Syntheses and structural characterizations of the first coordination polymers assembled from the Ni(cyclam)2+ cation and the benzene-1,3,5-tri­carboxyl­ate linker

Gavrish, S.P.; Shova, S.; Lampeka, Y.D.

doi:10.1107/S2056989022009860

Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

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Figure 1
The extended asymmetric unit in (a) I and (b) II showing the coordination environment of the Ni atoms and the atom-labeling scheme (displacement ellipsoids are drawn at the 30% probability level). C-bound H atoms are omitted for clarity. Intramolecular hydrogen bonds are shown as dotted lines. Symmetry codes: (i) −x + $[{3\over 2}]$ , y − $[{1\over 2}]$ , −z + $[{3\over 2}]$ ; (ii) −x + $[{3\over 2}]$ , y + $[{1\over 2}]$ , −z + $[{3\over 2}]$ ; (iii) −x + 1, −y, −z + 1; (iv) −x, −y + 1, −z + 1.

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 78| Part 11| November 2022| Pages 1122-1126

https://doi.org/10.1107/S2056989022009860

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