Figure 5
Out-of-plane plots (Kingsbury & Senge, 2021) of the chromophore conformations of (a), dihydroxychlorin 2PhH2·DMAP and dimethoxychlorin 4PhH2 (Samankumara et al., 2010), and (b), the equivalent plots of 2PhZn·EDA and 4CF3Zn·py (Sharma et al., 2017). The atoms indicated in red are the pyrroline β-carbons carrying the cis-hydroxy or methoxy groups. |