5)	0.0185 (5)	0.0020 (4)	0.0081 (4)	0.0008 (4)
Ag37	0.0155 (5)	0.0150 (5)	0.0119 (5)	−0.0021 (4)	0.0066 (4)	0.0020 (4)
Ag38	0.0213 (5)	0.0147 (5)	0.0094 (5)	−0.0013 (4)	0.0080 (4)	−0.0011 (4)
Ag39	0.0175 (5)	0.0120 (5)	0.0097 (5)	0.0002 (4)	0.0046 (4)	−0.0025 (4)
Ag40	0.0119 (5)	0.0134 (5)	0.0113 (5)	0.0021 (4)	0.0052 (4)	−0.0010 (4)
C1	0.006 (2)	0.006 (2)	0.006 (2)	0.0001 (10)	0.0032 (14)	−0.0001 (10)
C2	0.013 (3)	0.013 (3)	0.013 (3)	0.0002 (10)	0.0069 (16)	−0.0003 (10)
C3	0.010 (3)	0.010 (3)	0.010 (3)	−0.0003 (10)	0.0053 (15)	0.0001 (10)
C4	0.010 (3)	0.010 (3)	0.010 (3)	0.0001 (10)	0.0054 (15)	0.0003 (10)
C5	0.003 (2)	0.003 (2)	0.003 (2)	0.0000 (10)	0.0019 (14)	0.0001 (10)
C6	0.016 (3)	0.016 (3)	0.015 (3)	0.0000 (10)	0.0085 (17)	−0.0001 (10)
C7	0.009 (2)	0.009 (2)	0.009 (2)	0.0004 (10)	0.0048 (15)	−0.0003 (10)
C8	0.012 (3)	0.012 (3)	0.011 (3)	−0.0003 (10)	0.0063 (16)	0.0000 (10)
C9	0.009 (2)	0.009 (2)	0.009 (2)	0.0002 (10)	0.0048 (15)	−0.0002 (10)
C10	0.008 (2)	0.008 (2)	0.008 (2)	−0.0001 (10)	0.0041 (15)	0.0006 (10)
C11	0.010 (3)	0.010 (3)	0.010 (3)	−0.0002 (10)	0.0054 (15)	−0.0001 (10)
C12	0.014 (3)	0.014 (3)	0.014 (3)	0.0001 (10)	0.0079 (16)	−0.0003 (10)
O1	0.013 (4)	0.007 (4)	0.009 (4)	0.001 (3)	0.004 (4)	0.000 (3)
O2	0.010 (2)	0.010 (2)	0.010 (2)	0.0000 (10)	0.0052 (13)	−0.0005 (10)
O3	0.016 (5)	0.012 (4)	0.006 (4)	0.000 (4)	0.006 (4)	0.000 (3)
O4	0.021 (5)	0.015 (5)	0.013 (5)	−0.001 (4)	0.009 (4)	−0.004 (4)
O5	0.012 (5)	0.018 (5)	0.016 (5)	0.002 (4)	0.002 (4)	0.006 (4)
O6	0.010 (5)	0.016 (5)	0.027 (6)	0.001 (4)	0.011 (4)	−0.001 (4)
O7	0.012 (5)	0.018 (5)	0.008 (5)	−0.003 (4)	0.004 (4)	−0.003 (4)
O8	0.013 (5)	0.014 (5)	0.008 (5)	−0.002 (4)	0.004 (4)	−0.002 (4)
O9	0.025 (6)	0.010 (5)	0.030 (6)	0.003 (4)	0.018 (5)	0.003 (4)
O10	0.012 (2)	0.012 (2)	0.011 (2)	−0.0003 (10)	0.0060 (13)	0.0002 (10)
O11	0.012 (4)	0.009 (4)	0.010 (5)	0.000 (3)	0.004 (4)	−0.001 (3)
O12	0.018 (5)	0.006 (4)	0.021 (5)	0.001 (4)	0.015 (4)	0.002 (4)
O13	0.013 (5)	0.029 (6)	0.014 (5)	0.000 (4)	0.002 (4)	−0.005 (4)
O14	0.020 (5)	0.024 (6)	0.014 (5)	0.004 (4)	0.009 (5)	0.006 (4)
O15	0.023 (3)	0.024 (3)	0.024 (3)	0.0003 (10)	0.0129 (15)	0.0003 (10)
O16	0.012 (5)	0.023 (5)	0.009 (5)	0.001 (4)	0.006 (4)	−0.004 (4)
O17	0.010 (5)	0.016 (5)	0.019 (5)	0.001 (4)	0.005 (4)	0.001 (4)
O18	0.017 (5)	0.016 (5)	0.016 (5)	0.003 (4)	0.014 (4)	0.001 (4)
O19	0.016 (5)	0.019 (5)	0.009 (5)	0.001 (4)	0.004 (4)	−0.004 (4)
O20	0.019 (5)	0.014 (5)	0.009 (5)	0.001 (4)	0.010 (4)	0.001 (4)
O21	0.007 (4)	0.012 (4)	0.016 (5)	−0.005 (3)	0.004 (4)	−0.007 (4)
O22	0.016 (5)	0.014 (5)	0.007 (4)	0.001 (4)	0.007 (4)	0.001 (4)
O23	0.011 (4)	0.005 (4)	0.011 (5)	0.003 (3)	0.000 (4)	−0.001 (3)
O24	0.013 (5)	0.015 (5)	0.017 (5)	0.005 (4)	0.007 (4)	0.005 (4)
O25	0.009 (4)	0.014 (5)	0.006 (4)	−0.004 (3)	−0.001 (4)	0.002 (4)
O26	0.013 (5)	0.018 (5)	0.005 (4)	0.003 (4)	0.006 (4)	0.001 (4)
O27	0.012 (5)	0.011 (4)	0.014 (5)	0.001 (4)	0.004 (4)	−0.003 (4)
O28	0.013 (5)	0.011 (4)	0.006 (4)	−0.003 (3)	0.001 (4)	−0.006 (3)
O29	0.008 (4)	0.010 (4)	0.008 (4)	−0.001 (3)	0.002 (4)	0.002 (3)
O30	0.013 (5)	0.009 (4)	0.019 (5)	−0.002 (3)	0.009 (4)	0.000 (4)
O31	0.011 (4)	0.013 (4)	0.010 (5)	0.002 (3)	0.005 (4)	0.003 (4)
O32	0.009 (4)	0.012 (4)	0.011 (5)	−0.003 (3)	0.001 (4)	0.005 (4)
O33	0.018 (5)	0.012 (5)	0.010 (5)	−0.003 (4)	0.005 (4)	0.006 (4)
O34	0.029 (6)	0.013 (5)	0.008 (5)	−0.004 (4)	0.009 (4)	−0.001 (4)
O35	0.010 (5)	0.048 (7)	0.016 (5)	−0.011 (5)	0.004 (4)	−0.002 (5)
O36	0.022 (6)	0.017 (5)	0.031 (6)	−0.002 (4)	0.015 (5)	−0.001 (5)
I1	0.0093 (4)	0.0134 (4)	0.0081 (4)	−0.0014 (3)	0.0035 (3)	−0.0009 (3)
I2	0.0090 (4)	0.0099 (4)	0.0070 (4)	−0.0008 (3)	0.0032 (3)	0.0001 (3)
I3	0.0110 (4)	0.0106 (4)	0.0087 (4)	0.0012 (3)	0.0045 (3)	0.0018 (3)
I4	0.0097 (4)	0.0107 (4)	0.0075 (4)	−0.0008 (3)	0.0037 (3)	0.0001 (3)
I5	0.0087 (4)	0.0119 (4)	0.0092 (4)	−0.0005 (3)	0.0022 (3)	−0.0018 (3)
I6	0.0119 (4)	0.0114 (4)	0.0086 (4)	−0.0006 (3)	0.0063 (3)	−0.0012 (3)
I7	0.0087 (4)	0.0119 (4)	0.0082 (4)	−0.0006 (3)	0.0029 (3)	0.0009 (3)
I8	0.0087 (4)	0.0124 (4)	0.0079 (4)	0.0002 (3)	0.0028 (3)	−0.0004 (3)
I9	0.0094 (4)	0.0129 (4)	0.0071 (4)	0.0016 (3)	0.0035 (3)	0.0010 (3)
I10	0.0107 (4)	0.0102 (4)	0.0080 (4)	0.0001 (3)	0.0041 (3)	−0.0010 (3)
I11	0.0103 (4)	0.0097 (4)	0.0069 (4)	0.0007 (3)	0.0037 (3)	0.0003 (3)
I12	0.0153 (4)	0.0096 (4)	0.0087 (4)	−0.0010 (3)	0.0052 (3)	−0.0010 (3)
I13	0.0080 (4)	0.0126 (4)	0.0083 (4)	0.0012 (3)	0.0035 (3)	0.0019 (3)
I14	0.0087 (4)	0.0124 (4)	0.0085 (4)	0.0014 (3)	0.0040 (3)	0.0025 (3)
I15	0.0094 (4)	0.0109 (4)	0.0082 (4)	−0.0002 (3)	0.0038 (3)	0.0000 (3)
I16	0.0087 (4)	0.0136 (4)	0.0081 (4)	0.0011 (3)	0.0025 (3)	−0.0001 (3)

Geometric parameters (Å, º) top

Ag1—O4	2.416 (10)	Ag30—I4	2.7587 (14)
Ag1—O30ⁱ	2.462 (10)	Ag30—O12	2.852 (10)
Ag1—O2ⁱ	2.621 (9)	Ag30—I10^ix	2.9063 (14)
Ag1—I2ⁱ	2.8525 (13)	Ag30—Ag10^ix	3.0022 (15)
Ag1—I5	2.9644 (13)	Ag30—Ag31ⁱ	3.3862 (15)
Ag1—I1ⁱⁱ	3.0865 (13)	Ag31—O20	2.415 (9)
Ag1—Ag5	3.2978 (15)	Ag31—O12^x	2.536 (10)
Ag1—Ag2	3.3930 (16)	Ag31—O22^x	2.538 (10)
Ag2—O35ⁱⁱⁱ	2.427 (13)	Ag31—I4^x	2.8487 (13)
Ag2—O5	2.432 (11)	Ag31—I7^vi	3.0043 (13)
Ag2—O4	2.561 (10)	Ag31—I9	3.1169 (13)
Ag2—I1ⁱⁱ	2.8469 (14)	Ag31—Ag35^viii	3.0904 (14)
Ag2—I3	3.0712 (14)	Ag31—Ag30^x	3.3862 (15)
Ag2—Ag36^iv	3.0846 (15)	Ag32—O18^xi	2.277 (10)
Ag3—O36	2.310 (11)	Ag32—O20^iv	2.284 (10)
Ag3—O7	2.398 (10)	Ag32—I9^iv	2.8293 (14)
Ag3—I1^v	2.7620 (13)	Ag32—I6	3.1036 (14)
Ag3—O32^vi	2.777 (9)	Ag32—Ag10^iv	3.3724 (16)
Ag3—I3ⁱⁱ	3.1508 (14)	Ag33—O26	2.376 (10)
Ag3—Ag23	3.0984 (15)	Ag33—O16	2.522 (10)
Ag3—Ag38^vi	3.2525 (15)	Ag33—O18^iv	2.532 (10)
Ag3—Ag4^v	3.2774 (15)	Ag33—I8	2.7989 (13)
Ag4—O33	2.395 (11)	Ag33—O15	2.827 (12)
Ag4—O8^v	2.430 (10)	Ag33—I6ⁱⁱⁱ	3.2480 (14)
Ag4—O1^vi	2.620 (10)	Ag34—O15	2.323 (11)
Ag4—I2	2.8465 (13)	Ag34—O25	2.429 (10)
Ag4—I7^v	3.0366 (13)	Ag34—O23ⁱⁱ	2.577 (10)
Ag4—Ag9^vii	3.0588 (15)	Ag34—I4ⁱⁱ	2.7982 (13)
Ag4—Ag3^v	3.2774 (15)	Ag34—I5	3.4141 (14)
Ag5—O10ⁱ	2.372 (9)	Ag34—Ag39	3.0935 (15)
Ag5—O3ⁱ	2.495 (10)	Ag35—O29^ix	2.330 (9)
Ag5—O2ⁱ	2.556 (9)	Ag35—O22^ix	2.534 (10)
Ag5—I5	2.7769 (13)	Ag35—O24^ix	2.536 (10)
Ag5—I4ⁱⁱ	3.0768 (14)	Ag35—I7^v	2.8033 (13)
Ag5—Ag25ⁱ	3.1071 (15)	Ag35—O21^v	2.811 (10)
Ag5—Ag6	3.2630 (15)	Ag35—I2	3.1788 (14)
Ag6—O13	2.420 (11)	Ag35—Ag15^ix	3.0836 (15)
Ag6—O6	2.478 (10)	Ag35—Ag31^vii	3.0902 (14)
Ag6—O11	2.572 (10)	Ag36—O21	2.303 (10)
Ag6—I6ⁱⁱⁱ	3.0645 (14)	Ag36—O35^xi	2.417 (12)
Ag6—I5	3.0827 (14)	Ag36—O28^v	2.626 (10)
Ag6—I8	3.1602 (14)	Ag36—I1^v	2.9272 (14)
Ag6—Ag12	3.2479 (16)	Ag36—I3ⁱⁱ	3.0141 (13)
Ag7—O7	2.273 (10)	Ag36—Ag2^vi	3.0847 (15)
Ag7—O5ⁱⁱ	2.313 (10)	Ag36—Ag19^xi	3.3882 (16)
Ag7—I6	2.7140 (14)	Ag37—O26	2.304 (9)
Ag7—I3ⁱⁱ	3.1669 (15)	Ag37—O19ⁱⁱⁱ	2.383 (10)
Ag7—Ag37ⁱⁱ	3.0480 (16)	Ag37—I3	2.7154 (13)
Ag7—Ag8	3.0725 (15)	Ag37—I6ⁱⁱⁱ	2.9276 (14)
Ag8—O9	2.393 (11)	Ag37—Ag7ⁱⁱⁱ	3.0479 (16)
Ag8—O16	2.408 (10)	Ag37—Ag38	3.1027 (15)
Ag8—O14	2.698 (11)	Ag38—O27	2.364 (10)
Ag8—I6	2.8571 (14)	Ag38—O32	2.377 (10)
Ag8—I7	3.1721 (13)	Ag38—O34^iv	2.660 (11)
Ag8—I9^iv	3.2491 (14)	Ag38—I3	2.8340 (14)
Ag8—Ag9^iv	3.1717 (15)	Ag38—I1ⁱⁱ	3.2245 (14)
Ag8—Ag13	3.2882 (15)	Ag38—I5	3.3447 (14)
Ag9—O17	2.308 (10)	Ag38—Ag3^iv	3.2525 (15)
Ag9—O3^viii	2.340 (9)	Ag38—Ag39	3.2837 (15)
Ag9—O9^vi	2.732 (11)	Ag39—O31	2.312 (9)
Ag9—I7^vi	2.7431 (14)	Ag39—O24ⁱⁱ	2.329 (10)
Ag9—Ag4^viii	3.0588 (14)	Ag39—O27	2.596 (10)
Ag9—Ag8^vi	3.1717 (15)	Ag39—I5	2.8069 (14)
Ag9—Ag27^vi	3.3996 (16)	Ag40—O29	2.346 (9)
Ag10—O10	2.274 (10)	Ag40—O31ⁱⁱⁱ	2.376 (10)
Ag10—O17^vii	2.391 (10)	Ag40—I2	2.7526 (13)
Ag10—I10	2.7225 (13)	Ag40—I2^ix	2.9693 (13)
Ag10—I4^ix	3.0668 (14)	Ag40—Ag40^ix	2.968 (2)
Ag10—Ag30^ix	3.0022 (16)	Ag40—O30	2.932 (10)
Ag10—Ag11^x	3.1906 (15)	C1—O1^vi	1.251 (15)
Ag10—Ag32^vi	3.3724 (16)	C1—O2	1.282 (15)
Ag11—O12	2.377 (9)	C1—O3	1.328 (15)
Ag11—O22	2.384 (9)	C2—O4	1.264 (17)
Ag11—O20ⁱ	2.684 (10)	C2—O6	1.305 (17)
Ag11—I10ⁱ	2.8234 (13)	C2—O5	1.310 (17)
Ag11—I8	3.2455 (14)	C3—O9	1.272 (16)
Ag11—I13	3.2872 (14)	C3—O7	1.293 (16)
Ag11—Ag12	3.1734 (15)	C3—O8	1.302 (16)
Ag11—Ag10ⁱ	3.1905 (15)	C4—O12	1.279 (16)
Ag11—Ag15	3.3624 (15)	C4—O10ⁱ	1.283 (16)
Ag12—O23	2.252 (9)	C4—O11	1.307 (16)
Ag12—O13	2.428 (12)	C5—O15	1.267 (16)
Ag12—O12	2.761 (10)	C5—O14	1.295 (16)
Ag12—I8	2.7745 (14)	C5—O13ⁱⁱ	1.312 (15)
Ag13—O15	2.294 (12)	C6—O17^iv	1.281 (17)
Ag13—O25	2.363 (9)	C6—O16	1.283 (17)
Ag13—I9^iv	2.7529 (13)	C6—O18^iv	1.310 (17)
Ag13—O16	2.817 (10)	C7—O20^iv	1.267 (16)
Ag13—I11ⁱⁱ	3.1325 (14)	C7—O21	1.297 (15)
Ag13—Ag33	3.0620 (15)	C7—O19	1.311 (16)
Ag13—Ag14^iv	3.2462 (15)	C8—O23	1.256 (16)
Ag14—O18	2.313 (10)	C8—O22	1.291 (17)
Ag14—O19^xi	2.484 (10)	C8—O24	1.319 (17)
Ag14—O26^vi	2.589 (10)	C9—O27	1.272 (16)
Ag14—I14	2.8131 (13)	C9—O26	1.282 (16)
Ag14—I10^viii	3.0760 (13)	C9—O25	1.306 (16)
Ag14—Ag19	3.1494 (15)	C10—O30	1.256 (15)
Ag14—Ag13^vi	3.2463 (15)	C10—O28^ix	1.305 (16)
Ag15—O21^xii	2.313 (9)	C10—O29	1.312 (15)
Ag15—O28^ix	2.400 (9)	C11—O33ⁱⁱ	1.284 (16)
Ag15—I13	2.7543 (13)	C11—O32	1.284 (16)
Ag15—O22	2.808 (9)	C11—O31	1.297 (16)
Ag15—I12ⁱⁱ	3.1320 (14)	C12—O36	1.279 (18)
Ag15—Ag35^ix	3.0836 (15)	C12—O34	1.280 (17)
Ag15—Ag16	3.2907 (15)	C12—O35	1.310 (18)
Ag16—O29	2.397 (9)	O1—C1^iv	1.251 (15)
Ag16—O24	2.415 (10)	O1—Ag22^iv	2.294 (9)
Ag16—O31ⁱⁱⁱ	2.625 (10)	O1—Ag27ⁱⁱ	2.396 (9)
Ag16—I15ⁱⁱⁱ	2.8193 (13)	O2—Ag5^x	2.555 (9)
Ag16—I16	3.1336 (13)	O3—Ag9^vii	2.340 (9)
Ag16—Ag22	3.0444 (14)	O3—Ag26^vi	2.342 (9)
Ag17—O25	2.336 (10)	O3—Ag5^x	2.495 (10)
Ag17—O23ⁱⁱ	2.407 (9)	O4—Ag21ⁱ	2.467 (11)
Ag17—I15	2.7388 (13)	O5—Ag7ⁱⁱⁱ	2.312 (10)
Ag17—I11ⁱⁱ	2.9924 (13)	O5—Ag24ⁱⁱⁱ	2.429 (11)
Ag17—Ag27ⁱⁱ	2.9507 (15)	O6—Ag25ⁱ	2.338 (10)
Ag18—O34^iv	2.409 (10)	O6—Ag29ⁱⁱⁱ	2.362 (11)
Ag18—O32	2.530 (9)	O8—Ag4^v	2.430 (10)
Ag18—O27	2.545 (10)	O10—C4^x	1.283 (16)
Ag18—I15	2.8498 (13)	O10—Ag5^x	2.373 (9)
Ag18—I16^iv	3.0485 (13)	O10—Ag26^vi	2.503 (10)
Ag18—I14^iv	3.0730 (13)	O11—Ag25ⁱ	2.314 (9)
Ag18—Ag23^iv	3.1508 (14)	O12—Ag31ⁱ	2.536 (9)
Ag19—O34	2.300 (11)	O13—C5ⁱⁱⁱ	1.312 (15)
Ag19—O19^xi	2.370 (11)	O17—C6^vi	1.281 (17)
Ag19—O21^xi	2.915 (10)	O17—Ag10^viii	2.391 (10)
Ag19—I12^x	2.9205 (15)	O18—C6^vi	1.310 (17)
Ag19—O35	2.944 (13)	O18—Ag32^xi	2.277 (10)
Ag19—I14	3.0637 (15)	O18—Ag33^vi	2.532 (10)
Ag19—Ag36^xi	3.3883 (16)	O19—Ag19^xi	2.370 (11)
Ag20—O28ⁱⁱ	2.282 (10)	O19—Ag37ⁱⁱ	2.383 (10)
Ag20—O35ⁱⁱⁱ	2.376 (10)	O19—Ag14^xi	2.484 (10)
Ag20—I12	2.7264 (13)	O20—C7^vi	1.267 (16)
Ag20—I12^xiii	2.9991 (14)	O20—Ag32^vi	2.284 (10)
Ag20—Ag20^xiii	3.021 (2)	O21—Ag15^xiv	2.313 (9)
Ag20—Ag21ⁱ	3.0523 (15)	O22—Ag35^ix	2.535 (10)
Ag21—O30	2.440 (10)	O22—Ag31ⁱ	2.538 (10)
Ag21—O2	2.462 (9)	O23—Ag17ⁱⁱⁱ	2.407 (9)
Ag21—O4^x	2.467 (11)	O23—Ag34ⁱⁱⁱ	2.577 (10)
Ag21—I12^x	2.9562 (13)	O24—Ag39ⁱⁱⁱ	2.329 (10)
Ag21—I16	3.1225 (13)	O24—Ag35^ix	2.536 (10)
Ag21—I14	3.1435 (13)	O26—Ag14^iv	2.589 (10)
Ag21—Ag20^x	3.0524 (15)	O28—C10^ix	1.305 (16)
Ag21—Ag25	3.0592 (14)	O28—Ag20ⁱⁱⁱ	2.282 (10)
Ag21—Ag22	3.1148 (14)	O28—Ag15^ix	2.400 (9)
Ag22—O1^vi	2.294 (9)	O29—Ag35^ix	2.330 (9)
Ag22—O33	2.311 (10)	O30—Ag1^x	2.462 (10)
Ag22—O30	2.661 (10)	O31—Ag40ⁱⁱ	2.376 (10)
Ag22—I16	2.7609 (14)	O32—Ag23^iv	2.520 (10)
Ag22—Ag40	3.3647 (16)	O33—C11ⁱⁱⁱ	1.284 (16)
Ag23—O8	2.321 (10)	O33—Ag23^v	2.556 (10)
Ag23—O32^vi	2.520 (10)	O34—Ag18^vi	2.410 (10)
Ag23—O33^v	2.556 (10)	O35—Ag20ⁱⁱ	2.376 (10)
Ag23—I16	2.8004 (13)	O35—Ag36^xi	2.417 (12)
Ag23—O36	2.835 (12)	O35—Ag2ⁱⁱ	2.427 (13)
Ag23—I15ⁱⁱⁱ	3.1727 (14)	I1—Ag3^v	2.7620 (13)
Ag23—Ag18^vi	3.1507 (14)	I1—Ag2ⁱⁱⁱ	2.8470 (14)
Ag23—Ag24	3.2879 (15)	I1—Ag36^v	2.9272 (14)
Ag24—O36	2.299 (11)	I1—Ag1ⁱⁱⁱ	3.0867 (13)
Ag24—O5ⁱⁱ	2.429 (11)	I1—Ag38ⁱⁱⁱ	3.2246 (14)
Ag24—O7	2.617 (10)	I2—Ag1^x	2.8525 (13)
Ag24—I13	2.8377 (14)	I2—Ag40^ix	2.9692 (13)
Ag24—Ag29	3.0848 (15)	I3—Ag36ⁱⁱⁱ	3.0141 (13)
Ag24—I12ⁱⁱ	3.2144 (14)	I3—Ag3ⁱⁱⁱ	3.1509 (14)
Ag25—O11^x	2.314 (9)	I3—Ag7ⁱⁱⁱ	3.1669 (15)
Ag25—O6^x	2.338 (10)	I4—Ag34ⁱⁱⁱ	2.7982 (13)
Ag25—O2	2.569 (9)	I4—Ag31ⁱ	2.8487 (13)
Ag25—I14	2.7879 (13)	I4—Ag10^ix	3.0670 (14)
Ag25—I10^viii	3.2942 (13)	I4—Ag5ⁱⁱⁱ	3.0769 (14)
Ag25—Ag5^x	3.1070 (15)	I6—Ag37ⁱⁱ	2.9276 (14)
Ag26—O3^iv	2.342 (9)	I6—Ag6ⁱⁱ	3.0645 (14)
Ag26—O10^iv	2.503 (10)	I6—Ag33ⁱⁱ	3.2478 (14)
Ag26—O17^xi	2.683 (11)	I7—Ag9^iv	2.7430 (14)
Ag26—I11ⁱⁱ	2.9055 (13)	I7—Ag35^v	2.8034 (13)
Ag26—I9^iv	2.9222 (13)	I7—Ag31^iv	3.0042 (13)
Ag26—Ag32	2.9901 (15)	I7—Ag4^v	3.0367 (13)
Ag27—O8	2.330 (10)	I9—Ag13^vi	2.7528 (13)
Ag27—O1ⁱⁱⁱ	2.396 (9)	I9—Ag32^vi	2.8294 (14)
Ag27—I11	2.7347 (13)	I9—Ag26^vi	2.9223 (13)
Ag27—O9	2.941 (11)	I9—Ag8^vi	3.2491 (14)
Ag27—I15ⁱⁱⁱ	2.9739 (13)	I10—Ag11^x	2.8234 (13)
Ag27—Ag17ⁱⁱⁱ	2.9508 (15)	I10—Ag30^ix	2.9062 (14)
Ag27—Ag9^iv	3.3997 (16)	I10—Ag29^x	3.0691 (15)
Ag28—O14	2.383 (11)	I10—Ag14^vii	3.0759 (13)
Ag28—O9	2.488 (11)	I11—Ag26ⁱⁱⁱ	2.9055 (13)
Ag28—O16	2.584 (10)	I11—Ag17ⁱⁱⁱ	2.9925 (13)
Ag28—I11	2.8574 (13)	I11—Ag13ⁱⁱⁱ	3.1326 (14)
Ag28—I8	2.9725 (13)	I12—Ag19ⁱ	2.9205 (15)
Ag28—I13	3.1476 (13)	I12—Ag21ⁱ	2.9562 (13)
Ag28—Ag33	3.1352 (15)	I12—Ag20^xiii	2.9990 (14)
Ag29—O14	2.292 (11)	I12—Ag15ⁱⁱⁱ	3.1320 (14)
Ag29—O6ⁱⁱ	2.362 (11)	I12—Ag24ⁱⁱⁱ	3.2144 (14)
Ag29—I13	2.8812 (14)	I14—Ag18^vi	3.0729 (13)
Ag29—O5ⁱⁱ	2.989 (11)	I15—Ag16ⁱⁱ	2.8192 (13)
Ag29—I10ⁱ	3.0690 (15)	I15—Ag27ⁱⁱ	2.9741 (13)
Ag29—O13ⁱⁱ	3.001 (12)	I15—Ag23ⁱⁱ	3.1726 (14)
Ag30—O13	2.352 (11)	I16—Ag18^vi	3.0486 (13)
Ag30—O11	2.366 (10)

O4—Ag1—O30ⁱ	74.6 (3)	O20—Ag31—I7^vi	81.7 (2)
O4—Ag1—I2ⁱ	157.3 (3)	O12^x—Ag31—I7^vi	158.8 (2)
O30ⁱ—Ag1—I2ⁱ	99.6 (2)	O22^x—Ag31—I7^vi	106.0 (2)
O4—Ag1—I5	85.8 (2)	I4^x—Ag31—I7^vi	99.83 (4)
O30ⁱ—Ag1—I5	160.3 (2)	O20—Ag31—Ag35^viii	82.8 (2)
I2ⁱ—Ag1—I5	99.20 (4)	O12^x—Ag31—Ag35^viii	127.2 (2)
O4—Ag1—I1ⁱⁱ	99.3 (2)	O22^x—Ag31—Ag35^viii	52.4 (2)
O30ⁱ—Ag1—I1ⁱⁱ	80.8 (2)	I4^x—Ag31—Ag35^viii	86.17 (4)
I2ⁱ—Ag1—I1ⁱⁱ	101.31 (4)	I7^vi—Ag31—Ag35^viii	54.75 (3)
I5—Ag1—I1ⁱⁱ	101.33 (4)	O20—Ag31—I9	92.4 (2)
O4—Ag1—Ag5	83.8 (2)	O12^x—Ag31—I9	76.0 (2)
O30ⁱ—Ag1—Ag5	125.1 (2)	O22^x—Ag31—I9	151.3 (2)
I2ⁱ—Ag1—Ag5	81.94 (4)	I4^x—Ag31—I9	101.74 (4)
I5—Ag1—Ag5	52.32 (3)	I7^vi—Ag31—I9	99.32 (4)
I1ⁱⁱ—Ag1—Ag5	153.39 (4)	Ag35^viii—Ag31—I9	154.01 (4)
O35ⁱⁱⁱ—Ag2—O5	104.0 (4)	O18^xi—Ag32—O20^iv	110.0 (3)
O35ⁱⁱⁱ—Ag2—O4	103.6 (3)	O18^xi—Ag32—I9^iv	144.7 (3)
O5—Ag2—O4	52.9 (3)	O20^iv—Ag32—I9^iv	103.2 (2)
O35ⁱⁱⁱ—Ag2—I1ⁱⁱ	108.6 (3)	O18^xi—Ag32—Ag26	88.4 (2)
O5—Ag2—I1ⁱⁱ	143.3 (2)	O20^iv—Ag32—Ag26	130.8 (3)
O4—Ag2—I1ⁱⁱ	102.4 (2)	I9^iv—Ag32—Ag26	60.21 (3)
O35ⁱⁱⁱ—Ag2—I3	119.6 (3)	O18^xi—Ag32—I6	82.7 (2)
O5—Ag2—I3	80.9 (2)	O20^iv—Ag32—I6	113.9 (2)
O4—Ag2—I3	123.4 (2)	I9^iv—Ag32—I6	94.86 (4)
I1ⁱⁱ—Ag2—I3	96.94 (4)	Ag26—Ag32—I6	113.49 (4)
O35ⁱⁱⁱ—Ag2—Ag36^iv	50.3 (3)	O18^xi—Ag32—Ag10^iv	66.9 (2)
O5—Ag2—Ag36^iv	153.5 (3)	O20^iv—Ag32—Ag10^iv	77.7 (2)
O4—Ag2—Ag36^iv	119.9 (2)	I9^iv—Ag32—Ag10^iv	110.28 (4)
I1ⁱⁱ—Ag2—Ag36^iv	58.98 (3)	Ag26—Ag32—Ag10^iv	68.25 (3)
I3—Ag2—Ag36^iv	115.74 (4)	I6—Ag32—Ag10^iv	149.57 (4)
O36—Ag3—O7	78.9 (4)	O26—Ag33—O16	116.2 (3)
O36—Ag3—I1^v	142.7 (3)	O26—Ag33—O18^iv	78.6 (3)
O7—Ag3—I1^v	138.2 (2)	O16—Ag33—O18^iv	51.8 (3)
O36—Ag3—Ag23	61.2 (3)	O26—Ag33—I8	130.4 (2)
O7—Ag3—Ag23	74.3 (2)	O16—Ag33—I8	112.2 (2)
I1^v—Ag3—Ag23	122.58 (4)	O18^iv—Ag33—I8	144.6 (2)
O36—Ag3—I3ⁱⁱ	92.6 (3)	O26—Ag33—Ag13	74.8 (2)
O7—Ag3—I3ⁱⁱ	83.5 (2)	O16—Ag33—Ag13	59.7 (2)
I1^v—Ag3—I3ⁱⁱ	89.18 (4)	O18^iv—Ag33—Ag13	78.4 (2)
Ag23—Ag3—I3ⁱⁱ	148.13 (4)	I8—Ag33—Ag13	124.03 (5)
O36—Ag3—Ag38^vi	79.2 (3)	O26—Ag33—Ag28	169.0 (2)
O7—Ag3—Ag38^vi	157.2 (2)	O16—Ag33—Ag28	53.0 (2)
I1^v—Ag3—Ag38^vi	64.24 (3)	O18^iv—Ag33—Ag28	93.6 (2)
Ag23—Ag3—Ag38^vi	89.60 (4)	I8—Ag33—Ag28	59.80 (3)
I3ⁱⁱ—Ag3—Ag38^vi	103.73 (4)	Ag13—Ag33—Ag28	96.18 (4)
O36—Ag3—Ag4^v	131.1 (3)	O26—Ag33—I6ⁱⁱⁱ	81.0 (2)
O7—Ag3—Ag4^v	78.0 (2)	O16—Ag33—I6ⁱⁱⁱ	115.6 (2)
I1^v—Ag3—Ag4^v	73.65 (4)	O18^iv—Ag33—I6ⁱⁱⁱ	76.1 (2)
Ag23—Ag3—Ag4^v	71.24 (3)	I8—Ag33—I6ⁱⁱⁱ	87.98 (4)
I3ⁱⁱ—Ag3—Ag4^v	126.53 (4)	Ag13—Ag33—I6ⁱⁱⁱ	147.73 (4)
Ag38^vi—Ag3—Ag4^v	112.42 (4)	Ag28—Ag33—I6ⁱⁱⁱ	104.82 (4)
O33—Ag4—O8^v	76.7 (3)	O26—Ag33—Ag34	78.9 (2)
O33—Ag4—I2	108.5 (2)	O16—Ag33—Ag34	120.0 (2)
O8^v—Ag4—I2	163.8 (2)	O18^iv—Ag33—Ag34	146.5 (2)
O33—Ag4—I7^v	153.1 (2)	I8—Ag33—Ag34	67.94 (3)
O8^v—Ag4—I7^v	91.4 (2)	Ag13—Ag33—Ag34	71.85 (4)
I2—Ag4—I7^v	89.55 (4)	Ag28—Ag33—Ag34	104.45 (4)
O33—Ag4—Ag9^vii	142.6 (2)	I6ⁱⁱⁱ—Ag33—Ag34	124.16 (4)
O8^v—Ag4—Ag9^vii	77.8 (2)	O15—Ag34—O25	72.6 (4)
I2—Ag4—Ag9^vii	89.91 (4)	O15—Ag34—O23ⁱⁱ	93.3 (4)
I7^v—Ag4—Ag9^vii	53.49 (3)	O25—Ag34—O23ⁱⁱ	79.6 (3)
O33—Ag4—Ag3^v	77.3 (2)	O15—Ag34—I4ⁱⁱ	125.4 (3)
O8^v—Ag4—Ag3^v	64.8 (2)	O25—Ag34—I4ⁱⁱ	160.2 (2)
I2—Ag4—Ag3^v	130.88 (4)	O23ⁱⁱ—Ag34—I4ⁱⁱ	90.5 (2)
I7^v—Ag4—Ag3^v	75.85 (3)	O15—Ag34—Ag39	146.7 (3)
Ag9^vii—Ag4—Ag3^v	115.22 (4)	O25—Ag34—Ag39	74.4 (2)
O10ⁱ—Ag5—O3ⁱ	79.0 (3)	O23ⁱⁱ—Ag34—Ag39	76.1 (2)
O10ⁱ—Ag5—O2ⁱ	112.3 (3)	I4ⁱⁱ—Ag34—Ag39	86.64 (4)
O3ⁱ—Ag5—O2ⁱ	52.0 (3)	O15—Ag34—Ag33	56.4 (3)
O10ⁱ—Ag5—I5	134.3 (2)	O25—Ag34—Ag33	62.3 (2)
O3ⁱ—Ag5—I5	146.0 (2)	O23ⁱⁱ—Ag34—Ag33	136.0 (2)
O2ⁱ—Ag5—I5	106.9 (2)	I4ⁱⁱ—Ag34—Ag33	132.24 (4)
O10ⁱ—Ag5—I4ⁱⁱ	84.8 (2)	Ag39—Ag34—Ag33	110.85 (4)
O3ⁱ—Ag5—I4ⁱⁱ	83.9 (2)	O29^ix—Ag35—O22^ix	108.9 (3)
O2ⁱ—Ag5—I4ⁱⁱ	124.8 (2)	O29^ix—Ag35—O24^ix	75.8 (3)
I5—Ag5—I4ⁱⁱ	91.75 (4)	O22^ix—Ag35—O24^ix	51.8 (3)
O10ⁱ—Ag5—Ag25ⁱ	76.6 (2)	O29^ix—Ag35—I7^v	136.3 (2)
O3ⁱ—Ag5—Ag25ⁱ	78.4 (2)	O22^ix—Ag35—I7^v	112.2 (2)
O2ⁱ—Ag5—Ag25ⁱ	52.9 (2)	O24^ix—Ag35—I7^v	143.6 (2)
I5—Ag5—Ag25ⁱ	111.60 (4)	O29^ix—Ag35—Ag15^ix	68.4 (2)
I4ⁱⁱ—Ag5—Ag25ⁱ	156.42 (4)	O22^ix—Ag35—Ag15^ix	59.0 (2)
O10ⁱ—Ag5—Ag6	82.1 (2)	O24^ix—Ag35—Ag15^ix	79.8 (2)
O3ⁱ—Ag5—Ag6	147.4 (2)	I7^v—Ag35—Ag15^ix	123.08 (4)
O2ⁱ—Ag5—Ag6	113.8 (2)	O29^ix—Ag35—Ag31^vii	161.4 (2)
I5—Ag5—Ag6	60.75 (3)	O22^ix—Ag35—Ag31^vii	52.5 (2)
I4ⁱⁱ—Ag5—Ag6	120.56 (4)	O24^ix—Ag35—Ag31^vii	90.5 (2)
Ag25ⁱ—Ag5—Ag6	71.49 (3)	I7^v—Ag35—Ag31^vii	61.06 (3)
O10ⁱ—Ag5—Ag1	162.4 (2)	Ag15^ix—Ag35—Ag31^vii	97.01 (4)
O3ⁱ—Ag5—Ag1	92.1 (2)	O29^ix—Ag35—I2	81.8 (2)
O2ⁱ—Ag5—Ag1	51.3 (2)	O22^ix—Ag35—I2	123.4 (2)
I5—Ag5—Ag1	57.66 (3)	O24^ix—Ag35—I2	80.4 (2)
I4ⁱⁱ—Ag5—Ag1	109.61 (4)	I7^v—Ag35—I2	87.50 (4)
Ag25ⁱ—Ag5—Ag1	86.73 (4)	Ag15^ix—Ag35—I2	147.46 (4)
Ag6—Ag5—Ag1	98.25 (4)	Ag31^vii—Ag35—I2	108.73 (4)
O13—Ag6—O6	93.2 (4)	O21—Ag36—O35^xi	108.3 (4)
O13—Ag6—O11	71.7 (3)	O21—Ag36—I1^v	134.1 (3)
O6—Ag6—O11	72.0 (3)	O35^xi—Ag36—I1^v	106.4 (3)
O13—Ag6—I6ⁱⁱⁱ	84.1 (3)	O21—Ag36—I3ⁱⁱ	121.0 (2)
O6—Ag6—I6ⁱⁱⁱ	119.9 (2)	O35^xi—Ag36—I3ⁱⁱ	88.3 (3)
O11—Ag6—I6ⁱⁱⁱ	154.0 (2)	I1^v—Ag36—I3ⁱⁱ	88.88 (4)
O13—Ag6—I5	174.2 (3)	O21—Ag36—Ag2^vi	151.9 (2)
O6—Ag6—I5	87.1 (2)	O35^xi—Ag36—Ag2^vi	50.6 (3)
O11—Ag6—I5	113.8 (2)	I1^v—Ag36—Ag2^vi	56.46 (3)
I6ⁱⁱⁱ—Ag6—I5	90.70 (4)	I3ⁱⁱ—Ag36—Ag2^vi	80.62 (4)
O13—Ag6—I8	99.3 (3)	O26—Ag37—O19ⁱⁱⁱ	82.2 (3)
O6—Ag6—I8	153.1 (3)	O26—Ag37—I3	142.3 (2)
O11—Ag6—I8	89.4 (2)	O19ⁱⁱⁱ—Ag37—I3	112.9 (2)
I6ⁱⁱⁱ—Ag6—I8	85.16 (3)	O26—Ag37—I6ⁱⁱⁱ	89.6 (2)
I5—Ag6—I8	82.76 (3)	O19ⁱⁱⁱ—Ag37—I6ⁱⁱⁱ	97.7 (3)
O13—Ag6—Ag12	48.0 (3)	I3—Ag37—I6ⁱⁱⁱ	120.18 (5)
O6—Ag6—Ag12	135.3 (2)	O26—Ag37—Ag7ⁱⁱⁱ	134.5 (2)
O11—Ag6—Ag12	74.4 (2)	O19ⁱⁱⁱ—Ag37—Ag7ⁱⁱⁱ	124.4 (3)
I6ⁱⁱⁱ—Ag6—Ag12	82.49 (4)	I3—Ag37—Ag7ⁱⁱⁱ	66.37 (4)
I5—Ag6—Ag12	133.87 (4)	I6ⁱⁱⁱ—Ag37—Ag7ⁱⁱⁱ	53.98 (3)
I8—Ag6—Ag12	51.29 (3)	O26—Ag37—Ag38	84.6 (2)
O13—Ag6—Ag5	133.8 (3)	O19ⁱⁱⁱ—Ag37—Ag38	121.6 (3)
O6—Ag6—Ag5	76.9 (3)	I3—Ag37—Ag38	57.84 (3)
O11—Ag6—Ag5	62.4 (2)	I6ⁱⁱⁱ—Ag37—Ag38	138.84 (5)
I6ⁱⁱⁱ—Ag6—Ag5	139.87 (4)	Ag7ⁱⁱⁱ—Ag37—Ag38	104.70 (4)
I5—Ag6—Ag5	51.81 (3)	O27—Ag38—O32	79.0 (3)
I8—Ag6—Ag5	77.20 (3)	O27—Ag38—I3	126.8 (2)
Ag12—Ag6—Ag5	111.78 (4)	O32—Ag38—I3	141.8 (2)
O7—Ag7—O5ⁱⁱ	81.5 (4)	O27—Ag38—Ag37	73.7 (2)
O7—Ag7—I6	141.4 (3)	O32—Ag38—Ag37	146.3 (2)
O5ⁱⁱ—Ag7—I6	133.6 (3)	I3—Ag38—Ag37	54.21 (3)
O7—Ag7—Ag37ⁱⁱ	128.2 (3)	O27—Ag38—I1ⁱⁱ	136.8 (2)
O5ⁱⁱ—Ag7—Ag37ⁱⁱ	112.7 (3)	O32—Ag38—I1ⁱⁱ	75.7 (2)
I6—Ag7—Ag37ⁱⁱ	60.75 (3)	I3—Ag38—I1ⁱⁱ	93.83 (4)
O7—Ag7—Ag8	83.1 (3)	Ag37—Ag38—I1ⁱⁱ	138.02 (4)
O5ⁱⁱ—Ag7—Ag8	145.5 (3)	O27—Ag38—Ag3^iv	132.8 (2)
I6—Ag7—Ag8	58.78 (3)	O32—Ag38—Ag3^iv	56.6 (2)
Ag37ⁱⁱ—Ag7—Ag8	101.07 (4)	I3—Ag38—Ag3^iv	88.16 (4)
O7—Ag7—I3ⁱⁱ	85.2 (3)	Ag37—Ag38—Ag3^iv	137.71 (5)
O5ⁱⁱ—Ag7—I3ⁱⁱ	80.6 (3)	I1ⁱⁱ—Ag38—Ag3^iv	50.48 (3)
I6—Ag7—I3ⁱⁱ	112.37 (5)	O27—Ag38—Ag39	51.6 (2)
Ag37ⁱⁱ—Ag7—I3ⁱⁱ	51.77 (3)	O32—Ag38—Ag39	70.3 (2)
Ag8—Ag7—I3ⁱⁱ	128.50 (5)	I3—Ag38—Ag39	146.88 (5)
O7—Ag7—Ag29	80.2 (2)	Ag37—Ag38—Ag39	105.78 (4)
O5ⁱⁱ—Ag7—Ag29	60.2 (3)	I1ⁱⁱ—Ag38—Ag39	86.75 (4)
I6—Ag7—Ag29	102.20 (4)	Ag3^iv—Ag38—Ag39	116.48 (4)
Ag37ⁱⁱ—Ag7—Ag29	151.00 (5)	O31—Ag39—O24ⁱⁱ	82.0 (3)
Ag8—Ag7—Ag29	86.82 (4)	O31—Ag39—O27	99.3 (3)
I3ⁱⁱ—Ag7—Ag29	139.69 (4)	O24ⁱⁱ—Ag39—O27	122.3 (3)
O9—Ag8—O16	79.4 (3)	O31—Ag39—I5	132.5 (2)
O9—Ag8—I6	127.2 (3)	O24ⁱⁱ—Ag39—I5	138.8 (3)
O16—Ag8—I6	138.3 (2)	O27—Ag39—I5	79.4 (2)
O9—Ag8—Ag7	73.9 (3)	O31—Ag39—Ag34	157.0 (2)
O16—Ag8—Ag7	143.8 (2)	O24ⁱⁱ—Ag39—Ag34	78.1 (2)
I6—Ag8—Ag7	54.33 (3)	O27—Ag39—Ag34	81.9 (2)
O9—Ag8—Ag9^iv	56.8 (3)	I5—Ag39—Ag34	70.52 (3)
O16—Ag8—Ag9^iv	68.5 (2)	O31—Ag39—Ag38	79.3 (2)
I6—Ag8—Ag9^iv	150.99 (5)	O24ⁱⁱ—Ag39—Ag38	154.6 (3)
Ag7—Ag8—Ag9^iv	113.71 (4)	O27—Ag39—Ag38	45.6 (2)
O9—Ag8—I7	75.0 (3)	I5—Ag39—Ag38	66.08 (3)
O16—Ag8—I7	119.2 (2)	Ag34—Ag39—Ag38	115.42 (4)
I6—Ag8—I7	100.13 (4)	O29—Ag40—O31ⁱⁱⁱ	85.5 (3)
Ag7—Ag8—I7	76.91 (4)	O29—Ag40—I2	137.4 (2)
Ag9^iv—Ag8—I7	51.24 (3)	O31ⁱⁱⁱ—Ag40—I2	128.2 (2)
O9—Ag8—I9^iv	140.8 (3)	O29—Ag40—Ag40^ix	128.2 (2)
O16—Ag8—I9^iv	74.2 (2)	O31ⁱⁱⁱ—Ag40—Ag40^ix	119.5 (2)
I6—Ag8—I9^iv	91.25 (4)	I2—Ag40—Ag40^ix	62.40 (4)
Ag7—Ag8—I9^iv	140.53 (5)	O29—Ag40—I2^ix	86.3 (2)
Ag9^iv—Ag8—I9^iv	86.51 (4)	O31ⁱⁱⁱ—Ag40—I2^ix	85.3 (2)
I7—Ag8—I9^iv	93.21 (4)	I2—Ag40—I2^ix	117.65 (4)
O9—Ag8—Ag13	131.2 (3)	Ag40^ix—Ag40—I2^ix	55.24 (4)
O16—Ag8—Ag13	56.8 (2)	O29—Ag40—Ag22	71.3 (2)
I6—Ag8—Ag13	83.73 (4)	O31ⁱⁱⁱ—Ag40—Ag22	72.7 (2)
Ag7—Ag8—Ag13	130.23 (5)	I2—Ag40—Ag22	92.77 (4)
Ag9^iv—Ag8—Ag13	115.64 (4)	Ag40^ix—Ag40—Ag22	155.05 (6)
I7—Ag8—Ag13	143.00 (4)	I2^ix—Ag40—Ag22	149.47 (4)
I9^iv—Ag8—Ag13	49.81 (3)	O1^vi—C1—O2	122.8 (11)
O17—Ag9—O3^viii	80.9 (3)	O1^vi—C1—O3	121.0 (11)
O17—Ag9—I7^vi	136.2 (3)	O2—C1—O3	116.1 (11)
O3^viii—Ag9—I7^vi	136.3 (2)	O4—C2—O6	121.2 (13)
O17—Ag9—Ag4^viii	160.9 (3)	O4—C2—O5	119.7 (12)
O3^viii—Ag9—Ag4^viii	81.7 (2)	O6—C2—O5	119.1 (12)
I7^vi—Ag9—Ag4^viii	62.84 (3)	O9—C3—O7	122.6 (12)
O17—Ag9—Ag8^vi	84.5 (3)	O9—C3—O8	118.7 (12)
O3^viii—Ag9—Ag8^vi	158.1 (2)	O7—C3—O8	118.7 (12)
I7^vi—Ag9—Ag8^vi	64.39 (3)	O12—C4—O10ⁱ	122.9 (12)
Ag4^viii—Ag9—Ag8^vi	109.69 (4)	O12—C4—O11	118.7 (12)
O10—Ag10—O17^vii	89.4 (4)	O10ⁱ—C4—O11	118.4 (11)
O10—Ag10—I10	137.4 (2)	O15—C5—O14	121.2 (11)
O17^vii—Ag10—I10	127.2 (2)	O15—C5—O13ⁱⁱ	120.8 (11)
O10—Ag10—Ag30^ix	131.1 (2)	O14—C5—O13ⁱⁱ	117.7 (11)
O17^vii—Ag10—Ag30^ix	111.5 (3)	O17^iv—C6—O16	123.4 (13)
I10—Ag10—Ag30^ix	60.78 (4)	O17^iv—C6—O18^iv	119.7 (13)
O10—Ag10—I4^ix	86.7 (2)	O16—C6—O18^iv	116.7 (13)
O17^vii—Ag10—I4^ix	84.7 (2)	O20^iv—C7—O21	122.0 (12)
I10—Ag10—I4^ix	114.46 (4)	O20^iv—C7—O19	121.1 (12)
Ag30^ix—Ag10—I4^ix	54.06 (3)	O21—C7—O19	116.9 (12)
O10—Ag10—Ag11^x	81.1 (2)	O23—C8—O22	122.7 (12)
O17^vii—Ag10—Ag11^x	147.9 (3)	O23—C8—O24	121.1 (12)
I10—Ag10—Ag11^x	56.37 (3)	O22—C8—O24	116.2 (12)
Ag30^ix—Ag10—Ag11^x	97.51 (4)	O27—C9—O26	123.0 (12)
I4^ix—Ag10—Ag11^x	124.80 (4)	O27—C9—O25	119.9 (12)
O10—Ag10—Ag32^vi	75.4 (2)	O26—C9—O25	117.0 (11)
O17^vii—Ag10—Ag32^vi	67.4 (3)	O30—C10—O28^ix	123.3 (12)
I10—Ag10—Ag32^vi	97.49 (4)	O30—C10—O29	119.4 (12)
Ag30^ix—Ag10—Ag32^vi	153.06 (5)	O28^ix—C10—O29	117.2 (11)
I4^ix—Ag10—Ag32^vi	146.54 (4)	O33ⁱⁱ—C11—O32	120.2 (12)
Ag11^x—Ag10—Ag32^vi	80.60 (4)	O33ⁱⁱ—C11—O31	118.9 (12)
O12—Ag11—O22	81.5 (3)	O32—C11—O31	120.9 (12)
O12—Ag11—I10ⁱ	126.1 (3)	O36—C12—O34	121.8 (13)
O22—Ag11—I10ⁱ	138.0 (2)	O36—C12—O35	118.8 (13)
O12—Ag11—Ag12	57.5 (3)	O34—C12—O35	119.4 (13)
O22—Ag11—Ag12	69.8 (2)	C1^iv—O1—Ag22^iv	121.6 (8)
I10ⁱ—Ag11—Ag12	149.72 (5)	C1^iv—O1—Ag27ⁱⁱ	113.6 (8)
O12—Ag11—Ag10ⁱ	73.9 (2)	Ag22^iv—O1—Ag27ⁱⁱ	118.9 (4)
O22—Ag11—Ag10ⁱ	146.6 (2)	C1—O2—Ag21	126.6 (8)
I10ⁱ—Ag11—Ag10ⁱ	53.41 (3)	C1—O2—Ag5^x	93.9 (7)
Ag12—Ag11—Ag10ⁱ	112.89 (4)	Ag21—O2—Ag5^x	136.9 (4)
O12—Ag11—I8	75.9 (2)	C1—O2—Ag25	115.2 (8)
O22—Ag11—I8	120.1 (2)	Ag21—O2—Ag25	74.9 (3)
I10ⁱ—Ag11—I8	98.81 (4)	Ag5^x—O2—Ag25	74.6 (2)
Ag12—Ag11—I8	51.20 (3)	C1—O3—Ag9^vii	121.8 (8)
Ag10ⁱ—Ag11—I8	75.62 (3)	C1—O3—Ag26^vi	117.3 (8)
O12—Ag11—Ag15	132.2 (2)	Ag9^vii—O3—Ag26^vi	102.1 (4)
O22—Ag11—Ag15	55.4 (2)	C1—O3—Ag5^x	95.5 (7)
I10ⁱ—Ag11—Ag15	84.82 (4)	Ag9^vii—O3—Ag5^x	120.9 (4)
Ag12—Ag11—Ag15	115.09 (4)	Ag26^vi—O3—Ag5^x	97.8 (3)
Ag10ⁱ—Ag11—Ag15	131.93 (4)	C2—O4—Ag1	130.4 (9)
I8—Ag11—Ag15	140.93 (4)	C2—O4—Ag21ⁱ	126.0 (9)
O23—Ag12—O13	114.7 (4)	Ag1—O4—Ag21ⁱ	92.3 (3)
O23—Ag12—I8	134.8 (3)	C2—O4—Ag2	90.9 (8)
O13—Ag12—I8	110.6 (3)	Ag1—O4—Ag2	85.9 (3)
O23—Ag12—Ag11	82.6 (2)	Ag21ⁱ—O4—Ag2	128.5 (4)
O13—Ag12—Ag11	135.3 (2)	C2—O5—Ag7ⁱⁱⁱ	126.7 (9)
I8—Ag12—Ag11	65.74 (4)	C2—O5—Ag24ⁱⁱⁱ	111.7 (9)
O23—Ag12—Ag6	162.5 (3)	Ag7ⁱⁱⁱ—O5—Ag24ⁱⁱⁱ	102.4 (4)
O13—Ag12—Ag6	47.8 (3)	C2—O5—Ag2	95.7 (8)
I8—Ag12—Ag6	62.72 (3)	Ag7ⁱⁱⁱ—O5—Ag2	117.3 (4)
Ag11—Ag12—Ag6	109.78 (4)	Ag24ⁱⁱⁱ—O5—Ag2	100.5 (4)
O15—Ag13—O25	74.4 (4)	C2—O6—Ag25ⁱ	118.7 (9)
O15—Ag13—I9^iv	141.1 (3)	C2—O6—Ag29ⁱⁱⁱ	107.0 (9)
O25—Ag13—I9^iv	144.6 (2)	Ag25ⁱ—O6—Ag29ⁱⁱⁱ	119.1 (4)
O15—Ag13—Ag33	61.7 (3)	C2—O6—Ag6	114.9 (8)
O25—Ag13—Ag33	68.0 (3)	Ag25ⁱ—O6—Ag6	101.2 (4)
I9^iv—Ag13—Ag33	121.59 (5)	Ag29ⁱⁱⁱ—O6—Ag6	93.0 (4)
O15—Ag13—I11ⁱⁱ	95.3 (3)	C3—O7—Ag7	123.3 (8)
O25—Ag13—I11ⁱⁱ	84.8 (2)	C3—O7—Ag3	112.6 (8)
I9^iv—Ag13—I11ⁱⁱ	90.54 (4)	Ag7—O7—Ag3	114.4 (4)
Ag33—Ag13—I11ⁱⁱ	147.81 (4)	C3—O8—Ag23	122.1 (8)
O15—Ag13—Ag14^iv	131.5 (3)	C3—O8—Ag27	110.0 (8)
O25—Ag13—Ag14^iv	79.8 (2)	Ag23—O8—Ag27	113.0 (4)
I9^iv—Ag13—Ag14^iv	73.29 (4)	C3—O8—Ag4^v	106.9 (8)
Ag33—Ag13—Ag14^iv	70.68 (4)	Ag23—O8—Ag4^v	102.9 (4)
I11ⁱⁱ—Ag13—Ag14^iv	122.63 (4)	Ag27—O8—Ag4^v	98.8 (3)
O15—Ag13—Ag8	77.3 (3)	C3—O9—Ag8	126.6 (9)
O25—Ag13—Ag8	149.8 (3)	C3—O9—Ag28	133.2 (9)
I9^iv—Ag13—Ag8	64.36 (3)	Ag8—O9—Ag28	90.2 (3)
Ag33—Ag13—Ag8	89.43 (4)	C4^x—O10—Ag10	126.1 (8)
I11ⁱⁱ—Ag13—Ag8	108.24 (4)	C4^x—O10—Ag5^x	111.3 (8)
Ag14^iv—Ag13—Ag8	112.45 (4)	Ag10—O10—Ag5^x	111.1 (4)
O18—Ag14—O19^xi	87.5 (3)	C4^x—O10—Ag26^vi	109.1 (8)
O18—Ag14—O26^vi	78.6 (3)	Ag10—O10—Ag26^vi	97.1 (3)
O19^xi—Ag14—O26^vi	74.8 (3)	Ag5^x—O10—Ag26^vi	96.8 (3)
O18—Ag14—I14	157.5 (3)	C4—O11—Ag25ⁱ	126.0 (8)
O19^xi—Ag14—I14	109.0 (2)	C4—O11—Ag30	105.8 (8)
O26^vi—Ag14—I14	90.8 (2)	Ag25ⁱ—O11—Ag30	112.6 (4)
O18—Ag14—I10^viii	104.7 (3)	C4—O11—Ag6	107.7 (8)
O19^xi—Ag14—I10^viii	85.0 (2)	Ag25ⁱ—O11—Ag6	99.2 (3)
O26^vi—Ag14—I10^viii	159.4 (2)	Ag30—O11—Ag6	103.0 (3)
I14—Ag14—I10^viii	92.23 (4)	C4—O12—Ag11	127.9 (9)
O18—Ag14—Ag19	135.0 (2)	C4—O12—Ag31ⁱ	133.8 (8)
O19^xi—Ag14—Ag19	48.0 (2)	Ag11—O12—Ag31ⁱ	88.9 (3)
O26^vi—Ag14—Ag19	82.8 (2)	C5ⁱⁱⁱ—O13—Ag30	125.2 (9)
I14—Ag14—Ag19	61.53 (3)	C5ⁱⁱⁱ—O13—Ag6	122.5 (8)
I10^viii—Ag14—Ag19	80.76 (4)	Ag30—O13—Ag6	108.3 (4)
O18—Ag14—Ag13^vi	77.6 (3)	C5ⁱⁱⁱ—O13—Ag12	110.9 (8)
O19^xi—Ag14—Ag13^vi	142.8 (2)	Ag30—O13—Ag12	92.2 (4)
O26^vi—Ag14—Ag13^vi	69.0 (2)	Ag6—O13—Ag12	84.1 (4)
I14—Ag14—Ag13^vi	80.08 (4)	C5—O14—Ag29	113.3 (8)
I10^viii—Ag14—Ag13^vi	131.61 (4)	C5—O14—Ag28	128.4 (8)
Ag19—Ag14—Ag13^vi	131.82 (4)	Ag29—O14—Ag28	96.0 (4)
O21^xii—Ag15—O28^ix	78.2 (3)	C5—O15—Ag13	129.8 (9)
O21^xii—Ag15—I13	141.8 (2)	C5—O15—Ag34	120.1 (9)
O28^ix—Ag15—I13	139.6 (2)	Ag13—O15—Ag34	109.4 (5)
O21^xii—Ag15—Ag35^ix	60.8 (3)	C6—O16—Ag8	130.2 (9)
O28^ix—Ag15—Ag35^ix	74.4 (2)	C6—O16—Ag33	95.6 (9)
I13—Ag15—Ag35^ix	123.41 (4)	Ag8—O16—Ag33	130.1 (4)
O21^xii—Ag15—I12ⁱⁱ	89.6 (3)	C6—O16—Ag28	127.2 (9)
O28^ix—Ag15—I12ⁱⁱ	81.8 (2)	Ag8—O16—Ag28	87.6 (3)
I13—Ag15—I12ⁱⁱ	91.30 (4)	Ag33—O16—Ag28	75.8 (3)
Ag35^ix—Ag15—I12ⁱⁱ	144.96 (4)	C6^vi—O17—Ag9	117.4 (9)
O21^xii—Ag15—Ag16	130.5 (2)	C6^vi—O17—Ag10^viii	114.8 (9)
O28^ix—Ag15—Ag16	79.0 (2)	Ag9—O17—Ag10^viii	121.9 (4)
I13—Ag15—Ag16	75.04 (3)	C6^vi—O18—Ag32^xi	118.7 (9)
Ag35^ix—Ag15—Ag16	70.96 (3)	C6^vi—O18—Ag14	116.9 (9)
I12ⁱⁱ—Ag15—Ag16	129.35 (4)	Ag32^xi—O18—Ag14	107.9 (4)
O21^xii—Ag15—Ag11	78.8 (2)	C6^vi—O18—Ag33^vi	94.4 (8)
O28^ix—Ag15—Ag11	156.0 (2)	Ag32^xi—O18—Ag33^vi	119.2 (4)
I13—Ag15—Ag11	64.11 (3)	Ag14—O18—Ag33^vi	97.7 (4)
Ag35^ix—Ag15—Ag11	88.30 (4)	C7—O19—Ag19^xi	105.2 (8)
I12ⁱⁱ—Ag15—Ag11	104.95 (4)	C7—O19—Ag37ⁱⁱ	130.9 (9)
Ag16—Ag15—Ag11	111.47 (4)	Ag19^xi—O19—Ag37ⁱⁱ	97.9 (4)
O29—Ag16—O24	77.0 (3)	C7—O19—Ag14^xi	123.9 (8)
O29—Ag16—I15ⁱⁱⁱ	165.1 (2)	Ag19^xi—O19—Ag14^xi	80.9 (3)
O24—Ag16—I15ⁱⁱⁱ	110.7 (2)	Ag37ⁱⁱ—O19—Ag14^xi	101.9 (4)
O29—Ag16—Ag22	77.1 (2)	C7^vi—O20—Ag32^vi	115.0 (8)
O24—Ag16—Ag22	143.3 (2)	C7^vi—O20—Ag31	129.7 (8)
I15ⁱⁱⁱ—Ag16—Ag22	89.99 (4)	Ag32^vi—O20—Ag31	93.9 (3)
O29—Ag16—I16	90.0 (2)	C7—O21—Ag36	121.8 (8)
O24—Ag16—I16	151.4 (3)	C7—O21—Ag15^xiv	127.4 (8)
I15ⁱⁱⁱ—Ag16—I16	88.21 (4)	Ag36—O21—Ag15^xiv	110.2 (4)
Ag22—Ag16—I16	53.06 (3)	C8—O22—Ag11	129.8 (9)
O29—Ag16—Ag15	64.0 (2)	C8—O22—Ag35^ix	95.9 (8)
O24—Ag16—Ag15	77.3 (2)	Ag11—O22—Ag35^ix	132.0 (4)
I15ⁱⁱⁱ—Ag16—Ag15	129.34 (4)	C8—O22—Ag31ⁱ	122.5 (8)
Ag22—Ag16—Ag15	113.22 (4)	Ag11—O22—Ag31ⁱ	88.7 (3)
I16—Ag16—Ag15	74.05 (3)	Ag35^ix—O22—Ag31ⁱ	75.1 (3)
O25—Ag17—O23ⁱⁱ	85.0 (3)	C8—O23—Ag12	121.3 (9)
O25—Ag17—I15	136.3 (2)	C8—O23—Ag17ⁱⁱⁱ	111.2 (8)
O23ⁱⁱ—Ag17—I15	128.8 (2)	Ag12—O23—Ag17ⁱⁱⁱ	122.2 (4)
O25—Ag17—Ag27ⁱⁱ	129.8 (2)	C8—O23—Ag34ⁱⁱⁱ	107.3 (9)
O23ⁱⁱ—Ag17—Ag27ⁱⁱ	119.1 (2)	Ag12—O23—Ag34ⁱⁱⁱ	93.1 (3)
I15—Ag17—Ag27ⁱⁱ	62.90 (3)	Ag17ⁱⁱⁱ—O23—Ag34ⁱⁱⁱ	92.9 (3)
O25—Ag17—I11ⁱⁱ	88.6 (2)	C8—O24—Ag39ⁱⁱⁱ	126.3 (8)
O23ⁱⁱ—Ag17—I11ⁱⁱ	84.6 (2)	C8—O24—Ag16	113.6 (8)
I15—Ag17—I11ⁱⁱ	117.69 (4)	Ag39ⁱⁱⁱ—O24—Ag16	99.6 (4)
Ag27ⁱⁱ—Ag17—I11ⁱⁱ	54.79 (3)	C8—O24—Ag35^ix	95.1 (8)
O34^iv—Ag18—O32	78.3 (3)	Ag39ⁱⁱⁱ—O24—Ag35^ix	122.4 (4)
O34^iv—Ag18—O27	80.2 (3)	Ag16—O24—Ag35^ix	96.8 (3)
O32—Ag18—O27	72.9 (3)	C9—O25—Ag17	111.5 (8)
O34^iv—Ag18—I15	165.0 (3)	C9—O25—Ag13	121.2 (8)
O32—Ag18—I15	87.6 (2)	Ag17—O25—Ag13	108.8 (4)
O27—Ag18—I15	100.7 (2)	C9—O25—Ag34	110.4 (8)
O34^iv—Ag18—I16^iv	81.7 (2)	Ag17—O25—Ag34	98.7 (3)
O32—Ag18—I16^iv	103.8 (2)	Ag13—O25—Ag34	103.7 (4)
O27—Ag18—I16^iv	161.8 (2)	C9—O26—Ag37	122.2 (8)
I15—Ag18—I16^iv	96.91 (4)	C9—O26—Ag33	113.0 (8)
O34^iv—Ag18—I14^iv	94.9 (3)	Ag37—O26—Ag33	111.7 (4)
O32—Ag18—I14^iv	155.4 (2)	C9—O26—Ag14^iv	109.9 (8)
O27—Ag18—I14^iv	82.7 (2)	Ag37—O26—Ag14^iv	101.0 (3)
I15—Ag18—I14^iv	100.05 (4)	Ag33—O26—Ag14^iv	94.6 (3)
I16^iv—Ag18—I14^iv	98.54 (4)	C9—O27—Ag38	133.0 (9)
O34^iv—Ag18—Ag23^iv	82.8 (2)	C9—O27—Ag18	124.7 (8)
O32—Ag18—Ag23^iv	51.3 (2)	Ag38—O27—Ag18	88.6 (3)
O27—Ag18—Ag23^iv	123.8 (2)	C9—O27—Ag39	106.7 (8)
I15—Ag18—Ag23^iv	84.41 (4)	Ag38—O27—Ag39	82.8 (3)
I16^iv—Ag18—Ag23^iv	53.68 (3)	Ag18—O27—Ag39	114.4 (4)
I14^iv—Ag18—Ag23^iv	152.21 (4)	C10^ix—O28—Ag20ⁱⁱⁱ	121.7 (8)
O34—Ag19—O19^xi	114.5 (4)	C10^ix—O28—Ag15^ix	111.8 (8)
O34—Ag19—I12^x	117.8 (3)	Ag20ⁱⁱⁱ—O28—Ag15^ix	111.6 (4)
O19^xi—Ag19—I12^x	121.3 (2)	C10—O29—Ag35^ix	122.2 (8)
O34—Ag19—I14	97.5 (2)	C10—O29—Ag40	108.3 (8)
O19^xi—Ag19—I14	104.5 (2)	Ag35^ix—O29—Ag40	113.1 (4)
I12^x—Ag19—I14	93.67 (4)	C10—O29—Ag16	109.1 (8)
O34—Ag19—Ag14	122.6 (3)	Ag35^ix—O29—Ag16	103.1 (3)
O19^xi—Ag19—Ag14	51.1 (2)	Ag40—O29—Ag16	97.9 (3)
I12^x—Ag19—Ag14	113.16 (4)	C10—O30—Ag21	127.3 (9)
I14—Ag19—Ag14	53.82 (3)	C10—O30—Ag1^x	130.3 (8)
O28ⁱⁱ—Ag20—O35ⁱⁱⁱ	82.1 (4)	Ag21—O30—Ag1^x	91.9 (3)
O28ⁱⁱ—Ag20—I12	146.7 (2)	C11—O31—Ag39	123.2 (8)
O35ⁱⁱⁱ—Ag20—I12	117.4 (3)	C11—O31—Ag40ⁱⁱ	112.4 (8)
O28ⁱⁱ—Ag20—I12^xiii	86.8 (2)	Ag39—O31—Ag40ⁱⁱ	120.2 (4)
O35ⁱⁱⁱ—Ag20—I12^xiii	93.5 (3)	C11—O32—Ag38	130.8 (9)
I12—Ag20—I12^xiii	116.52 (4)	C11—O32—Ag23^iv	93.9 (8)
O28ⁱⁱ—Ag20—Ag20^xiii	134.3 (3)	Ag38—O32—Ag23^iv	132.2 (4)
O35ⁱⁱⁱ—Ag20—Ag20^xiii	118.4 (3)	C11—O32—Ag18	122.9 (8)
I12—Ag20—Ag20^xiii	62.66 (4)	Ag38—O32—Ag18	88.6 (3)
I12^xiii—Ag20—Ag20^xiii	53.86 (4)	Ag23^iv—O32—Ag18	77.2 (3)
O28ⁱⁱ—Ag20—Ag21ⁱ	85.4 (2)	C11ⁱⁱⁱ—O33—Ag22	127.7 (9)
O35ⁱⁱⁱ—Ag20—Ag21ⁱ	127.6 (3)	C11ⁱⁱⁱ—O33—Ag4	115.3 (9)
I12—Ag20—Ag21ⁱ	61.23 (3)	Ag22—O33—Ag4	99.5 (4)
I12^xiii—Ag20—Ag21ⁱ	136.37 (5)	C11ⁱⁱⁱ—O33—Ag23^v	92.3 (8)
Ag20^xiii—Ag20—Ag21ⁱ	106.51 (5)	Ag22—O33—Ag23^v	121.9 (4)
O30—Ag21—O2	79.1 (3)	Ag4—O33—Ag23^v	97.2 (3)
O30—Ag21—O4^x	74.1 (3)	C12—O34—Ag19	110.2 (9)
O2—Ag21—O4^x	74.3 (3)	C12—O34—Ag18^vi	129.5 (9)
O30—Ag21—I12^x	125.9 (2)	Ag19—O34—Ag18^vi	97.1 (4)
O2—Ag21—I12^x	136.8 (2)	C12—O35—Ag20ⁱⁱ	131.5 (9)
O4^x—Ag21—I12^x	79.9 (2)	C12—O35—Ag36^xi	122.3 (9)
O30—Ag21—Ag20^x	73.6 (2)	Ag20ⁱⁱ—O35—Ag36^xi	103.4 (4)
O2—Ag21—Ag20^x	143.1 (2)	C12—O35—Ag2ⁱⁱ	106.1 (9)
O4^x—Ag21—Ag20^x	74.6 (2)	Ag20ⁱⁱ—O35—Ag2ⁱⁱ	96.9 (4)
I12^x—Ag21—Ag20^x	53.94 (3)	Ag36^xi—O35—Ag2ⁱⁱ	79.1 (4)
O30—Ag21—Ag25	127.2 (2)	C12—O36—Ag24	123.0 (9)
O2—Ag21—Ag25	54.2 (2)	C12—O36—Ag3	127.8 (9)
O4^x—Ag21—Ag25	70.9 (2)	Ag24—O36—Ag3	109.0 (4)
I12^x—Ag21—Ag25	84.99 (4)	Ag3^v—I1—Ag2ⁱⁱⁱ	104.24 (4)
Ag20^x—Ag21—Ag25	130.08 (4)	Ag3^v—I1—Ag36^v	89.58 (4)
O30—Ag21—Ag22	55.6 (2)	Ag2ⁱⁱⁱ—I1—Ag36^v	64.56 (4)
O2—Ag21—Ag22	70.8 (2)	Ag3^v—I1—Ag1ⁱⁱⁱ	149.04 (4)
O4^x—Ag21—Ag22	122.5 (2)	Ag2ⁱⁱⁱ—I1—Ag1ⁱⁱⁱ	69.62 (4)
I12^x—Ag21—Ag22	151.34 (5)	Ag36^v—I1—Ag1ⁱⁱⁱ	112.72 (4)
Ag20^x—Ag21—Ag22	111.13 (4)	Ag3^v—I1—Ag38ⁱⁱⁱ	65.28 (4)
Ag25—Ag21—Ag22	117.60 (4)	Ag2ⁱⁱⁱ—I1—Ag38ⁱⁱⁱ	76.39 (4)
O30—Ag21—I16	75.0 (2)	Ag36^v—I1—Ag38ⁱⁱⁱ	126.35 (4)
O2—Ag21—I16	123.0 (2)	Ag1ⁱⁱⁱ—I1—Ag38ⁱⁱⁱ	83.94 (4)
O4^x—Ag21—I16	140.2 (2)	Ag40—I2—Ag4	78.75 (4)
I12^x—Ag21—I16	98.92 (4)	Ag40—I2—Ag1^x	77.99 (4)
Ag20^x—Ag21—I16	73.11 (3)	Ag4—I2—Ag1^x	117.64 (4)
Ag25—Ag21—I16	148.87 (4)	Ag40—I2—Ag40^ix	62.35 (4)
Ag22—Ag21—I16	52.54 (3)	Ag4—I2—Ag40^ix	114.93 (4)
O30—Ag21—I14	142.3 (2)	Ag1^x—I2—Ag40^ix	103.32 (4)
O2—Ag21—I14	76.0 (2)	Ag40—I2—Ag35	126.08 (4)
O4^x—Ag21—I14	124.2 (2)	Ag4—I2—Ag35	86.42 (3)
I12^x—Ag21—I14	91.35 (4)	Ag1^x—I2—Ag35	150.55 (4)
Ag20^x—Ag21—I14	139.39 (4)	Ag40^ix—I2—Ag35	78.70 (3)
Ag25—Ag21—I14	53.40 (3)	Ag37—I3—Ag38	67.95 (4)
Ag22—Ag21—I14	89.28 (4)	Ag37—I3—Ag36ⁱⁱⁱ	83.76 (4)
I16—Ag21—I14	95.52 (4)	Ag38—I3—Ag36ⁱⁱⁱ	112.46 (4)
O1^vi—Ag22—O33	82.5 (3)	Ag37—I3—Ag2	116.41 (4)
O1^vi—Ag22—I16	135.6 (2)	Ag38—I3—Ag2	79.14 (4)
O33—Ag22—I16	135.6 (3)	Ag36ⁱⁱⁱ—I3—Ag2	159.74 (4)
O1^vi—Ag22—Ag16	159.3 (2)	Ag37—I3—Ag3ⁱⁱⁱ	127.86 (4)
O33—Ag22—Ag16	78.8 (2)	Ag38—I3—Ag3ⁱⁱⁱ	161.60 (4)
I16—Ag22—Ag16	65.13 (3)	Ag36ⁱⁱⁱ—I3—Ag3ⁱⁱⁱ	81.11 (4)
O1^vi—Ag22—Ag21	82.9 (2)	Ag2—I3—Ag3ⁱⁱⁱ	84.43 (4)
O33—Ag22—Ag21	159.8 (3)	Ag37—I3—Ag7ⁱⁱⁱ	61.85 (3)
I16—Ag22—Ag21	63.87 (3)	Ag38—I3—Ag7ⁱⁱⁱ	108.36 (4)
Ag16—Ag22—Ag21	112.64 (4)	Ag36ⁱⁱⁱ—I3—Ag7ⁱⁱⁱ	109.16 (4)
O1^vi—Ag22—Ag40	96.1 (2)	Ag2—I3—Ag7ⁱⁱⁱ	81.01 (3)
O33—Ag22—Ag40	64.5 (3)	Ag3ⁱⁱⁱ—I3—Ag7ⁱⁱⁱ	76.84 (3)
I16—Ag22—Ag40	118.73 (4)	Ag30—I4—Ag34ⁱⁱⁱ	81.99 (4)
Ag16—Ag22—Ag40	67.66 (3)	Ag30—I4—Ag31ⁱ	74.28 (4)
Ag21—Ag22—Ag40	103.41 (4)	Ag34ⁱⁱⁱ—I4—Ag31ⁱ	115.44 (4)
O8—Ag23—O32^vi	109.4 (3)	Ag30—I4—Ag10^ix	61.77 (3)
O8—Ag23—O33^v	75.6 (3)	Ag34ⁱⁱⁱ—I4—Ag10^ix	114.25 (4)
O32^vi—Ag23—O33^v	52.0 (3)	Ag31ⁱ—I4—Ag10^ix	105.30 (4)
O8—Ag23—I16	136.2 (2)	Ag30—I4—Ag5ⁱⁱⁱ	130.53 (4)
O32^vi—Ag23—I16	111.5 (2)	Ag34ⁱⁱⁱ—I4—Ag5ⁱⁱⁱ	91.62 (4)
O33^v—Ag23—I16	144.5 (2)	Ag31ⁱ—I4—Ag5ⁱⁱⁱ	147.28 (4)
O8—Ag23—Ag3	69.2 (2)	Ag10^ix—I4—Ag5ⁱⁱⁱ	77.21 (3)
O32^vi—Ag23—Ag3	58.2 (2)	Ag5—I5—Ag39	104.44 (4)
O33^v—Ag23—Ag3	78.6 (2)	Ag5—I5—Ag1	70.03 (4)
I16—Ag23—Ag3	122.38 (4)	Ag39—I5—Ag1	80.84 (4)
O8—Ag23—Ag18^vi	160.8 (2)	Ag5—I5—Ag6	67.44 (3)
O32^vi—Ag23—Ag18^vi	51.5 (2)	Ag39—I5—Ag6	161.34 (4)
O33^v—Ag23—Ag18^vi	90.8 (2)	Ag1—I5—Ag6	110.23 (4)
I16—Ag23—Ag18^vi	61.30 (3)	Ag7—I6—Ag8	66.89 (4)
Ag3—Ag23—Ag18^vi	95.20 (4)	Ag7—I6—Ag37ⁱⁱ	65.28 (4)
O8—Ag23—I15ⁱⁱⁱ	82.2 (2)	Ag8—I6—Ag37ⁱⁱ	109.53 (4)
O32^vi—Ag23—I15ⁱⁱⁱ	123.7 (2)	Ag7—I6—Ag6ⁱⁱ	72.96 (4)
O33^v—Ag23—I15ⁱⁱⁱ	81.2 (2)	Ag8—I6—Ag6ⁱⁱ	112.38 (4)
I16—Ag23—I15ⁱⁱⁱ	87.77 (4)	Ag37ⁱⁱ—I6—Ag6ⁱⁱ	99.26 (4)
Ag3—Ag23—I15ⁱⁱⁱ	148.22 (4)	Ag7—I6—Ag32	123.20 (4)
Ag18^vi—Ag23—I15ⁱⁱⁱ	109.47 (4)	Ag8—I6—Ag32	80.53 (4)
O8—Ag23—Ag24	78.6 (2)	Ag37ⁱⁱ—I6—Ag32	85.53 (4)
O32^vi—Ag23—Ag24	119.7 (2)	Ag6ⁱⁱ—I6—Ag32	163.28 (4)
O33^v—Ag23—Ag24	146.2 (2)	Ag7—I6—Ag33ⁱⁱ	131.29 (4)
I16—Ag23—Ag24	68.21 (3)	Ag8—I6—Ag33ⁱⁱ	160.12 (4)
Ag3—Ag23—Ag24	71.92 (3)	Ag37ⁱⁱ—I6—Ag33ⁱⁱ	77.48 (3)
Ag18^vi—Ag23—Ag24	107.84 (4)	Ag6ⁱⁱ—I6—Ag33ⁱⁱ	83.85 (3)
I15ⁱⁱⁱ—Ag23—Ag24	116.54 (4)	Ag32—I6—Ag33ⁱⁱ	81.56 (3)
O36—Ag24—O5ⁱⁱ	88.3 (4)	Ag9^iv—I7—Ag35^v	108.57 (4)
O36—Ag24—I13	141.2 (3)	Ag9^iv—I7—Ag31^iv	80.64 (4)
O5ⁱⁱ—Ag24—I13	121.8 (3)	Ag35^v—I7—Ag31^iv	64.19 (3)
O36—Ag24—Ag29	148.0 (3)	Ag9^iv—I7—Ag4^v	63.67 (3)
O5ⁱⁱ—Ag24—Ag29	64.4 (3)	Ag35^v—I7—Ag4^v	89.99 (4)
I13—Ag24—Ag29	58.04 (3)	Ag31^iv—I7—Ag4^v	126.55 (4)
O36—Ag24—I12ⁱⁱ	118.6 (3)	Ag9^iv—I7—Ag8	64.37 (3)
O5ⁱⁱ—Ag24—I12ⁱⁱ	89.4 (2)	Ag35^v—I7—Ag8	149.45 (4)
I13—Ag24—I12ⁱⁱ	88.12 (4)	Ag31^iv—I7—Ag8	85.27 (4)
Ag29—Ag24—I12ⁱⁱ	79.51 (4)	Ag4^v—I7—Ag8	110.26 (4)
O36—Ag24—Ag23	57.8 (3)	Ag12—I8—Ag33	110.71 (4)
O5ⁱⁱ—Ag24—Ag23	133.5 (2)	Ag12—I8—Ag28	82.39 (4)
I13—Ag24—Ag23	83.41 (4)	Ag33—I8—Ag28	65.73 (3)
Ag29—Ag24—Ag23	130.45 (4)	Ag12—I8—Ag6	65.99 (4)
I12ⁱⁱ—Ag24—Ag23	133.17 (4)	Ag33—I8—Ag6	89.96 (4)
O11^x—Ag25—O6^x	79.4 (3)	Ag28—I8—Ag6	130.27 (4)
O11^x—Ag25—O2	119.2 (3)	Ag12—I8—Ag11	63.06 (3)
O6^x—Ag25—O2	99.0 (3)	Ag33—I8—Ag11	151.23 (4)
O11^x—Ag25—I14	134.1 (2)	Ag28—I8—Ag11	85.50 (4)
O6^x—Ag25—I14	141.5 (3)	Ag6—I8—Ag11	110.18 (4)
O2—Ag25—I14	81.2 (2)	Ag13^vi—I9—Ag32^vi	103.36 (4)
O11^x—Ag25—Ag21	160.3 (2)	Ag13^vi—I9—Ag26^vi	87.69 (4)
O6^x—Ag25—Ag21	85.3 (2)	Ag32^vi—I9—Ag26^vi	62.62 (3)
O2—Ag25—Ag21	51.0 (2)	Ag13^vi—I9—Ag31	147.96 (4)
I14—Ag25—Ag21	64.85 (3)	Ag32^vi—I9—Ag31	70.35 (3)
O11^x—Ag25—Ag5^x	67.4 (2)	Ag26^vi—I9—Ag31	114.28 (4)
O6^x—Ag25—Ag5^x	82.1 (3)	Ag13^vi—I9—Ag8^vi	65.83 (4)
O2—Ag25—Ag5^x	52.5 (2)	Ag32^vi—I9—Ag8^vi	78.44 (4)
I14—Ag25—Ag5^x	123.97 (4)	Ag26^vi—I9—Ag8^vi	126.18 (4)
Ag21—Ag25—Ag5^x	98.37 (4)	Ag31—I9—Ag8^vi	82.18 (3)
O3^iv—Ag26—O10^iv	79.4 (3)	Ag10—I10—Ag11^x	70.22 (4)
O3^iv—Ag26—I11ⁱⁱ	106.6 (2)	Ag10—I10—Ag30^ix	64.37 (4)
O10^iv—Ag26—I11ⁱⁱ	162.0 (2)	Ag11^x—I10—Ag30^ix	108.77 (4)
O3^iv—Ag26—I9^iv	153.3 (2)	Ag10—I10—Ag29^x	124.39 (4)
O10^iv—Ag26—I9^iv	88.8 (2)	Ag11^x—I10—Ag29^x	83.63 (4)
I11ⁱⁱ—Ag26—I9^iv	91.93 (4)	Ag30^ix—I10—Ag29^x	80.35 (4)
O3^iv—Ag26—Ag32	141.6 (2)	Ag10—I10—Ag14^vii	79.57 (4)
O10^iv—Ag26—Ag32	80.3 (2)	Ag11^x—I10—Ag14^vii	115.52 (4)
I11ⁱⁱ—Ag26—Ag32	85.04 (4)	Ag30^ix—I10—Ag14^vii	106.73 (4)
I9^iv—Ag26—Ag32	57.17 (3)	Ag29^x—I10—Ag14^vii	154.60 (4)
O8—Ag27—O1ⁱⁱⁱ	85.1 (3)	Ag27—I11—Ag28	79.43 (4)
O8—Ag27—I11	137.3 (2)	Ag27—I11—Ag26ⁱⁱⁱ	80.72 (4)
O1ⁱⁱⁱ—Ag27—I11	127.0 (2)	Ag28—I11—Ag26ⁱⁱⁱ	119.27 (4)
O8—Ag27—Ag17ⁱⁱⁱ	128.9 (2)	Ag27—I11—Ag17ⁱⁱⁱ	61.83 (3)
O1ⁱⁱⁱ—Ag27—Ag17ⁱⁱⁱ	120.2 (2)	Ag28—I11—Ag17ⁱⁱⁱ	105.19 (4)
I11—Ag27—Ag17ⁱⁱⁱ	63.38 (3)	Ag26ⁱⁱⁱ—I11—Ag17ⁱⁱⁱ	114.20 (4)
O8—Ag27—I15ⁱⁱⁱ	86.6 (2)	Ag27—I11—Ag13ⁱⁱⁱ	122.19 (4)
O1ⁱⁱⁱ—Ag27—I15ⁱⁱⁱ	86.8 (2)	Ag28—I11—Ag13ⁱⁱⁱ	153.98 (4)
I11—Ag27—I15ⁱⁱⁱ	118.44 (4)	Ag26ⁱⁱⁱ—I11—Ag13ⁱⁱⁱ	81.20 (3)
Ag17ⁱⁱⁱ—Ag27—I15ⁱⁱⁱ	55.06 (3)	Ag17ⁱⁱⁱ—I11—Ag13ⁱⁱⁱ	77.16 (3)
O14—Ag28—O9	77.4 (4)	Ag20—I12—Ag19ⁱ	120.04 (4)
O14—Ag28—O16	80.8 (3)	Ag20—I12—Ag21ⁱ	64.83 (3)
O9—Ag28—O16	74.4 (3)	Ag19ⁱ—I12—Ag21ⁱ	82.59 (4)
O14—Ag28—I11	166.7 (3)	Ag20—I12—Ag20^xiii	63.48 (4)
O9—Ag28—I11	98.4 (3)	Ag19ⁱ—I12—Ag20^xiii	84.97 (4)
O16—Ag28—I11	85.9 (2)	Ag21ⁱ—I12—Ag20^xiii	109.61 (4)
O14—Ag28—I8	85.5 (3)	Ag20—I12—Ag15ⁱⁱⁱ	130.11 (4)
O9—Ag28—I8	162.8 (3)	Ag19ⁱ—I12—Ag15ⁱⁱⁱ	84.83 (4)
O16—Ag28—I8	105.2 (2)	Ag21ⁱ—I12—Ag15ⁱⁱⁱ	164.41 (4)
I11—Ag28—I8	98.73 (4)	Ag20^xiii—I12—Ag15ⁱⁱⁱ	78.30 (3)
O14—Ag28—Ag33	85.1 (3)	Ag20—I12—Ag24ⁱⁱⁱ	81.27 (4)
O9—Ag28—Ag33	124.9 (2)	Ag19ⁱ—I12—Ag24ⁱⁱⁱ	158.30 (4)
O16—Ag28—Ag33	51.2 (2)	Ag21ⁱ—I12—Ag24ⁱⁱⁱ	112.73 (4)
I11—Ag28—Ag33	87.18 (4)	Ag20^xiii—I12—Ag24ⁱⁱⁱ	102.95 (4)
I8—Ag28—Ag33	54.47 (3)	Ag15ⁱⁱⁱ—I12—Ag24ⁱⁱⁱ	77.23 (3)
O14—Ag28—I13	91.9 (3)	Ag15—I13—Ag24	90.20 (4)
O9—Ag28—I13	78.4 (2)	Ag15—I13—Ag29	105.36 (4)
O16—Ag28—I13	152.8 (2)	Ag24—I13—Ag29	65.28 (4)
I11—Ag28—I13	99.65 (4)	Ag15—I13—Ag28	148.85 (4)
I8—Ag28—I13	100.34 (4)	Ag24—I13—Ag28	113.66 (4)
Ag33—Ag28—I13	154.77 (4)	Ag29—I13—Ag28	70.21 (3)
O14—Ag29—O6ⁱⁱ	119.4 (4)	Ag25—I14—Ag14	92.63 (4)
O14—Ag29—I13	101.0 (3)	Ag25—I14—Ag19	101.58 (4)
O6ⁱⁱ—Ag29—I13	136.3 (3)	Ag14—I14—Ag19	64.65 (3)
O14—Ag29—I10ⁱ	117.1 (3)	Ag25—I14—Ag18^vi	144.30 (4)
O6ⁱⁱ—Ag29—I10ⁱ	83.1 (2)	Ag14—I14—Ag18^vi	112.82 (4)
I13—Ag29—I10ⁱ	93.27 (4)	Ag19—I14—Ag18^vi	70.24 (3)
O14—Ag29—Ag24	123.4 (3)	Ag25—I14—Ag21	61.75 (3)
O6ⁱⁱ—Ag29—Ag24	85.7 (2)	Ag14—I14—Ag21	128.69 (4)
I13—Ag29—Ag24	56.68 (3)	Ag19—I14—Ag21	77.33 (3)
I10ⁱ—Ag29—Ag24	115.57 (4)	Ag18^vi—I14—Ag21	82.60 (3)
O14—Ag29—Ag7	70.3 (3)	Ag17—I15—Ag16ⁱⁱ	78.40 (4)
O6ⁱⁱ—Ag29—Ag7	74.4 (2)	Ag17—I15—Ag18	78.39 (4)
I13—Ag29—Ag7	107.45 (4)	Ag16ⁱⁱ—I15—Ag18	115.08 (4)
I10ⁱ—Ag29—Ag7	156.56 (5)	Ag17—I15—Ag27ⁱⁱ	62.03 (3)
Ag24—Ag29—Ag7	69.80 (4)	Ag16ⁱⁱ—I15—Ag27ⁱⁱ	114.94 (4)
O13—Ag30—O11	76.6 (3)	Ag18—I15—Ag27ⁱⁱ	105.28 (4)
O13—Ag30—I4	114.9 (3)	Ag17—I15—Ag23ⁱⁱ	126.19 (4)
O11—Ag30—I4	144.5 (2)	Ag16ⁱⁱ—I15—Ag23ⁱⁱ	88.27 (4)
O13—Ag30—I10^ix	102.7 (3)	Ag18—I15—Ag23ⁱⁱ	150.50 (4)
O11—Ag30—I10^ix	88.6 (2)	Ag27ⁱⁱ—I15—Ag23ⁱⁱ	78.17 (3)
I4—Ag30—I10^ix	118.60 (5)	Ag22—I16—Ag23	108.58 (4)
O13—Ag30—Ag10^ix	134.2 (3)	Ag22—I16—Ag18^vi	82.22 (4)
O11—Ag30—Ag10^ix	133.0 (2)	Ag23—I16—Ag18^vi	65.03 (3)
I4—Ag30—Ag10^ix	64.17 (3)	Ag22—I16—Ag21	63.58 (3)
I10^ix—Ag30—Ag10^ix	54.85 (3)	Ag23—I16—Ag21	148.35 (4)
O20—Ag31—O12^x	77.9 (3)	Ag18^vi—I16—Ag21	83.34 (4)
O20—Ag31—O22^x	78.3 (3)	Ag22—I16—Ag16	61.81 (3)
O12^x—Ag31—O22^x	75.6 (3)	Ag23—I16—Ag16	89.39 (4)
O20—Ag31—I4^x	165.3 (2)	Ag18^vi—I16—Ag16	126.65 (4)
O12^x—Ag31—I4^x	101.3 (2)	Ag21—I16—Ag16	110.02 (4)
O22^x—Ag31—I4^x	87.2 (2)

Symmetry codes: (i) −x, y−1/2, −z+1/2; (ii) x, −y+1/2, z−1/2; (iii) x, −y+1/2, z+1/2; (iv) −x+1, y−1/2, −z+1/2; (v) −x+1, −y+1, −z+1; (vi) −x+1, y+1/2, −z+1/2; (vii) x, −y+3/2, z+1/2; (viii) x, −y+3/2, z−1/2; (ix) −x, −y+1, −z+1; (x) −x, y+1/2, −z+1/2; (xi) −x+1, −y+1, −z; (xii) x−1, y, z; (xiii) −x, −y, −z+1; (xiv) x+1, y, z.

Shortest interatomic distances in the crystal structure of Ag₁₀(CO₃)₃I₄ top

Atom pair	Distance (Å)
Ag12—O23	2.252 (9)
Ag7—I6	2.7140 (14)
Ag26···Ag32 (in-layer)	2.9901 (15)
Ag13···Ag33 (out-of-layer; across CO₃ layer)	3.0620 (15)
Ag17···Ag27ⁱ (out-of-layer; across I layer)	2.9507 (15)
I10···I12ⁱⁱ	3.9564 (11)
C1—O1ⁱⁱⁱ (within a CO₃ group)	1.251 (15)
O25···O26 (within a CO₃ group)	2.206 (14)
O15···O25 (between different CO₃ groups)	2.816 (15)

Symmetry code: (i) x, -y + 1/2, z - 1/2; (ii) -x, -y + 1, -z + 1; (iii) x + 1, y + 1/2, z + 1/2.

Acknowledgements

This work was performed under the Cooperative Research Program of Network Joint Research Center for Materials and Devices.

Funding information

Funding for this research was provided by: Murata Science Foundation (grant No. H30-95).

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