Crystal structures of the complexes containing macrocyclic cations [M(cyclam)]2+ (M = Ni, Zn) and tetra­iodido­cadmate(2–) anion

Andriichuk, I.L.; Shova, S.; Lampeka, Y.D.

doi:10.1107/S2056989023007004

Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

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Figure 3
Nearest surrounding of the macrocyclic cation (a) and the anion (b) in I formed by N—H⋯I hydrogen bonding (black dashed lines). Symmetry codes: (i) −x + 1, −y + 1, −z + 1; (ii) x + $[{1\over 2}]$ , −y + $[{3\over 2}]$ , −z + $[{3\over 2}]$ ; (iii) −x + 1, y − $[{1\over 2}]$ , −z + 1; (iv) −x + $[{1\over 2}]$ , −y + 1, z − $[{1\over 2}]$ ; (v) x, −y + $[{3\over 2}]$ , z; (vi) −x + 1, y + $[{1\over 2}]$ , −z + 1; (vii) x − $[{1\over 2}]$ , −y + $[{3\over 2}]$ , −z + $[{3\over 2}]$ ; (viii) −x + $[{1\over 2}]$ , −y + 1, z + $[{1\over 2}]$ ; (ix) x − $[{1\over 2}]$ , y, −z + $[{3\over 2}]$ .

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 79| Part 9| September 2023| Pages 821-826

https://doi.org/10.1107/S2056989023007004

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