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ISSN: 2056-9890

Crystal structures of five compounds in the aluminium–ruthenium–silicon system

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aDepartment of Materials Science and Engineering, School of Electrical and Computer Engineering, National Defense Academy, Yokosuka 239-8686, Japan, bDepartment of Advanced Materials Science, Graduate School of Frontier Sciences, The University of Tokyo, Kashiwa 277-8561, Japan, cDivision of Applied Physics, Faculty of Engineering, Hokkaido University, Sapporo 060-8628, Japan, and dNational Institute for Materials Science (NIMS), Tsukuba 305-0047, Japan
*Correspondence e-mail: kokitaha@nda.ac.jp

Edited by M. Weil, Vienna University of Technology, Austria (Received 24 July 2023; accepted 25 September 2023; online 29 September 2023)

Single crystals of five compounds with approximate compositions ∼Ru16(Al0.78Si0.22)47, (I), ∼Ru9(Al0.70Si0.30)32, (II), ∼Ru10(Al0.67Si0.33)41, (III), ∼Ru(Al0.57Si0.43)5, (IV), and ∼Ru2(Al0.46Si0.54)9, (V), were obtained from polycrystalline lumps mainly composed of the target compounds, and their crystal structures were determined by means of single-crystal X-ray diffraction. The crystal structure of (I) can be related to that of a cubic rational crystalline approximant to an icosa­hedral quasicrystal through crystallographic shear and then unit-cell twinning. The crystal structure of (II) is isotypic with that of a phase with composition ∼Fe9(Al,Si)32. The crystal structure of (III) is comprised of edge-sharing Ru(Al,Si)9–11 polyhedra with disordered chains along edges of polyhedra. The crystal structure of (IV) is of the LiIrSn4 type. The crystal structure of (V) can be viewed as a crystallographic shear structure derived from that of (IV).

1. Chemical context

Semiconductors with complex crystal structures have attracted attention as thermoelectric materials (Snyder & Toberer, 2008[Snyder, G. J. & Toberer, E. S. (2008). Nat. Mater. 7, 105-114.]; Zhang & Zhao, 2015[Zhang, X. & Zhao, L.-D. (2015). J. Materiomics, 1, 92-105.]; Liu et al., 2017[Liu, W., Hu, J., Zhang, S., Deng, M., Han, C.-G. & Liu, Y. (2017). Mater. Today Phys. 1, 50-60.]). To facilitate a search for such materials, knowledge on crystal structures is essential because it serves as a basis for understanding how semiconductivity and structural complexity meet in a material. Recently, a semiconducting compound with a complex crystal structure, which is considered a cubic rational crystalline approximant to an icosa­hedral quasicrystal, was discovered near the composition Al67.6Ru23.5Si8.9 (Iwasaki et al., 2019[Iwasaki, Y., Kitahara, K. & Kimura, K. (2019). Phys. Rev. Mater. 3, 061601, 1-5.]). Following this discovery, phase equilibria in the Al–Ru–Si system at 1200 K were thoroughly investigated, and eleven new ternary phases were identified (Kitahara et al., 2023[Kitahara, K., Takakura, H., Iwasaki, Y. & Kimura, K. (2023). Mater. Trans. submitted.]). In the course of these investigations, single crystals of five new compounds with approximate compositions ∼Ru16(Al0.78Si0.22)47 (I), ∼Ru9(Al0.70Si0.30)32 (II), ∼Ru10(Al0.67Si0.33)41 (III), ∼Ru(Al0.57Si0.43)5 (IV) and ∼Ru2(Al0.46Si0.54)9 (V) could be obtained from polycrystalline lumps mainly composed of the target compounds. Here we report the crystal structures of these compounds.

2. Structural commentary

The crystal structure of (I) consists of Ru-centred polyhedra with coordination numbers ranging from nine to eleven [Fig. 1[link](ae, gi)] and (Si,Ru)-centred icosa­hedra [Fig. 1[link](f)]. Each polyhedron is connected to three, four, five, six or fourteen others through face-sharing. A sensible represent­ation of the crystal packing in (I) is obtained by using large structural units (clusters) [Fig. 2[link](b)] instead of using coordination polyhedra [Fig. 2[link](a)].

[Figure 1]
Figure 1
Coordination environments of (a) Ru1, (b) Ru2, (c) Ru3, (d) Ru4, (e) Ru5, (f) Si/Ru6, (g) Ru7, (h) Ru8 and (i) Ru9 in the crystal structure of (I) with displacement ellipsoids plotted at the 99% probability level. Unlabelled atoms in (af), (g) and (h) are related to the corresponding labelled atoms by (iii), (i) and (xix), respectively. Only the major disordered components are shown except for Ru8, Al20 and Al28A, for which two split components with equal occupancy are shown. Colour codes: Al and (Al/Si) (light blue); Ru (light brown); Si, (Si/Al) and (Si/Ru) (blue). [Symmetry codes: (i) x, y, −z + [{1\over 2}]; (iii) −x, y, z; (v) −x + [{1\over 2}], −y + [{1\over 2}], z + [{1\over 2}]; (vi) −x, −y, −z + 1; (vii) −x + [{1\over 2}], −y + [{1\over 2}], −z + 1; (ix) −x + [{1\over 2}], −y + [{1\over 2}], −z; (x) −x + [{1\over 2}], y + [{1\over 2}], z; (xii) −x, −y + 1, −z; (xiii) −x, −y + 1, z − [{1\over 2}]; (xiv) x + [{1\over 2}], y − [{1\over 2}], −z + [{1\over 2}]; (xv) x + [{1\over 2}], y − [{1\over 2}], z; (xvi) −x + [{1\over 2}], y − [{1\over 2}], −z + [{1\over 2}]; (xvii) −x + [{1\over 2}], y − [{1\over 2}], z; (xix) −x + 1, y, z; (xx) −x + [{1\over 2}], −y + [{1\over 2}], z − [{1\over 2}].]
[Figure 2]
Figure 2
Packing diagrams for (I) based on (a) the coordination polyhedra given in Fig. 1[link] and (b) larger structural units (clusters).

The crystal structure of (I) can be related to that of a rational crystalline approximant to an icosa­hedral quasicrystal through crystallographic shear and then unit-cell twinning, as detailed in the following. The crystallographic shear and unit-cell twinning are two of the most important structure building operations by which a recombination structure is derived from a simpler parent structure (Lima-de-Faria et al., 1990[Lima-de-Faria, J., Hellner, E., Liebau, F., Makovicky, E. & Parthé, E. (1990). Acta Cryst. A46, 1-11.]). In this case, the parent structure is a 1/0 cubic approximant to a Mackay-type icosa­hedral quasicrystal. Crystal structures of this type are known for the phases with approximate compositions ∼RhAl2.63 (ICSD 406525; Grin et al., 1997[Grin, Y., Peters, K., Burkhardt, U., Gotzmann, K. & Ellner, M. (1997). Z. Kristallogr. 212, 439-444.]), ∼IrAl2.75 (ICSD 406526; Grin et al., 1997[Grin, Y., Peters, K., Burkhardt, U., Gotzmann, K. & Ellner, M. (1997). Z. Kristallogr. 212, 439-444.]), ∼Al20.5Ru5.1Ni2.9 (ICSD 230569; Simura et al., 2017[Simura, R., Sugiyama, K., Suzuki, S. & Kawamata, T. (2017). Mater. Trans. 58, 1101-1105.]) and ∼Al5.64Fe0.96Pd1.04 (ICSD 45248; Li & Fan, 2019[Li, H. & Fan, C. (2019). Crystals, 9, 526, 1-11.]). The crystal structure of the semiconducting compound ∼Al67.6Ru23.5Si8.9 is also considered to fall into this type (Iwasaki et al., 2019[Iwasaki, Y., Kitahara, K. & Kimura, K. (2019). Phys. Rev. Mater. 3, 061601, 1-5.]). Fig. 3[link](a) shows an idealized crystal structure of this cubic approximant, which can be viewed as a CsCl-type packing of two types of clusters, icosa­hedral clusters and pseudo-Mackay clusters (Simura et al., 2017[Simura, R., Sugiyama, K., Suzuki, S. & Kawamata, T. (2017). Mater. Trans. 58, 1101-1105.]). Fig. 3[link](b) shows a crystallographic shear structure derived from the parent structure. The shear planes are (10[\overline{1}]) planes of the parent structure [Fig. 3[link](a)], and the shear operation was applied at cluster level. Fig. 3[link](c) shows the crystal structure obtained by applying unit-cell twinning to the sheared structure. The twin planes are (001) planes of the sheared structure [Fig. 3[link](b)], and the twin operation was applied at the atomic level. Two constituent parts of the twinned structure are related by reflection across the twin planes as the mirror planes. Atoms close to each twin plane were shifted onto the plane prior to the twinning. The twinned structure is comparable to the cluster-based representation of (I) shown in Fig. 2[link](b). Note that the shear structure shown in Fig. 3[link](b) can also be obtained through so-called linear phason strain (Yamamoto, 1996[Yamamoto, A. (1996). Acta Cryst. A52, 509-560.]) instead of crystallographic shear and hence directly relates to an icosa­hedral quasicrystal as a monoclinic approximant.

[Figure 3]
Figure 3
The structural units given in Fig. 2[link](b) as derived from (a) the parent cubic approximant structure by applying (b) crystallographic shear and then (c) unit-cell twinning. Shear planes [(10[\overline{1}]) planes of the parent structure] are indicated by arrows in (a). Twin planes [(001) planes of the sheared structure] are indicated by arrows in (b). Colour codes: icosa­hedral clusters (blue); pseudo-Mackay clusters (red).

The crystal structure of (II) consists of two types of Ru-centred polyhedra, RuAl12 cubocta­hedra [Fig. 4[link](a)] and Ru(Al,Si)9 square-face tricapped trigonal prisms [Fig. 4[link](b, c)]. Each cubocta­hedron is surrounded by eight square-face tricapped trigonal prisms sharing its eight triangular faces. Each square-face tricapped trigonal prism is in turn connected to others through edge-sharing.

[Figure 4]
Figure 4
Coordination environments of (a) Ru1, (b) Ru2 and (c) Ru3 in the crystal structure of (II) with displacement ellipsoids plotted at the 99% probability level. Colour codes: Al and Al/Si (light blue); Ru (light brown); Si (blue). [Symmetry codes: (i) x − y, x, −z + 1; (ii) −x + y, −x, z; (iii) −x, −y, −z + 1; (iv) −y, x − y, z; (v) y, −x + y, −z + 1; (vi) y − [{2\over 3}], −x + y − [{1\over 3}], −z + [{2\over 3}]; (vii) −y + [{2\over 3}], x − y + [{1\over 3}], z + [{1\over 3}]; (viii) x − [{1\over 3}], y − [{2\over 3}], z + [{1\over 3}]; (ix) −x + [{1\over 3}], −y + [{2\over 3}], −z + [{2\over 3}]; (x) x − y + [{1\over 3}], x − [{1\over 3}], −z + [{2\over 3}]; (xi) −x + y − [{1\over 3}], −x + [{1\over 3}], z + [{1\over 3}]; (xii) x − y + [{2\over 3}], x + [{1\over 3}], −z + [{1\over 3}]; (xiii) −x + y + [{1\over 3}], −x + [{2\over 3}], z − [{1\over 3}]; (xiv) −x + [{2\over 3}], −y + [{1\over 3}], −z + [{1\over 3}]; (xv) y, −x + y, −z.]

The crystal structure of (III) is comprised of Ru(Al,Si)10 [Fig. 5[link](a, b)], Ru(Al,Si)9 [Fig. 5[link](c)] and Ru(Al,Si)11 [Fig. 5[link](dg)] polyhedra. Unlike the polyhedra in (I) and (II), no faces are shared between these polyhedra. These polyhedra are connected through edge-sharing. As an unusual feature, extensive positional disorder within a chain motif along edges of Ru4- and Ru5-centred polyhedra [Fig. 6[link](a)] is found in (III). A similar disordered chain structure [Fig. 6[link](b)] was also reported for the phase with approximate composition ∼Fe2Al5 (Burkhardt et al., 1994[Burkhardt, U., Grin, Yu., Ellner, M. & Peters, K. (1994). Acta Cryst. B50, 313-316.]; Vinokur et al., 2019[Vinokur, A. I., Hilleke, K. P. & Fredrickson, D. C. (2019). Acta Cryst. A75, 297-306.]).

[Figure 5]
Figure 5
Coordination environments of (a) Ru1, (b) Ru2, (c) Ru3, (d) Ru4, (e) Ru5, (f) Ru6 and (g) Ru7 in the crystal structure of (III) with displacement ellipsoids plotted at the 99% probability level. Unlabelled atoms in (ad) are related to the corresponding labelled atoms by (vii). Only the major disordered components are shown. Colour codes: Al and Al/Si (light blue); Ru (light brown); Si (blue). [Symmetry codes: (i) −x + [{1\over 2}], y − [{1\over 2}], z + [{1\over 2}]; (iii) x − [{1\over 2}], y, −z + [{3\over 2}]; (iv) x + [{1\over 2}], y, −z + [{3\over 2}]; (v) x + [{1\over 2}], −y + [{1\over 2}], −z + [{1\over 2}]; (vi) x + [{1\over 2}], y, −z + [{1\over 2}]; (vii) x, −y + [{1\over 2}], z; (viii) −x + [{1\over 2}], y − [{1\over 2}], z − [{1\over 2}]; (x) −x + [{1\over 2}], −y, z + [{1\over 2}]; (xi) −x, y − [{1\over 2}], −z + 1.]
[Figure 6]
Figure 6
Disordered chains along polyhedral edges (a) in the crystal structure of (III) and (b) in ∼Fe2Al5 (CCDC 1880447; Vinokur et al., 2019[Vinokur, A. I., Hilleke, K. P. & Fredrickson, D. C. (2019). Acta Cryst. A75, 297-306.]). Colour codes: Al (light blue); Fe (brown); Ru (light brown); Si (blue).

The crystal structures of (IV) and (V) consist of Ru(Al,Si)10 bicapped square anti­prisms [Fig. 7[link](a, b)]. In both crystal structures, the two cap positions of each polyhedron [Al2i and Al2 in Fig. 7[link](a); Al6 and Al8iv in Fig. 7[link](b)] are occupied solely by Al, and each polyhedron is connected to four others in the (001) plane through edge-sharing. Along the [001] direction, each polyhedron is connected to two others sharing its vertices at the two cap positions in (IV) [Fig. 8[link](a)], while each polyhedron is connected to one another through vertex-sharing and two others through edge-sharing in (V) [Fig. 8[link](b)]. The structure of (V) can be viewed as a crystallographic shear structure derived from that of (IV). The corresponding shear planes are (001) planes of (IV) [Fig. 8[link](a)].

[Figure 7]
Figure 7
Coordination environments of (a) Ru1 in the crystal structure of (IV) [symmetry codes: (i) −x, y, −z + [{1\over 2}]; (ii) y − 1, −x, z; (iii) y − [{1\over 2}], −x + [{1\over 2}], −z + [{1\over 2}]; (iv) x, y − 1, z; (v) −x + [{1\over 2}], −y + [{1\over 2}], −z + [{1\over 2}]; (vi) −y + [{1\over 2}], x − [{1\over 2}], −z + [{1\over 2}]; (vii) −y + 1, x, z; (viii) x − [{1\over 2}], y − [{1\over 2}], −z + [{1\over 2}]; (ix) −x, −y + 1, z] and (b) Ru1 in the crystal structure of (V) [symmetry codes: (i) −x + [{1\over 2}], −y + [{1\over 2}], z − [{1\over 2}]; (ii) −x + [{1\over 2}], y − [{1\over 2}], z; (iv) −x + [{1\over 2}], −y + [{1\over 2}], −z] with displacement ellipsoids plotted at the 99% probability level. Colour codes: Al (light blue); Ru (light brown); Si and Si/Al (blue).
[Figure 8]
Figure 8
Packing diagrams for the crystal structures (a) of (IV) and (b) of (V). Crystallographic shear planes [(001) planes of (IV)] are indicated by arrows in (a). Colour codes: Al (light blue); Ru (light brown); Si (blue).

3. Database survey

Searches for isotypic crystal structures to those of the five compounds were carried out using the Inorganic Crystal Structure Database (ICSD, version 4.9.0; Zagorac et al., 2019[Zagorac, D., Müller, H., Ruehl, S., Zagorac, J. & Rehme, S. (2019). J. Appl. Cryst. 52, 918-925.]). For (I), (III) and (V), queries for structures with the Pearson symbols oS250–254, oP200–204 and oS88, respectively, were made, but no entries for isotypic crystals were found. For (II), a query for hR41 was made, and three nearly identical structures (ICSD 99169; Sugiyama et al., 2004[Sugiyama, K., Kaji, N. & Hiraga, K. (2004). J. Alloys Compd. 368, 251-255.]; ICSD 423182, 423183; Roger et al., 2011[Roger, J., Jeanneau, E. & Viala, J.-C. (2011). Z. Kristallogr. 226, 805-813.]) of the crystal ∼Fe9(Al,Si)32 were found. Although isotypism is indicated between (II) and ∼Fe9(Al,Si)32, unlike in (II), the centres of the cubocta­hedra are not occupied solely by transition-metal atoms in these structures. For (IV), a query for tI24 was made, and some isotypic crystals of the LiIrSn4 type (ICSD 412252; Wu et al., 2002[Wu, Z., Hoffmann, R.-D. & Pöttgen, R. (2002). Z. Anorg. Allg. Chem. 628, 1484-1488.]) were found. Limiting the results to Al-containing crystal structures, isotypic crystals in the Al–Fe–Si (ICSD 79709; Gueneau et al., 1995[Gueneau, C., Servant, C., d'Yvoire, F. & Rodier, N. (1995). Acta Cryst. C51, 177-179.]; ICSD 4837, 4839; Zhou et al., 2018[Zhou, Y., Wu, J., Ma, W., Lei, Y. & Dai, Y. (2018). J. Alloys Compd. 751, 257-265.]), Al–Fe–Ge (ICSD 235910; Reisinger et al., 2018[Reisinger, G. R., Effenberger, H. S. & Richter, K. W. (2018). J. Alloys Compd. 762, 849-857.]) and Al–Ge–Mn (ICSD 8608; Sasaki et al., 2019[Sasaki, T., Kato, T., Fukushima, J., Hayashi, Y. & Takizawa, H. (2019). J. Alloys Compd. 806, 58-62.]) systems were found. In these structures and that of (IV), the Li sites of the LiIrSn4-type structure are occupied solely by Al, whereas the Sn sites are occupied by (Al,Si) or (Al,Ge).

4. Synthesis and crystallization

Polycrystalline samples with the nominal compositions Al58.0Ru25.3Si16.7 for (I) and Al37.5Ru17.8Si44.7 for (V) were prepared from powders of aluminium (Kojundo Chemical Lab., Japan, 99.9%), ruthenium (Tanaka Kikinzoku Kogyo K. K., Japan, 99.90% or purer) and silicon (Kojundo Chemical Lab., Japan, 99.99% or purer) using arc melting in an argon atmosphere (NEV-ACD-05, Nissin Giken Corporation, Japan). Each sample was then wrapped in tantalum foil, sealed in a silica tube filled with argon and annealed in a furnace at 1200 K for approximately 264 h, followed by water quenching. Powders for polycrystalline samples with the nominal compositions Al55.5Ru21.7Si22.8 for (II), Al55.0Ru19.2Si25.8 for (III) and Al48.0Ru16.2Si35.8 for (IV) were mechanically compacted without melting. Each sample was then placed in an aluminium nitride crucible, sealed in a silica tube filled with argon and reacted in a furnace at 1200 K for approximately 160 h or longer, followed by water quenching. Single crystals were selected from crushed fragments of the polycrystalline samples (lumps), which are mainly composed of the target compounds. The compositions of the target compounds in the samples were analysed as described elsewhere (Kitahara et al., 2023[Kitahara, K., Takakura, H., Iwasaki, Y. & Kimura, K. (2023). Mater. Trans. submitted.]) using an energy-dispersive spectrometer (X-Max, Oxford Instruments, UK) equipped in a scanning electron microscope (SU6600, Hitachi High-Technologies Corporation, Japan). Determined compositions for equilibria at 1200 K are Al58.2 (5)Ru25.1 (4)Si16.7 (3) for (I), Al55.2 (6)Ru21.6 (4)Si23.1 (7) for (II), Al54.1 (5)Ru19.6 (3)Si26.3 (4) for (III), Al47.3 (6)Ru16.3 (3)Si36.4 (6) for (IV) and Al38.0 (5)Ru17.8 (3)Si44.2 (6) for (V). These compositions are similar to the nominal compositions and consistent with the approximate single-phase regions [from Al62Ru25Si13 to Al56Ru26Si18 for (I), from Al57Ru22Si21 to Al54Ru22Si24 for (II), from Al55Ru20Si25 to Al54Ru20Si26 for (III), from Al49Ru17Si34 to Al47Ru17Si36 for (IV) and from Al41Ru18Si41 to Al37Ru18Si45 for (V)] (Kitahara et al., 2023[Kitahara, K., Takakura, H., Iwasaki, Y. & Kimura, K. (2023). Mater. Trans. submitted.]).

5. Refinement

Crystal data, data collection and structure refinement details are summarized in Table 1[link].

Table 1
Experimental details

  (I) (II) (III) (IV) (V)
Crystal data
Chemical formula ∼Ru16(Al0.78Si0.22)47 ∼Ru9(Al0.70Si0.30)32 ∼Ru10(Al0.67Si0.33)41 ∼Ru(Al0.57Si0.43)5 ∼Ru2(Al0.46Si0.54)9
Mr 2900.59 1783.65 2122.53 238.38 450.41
Crystal system, space group Orthorhombic, Cmcm Trigonal, R[\overline{3}] Orthorhombic, Pnma Tetragonal, I4/mcm Orthorhombic, Cmcm
Temperature (K) 301 296 298 297 301
a, b, c (Å) 7.6217 (2), 23.4434 (6), 20.6877 (6) 10.4479 (2), 10.4479 (2), 19.6774 (4) 15.0794 (2), 11.8713 (2), 16.9291 (3) 6.20079 (8), 6.20079 (8), 9.6937 (2) 8.63058 (14), 8.79888 (15), 17.4620 (3)
α, β, γ (°) 90, 90, 90 90, 90, 120 90, 90, 90 90, 90, 90 90, 90, 90
V3) 3696.46 (19) 1860.17 (7) 3030.50 (9) 372.72 (1) 1326.05 (4)
Z 4 3 4 4 8
Radiation type Mo Kα Mo Kα Mo Kα Mo Kα Mo Kα
μ (mm−1) 7.59 6.59 6.18 5.32 5.88
Crystal size (mm) 0.04 × 0.02 × 0.02 0.03 × 0.03 × 0.03 0.04 × 0.02 × 0.02 0.05 × 0.03 × 0.02 0.05 × 0.04 × 0.04
 
Data collection
Diffractometer XtaLAB Synergy R, HyPix XtaLAB Synergy R, HyPix XtaLAB Synergy R, HyPix XtaLAB Synergy R, HyPix XtaLAB Synergy R, HyPix
Absorption correction Gaussian (CrysAlis PRO; Matsumoto et al., 2021[Matsumoto, T., Yamano, A., Sato, T., Ferrara, J. D., White, F. J. & Meyer, M. (2021). J. Chem. Crystallogr. 51, 438-450.]) Gaussian (CrysAlis PRO; Matsumoto et al., 2021[Matsumoto, T., Yamano, A., Sato, T., Ferrara, J. D., White, F. J. & Meyer, M. (2021). J. Chem. Crystallogr. 51, 438-450.]) Gaussian (CrysAlis PRO; Matsumoto et al., 2021[Matsumoto, T., Yamano, A., Sato, T., Ferrara, J. D., White, F. J. & Meyer, M. (2021). J. Chem. Crystallogr. 51, 438-450.]) Gaussian (CrysAlis PRO; Matsumoto et al., 2021[Matsumoto, T., Yamano, A., Sato, T., Ferrara, J. D., White, F. J. & Meyer, M. (2021). J. Chem. Crystallogr. 51, 438-450.]) Gaussian (CrysAlis PRO; Matsumoto et al., 2021[Matsumoto, T., Yamano, A., Sato, T., Ferrara, J. D., White, F. J. & Meyer, M. (2021). J. Chem. Crystallogr. 51, 438-450.])
Tmin, Tmax 0.824, 0.924 0.868, 0.879 0.867, 0.929 0.833, 0.906 0.826, 0.868
No. of measured, independent and observed [I > 2σ(I)] reflections 11822, 2616, 2280 14255, 1193, 1127 33654, 5672, 4940 8063, 295, 279 17672, 1029, 1001
Rint 0.020 0.027 0.022 0.029 0.016
(sin θ/λ)max−1) 0.718 0.720 0.781 0.864 0.719
 
Refinement
R[F2 > 2σ(F2)], wR(F2), S 0.015, 0.032, 1.04 0.013, 0.024, 1.08 0.015, 0.026, 1.01 0.009, 0.021, 1.21 0.011, 0.027, 1.31
No. of reflections 2616 1193 5672 295 1029
No. of parameters 218 66 303 13 61
No. of restraints 5 2 2 2 2
Δρmax, Δρmin (e Å−3) 0.64, −0.69 0.45, −0.53 0.78, −0.74 0.44, −0.42 0.37, −0.42
Computer programs: CrysAlis PRO (Matsumoto et al., 2021[Matsumoto, T., Yamano, A., Sato, T., Ferrara, J. D., White, F. J. & Meyer, M. (2021). J. Chem. Crystallogr. 51, 438-450.]), SHELXT (Sheldrick, 2015a[Sheldrick, G. M. (2015a). Acta Cryst. A71, 3-8.]), SHELXL (Sheldrick, 2015b[Sheldrick, G. M. (2015b). Acta Cryst. C71, 3-8.]), VESTA (Momma & Izumi, 2011[Momma, K. & Izumi, F. (2011). J. Appl. Cryst. 44, 1272-1276.]) and publCIF (Westrip, 2010[Westrip, S. P. (2010). J. Appl. Cryst. 43, 920-925.]).

For (I) and (III), significant residual electron density peaks were found around some sites after routine structure refinement procedures. To account for these peaks, some split sites were introduced for (I) [Ru7B from Ru7A; Ru8 (Wyckoff position changed into 8g from 4c); Al12B from Al12A; Si17B from Al17A; Si26B from Al26A; Al28A (16h from 8f); Al28B and Al28C from Al28A] and (III) [Ru4B from Ru4A; Ru5B from Ru5A; Si9B from Si9A; Al10B from Si10A; Al29B from Al29A; Al30B from Al30A; Al31B and Al31C from Al31A; Al32B from Al32A]. Anisotropic displacement parameters were not introduced for minor split components [Ru7B, Al12B, Si17B, Si26B, Al28B and Al28C in (I); Ru4B, Ru5B, Al10B, Al29B, Al30B, Al31B, Al31C and Al32B in (III)] except for Si9B in (III).

Choices of Al, Si or (Al,Si) mixing were basically based on the site-occupancy factors (SOFs). After routine structure-refinement procedures and adding split sites, the SOF of each site was refined independently one by one. (Al,Si) mixing was introduced for some sites for (I) (Si/Al10, Al/Si14, Al/Si18, Al/Si21 and Al/Si22), (II) (Al/Si6 and Al/Si7), (III) (Al/Si11, Al/Si20, Al/Si21 and Al/Si22), (IV) (Si/Al3) and (V) (Si/Al5 and Si/Al7) because the SOF becomes significantly higher than 1 with Al occupation only and lower than 1 with Si occupation only for these sites. The positions and displacement parameters of mixing components were constrained using EXYZ and EADP instructions of SHELXL (Sheldrick, 2015b[Sheldrick, G. M. (2015b). Acta Cryst. C71, 3-8.]). For split sites, (Al,Si) mixing was not introduced, and Al or Si was chosen for each site so that the sum of the SOFs of the split components are close to 1. Choice of Si for Si/Ru6 in (I) is rather arbitrary, and it may be Al or even a vacancy.

After assigning chemical species to each site, the sum of the SOFs for each group of mixed or split sites was constrained to 1 unless it was significantly lower than 1. Sites with SOFs lower than 1 were found for (I) (Al27) and (III) (Al15), and the SOFs for these sites were freely refined. For sites along disordered chains in (III) [Al31A, Al31B, Al31C, Al32A and Al32B; see also Structural commentary and Fig. 6[link](a)], there is no a priori expected value for the sum of the SOFs, and therefore the SOFs of these sites were refined without any constraints. For these partially occupied sites, the assignment as Al is by no means justified, and some of them may be occupied by Si.

Since it is generally difficult to distinguish between Al and Si solely from X-ray diffraction data, restraints on the chemical compositions based on the chemical analysis data including their uncertainties (see Synthesis and crystallization) were introduced using SUMP instructions of SHELXL (Sheldrick, 2015b[Sheldrick, G. M. (2015b). Acta Cryst. C71, 3-8.]) for the final refinement cycles. The compositions deduced from the final refinement are Al57.8 (3)Ru25.6Si16.6 (3) for (I), Al54.8 (5)Ru22.0Si23.3 (5) for (II), Al53.6 (3)Ru19.7Si26.6 (3) for (III), Al47.2 (5)Ru16.7Si36.1 (5) for (IV) and Al37.2 (4)Ru18.2Si44.6 (4) for (V). These compositions are consistent with the chemical analysis data.

Supporting information


Computing details top

For all structures, data collection: CrysAlis PRO (Matsumoto et al., 2021); cell refinement: CrysAlis PRO (Matsumoto et al., 2021); data reduction: CrysAlis PRO (Matsumoto et al., 2021); program(s) used to solve structure: SHELXT (Sheldrick, 2015a); program(s) used to refine structure: SHELXL (Sheldrick, 2015b); molecular graphics: VESTA (Momma & Izumi, 2011); software used to prepare material for publication: publCIF (Westrip, 2010).

Hexatriacontaaluminium hexadecaruthenium decasilicon (I) top
Crystal data top
~Ru16(Al0.78Si0.22)47Dx = 5.212 Mg m3
Mr = 2900.59Mo Kα radiation, λ = 0.71073 Å
Orthorhombic, CmcmCell parameters from 5906 reflections
a = 7.6217 (2) Åθ = 2.6–30.8°
b = 23.4434 (6) ŵ = 7.59 mm1
c = 20.6877 (6) ÅT = 301 K
V = 3696.46 (19) Å3Prism, metallic light colourless
Z = 40.04 × 0.02 × 0.02 mm
F(000) = 5237.80
Data collection top
XtaLAB Synergy R, HyPix
diffractometer
2616 independent reflections
Radiation source: micro-focus sealed X-ray tube, Mova (Mo) X-ray Source2280 reflections with I > 2σ(I)
Mirror monochromatorRint = 0.020
Detector resolution: 10.0000 pixels mm-1θmax = 30.7°, θmin = 1.7°
ω scansh = 97
Absorption correction: gaussian
(CrysAlisPro; Matsumoto et al., 2021)
k = 3233
Tmin = 0.824, Tmax = 0.924l = 2227
11822 measured reflections
Refinement top
Refinement on F2Primary atom site location: dual
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.015 w = 1/[σ2(Fo2) + (0.015P)2 + 1.7856P]
where P = (Fo2 + 2Fc2)/3
wR(F2) = 0.032(Δ/σ)max = 0.002
S = 1.04Δρmax = 0.64 e Å3
2616 reflectionsΔρmin = 0.69 e Å3
218 parametersExtinction correction: SHELXL-2019/3 (Sheldrick, 2015b), Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4
5 restraintsExtinction coefficient: 0.000036 (4)
Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Ru10.0000000.35437 (2)0.2500000.00702 (8)
Ru20.0000000.19071 (2)0.14245 (2)0.00523 (6)
Ru30.0000000.08703 (2)0.67676 (2)0.00497 (6)
Ru40.0000000.46501 (2)0.06755 (2)0.00580 (6)
Ru50.0000000.08260 (2)0.06182 (2)0.00605 (6)
Si60.0000000.63703 (3)0.09750 (4)0.0067 (3)0.9481 (19)
Ru60.0000000.63703 (3)0.09750 (4)0.0067 (3)0.0519 (19)
Ru7A0.2872 (5)0.05250 (15)0.2500000.0071 (3)0.87 (3)
Ru7B0.308 (2)0.0461 (8)0.2500000.0123 (19)*0.13 (3)
Ru80.4748 (2)0.24633 (2)0.2500000.0057 (4)0.5
Ru90.20167 (2)0.28208 (2)0.06561 (2)0.00560 (5)
Si100.0000000.00419 (5)0.2500000.0088 (6)0.73 (12)
Al100.0000000.00419 (5)0.2500000.0088 (6)0.27 (12)
Al110.0000000.63795 (6)0.2500000.0132 (3)
Al12A0.0000000.12915 (10)0.2500000.0126 (9)0.856 (12)
Al12B0.079 (3)0.1477 (10)0.2500000.020 (5)*0.072 (6)
Si130.0000000.29501 (3)0.15414 (4)0.00569 (17)
Al140.0000000.36199 (4)0.03013 (4)0.0068 (4)0.59 (8)
Si140.0000000.36199 (4)0.03013 (4)0.0068 (4)0.41 (8)
Al150.0000000.25809 (4)0.53285 (5)0.00662 (19)
Al160.0000000.52766 (5)0.16337 (5)0.0189 (2)
Al17A0.0000000.19089 (7)0.63750 (11)0.0091 (5)0.908 (9)
Si17B0.0000000.1757 (7)0.6124 (11)0.012 (4)*0.092 (9)
Al180.32754 (14)0.33805 (4)0.2500000.0126 (5)0.52 (9)
Si180.32754 (14)0.33805 (4)0.2500000.0126 (5)0.48 (9)
Al190.20942 (15)0.44221 (4)0.2500000.0133 (2)
Al200.1113 (3)0.23957 (8)0.2500000.0096 (4)0.5
Al210.20919 (10)0.10789 (3)0.15319 (3)0.0089 (3)0.63 (5)
Si210.20919 (10)0.10789 (3)0.15319 (3)0.0089 (3)0.37 (5)
Al220.18810 (10)0.17255 (3)0.03759 (4)0.0119 (3)0.81 (6)
Si220.18810 (10)0.17255 (3)0.03759 (4)0.0119 (3)0.19 (6)
Al230.31517 (10)0.05413 (3)0.03152 (3)0.00897 (14)
Al240.31724 (10)0.49470 (3)0.13170 (4)0.01044 (15)
Al250.18885 (12)0.38526 (3)0.13490 (4)0.0223 (2)
Al26A0.3202 (4)0.21649 (10)0.1531 (2)0.0070 (7)0.593 (13)
Si26B0.2898 (5)0.22406 (13)0.1730 (3)0.0125 (7)*0.407 (13)
Al270.0000000.0000000.0000000.0161 (6)0.853 (7)
Al28A0.0495 (3)0.10981 (8)0.55507 (9)0.0328 (10)0.445 (3)
Al28B0.0000000.0716 (12)0.5512 (8)0.008 (6)*0.064 (7)
Al28C0.0000000.0454 (15)0.5436 (12)0.011 (9)*0.046 (7)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ru10.0119 (2)0.00458 (16)0.00454 (16)0.0000.0000.000
Ru20.00655 (14)0.00520 (11)0.00395 (12)0.0000.0000.00041 (8)
Ru30.00556 (14)0.00514 (11)0.00421 (12)0.0000.0000.00000 (9)
Ru40.00580 (13)0.00635 (11)0.00525 (12)0.0000.0000.00106 (9)
Ru50.00665 (14)0.00574 (11)0.00577 (12)0.0000.0000.00051 (9)
Si60.0058 (5)0.0074 (4)0.0068 (4)0.0000.0000.0002 (3)
Ru60.0058 (5)0.0074 (4)0.0068 (4)0.0000.0000.0002 (3)
Ru7A0.0063 (5)0.0058 (5)0.0090 (3)0.0001 (3)0.0000.000
Ru80.0052 (11)0.00544 (18)0.00647 (19)0.0004 (2)0.0000.000
Ru90.00554 (10)0.00702 (8)0.00425 (9)0.00082 (6)0.00052 (7)0.00001 (6)
Si100.0060 (9)0.0114 (8)0.0092 (8)0.0000.0000.000
Al100.0060 (9)0.0114 (8)0.0092 (8)0.0000.0000.000
Al110.0105 (8)0.0060 (6)0.0230 (8)0.0000.0000.000
Al12A0.0192 (17)0.0135 (11)0.0053 (9)0.0000.0000.000
Si130.0069 (5)0.0054 (4)0.0047 (4)0.0000.0000.0008 (3)
Al140.0073 (6)0.0053 (6)0.0080 (6)0.0000.0000.0001 (3)
Si140.0073 (6)0.0053 (6)0.0080 (6)0.0000.0000.0001 (3)
Al150.0045 (5)0.0090 (4)0.0064 (4)0.0000.0000.0019 (3)
Al160.0037 (6)0.0390 (7)0.0140 (5)0.0000.0000.0183 (5)
Al17A0.0124 (7)0.0060 (7)0.0090 (10)0.0000.0000.0011 (6)
Al180.0091 (7)0.0167 (6)0.0120 (6)0.0067 (4)0.0000.000
Si180.0091 (7)0.0167 (6)0.0120 (6)0.0067 (4)0.0000.000
Al190.0138 (6)0.0084 (5)0.0178 (5)0.0024 (4)0.0000.000
Al200.0142 (12)0.0092 (9)0.0055 (9)0.0019 (7)0.0000.000
Al210.0103 (5)0.0068 (4)0.0095 (4)0.0021 (2)0.0039 (3)0.0005 (2)
Si210.0103 (5)0.0068 (4)0.0095 (4)0.0021 (2)0.0039 (3)0.0005 (2)
Al220.0112 (5)0.0097 (4)0.0148 (5)0.0015 (3)0.0059 (3)0.0041 (3)
Si220.0112 (5)0.0097 (4)0.0148 (5)0.0015 (3)0.0059 (3)0.0041 (3)
Al230.0091 (4)0.0088 (3)0.0090 (3)0.0011 (2)0.0030 (3)0.0015 (2)
Al240.0091 (4)0.0099 (3)0.0123 (3)0.0018 (3)0.0013 (3)0.0042 (3)
Al250.0262 (5)0.0121 (4)0.0285 (5)0.0080 (3)0.0213 (4)0.0051 (3)
Al26A0.0040 (9)0.0086 (7)0.0084 (13)0.0013 (5)0.0024 (8)0.0017 (7)
Al270.0105 (11)0.0136 (10)0.0243 (11)0.0000.0000.0147 (7)
Al28A0.069 (3)0.0227 (11)0.0063 (8)0.0029 (9)0.0017 (9)0.0007 (6)
Geometric parameters (Å, º) top
Ru1—Si132.4228 (9)Ru9—Si26B2.690 (3)
Ru1—Si13i2.4228 (9)Ru9—Al17Axx2.7899 (10)
Ru1—Si182.5255 (10)Si10—Al19xxi2.6487 (13)
Ru1—Al18ii2.5255 (10)Si10—Al19xvi2.6487 (13)
Ru1—Al192.6055 (11)Si10—Al24xxi2.8248 (7)
Ru1—Al19ii2.6056 (10)Si10—Al24xvi2.8248 (7)
Ru1—Al20ii2.8218 (19)Si10—Al24xvii2.8248 (7)
Ru1—Al202.8218 (19)Si10—Al24xxii2.8248 (7)
Ru1—Al252.8750 (10)Al12A—Al12Bii0.74 (3)
Ru1—Al25i2.8750 (10)Al12A—Al12B0.74 (3)
Ru1—Al25iii2.8750 (10)Al12A—Al21iii2.6080 (9)
Ru2—Si26B2.427 (3)Al12A—Al21i2.6080 (9)
Ru2—Si26Biii2.427 (3)Al12A—Al21ii2.6080 (9)
Ru2—Si132.4571 (8)Al12A—Al212.6080 (9)
Ru2—Al12B2.515 (9)Al12A—Al202.724 (3)
Ru2—Al12Bii2.515 (9)Al12A—Al20ii2.724 (3)
Ru2—Al21iii2.5221 (7)Al12B—Al12Bii1.20 (5)
Ru2—Al212.5222 (7)Al12B—Al202.17 (2)
Ru2—Al26Aiii2.524 (2)Al12B—Al21i2.423 (11)
Ru2—Al26A2.524 (2)Al12B—Al212.423 (11)
Ru2—Al222.6349 (7)Al12B—Al20ii2.595 (19)
Ru3—Si17B2.469 (11)Al12B—Si26Bi2.89 (2)
Ru3—Al24iv2.5456 (7)Al12B—Si26B2.89 (2)
Ru3—Al24v2.5456 (7)Si13—Al20ii2.5183 (14)
Ru3—Al17A2.5668 (13)Si13—Al202.5183 (14)
Ru3—Al28Aiii2.6011 (18)Si13—Al252.5897 (10)
Ru3—Al28A2.6011 (18)Si13—Al25iii2.5898 (10)
Ru3—Al25iv2.6069 (8)Si13—Si26B2.793 (4)
Ru3—Al25v2.6069 (8)Si13—Si26Biii2.793 (4)
Ru3—Si10vi2.6207 (11)Al14—Al252.6585 (11)
Ru3—Al28B2.623 (18)Al14—Al25iii2.6585 (11)
Ru3—Al18vii2.6662 (9)Al14—Al23ix2.7345 (10)
Ru3—Al18iv2.6662 (9)Al14—Al23viii2.7345 (10)
Ru4—Al162.4671 (11)Al14—Al15i2.7624 (13)
Ru4—Al23viii2.5271 (7)Al14—Al22viii2.8756 (9)
Ru4—Al23ix2.5271 (7)Al14—Al22ix2.8756 (9)
Ru4—Al142.5361 (9)Al15—Si17B2.538 (12)
Ru4—Al23x2.6278 (7)Al15—Al17A2.6774 (16)
Ru4—Al23xi2.6278 (7)Al15—Al22ii2.8634 (11)
Ru4—Al25iii2.7401 (8)Al15—Al22i2.8634 (11)
Ru4—Al252.7402 (8)Al15—Al22v2.8818 (9)
Ru4—Al242.8446 (8)Al15—Al22iv2.8818 (9)
Ru4—Al24iii2.8446 (8)Al16—Al242.6216 (8)
Ru5—Al272.3207 (2)Al16—Al24iii2.6216 (8)
Ru5—Al28Ci2.35 (2)Al16—Al21x2.9146 (11)
Ru5—Al28Bi2.352 (16)Al16—Al21xi2.9146 (11)
Ru5—Al28Aii2.5293 (18)Al17A—Si17B0.63 (2)
Ru5—Al28Ai2.5293 (18)Al17A—Al28Aiii2.581 (3)
Ru5—Al212.5429 (7)Al17A—Al28A2.581 (3)
Ru5—Al21iii2.5429 (7)Al17A—Al26Av2.588 (2)
Ru5—Al23iii2.5708 (7)Al17A—Al26Aiv2.588 (2)
Ru5—Al232.5708 (7)Al17A—Si26Bv2.661 (3)
Ru5—Al222.5988 (7)Al17A—Si26Biv2.661 (3)
Si6—Al26Ax2.583 (5)Al17A—Al18vii2.7577 (18)
Si6—Al26Axi2.583 (5)Al17A—Al18iv2.7577 (18)
Si6—Al21x2.5898 (8)Si17B—Al28Aiii1.98 (2)
Si6—Al21xi2.5898 (8)Si17B—Al28A1.98 (2)
Si6—Al14xii2.6404 (12)Si17B—Al28B2.75 (4)
Si6—Al23xi2.7613 (9)Si17B—Al25iv2.808 (7)
Si6—Al23x2.7613 (9)Si17B—Al25v2.808 (7)
Si6—Al15xiii2.7990 (12)Si18—Al192.6026 (14)
Si6—Al22xi2.8073 (9)Si18—Al252.8305 (10)
Si6—Al22x2.8073 (9)Si18—Al25i2.8305 (9)
Si6—Al162.9037 (15)Si18—Al202.837 (2)
Ru7A—Al212.460 (3)Al19—Al25i2.7344 (10)
Ru7A—Al21i2.460 (3)Al19—Al252.7344 (10)
Ru7A—Si102.465 (2)Al19—Al242.8599 (9)
Ru7A—Al16xiv2.486 (3)Al19—Al24i2.8599 (9)
Ru7A—Al16xv2.486 (3)Al20—Al20ii1.696 (4)
Ru7A—Al11xv2.5774 (16)Al20—Si26Bi2.127 (7)
Ru7A—Al19xvi2.586 (4)Al20—Si26B2.127 (7)
Ru7A—Al12B2.74 (2)Al20—Al26A2.616 (6)
Ru7A—Al12A2.832 (5)Al20—Al26Ai2.616 (6)
Ru7A—Al24xvii2.9086 (11)Al21—Al26A2.6828 (18)
Ru7B—Al16xiv2.355 (14)Al21—Al24xvii2.6980 (10)
Ru7B—Al16xv2.355 (14)Al21—Si26B2.822 (3)
Ru7B—Al19xvi2.440 (18)Al21—Al222.8362 (10)
Ru7B—Si102.543 (13)Al22—Al28Ai2.637 (2)
Ru7B—Al212.583 (15)Al22—Al26A2.791 (4)
Ru7B—Al21i2.583 (15)Al22—Al22iii2.8673 (15)
Ru7B—Al11xv2.604 (11)Al23—Al24xvii2.6935 (10)
Ru7B—Al24xvii2.890 (6)Al23—Al272.7939 (7)
Ru7B—Al24xvi2.890 (6)Al23—Al23xix2.8174 (15)
Ru7B—Ru7Bxviii2.93 (4)Al23—Al23xxiii2.8534 (13)
Ru8—Ru8xviii0.384 (4)Al23—Al28Ci2.868 (13)
Ru8—Si26Bi2.191 (4)Al24—Al28Cxx2.48 (2)
Ru8—Si26B2.191 (4)Al24—Al28Bxx2.670 (16)
Ru8—Si182.4257 (13)Al24—Al252.7467 (10)
Ru8—Al26A2.428 (3)Al24—Al24xix2.7858 (15)
Ru8—Al26Ai2.428 (3)Al25—Al28Axx2.592 (2)
Ru8—Si26Bxviii2.455 (3)Al26A—Si26B0.503 (2)
Ru8—Si26Bxix2.455 (3)Al26A—Al26Axix2.741 (6)
Ru8—Al11xv2.5478 (14)Al27—Al28Ci1.40 (3)
Ru8—Al18xviii2.6254 (15)Al27—Al28Cxxiv1.40 (3)
Ru8—Al26Axviii2.636 (3)Al27—Al28Bi1.98 (3)
Ru9—Si132.4102 (7)Al27—Al28Bxxiv1.98 (3)
Ru9—Al22ix2.5287 (7)Al27—Al28Ai2.8403 (19)
Ru9—Al142.5320 (7)Al27—Al28Axxiv2.8403 (19)
Ru9—Al26A2.5415 (17)Al28A—Al28Aiii0.754 (5)
Ru9—Al15xx2.5526 (5)Al28A—Al28B0.98 (2)
Ru9—Al15i2.6130 (8)Al28A—Al28C1.57 (4)
Ru9—Al222.6343 (7)Al28B—Al28C0.63 (2)
Ru9—Si17Bxx2.662 (6)Al28C—Al28Cvi2.79 (7)
Si13—Ru1—Si13i109.88 (4)Ru3—Al17A—Al28Aiii60.70 (6)
Si13—Ru1—Si1885.009 (14)Si17B—Al17A—Al28A16.0 (9)
Si13i—Ru1—Si1885.008 (14)Ru3—Al17A—Al28A60.69 (6)
Si13—Ru1—Al18ii85.008 (14)Al28Aiii—Al17A—Al28A16.81 (11)
Si13i—Ru1—Al18ii85.008 (14)Si17B—Al17A—Al26Av125.3 (8)
Si18—Ru1—Al18ii162.57 (5)Ru3—Al17A—Al26Av139.14 (13)
Si13—Ru1—Al19117.000 (18)Al28Aiii—Al17A—Al26Av141.06 (11)
Si13i—Ru1—Al19117.001 (18)Al28A—Al17A—Al26Av128.54 (8)
Si18—Ru1—Al1960.93 (3)Si17B—Al17A—Al26Aiv125.3 (8)
Al18ii—Ru1—Al19136.49 (4)Ru3—Al17A—Al26Aiv139.14 (13)
Si13—Ru1—Al19ii117.000 (18)Al28Aiii—Al17A—Al26Aiv128.53 (8)
Si13i—Ru1—Al19ii117.001 (18)Al28A—Al17A—Al26Aiv141.06 (11)
Si18—Ru1—Al19ii136.49 (4)Al26Av—Al17A—Al26Aiv63.95 (14)
Al18ii—Ru1—Al19ii60.93 (3)Si17B—Al17A—Si26Bv130.6 (7)
Al19—Ru1—Al19ii75.56 (5)Ru3—Al17A—Si26Bv128.58 (15)
Si13—Ru1—Al20ii56.78 (2)Al28Aiii—Al17A—Si26Bv145.29 (10)
Si13i—Ru1—Al20ii56.78 (2)Al28A—Al17A—Si26Bv130.25 (9)
Si18—Ru1—Al20ii98.78 (5)Al26Av—Al17A—Si26Bv10.89 (5)
Al18ii—Ru1—Al20ii63.79 (5)Al26Aiv—Al17A—Si26Bv69.85 (14)
Al19—Ru1—Al20ii159.71 (5)Si17B—Al17A—Si26Biv130.6 (7)
Al19ii—Ru1—Al20ii124.73 (5)Ru3—Al17A—Si26Biv128.58 (15)
Si13—Ru1—Al2056.78 (2)Al28Aiii—Al17A—Si26Biv130.25 (9)
Si13i—Ru1—Al2056.78 (2)Al28A—Al17A—Si26Biv145.29 (10)
Si18—Ru1—Al2063.80 (5)Al26Av—Al17A—Si26Biv69.85 (14)
Al18ii—Ru1—Al2098.78 (5)Al26Aiv—Al17A—Si26Biv10.89 (5)
Al19—Ru1—Al20124.73 (5)Si26Bv—Al17A—Si26Biv74.02 (16)
Al19ii—Ru1—Al20159.71 (5)Si17B—Al17A—Al1570.5 (11)
Al20ii—Ru1—Al2034.98 (9)Ru3—Al17A—Al15144.49 (11)
Si13—Ru1—Al2557.77 (2)Al28Aiii—Al17A—Al1584.21 (8)
Si13i—Ru1—Al25145.35 (2)Al28A—Al17A—Al1584.21 (8)
Si18—Ru1—Al2562.825 (19)Al26Av—Al17A—Al1566.88 (12)
Al18ii—Ru1—Al25122.209 (17)Al26Aiv—Al17A—Al1566.88 (12)
Al19—Ru1—Al2559.618 (17)Si26Bv—Al17A—Al1577.42 (14)
Al19ii—Ru1—Al2596.18 (2)Si26Biv—Al17A—Al1577.42 (14)
Al20ii—Ru1—Al25113.00 (3)Si17B—Al17A—Al18vii123.8 (9)
Al20—Ru1—Al2595.15 (3)Ru3—Al17A—Al18vii59.97 (3)
Si13—Ru1—Al25i145.35 (2)Al28Aiii—Al17A—Al18vii116.49 (7)
Si13i—Ru1—Al25i57.78 (2)Al28A—Al17A—Al18vii107.86 (6)
Si18—Ru1—Al25i62.825 (19)Al26Av—Al17A—Al18vii81.29 (14)
Al18ii—Ru1—Al25i122.210 (17)Al26Aiv—Al17A—Al18vii110.69 (12)
Al19—Ru1—Al25i59.616 (17)Si26Bv—Al17A—Al18vii70.40 (15)
Al19ii—Ru1—Al25i96.18 (2)Si26Biv—Al17A—Al18vii103.80 (13)
Al20ii—Ru1—Al25i113.00 (3)Al15—Al17A—Al18vii145.81 (5)
Al20—Ru1—Al25i95.15 (3)Si17B—Al17A—Al18iv123.8 (9)
Al25—Ru1—Al25i111.83 (3)Ru3—Al17A—Al18iv59.97 (3)
Si13—Ru1—Al25iii57.77 (2)Al28Aiii—Al17A—Al18iv107.86 (6)
Si13i—Ru1—Al25iii145.35 (2)Al28A—Al17A—Al18iv116.49 (7)
Si18—Ru1—Al25iii122.210 (17)Al26Av—Al17A—Al18iv110.69 (12)
Al18ii—Ru1—Al25iii62.825 (19)Al26Aiv—Al17A—Al18iv81.29 (14)
Al19—Ru1—Al25iii96.18 (2)Si26Bv—Al17A—Al18iv103.80 (13)
Al19ii—Ru1—Al25iii59.616 (17)Si26Biv—Al17A—Al18iv70.40 (15)
Al20ii—Ru1—Al25iii95.15 (3)Al15—Al17A—Al18iv145.81 (5)
Al20—Ru1—Al25iii113.00 (3)Al18vii—Al17A—Al18iv56.93 (5)
Al25—Ru1—Al25iii60.08 (3)Si17B—Al17A—Ru8vii175.5 (5)
Al25i—Ru1—Al25iii150.82 (3)Ru3—Al17A—Ru8vii103.83 (6)
Si26B—Ru2—Si26Biii131.1 (3)Al28Aiii—Al17A—Ru8vii163.69 (7)
Si26B—Ru2—Si1369.75 (9)Al28A—Al17A—Ru8vii159.96 (7)
Si26Biii—Ru2—Si1369.75 (9)Al26Av—Al17A—Ru8vii53.88 (9)
Si26B—Ru2—Al12B71.4 (7)Al26Aiv—Al17A—Ru8vii58.94 (9)
Si26Biii—Ru2—Al12B96.7 (5)Si26Bv—Al17A—Ru8vii47.63 (10)
Si13—Ru2—Al12B108.2 (5)Si26Biv—Al17A—Ru8vii53.82 (9)
Si26B—Ru2—Al12Bii96.7 (5)Al15—Al17A—Ru8vii111.59 (6)
Si26Biii—Ru2—Al12Bii71.4 (7)Al18vii—Al17A—Ru8vii52.15 (5)
Si13—Ru2—Al12Bii108.2 (5)Al18iv—Al17A—Ru8vii56.82 (6)
Al12B—Ru2—Al12Bii27.6 (12)Al17A—Si17B—Al28Aiii159.0 (12)
Si26B—Ru2—Al21iii143.17 (6)Al17A—Si17B—Al28A159.0 (12)
Si26Biii—Ru2—Al21iii69.49 (9)Al28Aiii—Si17B—Al28A21.9 (3)
Si13—Ru2—Al21iii139.236 (17)Al17A—Si17B—Ru391.8 (12)
Al12B—Ru2—Al21iii76.4 (6)Al28Aiii—Si17B—Ru370.5 (5)
Al12Bii—Ru2—Al21iii57.5 (4)Al28A—Si17B—Ru370.5 (5)
Si26B—Ru2—Al2169.49 (9)Al17A—Si17B—Al1596.0 (12)
Si26Biii—Ru2—Al21143.17 (6)Al28Aiii—Si17B—Al15101.8 (8)
Si13—Ru2—Al21139.237 (17)Al28A—Si17B—Al15101.8 (8)
Al12B—Ru2—Al2157.5 (4)Ru3—Si17B—Al15172.2 (12)
Al12Bii—Ru2—Al2176.4 (6)Al17A—Si17B—Ru9iv95.2 (8)
Al21iii—Ru2—Al2178.42 (3)Al28Aiii—Si17B—Ru9iv84.8 (5)
Si26B—Ru2—Al26Aiii141.3 (2)Al28A—Si17B—Ru9iv103.5 (8)
Si26Biii—Ru2—Al26Aiii11.46 (6)Ru3—Si17B—Ru9iv120.6 (2)
Si13—Ru2—Al26Aiii75.71 (7)Al15—Si17B—Ru9iv58.7 (2)
Al12B—Ru2—Al26Aiii104.4 (5)Al17A—Si17B—Ru9v95.2 (8)
Al12Bii—Ru2—Al26Aiii77.8 (6)Al28Aiii—Si17B—Ru9v103.5 (8)
Al21iii—Ru2—Al26Aiii64.24 (6)Al28A—Si17B—Ru9v84.8 (5)
Al21—Ru2—Al26Aiii141.99 (5)Ru3—Si17B—Ru9v120.6 (2)
Si26B—Ru2—Al26A11.46 (6)Al15—Si17B—Ru9v58.7 (2)
Si26Biii—Ru2—Al26A141.3 (2)Ru9iv—Si17B—Ru9v117.3 (4)
Si13—Ru2—Al26A75.70 (7)Al17A—Si17B—Al28B151.9 (13)
Al12B—Ru2—Al26A77.8 (6)Al28Aiii—Si17B—Al28B14.9 (3)
Al12Bii—Ru2—Al26A104.4 (5)Al28A—Si17B—Al28B14.9 (3)
Al21iii—Ru2—Al26A141.99 (4)Ru3—Si17B—Al28B60.1 (5)
Al21—Ru2—Al26A64.24 (6)Al15—Si17B—Al28B112.1 (9)
Al26Aiii—Ru2—Al26A150.45 (19)Ru9iv—Si17B—Al28B99.3 (7)
Si26B—Ru2—Al2276.76 (16)Ru9v—Si17B—Al28B99.3 (7)
Si26Biii—Ru2—Al22139.60 (14)Al17A—Si17B—Al25iv98.7 (8)
Si13—Ru2—Al22103.99 (2)Al28Aiii—Si17B—Al25iv62.7 (3)
Al12B—Ru2—Al22122.3 (4)Al28A—Si17B—Al25iv82.1 (6)
Al12Bii—Ru2—Al22142.5 (6)Ru3—Si17B—Al25iv58.8 (2)
Al21iii—Ru2—Al22106.99 (2)Al15—Si17B—Al25iv119.7 (3)
Al21—Ru2—Al2266.69 (2)Ru9iv—Si17B—Al25iv61.84 (8)
Al26Aiii—Ru2—Al22129.56 (11)Ru9v—Si17B—Al25iv166.1 (11)
Al26A—Ru2—Al2265.46 (12)Al28B—Si17B—Al25iv67.9 (4)
Si17B—Ru3—Al24iv115.9 (5)Al17A—Si17B—Al25v98.7 (8)
Si17B—Ru3—Al24v115.9 (5)Al28Aiii—Si17B—Al25v82.1 (6)
Al24iv—Ru3—Al24v66.35 (3)Al28A—Si17B—Al25v62.7 (3)
Si17B—Ru3—Al17A14.2 (6)Ru3—Si17B—Al25v58.8 (2)
Al24iv—Ru3—Al17A126.73 (5)Al15—Si17B—Al25v119.7 (3)
Al24v—Ru3—Al17A126.73 (5)Ru9iv—Si17B—Al25v166.1 (11)
Si17B—Ru3—Al28Aiii46.0 (6)Ru9v—Si17B—Al25v61.84 (8)
Al24iv—Ru3—Al28Aiii73.78 (5)Al28B—Si17B—Al25v67.9 (4)
Al24v—Ru3—Al28Aiii83.07 (5)Al25iv—Si17B—Al25v115.3 (5)
Al17A—Ru3—Al28Aiii59.93 (7)Ru8—Si18—Ru1126.28 (6)
Si17B—Ru3—Al28A46.0 (6)Ru8—Si18—Al19172.67 (7)
Al24iv—Ru3—Al28A83.07 (5)Ru1—Si18—Al1961.05 (3)
Al24v—Ru3—Al28A73.78 (5)Ru8—Si18—Ru8xviii7.45 (7)
Al17A—Ru3—Al28A59.93 (7)Ru1—Si18—Ru8xviii133.73 (6)
Al28Aiii—Ru3—Al28A16.68 (11)Al19—Si18—Ru8xviii165.22 (6)
Si17B—Ru3—Al25iv67.11 (10)Ru8—Si18—Al18xviii62.43 (5)
Al24iv—Ru3—Al25iv64.41 (2)Ru1—Si18—Al18xviii171.29 (2)
Al24v—Ru3—Al25iv124.31 (3)Al19—Si18—Al18xviii110.24 (3)
Al17A—Ru3—Al25iv70.03 (2)Ru8xviii—Si18—Al18xviii54.99 (4)
Al28Aiii—Ru3—Al25iv59.69 (6)Ru8—Si18—Ru3vii110.84 (5)
Al28A—Ru3—Al25iv76.07 (6)Ru1—Si18—Ru3vii112.80 (3)
Si17B—Ru3—Al25v67.11 (10)Al19—Si18—Ru3vii63.41 (3)
Al24iv—Ru3—Al25v124.31 (3)Ru8xviii—Si18—Ru3vii104.87 (4)
Al24v—Ru3—Al25v64.41 (2)Al18xviii—Si18—Ru3vii60.46 (2)
Al17A—Ru3—Al25v70.03 (2)Ru8—Si18—Ru3xx110.84 (5)
Al28Aiii—Ru3—Al25v76.07 (6)Ru1—Si18—Ru3xx112.80 (3)
Al28A—Ru3—Al25v59.69 (6)Al19—Si18—Ru3xx63.41 (3)
Al25iv—Ru3—Al25v130.93 (4)Ru8xviii—Si18—Ru3xx104.87 (4)
Si17B—Ru3—Si10vi177.3 (6)Al18xviii—Si18—Ru3xx60.46 (2)
Al24iv—Ru3—Si10vi66.27 (2)Ru3vii—Si18—Ru3xx69.26 (3)
Al24v—Ru3—Si10vi66.27 (2)Ru8—Si18—Al17Avii63.98 (5)
Al17A—Ru3—Si10vi163.13 (6)Ru1—Si18—Al17Avii120.56 (3)
Al28Aiii—Ru3—Si10vi136.65 (5)Al19—Si18—Al17Avii113.31 (5)
Al28A—Ru3—Si10vi136.64 (5)Ru8xviii—Si18—Al17Avii61.64 (5)
Al25iv—Ru3—Si10vi113.29 (2)Al18xviii—Si18—Al17Avii61.53 (3)
Al25v—Ru3—Si10vi113.29 (2)Ru3vii—Si18—Al17Avii56.46 (4)
Si17B—Ru3—Al28B65.3 (8)Ru3xx—Si18—Al17Avii114.00 (4)
Al24iv—Ru3—Al28B62.2 (5)Ru8—Si18—Al17Axx63.98 (5)
Al24v—Ru3—Al28B62.2 (5)Ru1—Si18—Al17Axx120.56 (3)
Al17A—Ru3—Al28B79.5 (6)Al19—Si18—Al17Axx113.31 (5)
Al28Aiii—Ru3—Al28B21.5 (5)Ru8xviii—Si18—Al17Axx61.64 (5)
Al28A—Ru3—Al28B21.5 (5)Al18xviii—Si18—Al17Axx61.53 (3)
Al25iv—Ru3—Al28B72.86 (18)Ru3vii—Si18—Al17Axx114.00 (4)
Al25v—Ru3—Al28B72.86 (18)Ru3xx—Si18—Al17Axx56.46 (4)
Si10vi—Ru3—Al28B117.4 (6)Al17Avii—Si18—Al17Axx115.12 (8)
Si17B—Ru3—Al18vii75.6 (5)Ru8—Si18—Al25121.29 (3)
Al24iv—Ru3—Al18vii166.84 (2)Ru1—Si18—Al2564.64 (3)
Al24v—Ru3—Al18vii115.73 (3)Al19—Si18—Al2560.26 (3)
Al17A—Ru3—Al18vii63.57 (5)Ru8xviii—Si18—Al25122.31 (3)
Al28Aiii—Ru3—Al18vii119.09 (5)Al18xviii—Si18—Al25111.93 (3)
Al28A—Ru3—Al18vii110.08 (5)Ru3vii—Si18—Al25113.87 (4)
Al25iv—Ru3—Al18vii118.23 (3)Ru3xx—Si18—Al2556.53 (2)
Al25v—Ru3—Al18vii64.92 (3)Al17Avii—Si18—Al25169.79 (5)
Si10vi—Ru3—Al18vii102.06 (2)Al17Axx—Si18—Al2564.16 (5)
Al28B—Ru3—Al18vii130.8 (4)Ru8—Si18—Al25i121.29 (3)
Si17B—Ru3—Al18iv75.6 (5)Ru1—Si18—Al25i64.64 (3)
Al24iv—Ru3—Al18iv115.73 (3)Al19—Si18—Al25i60.26 (3)
Al24v—Ru3—Al18iv166.84 (2)Ru8xviii—Si18—Al25i122.31 (3)
Al17A—Ru3—Al18iv63.57 (5)Al18xviii—Si18—Al25i111.93 (3)
Al28Aiii—Ru3—Al18iv110.07 (5)Ru3vii—Si18—Al25i56.53 (2)
Al28A—Ru3—Al18iv119.09 (5)Ru3xx—Si18—Al25i113.86 (4)
Al25iv—Ru3—Al18iv64.92 (3)Al17Avii—Si18—Al25i64.17 (5)
Al25v—Ru3—Al18iv118.23 (3)Al17Axx—Si18—Al25i169.79 (5)
Si10vi—Ru3—Al18iv102.06 (2)Al25—Si18—Al25i114.54 (5)
Al28B—Ru3—Al18iv130.8 (4)Ru8—Si18—Al2063.09 (6)
Al18vii—Ru3—Al18iv59.08 (4)Ru1—Si18—Al2063.19 (5)
Al16—Ru4—Al23viii139.23 (2)Al19—Si18—Al20124.24 (6)
Al16—Ru4—Al23ix139.23 (2)Ru8xviii—Si18—Al2070.54 (6)
Al23viii—Ru4—Al23ix67.76 (3)Al18xviii—Si18—Al20125.52 (5)
Al16—Ru4—Al14144.31 (4)Ru3vii—Si18—Al20145.349 (14)
Al23viii—Ru4—Al1465.38 (2)Ru3xx—Si18—Al20145.349 (14)
Al23ix—Ru4—Al1465.38 (2)Al17Avii—Si18—Al2094.40 (4)
Al16—Ru4—Al23x75.80 (3)Al17Axx—Si18—Al2094.40 (4)
Al23viii—Ru4—Al23x102.12 (2)Al25—Si18—Al2095.81 (4)
Al23ix—Ru4—Al23x67.19 (3)Al25i—Si18—Al2095.81 (4)
Al14—Ru4—Al23x132.11 (2)Ru7Bxxv—Al19—Ru7Axxv3.6 (4)
Al16—Ru4—Al23xi75.80 (3)Ru7Bxxv—Al19—Si18162.8 (5)
Al23viii—Ru4—Al23xi67.19 (3)Ru7Axxv—Al19—Si18159.20 (10)
Al23ix—Ru4—Al23xi102.12 (2)Ru7Bxxv—Al19—Ru1139.2 (5)
Al14—Ru4—Al23xi132.11 (2)Ru7Axxv—Al19—Ru1142.79 (9)
Al23x—Ru4—Al23xi64.83 (3)Si18—Al19—Ru158.02 (3)
Al16—Ru4—Al25iii89.86 (3)Ru7Bxxv—Al19—Si10xxvii59.8 (5)
Al23viii—Ru4—Al25iii89.91 (3)Ru7Axxv—Al19—Si10xxvii56.17 (9)
Al23ix—Ru4—Al25iii125.74 (2)Si18—Al19—Si10xxvii103.03 (5)
Al14—Ru4—Al25iii60.36 (2)Ru1—Al19—Si10xxvii161.04 (5)
Al23x—Ru4—Al25iii165.54 (3)Ru7Bxxv—Al19—Al25i118.98 (5)
Al23xi—Ru4—Al25iii113.90 (2)Ru7Axxv—Al19—Al25i119.26 (2)
Al16—Ru4—Al2589.86 (3)Si18—Al19—Al25i64.00 (3)
Al23viii—Ru4—Al25125.74 (2)Ru1—Al19—Al25i65.10 (3)
Al23ix—Ru4—Al2589.91 (3)Si10xxvii—Al19—Al25i108.41 (3)
Al14—Ru4—Al2560.36 (2)Ru7Bxxv—Al19—Al25118.98 (5)
Al23x—Ru4—Al25113.90 (2)Ru7Axxv—Al19—Al25119.26 (2)
Al23xi—Ru4—Al25165.54 (3)Si18—Al19—Al2564.00 (3)
Al25iii—Ru4—Al2563.37 (4)Ru1—Al19—Al2565.10 (3)
Al16—Ru4—Al2458.633 (16)Si10xxvii—Al19—Al25108.41 (3)
Al23viii—Ru4—Al24153.59 (2)Al25i—Al19—Al25121.10 (5)
Al23ix—Ru4—Al2487.02 (2)Ru7Bxxv—Al19—Ru3vii106.9 (4)
Al14—Ru4—Al24112.050 (17)Ru7Axxv—Al19—Ru3vii103.87 (7)
Al23x—Ru4—Al2458.81 (2)Si18—Al19—Ru3vii59.41 (3)
Al23xi—Ru4—Al24113.17 (2)Ru1—Al19—Ru3vii107.11 (3)
Al25iii—Ru4—Al24112.10 (3)Si10xxvii—Al19—Ru3vii57.80 (3)
Al25—Ru4—Al2458.89 (2)Al25i—Al19—Ru3vii56.54 (2)
Al16—Ru4—Al24iii58.634 (16)Al25—Al19—Ru3vii113.66 (4)
Al23viii—Ru4—Al24iii87.02 (2)Ru7Bxxv—Al19—Ru3xx106.9 (4)
Al23ix—Ru4—Al24iii153.59 (2)Ru7Axxv—Al19—Ru3xx103.87 (7)
Al14—Ru4—Al24iii112.049 (17)Si18—Al19—Ru3xx59.41 (3)
Al23x—Ru4—Al24iii113.17 (2)Ru1—Al19—Ru3xx107.11 (3)
Al23xi—Ru4—Al24iii58.81 (2)Si10xxvii—Al19—Ru3xx57.80 (3)
Al25iii—Ru4—Al24iii58.88 (2)Al25i—Al19—Ru3xx113.66 (4)
Al25—Ru4—Al24iii112.10 (3)Al25—Al19—Ru3xx56.54 (2)
Al24—Ru4—Al24iii116.42 (3)Ru3vii—Al19—Ru3xx66.33 (3)
Al27—Ru5—Al28Ci34.8 (9)Ru7Bxxv—Al19—Al2465.53 (15)
Al27—Ru5—Al28Bi50.3 (7)Ru7Axxv—Al19—Al2464.34 (3)
Al28Ci—Ru5—Al28Bi15.5 (6)Si18—Al19—Al24107.72 (3)
Al27—Ru5—Al28Aii71.55 (4)Ru1—Al19—Al24121.07 (2)
Al28Ci—Ru5—Al28Aii37.4 (9)Si10xxvii—Al19—Al2461.56 (2)
Al28Bi—Ru5—Al28Aii22.7 (6)Al25i—Al19—Al24166.35 (5)
Al27—Ru5—Al28Ai71.55 (4)Al25—Al19—Al2458.76 (2)
Al28Ci—Ru5—Al28Ai37.4 (9)Ru3vii—Al19—Al24110.17 (4)
Al28Bi—Ru5—Al28Ai22.7 (6)Ru3xx—Al19—Al2453.74 (2)
Al28Aii—Ru5—Al28Ai17.15 (11)Ru7Bxxv—Al19—Al24i65.53 (15)
Al27—Ru5—Al21127.171 (16)Ru7Axxv—Al19—Al24i64.34 (3)
Al28Ci—Ru5—Al21140.96 (9)Si18—Al19—Al24i107.71 (3)
Al28Bi—Ru5—Al21139.85 (16)Ru1—Al19—Al24i121.07 (2)
Al28Aii—Ru5—Al21138.19 (5)Si10xxvii—Al19—Al24i61.56 (2)
Al28Ai—Ru5—Al21123.94 (6)Al25i—Al19—Al24i58.76 (2)
Al27—Ru5—Al21iii127.172 (16)Al25—Al19—Al24i166.35 (5)
Al28Ci—Ru5—Al21iii140.96 (9)Ru3vii—Al19—Al24i53.74 (2)
Al28Bi—Ru5—Al21iii139.85 (16)Ru3xx—Al19—Al24i110.17 (4)
Al28Aii—Ru5—Al21iii123.94 (6)Al24—Al19—Al24i117.69 (4)
Al28Ai—Ru5—Al21iii138.19 (5)Al20ii—Al20—Si26Bi129.78 (9)
Al21—Ru5—Al21iii77.66 (3)Al20ii—Al20—Si26B129.78 (9)
Al27—Ru5—Al23iii69.449 (16)Si26Bi—Al20—Si26B97.04 (16)
Al28Ci—Ru5—Al23iii71.17 (14)Al20ii—Al20—Al12B83.4 (7)
Al28Bi—Ru5—Al23iii74.28 (16)Si26Bi—Al20—Al12B84.5 (4)
Al28Aii—Ru5—Al23iii72.12 (6)Si26B—Al20—Al12B84.5 (4)
Al28Ai—Ru5—Al23iii88.37 (6)Al20ii—Al20—Si13i70.32 (5)
Al21—Ru5—Al23iii145.86 (2)Si26Bi—Al20—Si13i73.37 (7)
Al21iii—Ru5—Al23iii69.88 (2)Si26B—Al20—Si13i153.36 (12)
Al27—Ru5—Al2369.449 (16)Al12B—Al20—Si13i118.3 (3)
Al28Ci—Ru5—Al2371.17 (14)Al20ii—Al20—Si1370.32 (5)
Al28Bi—Ru5—Al2374.28 (16)Si26Bi—Al20—Si13153.36 (12)
Al28Aii—Ru5—Al2388.38 (6)Si26B—Al20—Si1373.37 (7)
Al28Ai—Ru5—Al2372.12 (6)Al12B—Al20—Si13118.3 (3)
Al21—Ru5—Al2369.88 (2)Si13i—Al20—Si13103.91 (8)
Al21iii—Ru5—Al23145.86 (2)Al20ii—Al20—Al12Bii56.1 (6)
Al23iii—Ru5—Al23138.27 (3)Si26Bi—Al20—Al12Bii102.4 (4)
Al27—Ru5—Al22124.802 (18)Si26B—Al20—Al12Bii102.4 (4)
Al28Ci—Ru5—Al2297.0 (7)Al12B—Al20—Al12Bii27.3 (13)
Al28Bi—Ru5—Al2284.1 (6)Si13i—Al20—Al12Bii103.9 (4)
Al28Aii—Ru5—Al2272.13 (5)Si13—Al20—Al12Bii103.9 (4)
Al28Ai—Ru5—Al2261.87 (5)Al20ii—Al20—Al26A127.49 (5)
Al21—Ru5—Al2266.94 (2)Si26Bi—Al20—Al26A98.57 (10)
Al21iii—Ru5—Al22107.46 (2)Si26B—Al20—Al26A2.89 (9)
Al23iii—Ru5—Al22132.77 (2)Al12B—Al20—Al26A82.2 (4)
Al23—Ru5—Al2269.40 (2)Si13i—Al20—Al26A156.21 (10)
Al26Ax—Si6—Al26Axi64.09 (6)Si13—Al20—Al26A73.05 (3)
Al26Ax—Si6—Al21x62.48 (5)Al12Bii—Al20—Al26A99.7 (4)
Al26Axi—Si6—Al21x116.49 (5)Al20ii—Al20—Al26Ai127.49 (5)
Al26Ax—Si6—Al21xi116.49 (5)Si26Bi—Al20—Al26Ai2.89 (9)
Al26Axi—Si6—Al21xi62.48 (5)Si26B—Al20—Al26Ai98.58 (10)
Al21x—Si6—Al21xi117.71 (4)Al12B—Al20—Al26Ai82.2 (4)
Al26Ax—Si6—Al14xii116.06 (7)Si13i—Al20—Al26Ai73.05 (3)
Al26Axi—Si6—Al14xii116.06 (7)Si13—Al20—Al26Ai156.21 (10)
Al21x—Si6—Al14xii116.56 (2)Al12Bii—Al20—Al26Ai99.7 (4)
Al21xi—Si6—Al14xii116.56 (2)Al26A—Al20—Al26Ai100.00 (10)
Al26Ax—Si6—Al23xi176.81 (7)Al20ii—Al20—Ru271.28 (5)
Al26Axi—Si6—Al23xi117.20 (3)Si26Bi—Al20—Ru2139.65 (11)
Al21x—Si6—Al23xi118.09 (3)Si26B—Al20—Ru260.02 (8)
Al21xi—Si6—Al23xi66.27 (2)Al12B—Al20—Ru262.1 (2)
Al14xii—Si6—Al23xi60.78 (3)Si13i—Al20—Ru2141.15 (9)
Al26Ax—Si6—Al23x117.20 (3)Si13—Al20—Ru256.80 (3)
Al26Axi—Si6—Al23x176.81 (7)Al12Bii—Al20—Ru257.39 (4)
Al21x—Si6—Al23x66.27 (2)Al26A—Al20—Ru257.36 (4)
Al21xi—Si6—Al23x118.09 (3)Al26Ai—Al20—Ru2138.65 (8)
Al14xii—Si6—Al23x60.78 (3)Al20ii—Al20—Ru2i71.28 (5)
Al23xi—Si6—Al23x61.35 (3)Si26Bi—Al20—Ru2i60.03 (8)
Al26Ax—Si6—Al15xiii65.13 (7)Si26B—Al20—Ru2i139.65 (11)
Al26Axi—Si6—Al15xiii65.13 (7)Al12B—Al20—Ru2i62.1 (2)
Al21x—Si6—Al15xiii116.38 (2)Si13i—Al20—Ru2i56.80 (3)
Al21xi—Si6—Al15xiii116.38 (2)Si13—Al20—Ru2i141.15 (9)
Al14xii—Si6—Al15xiii60.96 (3)Al12Bii—Al20—Ru2i57.39 (4)
Al23xi—Si6—Al15xiii112.46 (3)Al26A—Al20—Ru2i138.65 (8)
Al23x—Si6—Al15xiii112.46 (3)Al26Ai—Al20—Ru2i57.36 (4)
Al26Ax—Si6—Al22xi115.60 (5)Ru2—Al20—Ru2i114.71 (7)
Al26Axi—Si6—Al22xi62.20 (5)Al20ii—Al20—Al12A71.86 (5)
Al21x—Si6—Al22xi178.04 (4)Si26Bi—Al20—Al12A92.10 (9)
Al21xi—Si6—Al22xi63.25 (2)Si26B—Al20—Al12A92.10 (9)
Al14xii—Si6—Al22xi63.63 (2)Al12B—Al20—Al12A11.6 (7)
Al23xi—Si6—Al22xi63.80 (2)Si13i—Al20—Al12A112.68 (6)
Al23x—Si6—Al22xi114.99 (3)Si13—Al20—Al12A112.68 (6)
Al15xiii—Si6—Al22xi61.86 (2)Al12Bii—Al20—Al12A15.8 (6)
Al26Ax—Si6—Al22x62.20 (5)Al26A—Al20—Al12A89.59 (6)
Al26Axi—Si6—Al22x115.60 (5)Al26Ai—Al20—Al12A89.59 (6)
Al21x—Si6—Al22x63.25 (2)Ru2—Al20—Al12A59.21 (4)
Al21xi—Si6—Al22x178.04 (4)Ru2i—Al20—Al12A59.21 (4)
Al14xii—Si6—Al22x63.63 (2)Al12B—Al21—Ru7A68.3 (4)
Al23xi—Si6—Al22x114.99 (3)Al12B—Al21—Ru261.1 (4)
Al23x—Si6—Al22x63.80 (2)Ru7A—Al21—Ru2129.12 (10)
Al15xiii—Si6—Al22x61.86 (2)Al12B—Al21—Ru5116.5 (6)
Al22xi—Si6—Al22x115.73 (4)Ru7A—Al21—Ru5129.33 (4)
Al26Ax—Si6—Al16115.32 (7)Ru2—Al21—Ru573.60 (2)
Al26Axi—Si6—Al16115.32 (7)Al12B—Al21—Ru7B72.2 (6)
Al21x—Si6—Al1663.79 (2)Ru7A—Al21—Ru7B4.0 (4)
Al21xi—Si6—Al1663.79 (2)Ru2—Al21—Ru7B133.1 (4)
Al14xii—Si6—Al16118.49 (4)Ru5—Al21—Ru7B128.9 (2)
Al23xi—Si6—Al1667.08 (3)Al12B—Al21—Si6xv128.1 (7)
Al23x—Si6—Al1667.08 (3)Ru7A—Al21—Si6xv107.13 (8)
Al15xiii—Si6—Al16179.45 (4)Ru2—Al21—Si6xv107.38 (3)
Al22xi—Si6—Al16117.98 (2)Ru5—Al21—Si6xv105.51 (3)
Al22x—Si6—Al16117.98 (2)Ru7B—Al21—Si6xv104.1 (4)
Al21—Ru7A—Al21i109.01 (17)Al12B—Al21—Al12A16.4 (7)
Al21—Ru7A—Si1091.59 (11)Ru7A—Al21—Al12A67.88 (10)
Al21i—Ru7A—Si1091.59 (11)Ru2—Al21—Al12A62.23 (4)
Al21—Ru7A—Al16xiv150.26 (7)Ru5—Al21—Al12A103.42 (3)
Al21i—Ru7A—Al16xiv72.21 (3)Ru7B—Al21—Al12A71.9 (4)
Si10—Ru7A—Al16xiv118.15 (7)Si6xv—Al21—Al12A144.53 (5)
Al21—Ru7A—Al16xv72.21 (3)Al12B—Al21—Al26A76.4 (6)
Al21i—Ru7A—Al16xv150.26 (7)Ru7A—Al21—Al26A115.15 (8)
Si10—Ru7A—Al16xv118.15 (7)Ru2—Al21—Al26A57.91 (6)
Al16xiv—Ru7A—Al16xv92.25 (16)Ru5—Al21—Al26A114.75 (5)
Al21—Ru7A—Al11xv75.04 (6)Ru7B—Al21—Al26A116.1 (2)
Al21i—Ru7A—Al11xv75.04 (6)Si6xv—Al21—Al26A58.64 (11)
Si10—Ru7A—Al11xv156.3 (2)Al12A—Al21—Al26A90.67 (13)
Al16xiv—Ru7A—Al11xv76.80 (6)Al12B—Al21—Al24xvii119.0 (6)
Al16xv—Ru7A—Al11xv76.80 (6)Ru7A—Al21—Al24xvii68.48 (6)
Al21—Ru7A—Al19xvi122.02 (4)Ru2—Al21—Al24xvii134.06 (3)
Al21i—Ru7A—Al19xvi122.02 (4)Ru5—Al21—Al24xvii66.51 (2)
Si10—Ru7A—Al19xvi63.21 (5)Ru7B—Al21—Al24xvii66.3 (3)
Al16xiv—Ru7A—Al19xvi76.07 (12)Si6xv—Al21—Al24xvii104.48 (3)
Al16xv—Ru7A—Al19xvi76.07 (12)Al12A—Al21—Al24xvii105.60 (6)
Al11xv—Ru7A—Al19xvi140.45 (19)Al26A—Al21—Al24xvii163.10 (12)
Al21—Ru7A—Al12B55.23 (12)Al12B—Al21—Si26B66.3 (6)
Al21i—Ru7A—Al12B55.23 (12)Ru7A—Al21—Si26B109.80 (10)
Si10—Ru7A—Al12B81.9 (6)Ru2—Al21—Si26B53.66 (7)
Al16xiv—Ru7A—Al12B124.7 (3)Ru5—Al21—Si26B118.00 (6)
Al16xv—Ru7A—Al12B124.7 (3)Ru7B—Al21—Si26B111.4 (3)
Al11xv—Ru7A—Al12B74.4 (6)Si6xv—Al21—Si26B67.88 (12)
Al19xvi—Ru7A—Al12B145.1 (6)Al12A—Al21—Si26B80.63 (14)
Al21—Ru7A—Al12A58.55 (10)Al26A—Al21—Si26B10.09 (5)
Al21i—Ru7A—Al12A58.55 (10)Al24xvii—Al21—Si26B171.65 (10)
Si10—Ru7A—Al12A66.73 (11)Al12B—Al21—Al22117.9 (4)
Al16xiv—Ru7A—Al12A130.76 (9)Ru7A—Al21—Al22169.24 (9)
Al16xv—Ru7A—Al12A130.76 (9)Ru2—Al21—Al2258.56 (2)
Al11xv—Ru7A—Al12A89.61 (12)Ru5—Al21—Al2257.47 (2)
Al19xvi—Ru7A—Al12A129.94 (10)Ru7B—Al21—Al22165.9 (4)
Al12B—Ru7A—Al12A15.2 (6)Si6xv—Al21—Al2262.12 (3)
Al21—Ru7A—Al24xvii59.64 (3)Al12A—Al21—Al22120.71 (5)
Al21i—Ru7A—Al24xvii149.86 (17)Al26A—Al21—Al2260.68 (8)
Si10—Ru7A—Al24xvii62.79 (3)Al24xvii—Al21—Al22112.49 (3)
Al16xiv—Ru7A—Al24xvii132.53 (18)Si26B—Al21—Al2267.59 (10)
Al16xv—Ru7A—Al24xvii57.51 (4)Ru9ix—Al22—Ru5133.43 (3)
Al11xv—Ru7A—Al24xvii122.30 (3)Ru9ix—Al22—Ru976.273 (19)
Al19xvi—Ru7A—Al24xvii62.41 (5)Ru5—Al22—Ru9140.36 (3)
Al12B—Ru7A—Al24xvii102.7 (3)Ru9ix—Al22—Ru2143.89 (3)
Al12A—Ru7A—Al24xvii94.82 (10)Ru5—Al22—Ru270.857 (19)
Al16xiv—Ru7B—Al16xv99.1 (8)Ru9—Al22—Ru271.503 (19)
Al16xiv—Ru7B—Al19xvi81.4 (6)Ru9ix—Al22—Al28Ai75.76 (5)
Al16xv—Ru7B—Al19xvi81.4 (6)Ru5—Al22—Al28Ai57.77 (5)
Al16xiv—Ru7B—Si10120.2 (3)Ru9—Al22—Al28Ai136.00 (5)
Al16xv—Ru7B—Si10120.2 (3)Ru2—Al22—Al28Ai118.07 (6)
Al19xvi—Ru7B—Si1064.2 (3)Ru9ix—Al22—Al26A116.62 (6)
Al16xiv—Ru7B—Al21150.9 (5)Ru5—Al22—Al26A109.46 (5)
Al16xv—Ru7B—Al2172.18 (11)Ru9—Al22—Al26A55.78 (4)
Al19xvi—Ru7B—Al21123.0 (2)Ru2—Al22—Al26A55.35 (9)
Si10—Ru7B—Al2187.1 (5)Al28Ai—Al22—Al26A166.65 (6)
Al16xiv—Ru7B—Al21i72.18 (11)Ru9ix—Al22—Si6xv102.48 (3)
Al16xv—Ru7B—Al21i150.9 (5)Ru5—Al22—Si6xv98.12 (3)
Al19xvi—Ru7B—Al21i123.0 (2)Ru9—Al22—Si6xv99.13 (3)
Si10—Ru7B—Al21i87.1 (5)Ru2—Al22—Si6xv98.35 (3)
Al21—Ru7B—Al21i101.7 (8)Al28Ai—Al22—Si6xv119.65 (6)
Al16xiv—Ru7B—Al11xv78.6 (3)Al26A—Al22—Si6xv54.96 (8)
Al16xv—Ru7B—Al11xv78.6 (3)Ru9ix—Al22—Al21156.62 (3)
Al19xvi—Ru7B—Al11xv148.8 (10)Ru5—Al22—Al2155.59 (2)
Si10—Ru7B—Al11xv147.0 (10)Ru9—Al22—Al21109.46 (3)
Al21—Ru7B—Al11xv72.6 (4)Ru2—Al22—Al2154.75 (2)
Al21i—Ru7B—Al11xv72.6 (4)Al28Ai—Al22—Al21109.73 (5)
Al16xiv—Ru7B—Al24xvii140.6 (9)Al26A—Al22—Al2156.94 (4)
Al16xv—Ru7B—Al24xvii58.93 (16)Si6xv—Al22—Al2154.63 (2)
Al19xvi—Ru7B—Al24xvii64.3 (3)Ru9ix—Al22—Al15i56.09 (2)
Si10—Ru7B—Al24xvii62.3 (2)Ru5—Al22—Al15i112.97 (3)
Al21—Ru7B—Al24xvii58.76 (13)Ru9—Al22—Al15i56.57 (2)
Al21i—Ru7B—Al24xvii142.6 (8)Ru2—Al22—Al15i91.92 (3)
Al11xv—Ru7B—Al24xvii122.0 (2)Al28Ai—Al22—Al15i79.64 (5)
Al16xiv—Ru7B—Al24xvi58.93 (16)Al26A—Al22—Al15i110.98 (5)
Al16xv—Ru7B—Al24xvi140.6 (9)Si6xv—Al22—Al15i148.91 (3)
Al19xvi—Ru7B—Al24xvi64.3 (3)Al21—Al22—Al15i146.28 (3)
Si10—Ru7B—Al24xvi62.3 (2)Ru9ix—Al22—Al22iii109.401 (18)
Al21—Ru7B—Al24xvi142.6 (8)Ru5—Al22—Al22iii56.521 (16)
Al21i—Ru7B—Al24xvi58.76 (13)Ru9—Al22—Al22iii92.250 (17)
Al11xv—Ru7B—Al24xvi122.0 (2)Ru2—Al22—Al22iii57.038 (17)
Al24xvii—Ru7B—Al24xvi115.8 (4)Al28Ai—Al22—Al22iii66.38 (5)
Al16xiv—Ru7B—Ru7Bxviii51.5 (3)Al26A—Al22—Al22iii111.14 (9)
Al16xv—Ru7B—Ru7Bxviii51.5 (3)Si6xv—Al22—Al22iii147.868 (19)
Al19xvi—Ru7B—Ru7Bxviii93.1 (4)Al21—Al22—Al22iii93.25 (2)
Si10—Ru7B—Ru7Bxviii157.3 (5)Al15i—Al22—Al22iii59.955 (17)
Al21—Ru7B—Ru7Bxviii106.9 (3)Ru9ix—Al22—Al14ix55.43 (2)
Al21i—Ru7B—Ru7Bxviii106.9 (3)Ru5—Al22—Al14ix108.75 (3)
Al11xv—Ru7B—Ru7Bxviii55.8 (5)Ru9—Al22—Al14ix110.44 (3)
Al24xvii—Ru7B—Ru7Bxviii109.2 (4)Ru2—Al22—Al14ix153.68 (4)
Al24xvi—Ru7B—Ru7Bxviii109.2 (4)Al28Ai—Al22—Al14ix79.63 (6)
Ru8xviii—Ru8—Si26Bi130.06 (17)Al26A—Al22—Al14ix102.89 (9)
Ru8xviii—Ru8—Si26B130.06 (17)Si6xv—Al22—Al14ix55.36 (3)
Si26Bi—Ru8—Si26B93.3 (3)Al21—Al22—Al14ix102.32 (3)
Ru8xviii—Ru8—Si18117.55 (5)Al15i—Al22—Al14ix111.30 (3)
Si26Bi—Ru8—Si1885.04 (12)Al22iii—Al22—Al14ix145.76 (2)
Si26B—Ru8—Si1885.03 (12)Ru4ix—Al23—Ru5139.89 (3)
Ru8xviii—Ru8—Al26A119.05 (12)Ru4ix—Al23—Ru4xv77.88 (2)
Si26Bi—Ru8—Al26A102.7 (2)Ru5—Al23—Ru4xv129.65 (3)
Si26B—Ru8—Al26A11.05 (8)Ru4ix—Al23—Al24xvii137.82 (3)
Si18—Ru8—Al26A91.76 (9)Ru5—Al23—Al24xvii66.20 (2)
Ru8xviii—Ru8—Al26Ai119.05 (12)Ru4xv—Al23—Al24xvii64.62 (2)
Si26Bi—Ru8—Al26Ai11.05 (8)Ru4ix—Al23—Al14ix57.47 (2)
Si26B—Ru8—Al26Ai102.7 (2)Ru5—Al23—Al14ix114.11 (3)
Si18—Ru8—Al26Ai91.76 (9)Ru4xv—Al23—Al14ix115.33 (3)
Al26A—Ru8—Al26Ai111.25 (18)Al24xvii—Al23—Al14ix157.49 (4)
Ru8xviii—Ru8—Si26Bxviii43.07 (15)Ru4ix—Al23—Si6xv103.97 (3)
Si26Bi—Ru8—Si26Bxviii87.0 (3)Ru5—Al23—Si6xv99.99 (2)
Si26B—Ru8—Si26Bxviii153.06 (14)Ru4xv—Al23—Si6xv98.39 (3)
Si18—Ru8—Si26Bxviii121.78 (6)Al24xvii—Al23—Si6xv100.07 (3)
Al26A—Ru8—Si26Bxviii146.00 (8)Al14ix—Al23—Si6xv57.43 (3)
Al26Ai—Ru8—Si26Bxviii76.0 (3)Ru4ix—Al23—Al27102.08 (2)
Ru8xviii—Ru8—Si26Bxix43.07 (15)Ru5—Al23—Al2751.056 (15)
Si26Bi—Ru8—Si26Bxix153.05 (14)Ru4xv—Al23—Al2799.56 (2)
Si26B—Ru8—Si26Bxix87.0 (3)Al24xvii—Al23—Al2767.82 (2)
Si18—Ru8—Si26Bxix121.78 (6)Al14ix—Al23—Al27131.35 (3)
Al26A—Ru8—Si26Bxix76.0 (3)Si6xv—Al23—Al27150.89 (3)
Al26Ai—Ru8—Si26Bxix146.00 (8)Ru4ix—Al23—Al23xix56.121 (17)
Si26Bxviii—Ru8—Si26Bxix80.9 (3)Ru5—Al23—Al23xix159.133 (17)
Ru8xviii—Ru8—Al11xv85.69 (4)Ru4xv—Al23—Al23xix57.583 (16)
Si26Bi—Ru8—Al11xv79.09 (8)Al24xvii—Al23—Al23xix112.01 (2)
Si26B—Ru8—Al11xv79.10 (8)Al14ix—Al23—Al23xix58.992 (18)
Si18—Ru8—Al11xv156.75 (8)Si6xv—Al23—Al23xix59.325 (17)
Al26A—Ru8—Al11xv75.48 (5)Al27—Al23—Al23xix149.293 (14)
Al26Ai—Ru8—Al11xv75.48 (5)Ru4ix—Al23—Al23xxiii58.09 (2)
Si26Bxviii—Ru8—Al11xv74.51 (7)Ru5—Al23—Al23xxiii110.021 (16)
Si26Bxix—Ru8—Al11xv74.51 (7)Ru4xv—Al23—Al23xxiii54.723 (19)
Ru8xviii—Ru8—Al18xviii54.98 (4)Al24xvii—Al23—Al23xxiii83.77 (3)
Si26Bi—Ru8—Al18xviii124.37 (8)Al14ix—Al23—Al23xxiii115.24 (4)
Si26B—Ru8—Al18xviii124.36 (8)Si6xv—Al23—Al23xxiii148.424 (19)
Si18—Ru8—Al18xviii62.58 (5)Al27—Al23—Al23xxiii59.293 (14)
Al26A—Ru8—Al18xviii120.97 (5)Al23xix—Al23—Al23xxiii90.0
Al26Ai—Ru8—Al18xviii120.97 (5)Ru4ix—Al23—Al28Ci90.8 (4)
Si26Bxviii—Ru8—Al18xviii75.82 (12)Ru5—Al23—Al28Ci50.8 (4)
Si26Bxix—Ru8—Al18xviii75.82 (12)Ru4xv—Al23—Al28Ci123.1 (7)
Al11xv—Ru8—Al18xviii140.67 (8)Al24xvii—Al23—Al28Ci93.8 (6)
Ru8xviii—Ru8—Al26Axviii53.64 (11)Al14ix—Al23—Al28Ci103.3 (7)
Si26Bi—Ru8—Al26Axviii76.4 (3)Si6xv—Al23—Al28Ci138.2 (7)
Si26B—Ru8—Al26Axviii150.61 (9)Al27—Al23—Al28Ci28.5 (7)
Si18—Ru8—Al26Axviii120.64 (4)Al23xix—Al23—Al28Ci146.9 (4)
Al26A—Ru8—Al26Axviii147.02 (8)Al23xxiii—Al23—Al28Ci71.9 (6)
Al26Ai—Ru8—Al26Axviii65.4 (2)Ru4ix—Al23—Al21158.01 (3)
Si26Bxviii—Ru8—Al26Axviii10.60 (7)Ru5—Al23—Al2154.62 (2)
Si26Bxix—Ru8—Al26Axviii90.2 (2)Ru4xv—Al23—Al21104.25 (3)
Al11xv—Ru8—Al26Axviii71.98 (4)Al24xvii—Al23—Al2157.17 (2)
Al18xviii—Ru8—Al26Axviii82.95 (9)Al14ix—Al23—Al21103.50 (3)
Si13—Ru9—Al22ix143.18 (3)Si6xv—Al23—Al2154.05 (2)
Si13—Ru9—Al1474.93 (3)Al27—Al23—Al2199.14 (3)
Al22ix—Ru9—Al1469.25 (2)Al23xix—Al23—Al21106.01 (2)
Si13—Ru9—Al26A76.19 (12)Al23xxiii—Al23—Al21140.86 (4)
Al22ix—Ru9—Al26A137.56 (11)Al28Ci—Al23—Al21105.4 (4)
Al14—Ru9—Al26A150.45 (13)Ru4ix—Al23—Al22112.68 (3)
Si13—Ru9—Al15xx144.71 (3)Ru5—Al23—Al2255.75 (2)
Al22ix—Ru9—Al15xx68.60 (3)Ru4xv—Al23—Al22156.11 (3)
Al14—Ru9—Al15xx137.45 (3)Al24xvii—Al23—Al22109.38 (3)
Al26A—Ru9—Al15xx69.48 (11)Al14ix—Al23—Al2260.73 (2)
Si13—Ru9—Al15i104.138 (19)Si6xv—Al23—Al2258.86 (2)
Al22ix—Ru9—Al15i68.15 (2)Al27—Al23—Al2298.94 (3)
Al14—Ru9—Al15i64.92 (3)Al23xix—Al23—Al22109.21 (2)
Al26A—Ru9—Al15i129.36 (6)Al23xxiii—Al23—Al22149.15 (4)
Al15xx—Ru9—Al15i103.749 (11)Al28Ci—Al23—Al2279.3 (7)
Si13—Ru9—Al22105.35 (3)Al21—Al23—Al2257.77 (2)
Al22ix—Ru9—Al22103.725 (19)Al28Cxx—Al24—Ru3xx71.1 (7)
Al14—Ru9—Al22129.31 (2)Al28Cxx—Al24—Al16144.5 (3)
Al26A—Ru9—Al2265.23 (9)Ru3xx—Al24—Al16129.42 (4)
Al15xx—Ru9—Al2267.48 (2)Al28Cxx—Al24—Al28Bxx13.5 (6)
Al15i—Ru9—Al2266.15 (3)Ru3xx—Al24—Al28Bxx60.3 (5)
Si13—Ru9—Si17Bxx102.8 (4)Al16—Al24—Al28Bxx144.0 (2)
Al22ix—Ru9—Si17Bxx82.4 (5)Al28Cxx—Al24—Al23x80.9 (7)
Al14—Ru9—Si17Bxx110.4 (4)Ru3xx—Al24—Al23x151.18 (4)
Al26A—Ru9—Si17Bxx70.2 (5)Al16—Al24—Al23x72.20 (4)
Al15xx—Ru9—Si17Bxx58.2 (2)Al28Bxx—Al24—Al23x90.9 (5)
Al15i—Ru9—Si17Bxx150.0 (5)Al28Cxx—Al24—Al21x122.4 (8)
Al22—Ru9—Si17Bxx118.4 (3)Ru3xx—Al24—Al21x136.11 (3)
Si13—Ru9—Si26B66.13 (13)Al16—Al24—Al21x66.43 (3)
Al22ix—Ru9—Si26B145.78 (11)Al28Bxx—Al24—Al21x135.6 (5)
Al14—Ru9—Si26B139.92 (13)Al23x—Al24—Al21x65.80 (3)
Al26A—Ru9—Si26B10.56 (5)Al28Cxx—Al24—Al2582.2 (8)
Al15xx—Ru9—Si26B79.06 (13)Ru3xx—Al24—Al2558.88 (2)
Al15i—Ru9—Si26B132.98 (6)Al16—Al24—Al2586.60 (4)
Al22—Ru9—Si26B72.46 (10)Al28Bxx—Al24—Al2570.0 (5)
Si17Bxx—Ru9—Si26B71.0 (6)Al23x—Al24—Al25111.61 (3)
Si13—Ru9—Al17Axx94.94 (4)Al21x—Al24—Al25152.63 (4)
Al22ix—Ru9—Al17Axx94.80 (5)Al28Cxx—Al24—Al24xix55.8 (3)
Al14—Ru9—Al17Axx118.76 (4)Ru3xx—Al24—Al24xix56.826 (17)
Al26A—Ru9—Al17Axx57.86 (6)Al16—Al24—Al24xix157.27 (3)
Al15xx—Ru9—Al17Axx59.96 (3)Al28Bxx—Al24—Al24xix58.6 (2)
Al15i—Ru9—Al17Axx160.71 (4)Al23x—Al24—Al24xix112.00 (2)
Al22—Ru9—Al17Axx111.76 (4)Al21x—Al24—Al24xix94.28 (2)
Si17Bxx—Ru9—Al17Axx13.0 (5)Al25—Al24—Al24xix110.87 (3)
Si26B—Ru9—Al17Axx58.07 (8)Al28Cxx—Al24—Si10xxvii112.9 (4)
Ru7Aii—Si10—Ru7A125.3 (2)Ru3xx—Al24—Si10xxvii58.14 (3)
Ru7Aii—Si10—Ru7Bii4.6 (4)Al16—Al24—Si10xxvii102.42 (3)
Ru7A—Si10—Ru7Bii129.9 (6)Al28Bxx—Al24—Si10xxvii109.2 (3)
Ru7Aii—Si10—Ru7B129.9 (6)Al23x—Al24—Si10xxvii144.16 (4)
Ru7A—Si10—Ru7B4.6 (4)Al21x—Al24—Si10xxvii79.43 (4)
Ru7Bii—Si10—Ru7B134.5 (10)Al25—Al24—Si10xxvii103.20 (4)
Ru7Aii—Si10—Ru3xxiv112.02 (9)Al24xix—Al24—Si10xxvii60.455 (15)
Ru7A—Si10—Ru3xxiv112.02 (9)Al28Cxx—Al24—Ru492.4 (3)
Ru7Bii—Si10—Ru3xxiv108.4 (4)Ru3xx—Al24—Ru4116.86 (3)
Ru7B—Si10—Ru3xxiv108.4 (4)Al16—Al24—Ru453.47 (3)
Ru7Aii—Si10—Ru3vi112.02 (9)Al28Bxx—Al24—Ru490.57 (19)
Ru7A—Si10—Ru3vi112.02 (9)Al23x—Al24—Ru456.57 (2)
Ru7Bii—Si10—Ru3vi108.4 (4)Al21x—Al24—Ru4104.72 (3)
Ru7B—Si10—Ru3vi108.4 (4)Al25—Al24—Ru458.66 (2)
Ru3xxiv—Si10—Ru3vi70.63 (3)Al24xix—Al24—Ru4148.210 (16)
Ru7Aii—Si10—Al19xxi60.62 (11)Si10xxvii—Al24—Ru4147.42 (3)
Ru7A—Si10—Al19xxi174.09 (12)Al28Cxx—Al24—Al19128.9 (8)
Ru7Bii—Si10—Al19xxi56.0 (5)Ru3xx—Al24—Al1961.31 (3)
Ru7B—Si10—Al19xxi169.5 (5)Al16—Al24—Al1969.38 (4)
Ru3xxiv—Si10—Al19xxi63.41 (3)Al28Bxx—Al24—Al19115.7 (5)
Ru3vi—Si10—Al19xxi63.41 (3)Al23x—Al24—Al19140.66 (4)
Ru7Aii—Si10—Al19xvi174.09 (12)Al21x—Al24—Al19105.11 (3)
Ru7A—Si10—Al19xvi60.62 (11)Al25—Al24—Al1958.34 (3)
Ru7Bii—Si10—Al19xvi169.5 (5)Al24xix—Al24—Al19106.70 (3)
Ru7B—Si10—Al19xvi56.0 (5)Si10xxvii—Al24—Al1955.54 (3)
Ru3xxiv—Si10—Al19xvi63.41 (3)Ru4—Al24—Al1992.85 (3)
Ru3vi—Si10—Al19xvi63.41 (3)Al28Cxx—Al24—Ru5xxvii68.3 (8)
Al19xxi—Si10—Al19xvi113.47 (6)Ru3xx—Al24—Ru5xxvii117.27 (3)
Ru7Aii—Si10—Al24xxi66.31 (4)Al16—Al24—Ru5xxvii111.16 (4)
Ru7A—Si10—Al24xxi118.30 (3)Al28Bxx—Al24—Ru5xxvii81.4 (5)
Ru7Bii—Si10—Al24xxi64.89 (15)Al23x—Al24—Ru5xxvii54.85 (2)
Ru7B—Si10—Al24xxi119.03 (7)Al21x—Al24—Ru5xxvii54.16 (2)
Ru3xxiv—Si10—Al24xxi55.588 (19)Al25—Al24—Ru5xxvii148.62 (4)
Ru3vi—Si10—Al24xxi115.89 (4)Al24xix—Al24—Ru5xxvii61.040 (15)
Al19xxi—Si10—Al24xxi62.902 (19)Si10xxvii—Al24—Ru5xxvii98.06 (3)
Al19xvi—Si10—Al24xxi111.66 (3)Ru4—Al24—Ru5xxvii110.63 (2)
Ru7Aii—Si10—Al24xvi118.31 (3)Al19—Al24—Ru5xxvii151.32 (3)
Ru7A—Si10—Al24xvi66.31 (4)Si13—Al25—Al28Axx124.19 (6)
Ru7Bii—Si10—Al24xvi119.03 (7)Si13—Al25—Ru3xx131.16 (3)
Ru7B—Si10—Al24xvi64.90 (15)Al28Axx—Al25—Ru3xx60.04 (5)
Ru3xxiv—Si10—Al24xvi115.89 (4)Si13—Al25—Al1469.92 (3)
Ru3vi—Si10—Al24xvi55.588 (19)Al28Axx—Al25—Al1484.62 (5)
Al19xxi—Si10—Al24xvi111.66 (3)Ru3xx—Al25—Al14144.54 (4)
Al19xvi—Si10—Al24xvi62.902 (18)Si13—Al25—Al19107.28 (4)
Al24xxi—Si10—Al24xvi170.96 (6)Al28Axx—Al25—Al19119.27 (6)
Ru7Aii—Si10—Al24xvii118.31 (3)Ru3xx—Al25—Al1962.41 (3)
Ru7A—Si10—Al24xvii66.31 (4)Al14—Al25—Al19147.27 (5)
Ru7Bii—Si10—Al24xvii119.03 (7)Si13—Al25—Ru4110.10 (3)
Ru7B—Si10—Al24xvii64.90 (15)Al28Axx—Al25—Ru492.85 (5)
Ru3xxiv—Si10—Al24xvii55.588 (19)Ru3xx—Al25—Ru4118.47 (3)
Ru3vi—Si10—Al24xvii115.89 (4)Al14—Al25—Ru456.01 (2)
Al19xxi—Si10—Al24xvii111.66 (3)Al19—Al25—Ru498.03 (3)
Al19xvi—Si10—Al24xvii62.902 (19)Si13—Al25—Al24164.76 (5)
Al24xxi—Si10—Al24xvii59.09 (3)Al28Axx—Al25—Al2470.66 (5)
Al24xvi—Si10—Al24xvii120.09 (3)Ru3xx—Al25—Al2456.71 (2)
Ru7Aii—Si10—Al24xxii66.31 (4)Al14—Al25—Al24111.40 (4)
Ru7A—Si10—Al24xxii118.30 (3)Al19—Al25—Al2462.90 (3)
Ru7Bii—Si10—Al24xxii64.89 (15)Ru4—Al25—Al2462.46 (2)
Ru7B—Si10—Al24xxii119.03 (7)Si13—Al25—Si17Bxx94.5 (4)
Ru3xxiv—Si10—Al24xxii115.89 (4)Al28Axx—Al25—Si17Bxx42.9 (5)
Ru3vi—Si10—Al24xxii55.588 (19)Ru3xx—Al25—Si17Bxx54.1 (2)
Al19xxi—Si10—Al24xxii62.902 (19)Al14—Al25—Si17Bxx102.6 (3)
Al19xvi—Si10—Al24xxii111.66 (3)Al19—Al25—Si17Bxx110.1 (3)
Al24xxi—Si10—Al24xxii120.09 (3)Ru4—Al25—Si17Bxx135.0 (5)
Al24xvi—Si10—Al24xxii59.09 (3)Al24—Al25—Si17Bxx99.8 (3)
Al24xvii—Si10—Al24xxii170.96 (6)Si13—Al25—Ru952.79 (2)
Ru8xxv—Al11—Ru8xi8.64 (8)Al28Axx—Al25—Ru971.76 (5)
Ru8xxv—Al11—Ru7Axi145.33 (12)Ru3xx—Al25—Ru9110.61 (3)
Ru8xi—Al11—Ru7Axi136.69 (12)Al14—Al25—Ru955.04 (2)
Ru8xxv—Al11—Ru7Axxv136.69 (12)Al19—Al25—Ru9149.49 (4)
Ru8xi—Al11—Ru7Axxv145.33 (12)Ru4—Al25—Ru9110.23 (3)
Ru7Axi—Al11—Ru7Axxv78.0 (2)Al24—Al25—Ru9141.11 (4)
Ru8xxv—Al11—Ru7Bxi150.1 (5)Si17Bxx—Al25—Ru956.5 (2)
Ru8xi—Al11—Ru7Bxi141.4 (5)Si13—Al25—Si1876.05 (3)
Ru7Axi—Al11—Ru7Bxi4.7 (4)Al28Axx—Al25—Si18105.43 (6)
Ru7Axxv—Al11—Ru7Bxi73.2 (6)Ru3xx—Al25—Si1858.55 (3)
Ru8xxv—Al11—Ru7Bxxv141.4 (5)Al14—Al25—Si18143.89 (4)
Ru8xi—Al11—Ru7Bxxv150.1 (5)Al19—Al25—Si1855.73 (3)
Ru7Axi—Al11—Ru7Bxxv73.2 (6)Ru4—Al25—Si18152.96 (4)
Ru7Axxv—Al11—Ru7Bxxv4.7 (4)Al24—Al25—Si18104.62 (4)
Ru7Bxi—Al11—Ru7Bxxv68.5 (10)Si17Bxx—Al25—Si1868.0 (5)
Al12Bii—Al12A—Al12B108 (3)Ru9—Al25—Si1894.56 (3)
Al12Bii—Al12A—Al21iii67.5 (8)Si26B—Al26A—Ru856.5 (4)
Al12B—Al12A—Al21iii127.4 (4)Si26B—Al26A—Ru273.2 (4)
Al12Bii—Al12A—Al21i127.4 (4)Ru8—Al26A—Ru2127.6 (2)
Al12B—Al12A—Al21i67.5 (8)Si26B—Al26A—Ru9101.8 (4)
Al21iii—Al12A—Al21i157.96 (11)Ru8—Al26A—Ru9125.89 (10)
Al12Bii—Al12A—Al21ii67.5 (8)Ru2—Al26A—Ru974.86 (4)
Al12B—Al12A—Al21ii127.4 (4)Si26B—Al26A—Si6xv149.4 (4)
Al21iii—Al12A—Al21ii100.34 (4)Ru8—Al26A—Si6xv108.54 (8)
Al21i—Al12A—Al21ii75.37 (3)Ru2—Al26A—Si6xv107.54 (11)
Al12Bii—Al12A—Al21127.4 (4)Ru9—Al26A—Si6xv107.90 (18)
Al12B—Al12A—Al2167.5 (8)Si26B—Al26A—Al17Axx92.8 (4)
Al21iii—Al12A—Al2175.37 (3)Ru8—Al26A—Al17Axx66.69 (7)
Al21i—Al12A—Al21100.34 (4)Ru2—Al26A—Al17Axx134.59 (9)
Al21ii—Al12A—Al21157.96 (11)Ru9—Al26A—Al17Axx65.89 (6)
Al12Bii—Al12A—Ru2i71.4 (7)Si6xv—Al26A—Al17Axx105.56 (15)
Al12B—Al12A—Ru2i71.4 (7)Si26B—Al26A—Al2012.3 (4)
Al21iii—Al12A—Ru2i138.44 (5)Ru8—Al26A—Al2066.65 (14)
Al21i—Al12A—Ru2i57.296 (18)Ru2—Al26A—Al2061.85 (11)
Al21ii—Al12A—Ru2i57.296 (18)Ru9—Al26A—Al20101.79 (13)
Al21—Al12A—Ru2i138.44 (5)Si6xv—Al26A—Al20144.43 (8)
Al12Bii—Al12A—Ru271.4 (7)Al17Axx—Al26A—Al20104.15 (16)
Al12B—Al12A—Ru271.4 (7)Si26B—Al26A—Ru8xviii63.8 (4)
Al21iii—Al12A—Ru257.297 (18)Ru8—Al26A—Ru8xviii7.31 (7)
Al21i—Al12A—Ru2138.44 (5)Ru2—Al26A—Ru8xviii134.7 (2)
Al21ii—Al12A—Ru2138.44 (5)Ru9—Al26A—Ru8xviii126.28 (8)
Al21—Al12A—Ru257.298 (18)Si6xv—Al26A—Ru8xviii102.45 (8)
Ru2i—Al12A—Ru2114.07 (9)Al17Axx—Al26A—Ru8xviii63.79 (7)
Al12Bii—Al12A—Al2072.2 (15)Al20—Al26A—Ru8xviii73.95 (14)
Al12B—Al12A—Al2035.9 (15)Si26B—Al26A—Al21100.9 (4)
Al21iii—Al12A—Al20111.84 (7)Ru8—Al26A—Al21115.23 (8)
Al21i—Al12A—Al2089.50 (5)Ru2—Al26A—Al2157.85 (3)
Al21ii—Al12A—Al20111.84 (7)Ru9—Al26A—Al21117.54 (9)
Al21—Al12A—Al2089.50 (5)Si6xv—Al26A—Al2158.88 (8)
Ru2i—Al12A—Al2058.86 (4)Al17Axx—Al26A—Al21164.4 (2)
Ru2—Al12A—Al2058.86 (4)Al20—Al26A—Al2190.24 (11)
Al12Bii—Al12A—Al20ii35.9 (15)Ru8xviii—Al26A—Al21116.01 (7)
Al12B—Al12A—Al20ii72.2 (15)Si26B—Al26A—Al26Axix117.3 (4)
Al21iii—Al12A—Al20ii89.50 (5)Ru8—Al26A—Al26Axix60.96 (12)
Al21i—Al12A—Al20ii111.84 (7)Ru2—Al26A—Al26Axix165.22 (9)
Al21ii—Al12A—Al20ii89.50 (5)Ru9—Al26A—Al26Axix110.82 (8)
Al21—Al12A—Al20ii111.84 (7)Si6xv—Al26A—Al26Axix57.95 (3)
Ru2i—Al12A—Al20ii58.86 (4)Al17Axx—Al26A—Al26Axix58.02 (7)
Ru2—Al12A—Al20ii58.86 (4)Al20—Al26A—Al26Axix127.49 (5)
Al20—Al12A—Al20ii36.28 (10)Ru8xviii—Al26A—Al26Axix53.64 (11)
Al12Bii—Al12A—Ru7A176.6 (15)Al21—Al26A—Al26Axix108.38 (7)
Al12B—Al12A—Ru7A75.3 (15)Al26A—Si26B—Al20164.8 (5)
Al21iii—Al12A—Ru7A110.57 (6)Al26A—Si26B—Ru8112.4 (4)
Al21i—Al12A—Ru7A53.57 (3)Al20—Si26B—Ru880.0 (2)
Al21ii—Al12A—Ru7A110.57 (6)Al26A—Si26B—Ru295.3 (4)
Al21—Al12A—Ru7A53.57 (3)Al20—Si26B—Ru270.59 (14)
Ru2i—Al12A—Ru7A110.196 (14)Ru8—Si26B—Ru2148.4 (3)
Ru2—Al12A—Ru7A110.197 (14)Al26A—Si26B—Ru8xviii105.6 (4)
Al20—Al12A—Ru7A111.24 (6)Al20—Si26B—Ru8xviii86.8 (2)
Al20ii—Al12A—Ru7A147.52 (8)Ru8—Si26B—Ru8xviii6.87 (7)
Al12A—Al12B—Al12Bii36.0 (15)Ru2—Si26B—Ru8xviii154.5 (3)
Al12A—Al12B—Al20133 (2)Al26A—Si26B—Al17Axx76.3 (4)
Al12Bii—Al12B—Al2096.6 (7)Al20—Si26B—Al17Axx117.6 (2)
Al12A—Al12B—Al21i96.1 (10)Ru8—Si26B—Al17Axx68.57 (8)
Al12Bii—Al12B—Al21i114.2 (6)Ru2—Si26B—Al17Axx135.85 (12)
Al20—Al12B—Al21i109.6 (8)Ru8xviii—Si26B—Al17Axx65.16 (8)
Al12A—Al12B—Al2196.1 (10)Al26A—Si26B—Ru967.6 (4)
Al12Bii—Al12B—Al21114.2 (6)Al20—Si26B—Ru9111.86 (15)
Al20—Al12B—Al21109.6 (8)Ru8—Si26B—Ru9129.86 (10)
Al21i—Al12B—Al21111.5 (8)Ru2—Si26B—Ru973.78 (8)
Al12A—Al12B—Ru2i92.4 (10)Ru8xviii—Si26B—Ru9127.65 (10)
Al12Bii—Al12B—Ru2i76.2 (6)Al17Axx—Si26B—Ru962.85 (9)
Al20—Al12B—Ru2i68.2 (5)Al26A—Si26B—Si13117.4 (4)
Al21i—Al12B—Ru2i61.39 (6)Al20—Si26B—Si1359.77 (13)
Al21—Al12B—Ru2i169.5 (12)Ru8—Si26B—Si13117.9 (2)
Al12A—Al12B—Ru292.4 (10)Ru2—Si26B—Si1355.64 (7)
Al12Bii—Al12B—Ru276.2 (6)Ru8xviii—Si26B—Si13122.8 (2)
Al20—Al12B—Ru268.2 (5)Al17Axx—Si26B—Si1389.50 (8)
Al21i—Al12B—Ru2169.5 (12)Ru9—Si26B—Si1352.12 (5)
Al21—Al12B—Ru261.39 (6)Al26A—Si26B—Al2169.0 (4)
Ru2i—Al12B—Ru2124.4 (8)Al20—Si26B—Al2197.72 (13)
Al12A—Al12B—Al20ii92.1 (17)Ru8—Si26B—Al21118.41 (9)
Al12Bii—Al12B—Al20ii56.1 (6)Ru2—Si26B—Al2156.84 (6)
Al20—Al12B—Al20ii40.5 (3)Ru8xviii—Si26B—Al21117.29 (9)
Al21i—Al12B—Al20ii123.3 (4)Al17Axx—Si26B—Al21144.5 (3)
Al21—Al12B—Al20ii123.3 (4)Ru9—Si26B—Al21108.29 (15)
Ru2i—Al12B—Al20ii62.3 (4)Si13—Si26B—Al21112.48 (9)
Ru2—Al12B—Al20ii62.3 (4)Al26A—Si26B—Al12B119.2 (5)
Al12A—Al12B—Ru7A89.5 (16)Al20—Si26B—Al12B48.4 (3)
Al12Bii—Al12B—Ru7A125.5 (6)Ru8—Si26B—Al12B96.0 (4)
Al20—Al12B—Ru7A138.0 (12)Ru2—Si26B—Al12B55.7 (4)
Al21i—Al12B—Ru7A56.5 (4)Ru8xviii—Si26B—Al12B100.4 (4)
Al21—Al12B—Ru7A56.5 (4)Al17Axx—Si26B—Al12B162.3 (4)
Ru2i—Al12B—Ru7A117.7 (4)Ru9—Si26B—Al12B129.1 (4)
Ru2—Al12B—Ru7A117.7 (4)Si13—Si26B—Al12B90.3 (4)
Al20ii—Al12B—Ru7A178.5 (12)Al21—Si26B—Al12B50.2 (3)
Al12A—Al12B—Si26Bi144.6 (7)Al28Ci—Al27—Al28Cxxiv180 (3)
Al12Bii—Al12B—Si26Bi123.9 (4)Al28Ci—Al27—Al28Bi8.0 (11)
Al20—Al12B—Si26Bi47.2 (5)Al28Cxxiv—Al27—Al28Bi172.0 (11)
Al21i—Al12B—Si26Bi63.5 (4)Al28Ci—Al27—Al28Bxxiv172.0 (11)
Al21—Al12B—Si26Bi117.8 (10)Al28Cxxiv—Al27—Al28Bxxiv8.0 (11)
Ru2i—Al12B—Si26Bi52.9 (3)Al28Bi—Al27—Al28Bxxiv180.0 (13)
Ru2—Al12B—Si26Bi111.9 (9)Al28Ci—Al27—Ru5xxviii106.3 (11)
Al20ii—Al12B—Si26Bi78.3 (6)Al28Cxxiv—Al27—Ru5xxviii73.7 (11)
Ru7A—Al12B—Si26Bi100.5 (7)Al28Bi—Al27—Ru5xxviii114.3 (5)
Al12A—Al12B—Si26B144.6 (7)Al28Bxxiv—Al27—Ru5xxviii65.7 (5)
Al12Bii—Al12B—Si26B123.9 (4)Al28Ci—Al27—Ru573.7 (11)
Al20—Al12B—Si26B47.2 (5)Al28Cxxiv—Al27—Ru5106.3 (11)
Al21i—Al12B—Si26B117.8 (10)Al28Bi—Al27—Ru565.7 (5)
Al21—Al12B—Si26B63.5 (4)Al28Bxxiv—Al27—Ru5114.3 (5)
Ru2i—Al12B—Si26B111.9 (9)Ru5xxviii—Al27—Ru5180.0
Ru2—Al12B—Si26B52.9 (3)Al28Ci—Al27—Al23xxviii101.3 (5)
Al20ii—Al12B—Si26B78.3 (6)Al28Cxxiv—Al27—Al23xxviii78.7 (5)
Ru7A—Al12B—Si26B100.5 (7)Al28Bi—Al27—Al23xxviii105.0 (2)
Si26Bi—Al12B—Si26B67.0 (6)Al28Bxxiv—Al27—Al23xxviii75.0 (2)
Ru9—Si13—Ru9iii79.25 (3)Ru5xxviii—Al27—Al23xxviii59.495 (14)
Ru9—Si13—Ru1133.97 (2)Ru5—Al27—Al23xxviii120.505 (14)
Ru9iii—Si13—Ru1133.97 (2)Al28Ci—Al27—Al23iii78.7 (5)
Ru9—Si13—Ru278.47 (2)Al28Cxxiv—Al27—Al23iii101.3 (5)
Ru9iii—Si13—Ru278.46 (2)Al28Bi—Al27—Al23iii75.0 (2)
Ru1—Si13—Ru2130.71 (4)Al28Bxxiv—Al27—Al23iii105.0 (2)
Ru9—Si13—Al20ii138.45 (5)Ru5xxviii—Al27—Al23iii120.505 (14)
Ru9iii—Si13—Al20ii108.59 (4)Ru5—Al27—Al23iii59.495 (14)
Ru1—Si13—Al20ii69.62 (4)Al23xxviii—Al27—Al23iii61.41 (3)
Ru2—Si13—Al20ii64.15 (4)Al28Ci—Al27—Al23xxiii101.3 (5)
Ru9—Si13—Al20108.59 (4)Al28Cxxiv—Al27—Al23xxiii78.7 (5)
Ru9iii—Si13—Al20138.44 (5)Al28Bi—Al27—Al23xxiii105.0 (2)
Ru1—Si13—Al2069.62 (4)Al28Bxxiv—Al27—Al23xxiii75.0 (2)
Ru2—Si13—Al2064.15 (4)Ru5xxviii—Al27—Al23xxiii59.495 (14)
Al20ii—Si13—Al2039.36 (10)Ru5—Al27—Al23xxiii120.505 (14)
Ru9—Si13—Al2568.38 (3)Al23xxviii—Al27—Al23xxiii118.59 (3)
Ru9iii—Si13—Al25109.91 (4)Al23iii—Al27—Al23xxiii180.00 (4)
Ru1—Si13—Al2569.91 (3)Al28Ci—Al27—Al2378.7 (5)
Ru2—Si13—Al25142.93 (3)Al28Cxxiv—Al27—Al23101.3 (5)
Al20ii—Si13—Al25136.87 (5)Al28Bi—Al27—Al2375.0 (2)
Al20—Si13—Al25110.82 (5)Al28Bxxiv—Al27—Al23105.0 (2)
Ru9—Si13—Al25iii109.91 (4)Ru5xxviii—Al27—Al23120.505 (14)
Ru9iii—Si13—Al25iii68.38 (3)Ru5—Al27—Al2359.495 (14)
Ru1—Si13—Al25iii69.91 (3)Al23xxviii—Al27—Al23180.0
Ru2—Si13—Al25iii142.93 (3)Al23iii—Al27—Al23118.59 (3)
Al20ii—Si13—Al25iii110.82 (5)Al23xxiii—Al27—Al2361.41 (3)
Al20—Si13—Al25iii136.87 (5)Al28Ci—Al27—Al28Ai18.1 (10)
Al25—Si13—Al25iii67.53 (4)Al28Cxxiv—Al27—Al28Ai161.9 (10)
Ru9—Si13—Si26B61.75 (12)Al28Bi—Al27—Al28Ai11.3 (4)
Ru9iii—Si13—Si26B122.39 (11)Al28Bxxiv—Al27—Al28Ai168.7 (4)
Ru1—Si13—Si26B103.17 (11)Ru5xxviii—Al27—Al28Ai122.36 (4)
Ru2—Si13—Si26B54.62 (6)Ru5—Al27—Al28Ai57.64 (4)
Al20ii—Si13—Si26B81.32 (11)Al23xxviii—Al27—Al28Ai115.61 (5)
Al20—Si13—Si26B46.86 (13)Al23iii—Al27—Al28Ai78.24 (5)
Al25—Si13—Si26B93.92 (6)Al23xxiii—Al27—Al28Ai101.76 (5)
Al25iii—Si13—Si26B161.39 (6)Al23—Al27—Al28Ai64.39 (5)
Ru9—Si13—Si26Biii122.39 (11)Al28Ci—Al27—Al28Axxiv161.9 (10)
Ru9iii—Si13—Si26Biii61.75 (12)Al28Cxxiv—Al27—Al28Axxiv18.1 (10)
Ru1—Si13—Si26Biii103.17 (11)Al28Bi—Al27—Al28Axxiv168.7 (4)
Ru2—Si13—Si26Biii54.62 (6)Al28Bxxiv—Al27—Al28Axxiv11.3 (4)
Al20ii—Si13—Si26Biii46.86 (13)Ru5xxviii—Al27—Al28Axxiv57.64 (4)
Al20—Si13—Si26Biii81.32 (11)Ru5—Al27—Al28Axxiv122.36 (4)
Al25—Si13—Si26Biii161.40 (6)Al23xxviii—Al27—Al28Axxiv64.39 (5)
Al25iii—Si13—Si26Biii93.93 (6)Al23iii—Al27—Al28Axxiv101.76 (5)
Si26B—Si13—Si26Biii104.56 (11)Al23xxiii—Al27—Al28Axxiv78.24 (5)
Ru9—Al14—Ru9iii74.75 (2)Al23—Al27—Al28Axxiv115.61 (5)
Ru9—Al14—Ru4128.03 (3)Al28Ai—Al27—Al28Axxiv180.00 (7)
Ru9iii—Al14—Ru4128.03 (3)Al28Aiii—Al28A—Al28B67.3 (6)
Ru9—Al14—Si6xii107.23 (3)Al28Aiii—Al28A—Al28C76.1 (3)
Ru9iii—Al14—Si6xii107.23 (3)Al28B—Al28A—Al28C9.6 (7)
Ru4—Al14—Si6xii107.28 (4)Al28Aiii—Al28A—Si17B79.04 (15)
Ru9—Al14—Al2565.59 (2)Al28B—Al28A—Si17B133.7 (9)
Ru9iii—Al14—Al25104.13 (4)Al28C—Al28A—Si17B142.3 (8)
Ru4—Al14—Al2563.62 (3)Al28Aiii—Al28A—Ru5i81.43 (6)
Si6xii—Al14—Al25144.44 (3)Al28B—Al28A—Ru5i68.4 (9)
Ru9—Al14—Al25iii104.13 (4)Al28C—Al28A—Ru5i65.1 (8)
Ru9iii—Al14—Al25iii65.60 (2)Si17B—Al28A—Ru5i137.7 (4)
Ru4—Al14—Al25iii63.62 (3)Al28Aiii—Al28A—Al17A81.59 (5)
Si6xii—Al14—Al25iii144.44 (3)Al28B—Al28A—Al17A132.4 (9)
Al25—Al14—Al25iii65.56 (5)Al28C—Al28A—Al17A140.4 (8)
Ru9—Al14—Al23ix110.764 (16)Si17B—Al28A—Al17A5.0 (4)
Ru9iii—Al14—Al23ix168.52 (4)Ru5i—Al28A—Al17A142.71 (9)
Ru4—Al14—Al23ix57.15 (2)Al28Aiii—Al28A—Al25v140.30 (5)
Si6xii—Al14—Al23ix61.80 (3)Al28B—Al28A—Al25v113.0 (7)
Al25—Al14—Al23ix87.35 (3)Al28C—Al28A—Al25v108.9 (6)
Al25iii—Al14—Al23ix120.77 (4)Si17B—Al28A—Al25v74.4 (3)
Ru9—Al14—Al23viii168.52 (4)Ru5i—Al28A—Al25v137.33 (10)
Ru9iii—Al14—Al23viii110.764 (16)Al17A—Al28A—Al25v70.04 (6)
Ru4—Al14—Al23viii57.15 (2)Al28Aiii—Al28A—Ru381.66 (5)
Si6xii—Al14—Al23viii61.80 (3)Al28B—Al28A—Ru380.5 (9)
Al25—Al14—Al23viii120.77 (4)Al28C—Al28A—Ru385.1 (9)
Al25iii—Al14—Al23viii87.35 (3)Si17B—Al28A—Ru363.5 (4)
Al23ix—Al14—Al23viii62.02 (4)Ru5i—Al28A—Ru3148.43 (9)
Ru9—Al14—Al15i58.96 (2)Al17A—Al28A—Ru359.38 (5)
Ru9iii—Al14—Al15i58.95 (2)Al25v—Al28A—Ru360.26 (5)
Ru4—Al14—Al15i169.63 (4)Al28Aiii—Al28A—Al22i113.62 (5)
Si6xii—Al14—Al15i62.36 (3)Al28B—Al28A—Al22i127.4 (10)
Al25—Al14—Al15i124.44 (3)Al28C—Al28A—Al22i121.4 (8)
Al25iii—Al14—Al15i124.44 (3)Si17B—Al28A—Al22i94.4 (3)
Al23ix—Al14—Al15i114.47 (4)Ru5i—Al28A—Al22i60.36 (4)
Al23viii—Al14—Al15i114.46 (4)Al17A—Al28A—Al22i97.35 (7)
Ru9—Al14—Al22viii115.76 (3)Al25v—Al28A—Al22i97.47 (8)
Ru9iii—Al14—Al22viii55.318 (17)Ru3—Al28A—Al22i151.18 (9)
Ru4—Al14—Al22viii114.64 (2)Al28Aiii—Al28A—Al27xxix82.37 (5)
Si6xii—Al14—Al22viii61.01 (2)Al28B—Al28A—Al27xxix23.5 (9)
Al25—Al14—Al22viii154.49 (4)Al28C—Al28A—Al27xxix15.9 (8)
Al25iii—Al14—Al22viii90.42 (3)Si17B—Al28A—Al27xxix157.0 (2)
Al23ix—Al14—Al22viii113.65 (4)Ru5i—Al28A—Al27xxix50.81 (4)
Al23viii—Al14—Al22viii63.22 (2)Al17A—Al28A—Al27xxix155.92 (9)
Al15i—Al14—Al22viii61.44 (2)Al25v—Al28A—Al27xxix113.47 (8)
Ru9—Al14—Al22ix55.319 (17)Ru3—Al28A—Al27xxix100.54 (6)
Ru9iii—Al14—Al22ix115.76 (3)Al22i—Al28A—Al27xxix105.50 (6)
Ru4—Al14—Al22ix114.64 (2)Al28C—Al28B—Al28A155.5 (14)
Si6xii—Al14—Al22ix61.01 (2)Al28C—Al28B—Al28Aiii155.5 (14)
Al25—Al14—Al22ix90.42 (3)Al28A—Al28B—Al28Aiii45.5 (13)
Al25iii—Al14—Al22ix154.49 (4)Al28C—Al28B—Al27xxix18 (2)
Al23ix—Al14—Al22ix63.22 (2)Al28A—Al28B—Al27xxix145.2 (11)
Al23viii—Al14—Al22ix113.65 (4)Al28Aiii—Al28B—Al27xxix145.2 (11)
Al15i—Al14—Al22ix61.44 (2)Al28C—Al28B—Ru5i82 (3)
Al22viii—Al14—Al22ix111.52 (4)Al28A—Al28B—Ru5i88.9 (10)
Si17B—Al15—Ru9iv63.07 (3)Al28Aiii—Al28B—Ru5i88.9 (10)
Si17B—Al15—Ru9v63.07 (3)Al27xxix—Al28B—Ru5i64.0 (6)
Ru9iv—Al15—Ru9v125.94 (4)Al28C—Al28B—Ru3112 (3)
Si17B—Al15—Ru9ii132.0 (4)Al28A—Al28B—Ru378.0 (11)
Ru9iv—Al15—Ru9ii76.250 (11)Al28Aiii—Al28B—Ru378.0 (11)
Ru9v—Al15—Ru9ii144.13 (4)Al27xxix—Al28B—Ru3130.2 (10)
Si17B—Al15—Ru9i132.0 (4)Ru5i—Al28B—Ru3165.8 (12)
Ru9iv—Al15—Ru9i144.13 (4)Al28C—Al28B—Al24v66 (2)
Ru9v—Al15—Ru9i76.250 (11)Al28A—Al28B—Al24v106.4 (7)
Ru9ii—Al15—Ru9i72.07 (3)Al28Aiii—Al28B—Al24v133.2 (14)
Si17B—Al15—Al17A13.5 (5)Al27xxix—Al28B—Al24v80.8 (8)
Ru9iv—Al15—Al17A64.43 (2)Ru5i—Al28B—Al24v133.1 (8)
Ru9v—Al15—Al17A64.43 (2)Ru3—Al28B—Al24v57.5 (3)
Ru9ii—Al15—Al17A139.19 (3)Al28C—Al28B—Al24iv66 (2)
Ru9i—Al15—Al17A139.19 (3)Al28A—Al28B—Al24iv133.2 (14)
Si17B—Al15—Al14i167.7 (6)Al28Aiii—Al28B—Al24iv106.4 (7)
Ru9iv—Al15—Al14i116.772 (19)Al27xxix—Al28B—Al24iv80.8 (8)
Ru9v—Al15—Al14i116.772 (19)Ru5i—Al28B—Al24iv133.1 (8)
Ru9ii—Al15—Al14i56.12 (2)Ru3—Al28B—Al24iv57.5 (3)
Ru9i—Al15—Al14i56.12 (2)Al24v—Al28B—Al24iv62.9 (4)
Al17A—Al15—Al14i154.18 (7)Al28C—Al28B—Si17B167 (3)
Si17B—Al15—Si6xxvi111.0 (6)Al28A—Al28B—Si17B31.4 (8)
Ru9iv—Al15—Si6xxvi101.37 (2)Al28Aiii—Al28B—Si17B31.4 (8)
Ru9v—Al15—Si6xxvi101.37 (2)Al27xxix—Al28B—Si17B175.2 (9)
Ru9ii—Al15—Si6xxvi100.57 (3)Ru5i—Al28B—Si17B111.1 (9)
Ru9i—Al15—Si6xxvi100.57 (3)Ru3—Al28B—Si17B54.6 (6)
Al17A—Al15—Si6xxvi97.50 (6)Al24v—Al28B—Si17B103.3 (6)
Al14i—Al15—Si6xxvi56.68 (3)Al24iv—Al28B—Si17B103.3 (6)
Si17B—Al15—Al22ii78.3 (5)Al28C—Al28B—Al23ii74.0 (15)
Ru9iv—Al15—Al22ii55.306 (19)Al28A—Al28B—Al23ii119.0 (11)
Ru9v—Al15—Al22ii108.83 (3)Al28Aiii—Al28B—Al23ii82.0 (5)
Ru9ii—Al15—Al22ii57.28 (2)Al27xxix—Al28B—Al23ii65.0 (4)
Ru9i—Al15—Al22ii92.78 (3)Ru5i—Al28B—Al23ii56.2 (3)
Al17A—Al15—Al22ii89.97 (5)Ru3—Al28B—Al23ii126.0 (3)
Al14i—Al15—Al22ii112.18 (4)Al24v—Al28B—Al23ii134.4 (9)
Si6xxvi—Al15—Al22ii149.13 (2)Al24iv—Al28B—Al23ii81.8 (3)
Si17B—Al15—Al22i78.3 (5)Si17B—Al28B—Al23ii112.8 (6)
Ru9iv—Al15—Al22i108.83 (3)Al28C—Al28B—Al23i74.0 (15)
Ru9v—Al15—Al22i55.306 (19)Al28A—Al28B—Al23i82.0 (5)
Ru9ii—Al15—Al22i92.78 (3)Al28Aiii—Al28B—Al23i119.0 (11)
Ru9i—Al15—Al22i57.28 (2)Al27xxix—Al28B—Al23i65.0 (4)
Al17A—Al15—Al22i89.97 (5)Ru5i—Al28B—Al23i56.2 (3)
Al14i—Al15—Al22i112.18 (4)Ru3—Al28B—Al23i126.0 (3)
Si6xxvi—Al15—Al22i149.13 (2)Al24v—Al28B—Al23i81.8 (3)
Al22ii—Al15—Al22i60.09 (3)Al24iv—Al28B—Al23i134.4 (9)
Si17B—Al15—Al22v114.0 (3)Si17B—Al28B—Al23i112.8 (6)
Ru9iv—Al15—Al22v159.05 (4)Al23ii—Al28B—Al23i107.6 (6)
Ru9v—Al15—Al22v57.609 (15)Al28B—Al28C—Al27xxix154 (4)
Ru9ii—Al15—Al22v112.97 (3)Al28B—Al28C—Al28A14.9 (8)
Ru9i—Al15—Al22v54.534 (18)Al27xxix—Al28C—Al28A146.0 (16)
Al17A—Al15—Al22v107.73 (4)Al28B—Al28C—Al28Aiii14.9 (8)
Al14i—Al15—Al22v61.21 (2)Al27xxix—Al28C—Al28Aiii146.0 (16)
Si6xxvi—Al15—Al22v59.21 (2)Al28A—Al28C—Al28Aiii27.7 (7)
Al22ii—Al15—Al22v145.63 (3)Al28B—Al28C—Ru5i83 (3)
Al22i—Al15—Al22v89.97 (2)Al27xxix—Al28C—Ru5i71.5 (10)
Si17B—Al15—Al22iv114.0 (3)Al28A—Al28C—Ru5i77.5 (11)
Ru9iv—Al15—Al22iv57.609 (15)Al28Aiii—Al28C—Ru5i77.5 (11)
Ru9v—Al15—Al22iv159.05 (4)Al28B—Al28C—Al24v101 (2)
Ru9ii—Al15—Al22iv54.534 (18)Al27xxix—Al28C—Al24v100.7 (14)
Ru9i—Al15—Al22iv112.97 (3)Al28A—Al28C—Al24v96.8 (10)
Al17A—Al15—Al22iv107.73 (4)Al28Aiii—Al28C—Al24v112.8 (14)
Al14i—Al15—Al22iv61.21 (2)Ru5i—Al28C—Al24v145.4 (4)
Si6xxvi—Al15—Al22iv59.21 (2)Al28B—Al28C—Al24iv101 (2)
Al22ii—Al15—Al22iv89.97 (2)Al27xxix—Al28C—Al24iv100.7 (14)
Al22i—Al15—Al22iv145.63 (3)Al28A—Al28C—Al24iv112.8 (14)
Al22v—Al15—Al22iv111.16 (4)Al28Aiii—Al28C—Al24iv96.8 (10)
Ru7Bxxv—Al16—Ru7Bxi77.0 (6)Ru5i—Al28C—Al24iv145.4 (4)
Ru7Bxxv—Al16—Ru4136.1 (2)Al24v—Al28C—Al24iv68.4 (6)
Ru7Bxi—Al16—Ru4136.1 (2)Al28B—Al28C—Al28Cvi154 (4)
Ru7Bxxv—Al16—Ru7Axxv4.1 (4)Al27xxix—Al28C—Al28Cvi0.0 (8)
Ru7Bxi—Al16—Ru7Axxv79.3 (3)Al28A—Al28C—Al28Cvi146.0 (16)
Ru4—Al16—Ru7Axxv135.94 (4)Al28Aiii—Al28C—Al28Cvi146.0 (16)
Ru7Bxxv—Al16—Ru7Axi79.3 (3)Ru5i—Al28C—Al28Cvi71.5 (10)
Ru7Bxi—Al16—Ru7Axi4.1 (4)Al24v—Al28C—Al28Cvi100.7 (14)
Ru4—Al16—Ru7Axi135.94 (4)Al24iv—Al28C—Al28Cvi100.7 (14)
Ru7Axxv—Al16—Ru7Axi81.43 (11)Al28B—Al28C—Al23ii93.7 (16)
Ru7Bxxv—Al16—Al2470.8 (3)Al27xxix—Al28C—Al23ii72.8 (7)
Ru7Bxi—Al16—Al24144.9 (4)Al28A—Al28C—Al23ii102.4 (11)
Ru4—Al16—Al2467.90 (3)Al28Aiii—Al28C—Al23ii79.2 (6)
Ru7Axxv—Al16—Al2469.37 (4)Ru5i—Al28C—Al23ii58.0 (4)
Ru7Axi—Al16—Al24148.30 (9)Al24v—Al28C—Al23ii153.6 (10)
Ru7Bxxv—Al16—Al24iii144.9 (4)Al24iv—Al28C—Al23ii87.4 (2)
Ru7Bxi—Al16—Al24iii70.8 (3)Al28Cvi—Al28C—Al23ii72.8 (7)
Ru4—Al16—Al24iii67.90 (3)Al28B—Al28C—Al23i93.7 (16)
Ru7Axxv—Al16—Al24iii148.30 (9)Al27xxix—Al28C—Al23i72.8 (7)
Ru7Axi—Al16—Al24iii69.37 (4)Al28A—Al28C—Al23i79.2 (6)
Al24—Al16—Al24iii134.53 (5)Al28Aiii—Al28C—Al23i102.4 (11)
Ru7Bxxv—Al16—Si6101.2 (5)Ru5i—Al28C—Al23i58.0 (4)
Ru7Bxi—Al16—Si6101.2 (5)Al24v—Al28C—Al23i87.4 (2)
Ru4—Al16—Si698.54 (4)Al24iv—Al28C—Al23i153.6 (10)
Ru7Axxv—Al16—Si697.56 (9)Al28Cvi—Al28C—Al23i72.8 (7)
Ru7Axi—Al16—Si697.56 (9)Al23ii—Al28C—Al23i113.7 (8)
Al24—Al16—Si698.22 (3)Al28B—Al28C—Ru356 (3)
Al24iii—Al16—Si698.22 (3)Al27xxix—Al28C—Ru3149.8 (17)
Ru7Bxxv—Al16—Al21x57.5 (5)Al28A—Al28C—Ru362.5 (10)
Ru7Bxi—Al16—Al21x114.2 (3)Al28Aiii—Al28C—Ru362.5 (10)
Ru4—Al16—Al21x109.03 (3)Ru5i—Al28C—Ru3138.7 (15)
Ru7Axxv—Al16—Al21x53.48 (9)Al24v—Al28C—Ru355.5 (5)
Ru7Axi—Al16—Al21x113.39 (5)Al24iv—Al28C—Ru355.5 (5)
Al24—Al16—Al21x58.04 (2)Al28Cvi—Al28C—Ru3149.8 (17)
Al24iii—Al16—Al21x150.87 (5)Al23ii—Al28C—Ru3119.1 (7)
Si6—Al16—Al21x52.86 (3)Al23i—Al28C—Ru3119.1 (7)
Ru7Bxxv—Al16—Al21xi114.2 (3)Al28B—Al28C—Ru5xxix159 (3)
Ru7Bxi—Al16—Al21xi57.5 (5)Al27xxix—Al28C—Ru5xxix47.4 (10)
Ru4—Al16—Al21xi109.03 (3)Al28A—Al28C—Ru5xxix158.9 (10)
Ru7Axxv—Al16—Al21xi113.39 (5)Al28Aiii—Al28C—Ru5xxix158.9 (10)
Ru7Axi—Al16—Al21xi53.48 (9)Ru5i—Al28C—Ru5xxix118.9 (13)
Al24—Al16—Al21xi150.87 (5)Al24v—Al28C—Ru5xxix62.1 (7)
Al24iii—Al16—Al21xi58.04 (2)Al24iv—Al28C—Ru5xxix62.1 (7)
Si6—Al16—Al21xi52.86 (3)Al28Cvi—Al28C—Ru5xxix47.4 (10)
Al21x—Al16—Al21xi99.01 (5)Al23ii—Al28C—Ru5xxix97.9 (8)
Si17B—Al17A—Ru374.0 (11)Al23i—Al28C—Ru5xxix97.9 (8)
Si17B—Al17A—Al28Aiii16.0 (9)Ru3—Al28C—Ru5xxix102.3 (7)
Symmetry codes: (i) x, y, z+1/2; (ii) x, y, z+1/2; (iii) x, y, z; (iv) x1/2, y+1/2, z+1/2; (v) x+1/2, y+1/2, z+1/2; (vi) x, y, z+1; (vii) x+1/2, y+1/2, z+1; (viii) x1/2, y+1/2, z; (ix) x+1/2, y+1/2, z; (x) x+1/2, y+1/2, z; (xi) x1/2, y+1/2, z; (xii) x, y+1, z; (xiii) x, y+1, z1/2; (xiv) x+1/2, y1/2, z+1/2; (xv) x+1/2, y1/2, z; (xvi) x+1/2, y1/2, z+1/2; (xvii) x+1/2, y1/2, z; (xviii) x+1, y, z+1/2; (xix) x+1, y, z; (xx) x+1/2, y+1/2, z1/2; (xxi) x1/2, y1/2, z; (xxii) x1/2, y1/2, z+1/2; (xxiii) x, y, z; (xxiv) x, y, z1/2; (xxv) x+1/2, y+1/2, z+1/2; (xxvi) x, y+1, z+1/2; (xxvii) x+1/2, y+1/2, z; (xxviii) x, y, z; (xxix) x, y, z+1/2.
Docosaaluminium nonaruthenium decasilicon (II) top
Crystal data top
~Ru9(Al0.70Si0.30)32Dx = 4.777 Mg m3
Mr = 1783.65Mo Kα radiation, λ = 0.71073 Å
Trigonal, R3Cell parameters from 10605 reflections
a = 10.4479 (2) Åθ = 3.9–30.7°
c = 19.6774 (4) ŵ = 6.59 mm1
V = 1860.17 (7) Å3T = 296 K
Z = 3Irregular, metallic light silver
F(000) = 2436.840.03 × 0.03 × 0.03 mm
Data collection top
XtaLAB Synergy R, HyPix
diffractometer
1193 independent reflections
Radiation source: micro-focus sealed X-ray tube, Mova (Mo) X-ray Source1127 reflections with I > 2σ(I)
Mirror monochromatorRint = 0.027
Detector resolution: 10.0000 pixels mm-1θmax = 30.8°, θmin = 3.9°
ω scansh = 1414
Absorption correction: gaussian
(CrysAlisPro; Matsumoto et al., 2021)
k = 1414
Tmin = 0.868, Tmax = 0.879l = 2728
14255 measured reflections
Refinement top
Refinement on F2Primary atom site location: dual
Least-squares matrix: full w = 1/[σ2(Fo2) + (0.0111P)2 + 0.5812P]
where P = (Fo2 + 2Fc2)/3
R[F2 > 2σ(F2)] = 0.013(Δ/σ)max = 0.002
wR(F2) = 0.024Δρmax = 0.45 e Å3
S = 1.08Δρmin = 0.53 e Å3
1193 reflectionsExtinction correction: SHELXL-2019/3 (Sheldrick, 2015b), Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4
66 parametersExtinction coefficient: 0.000262 (16)
2 restraints
Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Ru10.0000000.0000000.5000000.00463 (7)
Ru20.0000000.0000000.28833 (2)0.00519 (6)
Ru30.24368 (2)0.24916 (2)0.09171 (2)0.00467 (5)
Al40.0000000.0000000.12554 (5)0.01068 (17)
Si50.06845 (5)0.25394 (5)0.29541 (2)0.00880 (9)
Al60.22915 (5)0.16512 (5)0.21432 (2)0.0079 (2)0.58 (4)
Si60.22915 (5)0.16512 (5)0.21432 (2)0.0079 (2)0.42 (4)
Al70.00143 (5)0.21088 (5)0.03958 (2)0.0076 (2)0.82 (4)
Si70.00143 (5)0.21088 (5)0.03958 (2)0.0076 (2)0.18 (4)
Al80.16504 (5)0.12448 (5)0.39021 (2)0.00948 (10)
Al90.12627 (6)0.37148 (6)0.16275 (2)0.01084 (11)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ru10.00464 (9)0.00464 (9)0.00459 (13)0.00232 (5)0.0000.000
Ru20.00444 (7)0.00444 (7)0.00667 (10)0.00222 (4)0.0000.000
Ru30.00486 (7)0.00394 (7)0.00529 (7)0.00224 (5)0.00054 (4)0.00006 (4)
Al40.0066 (2)0.0066 (2)0.0189 (4)0.00329 (12)0.0000.000
Si50.0109 (2)0.0054 (2)0.0101 (2)0.00405 (18)0.00401 (16)0.00003 (16)
Al60.0076 (3)0.0096 (3)0.0073 (3)0.0048 (2)0.00127 (16)0.00249 (17)
Si60.0076 (3)0.0096 (3)0.0073 (3)0.0048 (2)0.00127 (16)0.00249 (17)
Al70.0059 (3)0.0102 (3)0.0061 (3)0.0036 (2)0.00001 (16)0.00019 (17)
Si70.0059 (3)0.0102 (3)0.0061 (3)0.0036 (2)0.00001 (16)0.00019 (17)
Al80.0074 (2)0.0088 (2)0.0076 (2)0.00063 (19)0.00180 (18)0.00055 (17)
Al90.0098 (2)0.0097 (2)0.0121 (2)0.0042 (2)0.00506 (18)0.00117 (19)
Geometric parameters (Å, º) top
Ru1—Al8i2.6625 (5)Ru3—Al7xv2.6119 (5)
Ru1—Al8ii2.6625 (5)Ru3—Al42.6597 (3)
Ru1—Al8iii2.6625 (5)Ru3—Al7ii2.6643 (5)
Ru1—Al8iv2.6626 (5)Al4—Al6iv2.7622 (7)
Ru1—Al8v2.6626 (5)Al4—Al6ii2.7622 (7)
Ru1—Al82.6626 (5)Al4—Al62.7622 (7)
Ru1—Al9vi2.7432 (5)Al4—Al72.7718 (7)
Ru1—Al9vii2.7432 (5)Al4—Al7iv2.7718 (7)
Ru1—Al9viii2.7432 (5)Al4—Al7ii2.7718 (7)
Ru1—Al9ix2.7432 (5)Si5—Si5ix2.4056 (9)
Ru1—Al9x2.7433 (5)Si5—Al8ix2.6749 (6)
Ru1—Al9xi2.7433 (5)Si5—Al6iv2.7560 (6)
Ru2—Si5ii2.3817 (4)Si5—Al82.7736 (6)
Ru2—Si52.3817 (4)Si5—Al62.7899 (6)
Ru2—Si5iv2.3817 (4)Si5—Al92.8188 (7)
Ru2—Al82.5380 (5)Si5—Al8iv2.8319 (7)
Ru2—Al8ii2.5380 (5)Al6—Al7xii2.6531 (6)
Ru2—Al8iv2.5381 (5)Al6—Al9xii2.8394 (7)
Ru2—Al6ii2.5880 (5)Al6—Al6xiv2.8614 (9)
Ru2—Al6iv2.5880 (5)Al7—Al7xvi2.6922 (6)
Ru2—Al62.5881 (5)Al7—Al7xv2.6922 (6)
Ru3—Si5xii2.4214 (4)Al7—Al92.8639 (7)
Ru3—Al8xiii2.5175 (5)Al8—Al9vii2.6172 (7)
Ru3—Al62.5459 (5)Al8—Al8ii2.6956 (8)
Ru3—Al72.5702 (5)Al8—Al8iv2.6957 (8)
Ru3—Al9xii2.5708 (5)Al8—Al9ix2.7562 (7)
Ru3—Al92.5806 (5)Al9—Al9xii2.7465 (5)
Ru3—Al6xiv2.6110 (5)Al9—Al9xvii2.7465 (5)
Al8i—Ru1—Al8ii180.0Si5ix—Si5—Al8ix65.93 (2)
Al8i—Ru1—Al8iii60.824 (17)Ru3xvii—Si5—Al8ix58.956 (14)
Al8ii—Ru1—Al8iii119.176 (17)Ru2—Si5—Al6iv59.969 (14)
Al8i—Ru1—Al8iv119.176 (17)Si5ix—Si5—Al6iv177.02 (3)
Al8ii—Ru1—Al8iv60.824 (17)Ru3xvii—Si5—Al6iv60.159 (14)
Al8iii—Ru1—Al8iv119.176 (17)Al8ix—Si5—Al6iv115.87 (2)
Al8i—Ru1—Al8v60.824 (17)Ru2—Si5—Al858.394 (14)
Al8ii—Ru1—Al8v119.176 (17)Si5ix—Si5—Al861.71 (2)
Al8iii—Ru1—Al8v60.824 (17)Ru3xvii—Si5—Al8159.94 (2)
Al8iv—Ru1—Al8v180.000 (12)Al8ix—Si5—Al8127.637 (19)
Al8i—Ru1—Al8119.177 (17)Al6iv—Si5—Al8116.45 (2)
Al8ii—Ru1—Al860.823 (17)Ru2—Si5—Al659.434 (14)
Al8iii—Ru1—Al8179.999 (12)Si5ix—Si5—Al697.84 (3)
Al8iv—Ru1—Al860.824 (17)Ru3xvii—Si5—Al6119.201 (19)
Al8v—Ru1—Al8119.176 (17)Al8ix—Si5—Al6109.51 (2)
Al8i—Ru1—Al9vi89.014 (15)Al6iv—Si5—Al683.85 (2)
Al8ii—Ru1—Al9vi90.986 (15)Al8—Si5—Al678.242 (18)
Al8iii—Ru1—Al9vi57.891 (14)Ru2—Si5—Al9108.102 (19)
Al8iv—Ru1—Al9vi61.286 (14)Si5ix—Si5—Al9110.55 (3)
Al8v—Ru1—Al9vi118.714 (14)Ru3xvii—Si5—Al958.171 (14)
Al8—Ru1—Al9vi122.110 (14)Al8ix—Si5—Al960.157 (17)
Al8i—Ru1—Al9vii90.986 (15)Al6iv—Si5—Al972.378 (18)
Al8ii—Ru1—Al9vii89.014 (15)Al8—Si5—Al9141.66 (2)
Al8iii—Ru1—Al9vii122.109 (14)Al6—Si5—Al965.278 (17)
Al8iv—Ru1—Al9vii118.714 (14)Ru2—Si5—Al8iv57.488 (14)
Al8v—Ru1—Al9vii61.286 (14)Si5ix—Si5—Al8iv99.22 (3)
Al8—Ru1—Al9vii57.890 (14)Ru3xvii—Si5—Al8iv103.669 (19)
Al9vi—Ru1—Al9vii180.0Al8ix—Si5—Al8iv134.55 (2)
Al8i—Ru1—Al9viii122.109 (14)Al6iv—Si5—Al8iv77.825 (18)
Al8ii—Ru1—Al9viii57.891 (14)Al8—Si5—Al8iv57.48 (2)
Al8iii—Ru1—Al9viii61.285 (14)Al6—Si5—Al8iv115.13 (2)
Al8iv—Ru1—Al9viii89.013 (15)Al9—Si5—Al8iv150.02 (2)
Al8v—Ru1—Al9viii90.987 (15)Ru3—Al6—Ru2129.707 (19)
Al8—Ru1—Al9viii118.714 (14)Ru3—Al6—Ru3xiv112.612 (17)
Al9vi—Ru1—Al9viii60.077 (1)Ru2—Al6—Ru3xiv106.091 (16)
Al9vii—Ru1—Al9viii119.923 (1)Ru3—Al6—Al7xii116.69 (2)
Al8i—Ru1—Al9ix57.891 (14)Ru2—Al6—Al7xii109.655 (19)
Al8ii—Ru1—Al9ix122.109 (14)Ru3xiv—Al6—Al7xii60.806 (14)
Al8iii—Ru1—Al9ix118.715 (14)Ru3—Al6—Si5ii143.99 (2)
Al8iv—Ru1—Al9ix90.987 (15)Ru2—Al6—Si5ii52.818 (13)
Al8v—Ru1—Al9ix89.013 (15)Ru3xiv—Al6—Si5ii53.554 (13)
Al8—Ru1—Al9ix61.286 (14)Al7xii—Al6—Si5ii86.919 (19)
Al9vi—Ru1—Al9ix119.923 (1)Ru3—Al6—Al459.976 (17)
Al9vii—Ru1—Al9ix60.077 (1)Ru2—Al6—Al473.471 (19)
Al9viii—Ru1—Al9ix180.0Ru3xiv—Al6—Al4119.885 (18)
Al8i—Ru1—Al9x118.713 (14)Al7xii—Al6—Al4176.66 (3)
Al8ii—Ru1—Al9x61.287 (14)Si5ii—Al6—Al496.03 (2)
Al8iii—Ru1—Al9x89.012 (15)Ru3—Al6—Si5111.671 (19)
Al8iv—Ru1—Al9x122.111 (14)Ru2—Al6—Si552.410 (13)
Al8v—Ru1—Al9x57.889 (14)Ru3xiv—Al6—Si5133.10 (2)
Al8—Ru1—Al9x90.987 (15)Al7xii—Al6—Si585.969 (18)
Al9vi—Ru1—Al9x119.921 (1)Si5ii—Al6—Si595.90 (2)
Al9vii—Ru1—Al9x60.079 (1)Al4—Al6—Si595.257 (19)
Al9viii—Ru1—Al9x60.079 (1)Ru3—Al6—Al9xii56.713 (13)
Al9ix—Ru1—Al9x119.921 (1)Ru2—Al6—Al9xii144.13 (2)
Al8i—Ru1—Al9xi61.287 (14)Ru3xiv—Al6—Al9xii99.795 (18)
Al8ii—Ru1—Al9xi118.713 (14)Al7xii—Al6—Al9xii62.748 (17)
Al8iii—Ru1—Al9xi90.988 (15)Si5ii—Al6—Al9xii148.12 (2)
Al8iv—Ru1—Al9xi57.889 (14)Al4—Al6—Al9xii114.07 (2)
Al8v—Ru1—Al9xi122.111 (14)Si5—Al6—Al9xii91.741 (19)
Al8—Ru1—Al9xi89.013 (15)Ru3—Al6—Al6xiv57.391 (15)
Al9vi—Ru1—Al9xi60.079 (1)Ru2—Al6—Al6xiv145.22 (3)
Al9vii—Ru1—Al9xi119.921 (1)Ru3xiv—Al6—Al6xiv55.221 (15)
Al9viii—Ru1—Al9xi119.921 (1)Al7xii—Al6—Al6xiv87.39 (2)
Al9ix—Ru1—Al9xi60.079 (1)Si5ii—Al6—Al6xiv100.23 (2)
Al9x—Ru1—Al9xi180.0Al4—Al6—Al6xiv90.54 (2)
Si5ii—Ru2—Si5119.661 (2)Si5—Al6—Al6xiv162.19 (3)
Si5ii—Ru2—Si5iv119.662 (2)Al9xii—Al6—Al6xiv70.54 (2)
Si5—Ru2—Si5iv119.659 (2)Ru3—Al7—Ru3xvi117.649 (18)
Si5ii—Ru2—Al870.202 (16)Ru3—Al7—Al6xvii116.63 (2)
Si5—Ru2—Al868.549 (15)Ru3xvi—Al7—Al6xvii119.15 (2)
Si5iv—Ru2—Al8124.453 (17)Ru3—Al7—Ru3iv116.862 (18)
Si5ii—Ru2—Al8ii68.549 (15)Ru3xvi—Al7—Ru3iv114.346 (17)
Si5—Ru2—Al8ii124.452 (17)Al6xvii—Al7—Ru3iv58.818 (14)
Si5iv—Ru2—Al8ii70.202 (16)Ru3—Al7—Al7xvi134.381 (13)
Al8—Ru2—Al8ii64.153 (18)Ru3xvi—Al7—Al7xvi57.944 (19)
Si5ii—Ru2—Al8iv124.453 (17)Al6xvii—Al7—Al7xvi99.12 (2)
Si5—Ru2—Al8iv70.202 (16)Ru3iv—Al7—Al7xvi58.365 (12)
Si5iv—Ru2—Al8iv68.548 (15)Ru3—Al7—Al7xv59.461 (12)
Al8—Ru2—Al8iv64.153 (18)Ru3xvi—Al7—Al7xv60.283 (19)
Al8ii—Ru2—Al8iv64.152 (18)Al6xvii—Al7—Al7xv168.67 (2)
Si5ii—Ru2—Al6ii68.158 (15)Ru3iv—Al7—Al7xv132.432 (13)
Si5—Ru2—Al6ii149.111 (17)Al7xvi—Al7—Al7xv89.88 (2)
Si5iv—Ru2—Al6ii67.213 (15)Ru3—Al7—Al459.578 (10)
Al8—Ru2—Al6ii135.530 (15)Ru3xvi—Al7—Al4135.92 (2)
Al8ii—Ru2—Al6ii86.437 (15)Al6xvii—Al7—Al494.86 (2)
Al8iv—Ru2—Al6ii132.991 (15)Ru3iv—Al7—Al458.545 (10)
Si5ii—Ru2—Al6iv149.112 (17)Al7xvi—Al7—Al491.721 (15)
Si5—Ru2—Al6iv67.211 (15)Al7xv—Al7—Al491.721 (15)
Si5iv—Ru2—Al6iv68.157 (15)Ru3—Al7—Al956.394 (14)
Al8—Ru2—Al6iv132.990 (15)Ru3xvi—Al7—Al9142.61 (2)
Al8ii—Ru2—Al6iv135.529 (15)Al6xvii—Al7—Al961.810 (17)
Al8iv—Ru2—Al6iv86.436 (15)Ru3iv—Al7—Al997.917 (17)
Al6ii—Ru2—Al6iv91.441 (15)Al7xvi—Al7—Al9156.03 (3)
Si5ii—Ru2—Al667.213 (15)Al7xv—Al7—Al9111.07 (2)
Si5—Ru2—Al668.157 (15)Al4—Al7—Al976.65 (2)
Si5iv—Ru2—Al6149.112 (17)Ru3vii—Al8—Ru2143.54 (2)
Al8—Ru2—Al686.435 (15)Ru3vii—Al8—Al9vii60.306 (15)
Al8ii—Ru2—Al6132.991 (15)Ru2—Al8—Al9vii145.45 (2)
Al8iv—Ru2—Al6135.529 (15)Ru3vii—Al8—Ru1109.918 (17)
Al6ii—Ru2—Al691.442 (15)Ru2—Al8—Ru1106.409 (17)
Al6iv—Ru2—Al691.441 (15)Al9vii—Al8—Ru162.599 (15)
Si5xii—Ru3—Al8xiii65.551 (15)Ru3vii—Al8—Si5ix55.492 (14)
Si5xii—Ru3—Al6120.406 (15)Ru2—Al8—Si5ix104.439 (19)
Al8xiii—Ru3—Al6124.414 (16)Al9vii—Al8—Si5ix109.63 (2)
Si5xii—Ru3—Al7122.217 (15)Ru1—Al8—Si5ix117.12 (2)
Al8xiii—Ru3—Al773.932 (16)Ru3vii—Al8—Al8ii149.08 (3)
Al6—Ru3—Al7116.122 (15)Ru2—Al8—Al8ii57.924 (9)
Si5xii—Ru3—Al9xii68.678 (16)Al9vii—Al8—Al8ii91.00 (2)
Al8xiii—Ru3—Al9xii65.586 (16)Ru1—Al8—Al8ii59.587 (8)
Al6—Ru3—Al9xii67.410 (16)Si5ix—Al8—Al8ii155.06 (3)
Al7—Ru3—Al9xii127.455 (16)Ru3vii—Al8—Al8iv143.73 (3)
Si5xii—Ru3—Al9119.665 (16)Ru2—Al8—Al8iv57.925 (9)
Al8xiii—Ru3—Al961.760 (16)Al9vii—Al8—Al8iv122.187 (15)
Al6—Ru3—Al972.324 (16)Ru1—Al8—Al8iv59.588 (8)
Al7—Ru3—Al967.560 (16)Si5ix—Al8—Al8iv96.24 (3)
Al9xii—Ru3—Al964.436 (17)Al8ii—Al8—Al8iv60.0
Si5xii—Ru3—Al6xiv66.289 (14)Ru3vii—Al8—Al9ix58.136 (15)
Al8xiii—Ru3—Al6xiv127.640 (16)Ru2—Al8—Al9ix145.13 (2)
Al6—Ru3—Al6xiv67.389 (17)Al9vii—Al8—Al9ix61.411 (12)
Al7—Ru3—Al6xiv153.459 (16)Ru1—Al8—Al9ix60.799 (14)
Al9xii—Ru3—Al6xiv78.881 (16)Si5ix—Al8—Al9ix62.510 (18)
Al9—Ru3—Al6xiv133.370 (16)Al8ii—Al8—Al9ix120.386 (14)
Si5xii—Ru3—Al7xv71.465 (15)Al8iv—Al8—Al9ix90.01 (2)
Al8xiii—Ru3—Al7xv80.729 (15)Ru3vii—Al8—Si5104.754 (19)
Al6—Ru3—Al7xv154.440 (16)Ru2—Al8—Si553.057 (13)
Al7—Ru3—Al7xv62.594 (14)Al9vii—Al8—Si5161.49 (2)
Al9xii—Ru3—Al7xv135.585 (16)Ru1—Al8—Si5118.64 (2)
Al9—Ru3—Al7xv123.870 (16)Si5ix—Al8—Si552.363 (19)
Al6xiv—Ru3—Al7xv102.325 (15)Al8ii—Al8—Si5105.493 (16)
Si5xii—Ru3—Al4156.665 (16)Al8iv—Al8—Si562.348 (19)
Al8xiii—Ru3—Al4133.431 (13)Al9ix—Al8—Si5102.09 (2)
Al6—Ru3—Al464.05 (2)Ru3vii—Al8—Si5ii111.11 (2)
Al7—Ru3—Al463.982 (15)Ru2—Al8—Si5ii52.311 (13)
Al9xii—Ru3—Al4127.93 (2)Al9vii—Al8—Si5ii101.04 (2)
Al9—Ru3—Al483.669 (15)Ru1—Al8—Si5ii116.598 (19)
Al6xiv—Ru3—Al498.593 (12)Si5ix—Al8—Si5ii125.72 (2)
Al7xv—Ru3—Al496.13 (2)Al8ii—Al8—Si5ii60.177 (19)
Si5xii—Ru3—Al7ii93.941 (15)Al8iv—Al8—Si5ii103.902 (16)
Al8xiii—Ru3—Al7ii141.416 (15)Al9ix—Al8—Si5ii162.00 (2)
Al6—Ru3—Al7ii94.038 (15)Si5—Al8—Si5ii94.55 (2)
Al7—Ru3—Al7ii93.18 (2)Ru3xvii—Al9—Ru3147.99 (2)
Al9xii—Ru3—Al7ii139.245 (16)Ru3xvii—Al9—Al8xiii148.40 (2)
Al9—Ru3—Al7ii146.275 (16)Ru3—Al9—Al8xiii57.934 (15)
Al6xiv—Ru3—Al7ii60.377 (15)Ru3xvii—Al9—Ru1xviii105.884 (17)
Al7xv—Ru3—Al7ii61.353 (14)Ru3—Al9—Ru1xviii105.607 (17)
Al4—Ru3—Al7ii62.748 (15)Al8xiii—Al9—Ru1xviii59.509 (15)
Ru3—Al4—Ru3iv113.957 (15)Ru3xvii—Al9—Al9xii138.86 (3)
Ru3—Al4—Ru3ii113.956 (15)Ru3—Al9—Al9xii57.609 (18)
Ru3iv—Al4—Ru3ii113.956 (15)Al8xiii—Al9—Al9xii61.789 (18)
Ru3—Al4—Al6iv109.230 (14)Ru1xviii—Al9—Al9xii59.959 (1)
Ru3iv—Al4—Al6iv55.974 (11)Ru3xvii—Al9—Al9xvii57.955 (19)
Ru3ii—Al4—Al6iv134.84 (2)Ru3—Al9—Al9xvii148.22 (3)
Ru3—Al4—Al6ii134.84 (2)Al8xiii—Al9—Al9xvii91.89 (2)
Ru3iv—Al4—Al6ii109.230 (14)Ru1xviii—Al9—Al9xvii60.0
Ru3ii—Al4—Al6ii55.974 (11)Al9xii—Al9—Al9xvii119.687 (4)
Al6iv—Al4—Al6ii84.26 (3)Ru3xvii—Al9—Al8ix56.276 (14)
Ru3—Al4—Al655.973 (11)Ru3—Al9—Al8ix143.01 (2)
Ru3iv—Al4—Al6134.84 (2)Al8xiii—Al9—Al8ix117.42 (3)
Ru3ii—Al4—Al6109.231 (14)Ru1xviii—Al9—Al8ix57.913 (14)
Al6iv—Al4—Al684.26 (3)Al9xii—Al9—Al8ix87.05 (2)
Al6ii—Al4—Al684.26 (3)Al9xvii—Al9—Al8ix56.799 (18)
Ru3—Al4—Al756.440 (13)Ru3xvii—Al9—Si553.152 (13)
Ru3iv—Al4—Al758.708 (14)Ru3—Al9—Si5109.71 (2)
Ru3ii—Al4—Al7127.88 (3)Al8xiii—Al9—Si5154.89 (3)
Al6iv—Al4—Al787.091 (13)Ru1xviii—Al9—Si5109.909 (19)
Al6ii—Al4—Al7167.862 (14)Al9xii—Al9—Si593.10 (3)
Al6—Al4—Al7103.356 (14)Al9xvii—Al9—Si5102.00 (3)
Ru3—Al4—Al7iv127.88 (3)Al8ix—Al9—Si557.332 (16)
Ru3iv—Al4—Al7iv56.439 (13)Ru3xvii—Al9—Al6xvii55.877 (14)
Ru3ii—Al4—Al7iv58.708 (14)Ru3—Al9—Al6xvii110.10 (2)
Al6iv—Al4—Al7iv103.357 (14)Al8xiii—Al9—Al6xvii105.54 (2)
Al6ii—Al4—Al7iv87.091 (13)Ru1xviii—Al9—Al6xvii121.90 (2)
Al6—Al4—Al7iv167.862 (14)Al9xii—Al9—Al6xvii165.26 (3)
Al7—Al4—Al7iv86.64 (2)Al9xvii—Al9—Al6xvii65.56 (2)
Ru3—Al4—Al7ii58.708 (14)Al8ix—Al9—Al6xvii106.35 (2)
Ru3iv—Al4—Al7ii127.88 (3)Si5—Al9—Al6xvii99.26 (2)
Ru3ii—Al4—Al7ii56.439 (13)Ru3xvii—Al9—Al7108.93 (2)
Al6iv—Al4—Al7ii167.862 (14)Ru3—Al9—Al756.047 (14)
Al6ii—Al4—Al7ii103.357 (14)Al8xiii—Al9—Al767.695 (18)
Al6—Al4—Al7ii87.091 (13)Ru1xviii—Al9—Al7123.68 (2)
Al7—Al4—Al7ii86.64 (2)Al9xii—Al9—Al7110.49 (3)
Al7iv—Al4—Al7ii86.64 (2)Al9xvii—Al9—Al7105.97 (3)
Ru2—Si5—Si5ix118.81 (3)Al8ix—Al9—Al7160.85 (2)
Ru2—Si5—Ru3xvii119.762 (18)Si5—Al9—Al7126.36 (2)
Si5ix—Si5—Ru3xvii120.64 (3)Al6xvii—Al9—Al755.443 (16)
Ru2—Si5—Al8ix167.65 (2)
Symmetry codes: (i) xy, x, z+1; (ii) x+y, x, z; (iii) x, y, z+1; (iv) y, xy, z; (v) y, x+y, z+1; (vi) y2/3, x+y1/3, z+2/3; (vii) y+2/3, xy+1/3, z+1/3; (viii) x1/3, y2/3, z+1/3; (ix) x+1/3, y+2/3, z+2/3; (x) xy+1/3, x1/3, z+2/3; (xi) x+y1/3, x+1/3, z+1/3; (xii) xy+2/3, x+1/3, z+1/3; (xiii) x+y+1/3, x+2/3, z1/3; (xiv) x+2/3, y+1/3, z+1/3; (xv) y, x+y, z; (xvi) xy, x, z; (xvii) y1/3, x+y+1/3, z+1/3; (xviii) x+1/3, y+2/3, z1/3.
Heptacosaaluminium decaruthenium tridecasilicon (III) top
Crystal data top
~Ru10(Al0.67Si0.33)41Dx = 4.652 Mg m3
Mr = 2122.53Mo Kα radiation, λ = 0.71073 Å
Orthorhombic, PnmaCell parameters from 16783 reflections
a = 15.0794 (2) Åθ = 3.4–33.8°
b = 11.8713 (2) ŵ = 6.18 mm1
c = 16.9291 (3) ÅT = 298 K
V = 3030.50 (9) Å3Irregular, metallic light silver
Z = 40.04 × 0.02 × 0.02 mm
F(000) = 3888.20
Data collection top
XtaLAB Synergy R, HyPix
diffractometer
5672 independent reflections
Radiation source: micro-focus sealed X-ray tube, Mova (Mo) X-ray Source4940 reflections with I > 2σ(I)
Mirror monochromatorRint = 0.022
Detector resolution: 10.0000 pixels mm-1θmax = 33.7°, θmin = 3.2°
ω scansh = 2321
Absorption correction: gaussian
(CrysAlisPro; Matsumoto et al., 2021)
k = 1718
Tmin = 0.867, Tmax = 0.929l = 2524
33654 measured reflections
Refinement top
Refinement on F2Primary atom site location: dual
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.015 w = 1/[σ2(Fo2) + (0.0093P)2 + 1.1293P]
where P = (Fo2 + 2Fc2)/3
wR(F2) = 0.026(Δ/σ)max = 0.003
S = 1.01Δρmax = 0.78 e Å3
5672 reflectionsΔρmin = 0.74 e Å3
303 parametersExtinction correction: SHELXL-2019/3 (Sheldrick, 2015b), Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4
2 restraintsExtinction coefficient: 0.000039 (4)
Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Ru10.15195 (2)0.2500000.76146 (2)0.00513 (3)
Ru20.41069 (2)0.2500000.87752 (2)0.00474 (3)
Ru30.45013 (2)0.2500000.16946 (2)0.00542 (3)
Ru4A0.1834 (2)0.2500000.02174 (3)0.00665 (15)0.933 (16)
Ru4B0.1655 (15)0.2500000.0209 (4)0.0036 (13)*0.067 (16)
Ru5A0.42722 (8)0.0630 (2)0.38435 (7)0.00501 (13)0.74 (2)
Ru5B0.4253 (3)0.0509 (5)0.3844 (2)0.0052 (4)*0.26 (2)
Ru60.17223 (2)0.06068 (2)0.25159 (2)0.00500 (3)
Ru70.15518 (2)0.05637 (2)0.52078 (2)0.00672 (3)
Si80.20752 (4)0.2500000.31440 (3)0.00625 (11)
Si9A0.37913 (7)0.2500000.62569 (5)0.0103 (3)0.727 (3)
Si9B0.43672 (17)0.2500000.59893 (13)0.0095 (7)0.273 (3)
Si10A0.3512 (4)0.2500000.38677 (9)0.0081 (6)0.85 (2)
Al10B0.3758 (16)0.2500000.3830 (5)0.0082 (18)*0.15 (2)
Al110.19544 (4)0.2500000.47722 (4)0.0089 (3)0.65 (6)
Si110.19544 (4)0.2500000.47722 (4)0.0089 (3)0.35 (6)
Al120.48579 (4)0.2500000.74245 (4)0.00666 (12)
Al130.16461 (4)0.2500000.16972 (4)0.00748 (12)
Al140.08651 (5)0.2500000.60711 (4)0.01395 (15)
Al150.33501 (5)0.2500000.07842 (5)0.0183 (3)0.950 (4)
Si160.05763 (3)0.56298 (4)0.31273 (2)0.00608 (8)
Si170.41912 (3)0.56490 (4)0.26431 (2)0.00638 (8)
Si180.19988 (3)0.62931 (4)0.45426 (2)0.00859 (8)
Si190.02383 (3)0.14871 (4)0.21915 (2)0.00739 (8)
Al200.21386 (3)0.63959 (4)0.30297 (3)0.0109 (2)0.55 (5)
Si200.21386 (3)0.63959 (4)0.30297 (3)0.0109 (2)0.45 (5)
Al210.42109 (3)0.04580 (4)0.12868 (3)0.0072 (2)0.64 (5)
Si210.42109 (3)0.04580 (4)0.12868 (3)0.0072 (2)0.36 (5)
Al220.33859 (3)0.11923 (4)0.51409 (3)0.0115 (2)0.67 (5)
Si220.33859 (3)0.11923 (4)0.51409 (3)0.0115 (2)0.33 (5)
Al230.33880 (3)0.12822 (4)0.25123 (3)0.00721 (9)
Al240.25334 (3)0.04455 (4)0.38472 (3)0.00724 (9)
Al250.07288 (3)0.54572 (4)0.15156 (3)0.00777 (9)
Al260.08203 (3)0.13043 (4)0.38371 (3)0.00734 (9)
Al270.21669 (3)0.06506 (4)0.09349 (3)0.01224 (10)
Al280.02308 (3)0.59649 (5)0.46632 (3)0.01334 (10)
Al29A0.3572 (3)0.64190 (10)0.3938 (2)0.0077 (5)0.79 (2)
Al29B0.3742 (7)0.6377 (5)0.4074 (7)0.0109 (11)*0.21 (2)
Al30A0.28629 (14)0.6034 (3)0.16459 (9)0.0188 (6)0.754 (11)
Al30B0.2701 (3)0.6380 (5)0.1547 (2)0.0136 (8)*0.246 (11)
Al31A0.01771 (7)0.2500000.07942 (7)0.0153 (5)0.728 (5)
Al31B0.0308 (4)0.1965 (6)0.0529 (4)0.015 (2)*0.104 (3)
Al31C0.0457 (8)0.1351 (13)0.0372 (7)0.016 (4)*0.047 (3)
Al32A0.06370 (5)0.06801 (7)0.01653 (4)0.0151 (3)0.716 (3)
Al32B0.0186 (3)0.0224 (4)0.0048 (3)0.0129 (15)*0.121 (3)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ru10.00431 (7)0.00457 (8)0.00651 (7)0.0000.00060 (6)0.000
Ru20.00433 (7)0.00403 (7)0.00587 (7)0.0000.00033 (5)0.000
Ru30.00414 (7)0.00694 (8)0.00517 (7)0.0000.00026 (6)0.000
Ru4A0.0081 (5)0.00790 (13)0.00392 (11)0.0000.00035 (13)0.000
Ru5A0.00401 (16)0.0042 (3)0.00676 (16)0.00089 (18)0.00098 (7)0.00108 (17)
Ru60.00449 (5)0.00601 (6)0.00452 (5)0.00090 (4)0.00053 (4)0.00048 (4)
Ru70.00645 (5)0.00859 (6)0.00513 (5)0.00172 (4)0.00042 (4)0.00090 (4)
Si80.0067 (3)0.0055 (3)0.0065 (3)0.0000.0001 (2)0.000
Si9A0.0154 (5)0.0066 (4)0.0088 (4)0.0000.0050 (3)0.000
Si9B0.0144 (15)0.0052 (11)0.0091 (11)0.0000.0036 (9)0.000
Si10A0.0098 (14)0.0055 (4)0.0090 (4)0.0000.0013 (4)0.000
Al110.0091 (4)0.0069 (4)0.0108 (4)0.0000.0005 (2)0.000
Si110.0091 (4)0.0069 (4)0.0108 (4)0.0000.0005 (2)0.000
Al120.0060 (3)0.0063 (3)0.0076 (3)0.0000.0008 (2)0.000
Al130.0108 (3)0.0065 (3)0.0051 (3)0.0000.0012 (2)0.000
Al140.0090 (3)0.0204 (4)0.0124 (3)0.0000.0002 (3)0.000
Al150.0172 (5)0.0158 (5)0.0219 (5)0.0000.0147 (3)0.000
Si160.00579 (18)0.00568 (19)0.00676 (18)0.00030 (15)0.00049 (14)0.00084 (14)
Si170.00719 (18)0.00518 (19)0.00678 (18)0.00049 (15)0.00114 (14)0.00033 (14)
Si180.0088 (2)0.0083 (2)0.00861 (19)0.00025 (16)0.00109 (15)0.00063 (15)
Si190.00649 (18)0.0067 (2)0.00891 (19)0.00029 (16)0.00037 (14)0.00100 (15)
Al200.0094 (3)0.0074 (3)0.0159 (3)0.00202 (17)0.00544 (17)0.00150 (17)
Si200.0094 (3)0.0074 (3)0.0159 (3)0.00202 (17)0.00544 (17)0.00150 (17)
Al210.0072 (3)0.0072 (3)0.0072 (3)0.00030 (17)0.00040 (15)0.00223 (16)
Si210.0072 (3)0.0072 (3)0.0072 (3)0.00030 (17)0.00040 (15)0.00223 (16)
Al220.0143 (3)0.0126 (3)0.0075 (3)0.00185 (19)0.00166 (17)0.00134 (17)
Si220.0143 (3)0.0126 (3)0.0075 (3)0.00185 (19)0.00166 (17)0.00134 (17)
Al230.0067 (2)0.0077 (2)0.0072 (2)0.00081 (17)0.00118 (16)0.00033 (16)
Al240.0070 (2)0.0080 (2)0.0068 (2)0.00033 (17)0.00041 (16)0.00027 (16)
Al250.0073 (2)0.0074 (2)0.0086 (2)0.00030 (17)0.00002 (16)0.00109 (17)
Al260.0060 (2)0.0076 (2)0.0085 (2)0.00025 (17)0.00033 (16)0.00000 (16)
Al270.0154 (2)0.0077 (2)0.0135 (2)0.0003 (2)0.00641 (19)0.00069 (18)
Al280.0115 (2)0.0150 (3)0.0135 (2)0.0029 (2)0.00047 (18)0.00552 (19)
Al29A0.0139 (8)0.0046 (4)0.0047 (6)0.0026 (3)0.0010 (6)0.0011 (3)
Al30A0.0182 (6)0.0278 (11)0.0103 (4)0.0093 (7)0.0000 (4)0.0088 (5)
Al31A0.0090 (5)0.0215 (9)0.0155 (6)0.0000.0021 (4)0.000
Al32A0.0167 (5)0.0181 (5)0.0105 (4)0.0000 (3)0.0052 (3)0.0019 (3)
Geometric parameters (Å, º) top
Ru1—Si17i2.4453 (4)Si9B—Al25ii2.5876 (10)
Ru1—Si17ii2.4453 (4)Si9B—Al25i2.5876 (10)
Ru1—Al12iii2.5063 (7)Si10A—Al31Avi2.576 (5)
Ru1—Al20ii2.5113 (5)Si10A—Al22vii2.6631 (16)
Ru1—Al20i2.5113 (5)Si10A—Al222.6631 (16)
Ru1—Al30Bi2.534 (3)Si10A—Al23vii2.7183 (11)
Ru1—Al30Bii2.534 (3)Si10A—Al232.7183 (11)
Ru1—Al30Ai2.5661 (12)Si10A—Al112.803 (5)
Ru1—Al30Aii2.5661 (12)Al10B—Al31Avi2.23 (2)
Ru1—Al29Aii2.585 (4)Al10B—Al31Bv2.65 (2)
Ru1—Al29Ai2.585 (4)Al10B—Al31Bvi2.65 (2)
Ru1—Al142.7932 (7)Al10B—Al23vii2.716 (7)
Ru2—Si16i2.5220 (4)Al10B—Al232.716 (7)
Ru2—Si16ii2.5220 (4)Al10B—Al22vii2.766 (10)
Ru2—Al122.5516 (6)Al10B—Al222.766 (10)
Ru2—Si18i2.5536 (5)Al11—Al26vii2.7287 (7)
Ru2—Si18ii2.5536 (4)Al11—Al262.7288 (7)
Ru2—Al28ii2.5649 (5)Al11—Al22vii2.7310 (7)
Ru2—Al28i2.5649 (5)Al11—Al222.7310 (7)
Ru2—Al20i2.6150 (5)Al11—Al142.7447 (9)
Ru2—Al20ii2.6150 (5)Al12—Si16ii2.6025 (5)
Ru2—Al14iv2.6640 (7)Al12—Si16i2.6025 (5)
Ru3—Al152.3213 (8)Al12—Si17xii2.6263 (6)
Ru3—Si19v2.4975 (4)Al12—Si17xiii2.6263 (6)
Ru3—Si19vi2.4975 (4)Al12—Al14iv2.9652 (10)
Ru3—Al21vii2.5582 (5)Al13—Si19vii2.5792 (7)
Ru3—Al212.5582 (5)Al13—Si192.5793 (7)
Ru3—Al26v2.6041 (5)Al13—Al272.6650 (6)
Ru3—Al26vi2.6041 (5)Al13—Al27vii2.6650 (6)
Ru3—Al23vii2.6124 (5)Al13—Al31A2.6914 (12)
Ru3—Al232.6124 (5)Al13—Al31B2.896 (6)
Ru4A—Al31B2.445 (6)Al13—Al31Bvii2.896 (6)
Ru4A—Al31Bvii2.445 (6)Al14—Al30Bii2.663 (3)
Ru4A—Al152.479 (3)Al14—Al30Bi2.663 (3)
Ru4A—Al31Cvii2.498 (12)Al14—Al28xi2.7563 (7)
Ru4A—Al31C2.498 (12)Al14—Al28xiv2.7563 (7)
Ru4A—Al29Bviii2.505 (6)Al14—Al30Aii2.7665 (17)
Ru4A—Al29Bix2.505 (6)Al14—Al30Ai2.7665 (16)
Ru4A—Al132.5211 (8)Al15—Si18viii2.5976 (8)
Ru4A—Si18ix2.541 (2)Al15—Si18ix2.5976 (8)
Ru4A—Si18viii2.541 (2)Al15—Al27vii2.8406 (7)
Ru4A—Al272.5588 (9)Al15—Al272.8406 (7)
Ru4A—Al27vii2.5588 (9)Al15—Al212.8784 (6)
Ru4B—Al31B2.20 (2)Al15—Al21vii2.8784 (6)
Ru4B—Al31Bvii2.20 (2)Si16—Si17xv2.4623 (6)
Ru4B—Al31Cvii2.28 (2)Si16—Al202.5307 (6)
Ru4B—Al31C2.28 (2)Si16—Al26vii2.6175 (6)
Ru4B—Al29Bviii2.413 (11)Si16—Al21xvi2.6250 (6)
Ru4B—Al29Bix2.413 (11)Si16—Al282.6816 (6)
Ru4B—Al31A2.44 (2)Si16—Al252.7456 (6)
Ru4B—Al132.520 (7)Si17—Al29A2.5512 (15)
Ru4B—Al29Aviii2.529 (7)Si17—Al23vii2.6024 (6)
Ru4B—Al29Aix2.529 (7)Si17—Al21vii2.6456 (6)
Ru4B—Al272.632 (8)Si17—Al30A2.659 (3)
Ru4B—Al27vii2.632 (8)Si17—Al29B2.660 (8)
Ru5A—Al10B2.352 (9)Si17—Al25vi2.7306 (6)
Ru5A—Al32Bvi2.377 (5)Si18—Al24vii2.5092 (6)
Ru5A—Al31Cvi2.385 (12)Si18—Al202.5727 (6)
Ru5A—Al32Bx2.419 (5)Si18—Al29A2.589 (3)
Ru5A—Al31Bvi2.466 (6)Si18—Al282.7022 (7)
Ru5A—Si19vi2.4958 (19)Si18—Al29B2.748 (7)
Ru5A—Si10A2.499 (4)Si18—Al27xvii2.7785 (6)
Ru5A—Si17vii2.5395 (19)Si19—Si19vii2.4048 (9)
Ru5A—Al29Bvii2.543 (7)Si19—Al31A2.6552 (12)
Ru5A—Al25v2.6190 (16)Si19—Al25vii2.6803 (6)
Ru5A—Al242.6311 (14)Si19—Al23xv2.8453 (6)
Ru5A—Al29Avii2.656 (4)Si19—Al31B2.874 (6)
Ru5B—Al32Bvi2.368 (6)Al20—Al30A2.6202 (10)
Ru5B—Al32Bx2.372 (6)Al20—Al20xviii2.6215 (10)
Ru5B—Al29Bvii2.400 (9)Al20—Al30B2.650 (3)
Ru5B—Si17vii2.456 (5)Al20—Al29A2.653 (6)
Ru5B—Al31Cvi2.460 (13)Al20—Al24vii2.6549 (7)
Ru5B—Al10B2.479 (9)Al20—Al29B2.996 (14)
Ru5B—Al29Avii2.513 (7)Al21—Al232.6080 (6)
Ru5B—Si19vi2.575 (5)Al21—Al26vi2.6350 (6)
Ru5B—Al25v2.576 (4)Al21—Al30Avii2.764 (3)
Ru5B—Al31Bvi2.578 (8)Al21—Al28v2.7938 (7)
Ru5B—Al242.594 (4)Al21—Al28viii2.9369 (7)
Ru5B—Si10A2.615 (6)Al22—Al32Ax2.6670 (10)
Ru6—Si16vii2.4926 (4)Al22—Al242.6898 (6)
Ru6—Si192.5300 (4)Al22—Al27x2.6996 (7)
Ru6—Si82.5426 (3)Al22—Al32Bx2.737 (5)
Ru6—Al242.5715 (5)Al23—Al242.7846 (6)
Ru6—Al25vii2.5898 (5)Al24—Al29Avii2.716 (3)
Ru6—Al20vii2.6083 (5)Al24—Al262.7772 (6)
Ru6—Al232.6367 (5)Al25—Al32Avii2.6586 (8)
Ru6—Al132.6429 (4)Al25—Al27vii2.7200 (7)
Ru6—Al262.7455 (5)Al25—Al32Bvii2.738 (4)
Ru6—Al272.7596 (5)Al26—Al26vii2.8388 (10)
Ru6—Al30Avii2.987 (2)Al27—Al30Avii2.5594 (16)
Ru7—Al21x2.4760 (5)Al27—Al32A2.6497 (10)
Ru7—Al112.4892 (3)Al27—Al30Bvii2.744 (4)
Ru7—Si18vii2.5655 (5)Al28—Al28xiv2.6519 (10)
Ru7—Al30Ai2.6492 (8)Al29A—Al32Axvii2.551 (5)
Ru7—Al27x2.7068 (5)Al29A—Al29Axviii2.567 (2)
Ru7—Al30Bi2.711 (3)Al29A—Al29Bxviii2.639 (6)
Ru7—Al262.7156 (5)Al29B—Al32Axvii2.229 (14)
Ru7—Al28xi2.7385 (5)Al29B—Al31Cxvii2.507 (19)
Ru7—Al242.7416 (5)Al29B—Al29Bxviii2.666 (12)
Ru7—Al28vii2.8479 (5)Al29B—Al32Bxvii2.684 (15)
Ru7—Al222.8669 (5)Al30A—Al30B0.507 (4)
Si8—Si10A2.489 (5)Al30B—Al30Bxviii2.659 (12)
Si8—Al132.5334 (8)Al31A—Al31Bvii0.802 (8)
Si8—Al26vii2.6404 (7)Al31A—Al31B0.802 (8)
Si8—Al262.6404 (7)Al31A—Al31C1.596 (16)
Si8—Al23vii2.6744 (7)Al31A—Al31Cvii1.596 (16)
Si8—Al232.6744 (7)Al31A—Al32Avii2.5064 (11)
Si8—Al112.7624 (9)Al31A—Al32A2.5064 (11)
Si8—Al10B2.79 (2)Al31B—Al31C0.808 (15)
Si8—Al24vii2.8005 (5)Al31B—Al31Bvii1.269 (15)
Si9A—Si9B0.979 (3)Al31B—Al32A1.718 (8)
Si9A—Al22vii2.5205 (8)Al31B—Al31Cvii2.028 (19)
Si9A—Al222.5205 (8)Al31B—Al32B2.229 (9)
Si9A—Al122.5484 (10)Al31C—Al32A0.912 (16)
Si9A—Al25ii2.5683 (6)Al31C—Al32B1.503 (16)
Si9A—Al25i2.5683 (6)Al31C—Al32Bxix2.223 (15)
Si9A—Al30Bi2.659 (7)Al31C—Al31Cvii2.73 (3)
Si9A—Al30Bii2.659 (7)Al32A—Al32B0.892 (4)
Si9B—Al122.540 (2)Al32A—Al32Bxix1.680 (5)
Si9B—Al22vii2.5812 (19)Al32A—Al32Axix2.5713 (17)
Si9B—Al222.5812 (19)Al32B—Al32Bxix0.790 (9)
Si17i—Ru1—Si17ii127.96 (2)Ru2ix—Si18—Al15ii88.28 (2)
Si17i—Ru1—Al12iii64.049 (11)Ru7vii—Si18—Al15ii93.755 (17)
Si17ii—Ru1—Al12iii64.049 (11)Al20—Si18—Al15ii142.75 (2)
Si17i—Ru1—Al20ii144.754 (15)Al29A—Si18—Al15ii118.30 (8)
Si17ii—Ru1—Al20ii83.029 (15)Al24vii—Si18—Al28103.52 (2)
Al12iii—Ru1—Al20ii144.381 (13)Ru4Aii—Si18—Al28136.96 (5)
Si17i—Ru1—Al20i83.029 (15)Ru2ix—Si18—Al2858.339 (14)
Si17ii—Ru1—Al20i144.754 (15)Ru7vii—Si18—Al2865.395 (15)
Al12iii—Ru1—Al20i144.381 (14)Al20—Si18—Al2899.38 (2)
Al20ii—Ru1—Al20i62.92 (2)Al29A—Si18—Al28160.49 (10)
Si17i—Ru1—Al30Bi75.28 (17)Al15ii—Si18—Al2879.54 (2)
Si17ii—Ru1—Al30Bi133.55 (13)Al24vii—Si18—Ru4Bii112.7 (3)
Al12iii—Ru1—Al30Bi116.43 (11)Ru4Aii—Si18—Ru4Bii4.2 (3)
Al20ii—Ru1—Al30Bi95.71 (13)Ru2ix—Si18—Ru4Bii113.67 (18)
Al20i—Ru1—Al30Bi63.37 (8)Ru7vii—Si18—Ru4Bii117.73 (11)
Si17i—Ru1—Al30Bii133.55 (13)Al20—Si18—Ru4Bii109.0 (2)
Si17ii—Ru1—Al30Bii75.28 (17)Al29A—Si18—Ru4Bii56.7 (3)
Al12iii—Ru1—Al30Bii116.43 (11)Al15ii—Si18—Ru4Bii61.8 (3)
Al20ii—Ru1—Al30Bii63.37 (8)Al28—Si18—Ru4Bii141.1 (3)
Al20i—Ru1—Al30Bii95.71 (13)Al24vii—Si18—Al29B65.62 (12)
Al30Bi—Ru1—Al30Bii63.3 (3)Ru4Aii—Si18—Al29B56.4 (2)
Si17i—Ru1—Al30Ai64.04 (9)Ru2ix—Si18—Al29B117.2 (3)
Si17ii—Ru1—Al30Ai141.35 (6)Ru7vii—Si18—Al29B114.16 (19)
Al12iii—Ru1—Al30Ai110.24 (6)Al20—Si18—Al29B68.5 (3)
Al20ii—Ru1—Al30Ai103.90 (7)Al29A—Si18—Al29B6.68 (19)
Al20i—Ru1—Al30Ai62.12 (2)Al15ii—Si18—Al29B114.0 (2)
Al30Bi—Ru1—Al30Ai11.38 (9)Al28—Si18—Al29B166.2 (2)
Al30Bii—Ru1—Al30Ai74.4 (3)Ru4Bii—Si18—Al29B52.3 (4)
Si17i—Ru1—Al30Aii141.35 (6)Al24vii—Si18—Al27xvii91.53 (2)
Si17ii—Ru1—Al30Aii64.04 (9)Ru4Aii—Si18—Al27xvii57.299 (16)
Al12iii—Ru1—Al30Aii110.24 (6)Ru2ix—Si18—Al27xvii151.80 (2)
Al20ii—Ru1—Al30Aii62.12 (2)Ru7vii—Si18—Al27xvii60.707 (14)
Al20i—Ru1—Al30Aii103.90 (7)Al20—Si18—Al27xvii145.13 (2)
Al30Bi—Ru1—Al30Aii74.4 (3)Al29A—Si18—Al27xvii86.36 (11)
Al30Bii—Ru1—Al30Aii11.38 (9)Al15ii—Si18—Al27xvii63.69 (2)
Al30Ai—Ru1—Al30Aii85.39 (18)Al28—Si18—Al27xvii110.06 (2)
Si17i—Ru1—Al29Aii113.93 (8)Ru4Bii—Si18—Al27xvii57.10 (11)
Si17ii—Ru1—Al29Aii60.88 (3)Al29B—Si18—Al27xvii79.7 (3)
Al12iii—Ru1—Al29Aii88.24 (10)Si19vii—Si19—Ru5Axv114.07 (6)
Al20ii—Ru1—Al29Aii62.72 (10)Si19vii—Si19—Ru3xv61.220 (10)
Al20i—Ru1—Al29Aii93.44 (7)Ru5Axv—Si19—Ru3xv117.82 (4)
Al30Bi—Ru1—Al29Aii154.64 (12)Si19vii—Si19—Ru6114.396 (10)
Al30Bii—Ru1—Al29Aii112.49 (16)Ru5Axv—Si19—Ru6120.02 (5)
Al30Ai—Ru1—Al29Aii155.48 (6)Ru3xv—Si19—Ru6115.378 (16)
Al30Aii—Ru1—Al29Aii103.68 (10)Si19vii—Si19—Ru5Bxv116.81 (12)
Si17i—Ru1—Al29Ai60.88 (3)Ru5Axv—Si19—Ru5Bxv2.78 (10)
Si17ii—Ru1—Al29Ai113.93 (8)Ru3xv—Si19—Ru5Bxv118.33 (8)
Al12iii—Ru1—Al29Ai88.24 (10)Ru6—Si19—Ru5Bxv118.15 (10)
Al20ii—Ru1—Al29Ai93.44 (7)Si19vii—Si19—Al1362.212 (12)
Al20i—Ru1—Al29Ai62.72 (10)Ru5Axv—Si19—Al13116.28 (4)
Al30Bi—Ru1—Al29Ai112.49 (15)Ru3xv—Si19—Al13112.756 (19)
Al30Bii—Ru1—Al29Ai154.64 (12)Ru6—Si19—Al1362.290 (14)
Al30Ai—Ru1—Al29Ai103.68 (10)Ru5Bxv—Si19—Al13117.66 (10)
Al30Aii—Ru1—Al29Ai155.48 (6)Si19vii—Si19—Al31A63.073 (15)
Al29Aii—Ru1—Al29Ai59.54 (7)Ru5Axv—Si19—Al31A62.54 (5)
Si17i—Ru1—Al1482.158 (12)Ru3xv—Si19—Al31A116.05 (2)
Si17ii—Ru1—Al1482.158 (12)Ru6—Si19—Al31A114.28 (3)
Al12iii—Ru1—Al1467.80 (2)Ru5Bxv—Si19—Al31A65.01 (12)
Al20ii—Ru1—Al14123.122 (17)Al13—Si19—Al31A61.86 (3)
Al20i—Ru1—Al14123.122 (17)Si19vii—Si19—Al25vii149.448 (13)
Al30Bi—Ru1—Al1459.76 (8)Ru5Axv—Si19—Al25vii60.67 (5)
Al30Bii—Ru1—Al1459.76 (8)Ru3xv—Si19—Al25vii149.29 (2)
Al30Ai—Ru1—Al1461.99 (3)Ru6—Si19—Al25vii59.526 (14)
Al30Aii—Ru1—Al1461.99 (3)Ru5Bxv—Si19—Al25vii58.67 (10)
Al29Aii—Ru1—Al14142.33 (5)Al13—Si19—Al25vii92.054 (18)
Al29Ai—Ru1—Al14142.33 (5)Al31A—Si19—Al25vii91.10 (2)
Si16i—Ru2—Si16ii123.36 (2)Si19vii—Si19—Al23xv94.905 (13)
Si16i—Ru2—Al1261.718 (10)Ru5Axv—Si19—Al23xv61.08 (3)
Si16ii—Ru2—Al1261.718 (10)Ru3xv—Si19—Al23xv58.108 (13)
Si16i—Ru2—Si18i81.434 (14)Ru6—Si19—Al23xv142.54 (2)
Si16ii—Ru2—Si18i147.022 (15)Ru5Bxv—Si19—Al23xv61.03 (8)
Al12—Ru2—Si18i138.220 (13)Al13—Si19—Al23xv154.71 (2)
Si16i—Ru2—Si18ii147.022 (15)Al31A—Si19—Al23xv99.30 (3)
Si16ii—Ru2—Si18ii81.434 (14)Al25vii—Si19—Al23xv105.80 (2)
Al12—Ru2—Si18ii138.220 (13)Si19vii—Si19—Al31B78.60 (16)
Si18i—Ru2—Si18ii68.26 (2)Ru5Axv—Si19—Al31B54.13 (13)
Si16i—Ru2—Al28ii143.769 (17)Ru3xv—Si19—Al31B131.36 (16)
Si16ii—Ru2—Al28ii63.620 (15)Ru6—Si19—Al31B105.19 (13)
Al12—Ru2—Al28ii110.636 (16)Ru5Bxv—Si19—Al31B56.15 (17)
Si18i—Ru2—Al28ii110.775 (16)Al13—Si19—Al31B63.90 (11)
Si18ii—Ru2—Al28ii63.730 (15)Al31A—Si19—Al31B16.07 (16)
Si16i—Ru2—Al28i63.620 (15)Al25vii—Si19—Al31B75.04 (16)
Si16ii—Ru2—Al28i143.769 (17)Al23xv—Si19—Al31B103.02 (11)
Al12—Ru2—Al28i110.636 (16)Ru1ix—Al20—Si16162.93 (2)
Si18i—Ru2—Al28i63.730 (15)Ru1ix—Al20—Si18111.67 (2)
Si18ii—Ru2—Al28i110.775 (16)Si16—Al20—Si1880.894 (18)
Al28ii—Ru2—Al28i90.55 (2)Ru1ix—Al20—Ru6vii125.197 (19)
Si16i—Ru2—Al20i58.997 (14)Si16—Al20—Ru6vii58.004 (14)
Si16ii—Ru2—Al20i111.555 (15)Si18—Al20—Ru6vii105.61 (2)
Al12—Ru2—Al20i83.470 (17)Ru1ix—Al20—Ru2ix116.882 (18)
Si18i—Ru2—Al20i59.691 (15)Si16—Al20—Ru2ix58.669 (14)
Si18ii—Ru2—Al20i93.313 (15)Si18—Al20—Ru2ix58.968 (14)
Al28ii—Ru2—Al20i156.733 (17)Ru6vii—Al20—Ru2ix116.420 (18)
Al28i—Ru2—Al20i101.912 (16)Ru1ix—Al20—Al30A59.97 (3)
Si16i—Ru2—Al20ii111.555 (15)Si16—Al20—Al30A112.80 (3)
Si16ii—Ru2—Al20ii58.997 (14)Si18—Al20—Al30A156.41 (9)
Al12—Ru2—Al20ii83.470 (17)Ru6vii—Al20—Al30A69.68 (6)
Si18i—Ru2—Al20ii93.313 (15)Ru2ix—Al20—Al30A144.39 (9)
Si18ii—Ru2—Al20ii59.691 (15)Ru1ix—Al20—Al20xviii58.538 (11)
Al28ii—Ru2—Al20ii101.912 (16)Si16—Al20—Al20xviii111.059 (14)
Al28i—Ru2—Al20ii156.733 (17)Si18—Al20—Al20xviii92.718 (15)
Al20i—Ru2—Al20ii60.16 (2)Ru6vii—Al20—Al20xviii155.712 (11)
Si16i—Ru2—Al14iv81.602 (12)Ru2ix—Al20—Al20xviii59.918 (10)
Si16ii—Ru2—Al14iv81.602 (12)Al30A—Al20—Al20xviii99.43 (8)
Al12—Ru2—Al14iv69.26 (2)Ru1ix—Al20—Al30B58.73 (7)
Si18i—Ru2—Al14iv126.881 (15)Si16—Al20—Al30B110.92 (8)
Si18ii—Ru2—Al14iv126.881 (15)Si18—Al20—Al30B165.71 (13)
Al28ii—Ru2—Al14iv63.592 (15)Ru6vii—Al20—Al30B75.79 (10)
Al28i—Ru2—Al14iv63.592 (15)Ru2ix—Al20—Al30B133.67 (16)
Al20i—Ru2—Al14iv139.634 (15)Al30A—Al20—Al30B11.01 (8)
Al20ii—Ru2—Al14iv139.634 (15)Al20xviii—Al20—Al30B90.41 (13)
Al15—Ru3—Si19v146.524 (15)Ru1ix—Al20—Al29A60.00 (3)
Al15—Ru3—Si19vi146.524 (15)Si16—Al20—Al29A136.44 (3)
Si19v—Ru3—Si19vi57.56 (2)Si18—Al20—Al29A59.37 (3)
Al15—Ru3—Al21vii72.113 (11)Ru6vii—Al20—Al29A113.50 (3)
Si19v—Ru3—Al21vii79.846 (14)Ru2ix—Al20—Al29A107.50 (3)
Si19vi—Ru3—Al21vii137.403 (15)Al30A—Al20—Al29A100.36 (6)
Al15—Ru3—Al2172.112 (11)Al20xviii—Al20—Al29A89.41 (3)
Si19v—Ru3—Al21137.404 (15)Al30B—Al20—Al29A106.75 (11)
Si19vi—Ru3—Al2179.847 (14)Ru1ix—Al20—Al24vii113.26 (2)
Al21vii—Ru3—Al21142.73 (2)Si16—Al20—Al24vii83.043 (19)
Al15—Ru3—Al26v109.98 (2)Si18—Al20—Al24vii57.344 (17)
Si19v—Ru3—Al26v70.039 (14)Ru6vii—Al20—Al24vii58.487 (14)
Si19vi—Ru3—Al26v100.573 (15)Ru2ix—Al20—Al24vii108.797 (19)
Al21vii—Ru3—Al26v61.378 (15)Al30A—Al20—Al24vii103.75 (9)
Al21—Ru3—Al26v123.640 (16)Al20xviii—Al20—Al24vii145.427 (14)
Al15—Ru3—Al26vi109.98 (2)Al30B—Al20—Al24vii114.60 (16)
Si19v—Ru3—Al26vi100.573 (15)Al29A—Al20—Al24vii61.56 (3)
Si19vi—Ru3—Al26vi70.039 (14)Ru1ix—Al20—Al29B61.22 (13)
Al21vii—Ru3—Al26vi123.640 (16)Si16—Al20—Al29B135.26 (13)
Al21—Ru3—Al26vi61.378 (15)Si18—Al20—Al29B58.55 (11)
Al26v—Ru3—Al26vi66.06 (2)Ru6vii—Al20—Al29B112.61 (11)
Al15—Ru3—Al23vii82.61 (2)Ru2ix—Al20—Al29B107.37 (10)
Si19v—Ru3—Al23vii67.631 (14)Al30A—Al20—Al29B100.96 (12)
Si19vi—Ru3—Al23vii98.759 (15)Al20xviii—Al20—Al29B90.42 (11)
Al21vii—Ru3—Al23vii60.570 (14)Al30B—Al20—Al29B107.52 (16)
Al21—Ru3—Al23vii123.873 (15)Al29A—Al20—Al29B1.27 (13)
Al26v—Ru3—Al23vii111.863 (15)Al24vii—Al20—Al29B60.35 (12)
Al26vi—Ru3—Al23vii167.327 (15)Ru7xx—Al21—Ru3137.97 (2)
Al15—Ru3—Al2382.61 (2)Ru7xx—Al21—Al23123.35 (2)
Si19v—Ru3—Al2398.760 (15)Ru3—Al21—Al2360.742 (15)
Si19vi—Ru3—Al2367.632 (14)Ru7xx—Al21—Si16v113.707 (19)
Al21vii—Ru3—Al23123.873 (16)Ru3—Al21—Si16v103.294 (18)
Al21—Ru3—Al2360.570 (14)Al23—Al21—Si16v104.90 (2)
Al26v—Ru3—Al23167.328 (15)Ru7xx—Al21—Al26vi123.77 (2)
Al26vi—Ru3—Al23111.862 (15)Ru3—Al21—Al26vi60.167 (15)
Al23vii—Ru3—Al2367.20 (2)Al23—Al21—Al26vi111.01 (2)
Al31B—Ru4A—Al31Bvii30.1 (4)Si16v—Al21—Al26vi59.684 (17)
Al31B—Ru4A—Al15141.68 (13)Ru7xx—Al21—Si17vii113.06 (2)
Al31Bvii—Ru4A—Al15141.68 (13)Ru3—Al21—Si17vii103.791 (18)
Al31B—Ru4A—Al31Cvii48.4 (5)Al23—Al21—Si17vii59.380 (16)
Al31Bvii—Ru4A—Al31Cvii18.8 (3)Si16v—Al21—Si17vii55.701 (16)
Al15—Ru4A—Al31Cvii136.5 (3)Al26vi—Al21—Si17vii105.59 (2)
Al31B—Ru4A—Al31C18.8 (3)Ru7xx—Al21—Al30Avii60.44 (5)
Al31Bvii—Ru4A—Al31C48.4 (5)Ru3—Al21—Al30Avii132.37 (5)
Al15—Ru4A—Al31C136.5 (3)Al23—Al21—Al30Avii73.48 (6)
Al31Cvii—Ru4A—Al31C66.2 (7)Si16v—Al21—Al30Avii100.28 (3)
Al31B—Ru4A—Al29Bviii72.6 (4)Al26vi—Al21—Al30Avii159.92 (3)
Al31Bvii—Ru4A—Al29Bviii88.7 (3)Si17vii—Al21—Al30Avii58.84 (3)
Al15—Ru4A—Al29Bviii128.2 (2)Ru7xx—Al21—Al28v62.275 (15)
Al31Cvii—Ru4A—Al29Bviii94.8 (3)Ru3—Al21—Al28v129.35 (2)
Al31C—Ru4A—Al29Bviii60.1 (4)Al23—Al21—Al28v161.21 (2)
Al31B—Ru4A—Al29Bix88.7 (3)Si16v—Al21—Al28v59.224 (16)
Al31Bvii—Ru4A—Al29Bix72.6 (4)Al26vi—Al21—Al28v71.198 (18)
Al15—Ru4A—Al29Bix128.2 (2)Si17vii—Al21—Al28v101.86 (2)
Al31Cvii—Ru4A—Al29Bix60.1 (4)Al30Avii—Al21—Al28v98.28 (5)
Al31C—Ru4A—Al29Bix94.8 (3)Ru7xx—Al21—Al1589.143 (19)
Al29Bviii—Ru4A—Al29Bix64.3 (3)Ru3—Al21—Al1550.129 (15)
Al31B—Ru4A—Al1371.34 (15)Al23—Al21—Al1572.82 (2)
Al31Bvii—Ru4A—Al1371.34 (15)Si16v—Al21—Al15151.61 (2)
Al15—Ru4A—Al1373.69 (5)Al26vi—Al21—Al1594.05 (2)
Al31Cvii—Ru4A—Al1378.6 (3)Si17vii—Al21—Al15132.05 (3)
Al31C—Ru4A—Al1378.6 (3)Al30Avii—Al21—Al15105.85 (3)
Al29Bviii—Ru4A—Al13136.8 (3)Al28v—Al21—Al15125.96 (3)
Al29Bix—Ru4A—Al13136.8 (3)Ru7xx—Al21—Al28viii62.811 (15)
Al31B—Ru4A—Si18ix153.56 (16)Ru3—Al21—Al28viii90.535 (18)
Al31Bvii—Ru4A—Si18ix127.1 (2)Al23—Al21—Al28viii143.52 (2)
Al15—Ru4A—Si18ix62.31 (7)Si16v—Al21—Al28viii103.27 (2)
Al31Cvii—Ru4A—Si18ix108.4 (4)Al26vi—Al21—Al28viii65.378 (17)
Al31C—Ru4A—Si18ix158.6 (3)Si17vii—Al21—Al28viii156.51 (2)
Al29Bviii—Ru4A—Si18ix101.1 (3)Al30Avii—Al21—Al28viii123.23 (5)
Al29Bix—Ru4A—Si18ix66.0 (2)Al28v—Al21—Al28viii55.06 (2)
Al13—Ru4A—Si18ix121.64 (8)Al15—Al21—Al28viii71.34 (2)
Al31B—Ru4A—Si18viii127.1 (2)Si9A—Al22—Si9B22.09 (6)
Al31Bvii—Ru4A—Si18viii153.56 (16)Si9A—Al22—Ru5A130.73 (6)
Al15—Ru4A—Si18viii62.31 (7)Si9B—Al22—Ru5A108.84 (7)
Al31Cvii—Ru4A—Si18viii158.6 (3)Si9A—Al22—Si10A103.32 (3)
Al31C—Ru4A—Si18viii108.4 (4)Si9B—Al22—Si10A93.38 (8)
Al29Bviii—Ru4A—Si18viii66.0 (2)Ru5A—Al22—Si10A56.05 (10)
Al29Bix—Ru4A—Si18viii101.1 (3)Si9A—Al22—Al32Ax111.57 (3)
Al13—Ru4A—Si18viii121.64 (8)Si9B—Al22—Al32Ax100.13 (4)
Si18ix—Ru4A—Si18viii68.65 (6)Ru5A—Al22—Al32Ax61.66 (6)
Al31B—Ru4A—Al2781.93 (16)Si10A—Al22—Al32Ax117.32 (9)
Al31Bvii—Ru4A—Al27107.8 (2)Si9A—Al22—Ru5B132.98 (12)
Al15—Ru4A—Al2768.62 (6)Si9B—Al22—Ru5B110.98 (13)
Al31Cvii—Ru4A—Al27125.6 (4)Ru5A—Al22—Ru5B3.10 (10)
Al31C—Ru4A—Al2769.2 (3)Si10A—Al22—Ru5B58.60 (13)
Al29Bviii—Ru4A—Al2788.75 (18)Al32Ax—Al22—Ru5B59.40 (10)
Al29Bix—Ru4A—Al27153.02 (17)Si9A—Al22—Al24158.31 (3)
Al13—Ru4A—Al2763.279 (16)Si9B—Al22—Al24157.71 (5)
Si18ix—Ru4A—Al27124.15 (11)Ru5A—Al22—Al2458.96 (3)
Si18viii—Ru4A—Al2766.03 (4)Si10A—Al22—Al2464.35 (6)
Al31B—Ru4A—Al27vii107.8 (2)Al32Ax—Al22—Al2490.11 (2)
Al31Bvii—Ru4A—Al27vii81.93 (16)Ru5B—Al22—Al2457.77 (10)
Al15—Ru4A—Al27vii68.62 (6)Si9A—Al22—Al27x101.59 (2)
Al31Cvii—Ru4A—Al27vii69.2 (3)Si9B—Al22—Al27x112.79 (4)
Al31C—Ru4A—Al27vii125.6 (4)Ru5A—Al22—Al27x111.30 (7)
Al29Bviii—Ru4A—Al27vii153.02 (17)Si10A—Al22—Al27x153.82 (6)
Al29Bix—Ru4A—Al27vii88.75 (18)Al32Ax—Al22—Al27x59.17 (2)
Al13—Ru4A—Al27vii63.280 (16)Ru5B—Al22—Al27x108.24 (13)
Si18ix—Ru4A—Al27vii66.03 (4)Al24—Al22—Al27x89.47 (2)
Si18viii—Ru4A—Al27vii124.15 (11)Si9A—Al22—Al1190.74 (3)
Al27—Ru4A—Al27vii118.19 (6)Si9B—Al22—Al11103.79 (4)
Al31B—Ru4B—Al31Bvii33.6 (5)Ru5A—Al22—Al11110.59 (4)
Al31B—Ru4B—Al31Cvii53.9 (7)Si10A—Al22—Al1162.61 (12)
Al31Bvii—Ru4B—Al31Cvii20.7 (4)Al32Ax—Al22—Al11156.05 (3)
Al31B—Ru4B—Al31C20.7 (4)Ru5B—Al22—Al11111.75 (8)
Al31Bvii—Ru4B—Al31C53.9 (7)Al24—Al22—Al1167.886 (18)
Al31Cvii—Ru4B—Al31C73.5 (10)Al27x—Al22—Al11109.29 (2)
Al31B—Ru4B—Al29Bviii78.9 (6)Si9A—Al22—Al32Bx103.33 (10)
Al31Bvii—Ru4B—Al29Bviii97.3 (8)Si9B—Al22—Al32Bx87.15 (11)
Al31Cvii—Ru4B—Al29Bviii103.3 (8)Ru5A—Al22—Al32Bx53.28 (10)
Al31C—Ru4B—Al29Bviii64.5 (6)Si10A—Al22—Al32Bx104.81 (14)
Al31B—Ru4B—Al29Bix97.3 (8)Al32Ax—Al22—Al32Bx18.94 (9)
Al31Bvii—Ru4B—Al29Bix78.9 (6)Ru5B—Al22—Al32Bx51.91 (12)
Al31Cvii—Ru4B—Al29Bix64.5 (6)Al24—Al22—Al32Bx97.29 (10)
Al31C—Ru4B—Al29Bix103.3 (8)Al27x—Al22—Al32Bx76.92 (10)
Al29Bviii—Ru4B—Al29Bix67.1 (5)Al11—Al22—Al32Bx163.34 (9)
Al31B—Ru4B—Al31A19.0 (3)Si9A—Al22—Al10B101.92 (15)
Al31Bvii—Ru4B—Al31A19.0 (3)Si9B—Al22—Al10B89.6 (3)
Al31Cvii—Ru4B—Al31A39.4 (5)Ru5A—Al22—Al10B51.4 (3)
Al31C—Ru4B—Al31A39.4 (5)Si10A—Al22—Al10B7.7 (4)
Al29Bviii—Ru4B—Al31A95.5 (7)Al32Ax—Al22—Al10B111.6 (4)
Al29Bix—Ru4B—Al31A95.5 (7)Ru5B—Al22—Al10B54.1 (3)
Al31B—Ru4B—Al1375.4 (4)Al24—Al22—Al10B68.2 (3)
Al31Bvii—Ru4B—Al1375.4 (4)Al27x—Al22—Al10B156.49 (16)
Al31Cvii—Ru4B—Al1382.8 (5)Al11—Al22—Al10B70.0 (5)
Al31C—Ru4B—Al1382.8 (5)Al32Bx—Al22—Al10B98.0 (4)
Al29Bviii—Ru4B—Al13142.6 (5)Si17vii—Al23—Al2161.029 (17)
Al29Bix—Ru4B—Al13142.6 (5)Si17vii—Al23—Ru3103.499 (18)
Al31A—Ru4B—Al1365.7 (3)Al21—Al23—Ru358.687 (14)
Al31B—Ru4B—Al29Aviii86.4 (6)Si17vii—Al23—Ru6100.099 (19)
Al31Bvii—Ru4B—Al29Aviii103.4 (8)Al21—Al23—Ru6109.94 (2)
Al31Cvii—Ru4B—Al29Aviii107.4 (8)Ru3—Al23—Ru6141.414 (19)
Al31C—Ru4B—Al29Aviii72.1 (5)Si17vii—Al23—Si8141.88 (2)
Al29Bviii—Ru4B—Al29Aviii7.6 (2)Al21—Al23—Si8150.82 (2)
Al29Bix—Ru4B—Al29Aviii64.5 (3)Ru3—Al23—Si8112.858 (19)
Al31A—Ru4B—Al29Aviii102.8 (7)Ru6—Al23—Si857.201 (13)
Al13—Ru4B—Al29Aviii148.2 (3)Si17vii—Al23—Al10B107.7 (3)
Al31B—Ru4B—Al29Aix103.4 (8)Al21—Al23—Al10B139.1 (5)
Al31Bvii—Ru4B—Al29Aix86.4 (6)Ru3—Al23—Al10B90.5 (4)
Al31Cvii—Ru4B—Al29Aix72.1 (5)Ru6—Al23—Al10B110.8 (5)
Al31C—Ru4B—Al29Aix107.4 (8)Si8—Al23—Al10B62.3 (5)
Al29Bviii—Ru4B—Al29Aix64.5 (3)Si17vii—Al23—Si10A111.40 (6)
Al29Bix—Ru4B—Al29Aix7.6 (2)Al21—Al23—Si10A146.97 (12)
Al31A—Ru4B—Al29Aix102.8 (7)Ru3—Al23—Si10A96.25 (9)
Al13—Ru4B—Al29Aix148.2 (3)Ru6—Al23—Si10A103.01 (12)
Al29Aviii—Ru4B—Al29Aix61.0 (2)Si8—Al23—Si10A54.96 (11)
Al31B—Ru4B—Al2785.1 (3)Al10B—Al23—Si10A7.9 (4)
Al31Bvii—Ru4B—Al27113.4 (5)Si17vii—Al23—Ru5A56.81 (5)
Al31Cvii—Ru4B—Al27132.4 (7)Al21—Al23—Ru5A108.53 (4)
Al31C—Ru4B—Al2771.1 (4)Ru3—Al23—Ru5A106.29 (5)
Al29Bviii—Ru4B—Al2789.08 (17)Ru6—Al23—Ru5A112.15 (4)
Al29Bix—Ru4B—Al27154.9 (4)Si8—Al23—Ru5A100.65 (4)
Al31A—Ru4B—Al2794.5 (3)Al10B—Al23—Ru5A51.2 (2)
Al13—Ru4B—Al2762.25 (17)Si10A—Al23—Ru5A54.60 (8)
Al29Aviii—Ru4B—Al2790.80 (10)Si17vii—Al23—Ru5B54.40 (11)
Al29Aix—Ru4B—Al27149.4 (3)Al21—Al23—Ru5B107.46 (8)
Al31B—Ru4B—Al27vii113.4 (5)Ru3—Al23—Ru5B108.24 (11)
Al31Bvii—Ru4B—Al27vii85.1 (3)Ru6—Al23—Ru5B110.30 (10)
Al31Cvii—Ru4B—Al27vii71.1 (4)Si8—Al23—Ru5B101.71 (8)
Al31C—Ru4B—Al27vii132.4 (7)Al10B—Al23—Ru5B53.8 (2)
Al29Bviii—Ru4B—Al27vii154.9 (4)Si10A—Al23—Ru5B57.00 (12)
Al29Bix—Ru4B—Al27vii89.08 (17)Ru5A—Al23—Ru5B2.98 (10)
Al31A—Ru4B—Al27vii94.5 (3)Si17vii—Al23—Al2480.338 (18)
Al13—Ru4B—Al27vii62.25 (17)Al21—Al23—Al24137.05 (2)
Al29Aviii—Ru4B—Al27vii149.4 (3)Ru3—Al23—Al24157.64 (2)
Al29Aix—Ru4B—Al27vii90.80 (10)Ru6—Al23—Al2456.553 (13)
Al27—Ru4B—Al27vii113.0 (5)Si8—Al23—Al2461.690 (16)
Al10B—Ru5A—Al32Bvi113.0 (3)Al10B—Al23—Al2467.6 (4)
Al10B—Ru5A—Al31Cvi85.0 (6)Si10A—Al23—Al2462.38 (8)
Al32Bvi—Ru5A—Al31Cvi36.8 (4)Ru5A—Al23—Al2456.98 (4)
Al10B—Ru5A—Al32Bx121.0 (2)Ru5B—Al23—Al2455.77 (9)
Al32Bvi—Ru5A—Al32Bx18.9 (2)Si17vii—Al23—Si19vi66.662 (17)
Al31Cvi—Ru5A—Al32Bx55.1 (4)Al21—Al23—Si19vi72.882 (17)
Al10B—Ru5A—Al31Bvi66.8 (5)Ru3—Al23—Si19vi54.261 (13)
Al32Bvi—Ru5A—Al31Bvi54.8 (2)Ru6—Al23—Si19vi163.70 (2)
Al31Cvi—Ru5A—Al31Bvi19.1 (4)Si8—Al23—Si19vi127.53 (2)
Al32Bx—Ru5A—Al31Bvi72.1 (2)Al10B—Al23—Si19vi67.0 (5)
Al10B—Ru5A—Si19vi78.5 (5)Si10A—Al23—Si19vi74.84 (12)
Al32Bvi—Ru5A—Si19vi107.37 (12)Ru5A—Al23—Si19vi53.13 (4)
Al31Cvi—Ru5A—Si19vi78.9 (3)Ru5B—Al23—Si19vi54.65 (10)
Al32Bx—Ru5A—Si19vi124.43 (12)Al24—Al23—Si19vi109.956 (19)
Al31Bvi—Ru5A—Si19vi70.77 (16)Si18vii—Al24—Ru6108.644 (19)
Al10B—Ru5A—Si10A8.2 (5)Si18vii—Al24—Ru5B110.23 (12)
Al32Bvi—Ru5A—Si10A115.65 (14)Ru6—Al24—Ru5B118.14 (8)
Al31Cvi—Ru5A—Si10A90.9 (4)Si18vii—Al24—Ru5A112.93 (6)
Al32Bx—Ru5A—Si10A120.89 (13)Ru6—Al24—Ru5A117.76 (3)
Al31Bvi—Ru5A—Si10A73.3 (2)Ru5B—Al24—Ru5A3.11 (10)
Si19vi—Ru5A—Si10A85.24 (13)Si18vii—Al24—Al20vii59.685 (17)
Al10B—Ru5A—Si17vii122.7 (2)Ru6—Al24—Al20vii59.851 (14)
Al32Bvi—Ru5A—Si17vii122.58 (15)Ru5B—Al24—Al20vii104.30 (12)
Al31Cvi—Ru5A—Si17vii134.1 (3)Ru5A—Al24—Al20vii106.90 (6)
Al32Bx—Ru5A—Si17vii116.12 (16)Si18vii—Al24—Al2292.44 (2)
Al31Bvi—Ru5A—Si17vii139.43 (14)Ru6—Al24—Al22156.41 (2)
Si19vi—Ru5A—Si17vii73.14 (3)Ru5B—Al24—Al2260.94 (9)
Si10A—Ru5A—Si17vii121.47 (7)Ru5A—Al24—Al2259.89 (3)
Al10B—Ru5A—Al29Bvii141.5 (6)Al20vii—Al24—Al22143.42 (2)
Al32Bvi—Ru5A—Al29Bvii82.6 (4)Si18vii—Al24—Al29Avii59.24 (4)
Al31Cvi—Ru5A—Al29Bvii119.1 (5)Ru6—Al24—Al29Avii112.61 (10)
Al32Bx—Ru5A—Al29Bvii65.4 (4)Ru5B—Al24—Al29Avii56.43 (16)
Al31Bvi—Ru5A—Al29Bvii137.3 (4)Ru5A—Al24—Al29Avii59.53 (11)
Si19vi—Ru5A—Al29Bvii132.33 (18)Al20vii—Al24—Al29Avii59.19 (11)
Si10A—Ru5A—Al29Bvii133.3 (2)Al22—Al24—Al29Avii86.96 (11)
Si17vii—Ru5A—Al29Bvii63.1 (3)Si18vii—Al24—Ru758.295 (14)
Al10B—Ru5A—Al25v137.7 (6)Ru6—Al24—Ru7118.408 (17)
Al32Bvi—Ru5A—Al25v66.26 (12)Ru5B—Al24—Ru7122.67 (8)
Al31Cvi—Ru5A—Al25v71.2 (3)Ru5A—Al24—Ru7122.40 (3)
Al32Bx—Ru5A—Al25v72.90 (12)Al20vii—Al24—Ru7111.042 (19)
Al31Bvi—Ru5A—Al25v83.44 (16)Al22—Al24—Ru763.710 (14)
Si19vi—Ru5A—Al25v63.15 (3)Al29Avii—Al24—Ru7107.81 (4)
Si10A—Ru5A—Al25v145.72 (16)Si18vii—Al24—Al2690.35 (2)
Si17vii—Ru5A—Al25v63.90 (5)Ru6—Al24—Al2661.627 (14)
Al29Bvii—Ru5A—Al25v80.65 (16)Ru5B—Al24—Al26156.80 (13)
Al10B—Ru5A—Al2475.5 (6)Ru5A—Al24—Al26153.69 (7)
Al32Bvi—Ru5A—Al24123.97 (13)Al20vii—Al24—Al2695.19 (2)
Al31Cvi—Ru5A—Al24140.8 (3)Al22—Al24—Al26109.18 (2)
Al32Bx—Ru5A—Al24107.45 (13)Al29Avii—Al24—Al26146.73 (8)
Al31Bvi—Ru5A—Al24133.11 (16)Ru7—Al24—Al2658.949 (13)
Si19vi—Ru5A—Al24128.12 (6)Si18vii—Al24—Al23145.37 (2)
Si10A—Ru5A—Al2467.45 (12)Ru6—Al24—Al2358.819 (13)
Si17vii—Ru5A—Al2484.51 (5)Ru5B—Al24—Al2361.68 (8)
Al29Bvii—Ru5A—Al2467.0 (2)Ru5A—Al24—Al2360.48 (4)
Al25v—Ru5A—Al24142.69 (11)Al20vii—Al24—Al2388.534 (19)
Al10B—Ru5A—Al29Avii137.2 (6)Al22—Al24—Al23108.79 (2)
Al32Bvi—Ru5A—Al29Avii89.86 (18)Al29Avii—Al24—Al2393.98 (3)
Al31Cvi—Ru5A—Al29Avii126.4 (4)Ru7—Al24—Al23155.98 (2)
Al32Bx—Ru5A—Al29Avii72.55 (17)Al26—Al24—Al23107.13 (2)
Al31Bvi—Ru5A—Al29Avii144.5 (2)Si18vii—Al24—Si8146.78 (2)
Si19vi—Ru5A—Al29Avii130.35 (8)Ru6—Al24—Si856.304 (14)
Si10A—Ru5A—Al29Avii129.07 (15)Ru5B—Al24—Si8102.75 (12)
Si17vii—Ru5A—Al29Avii58.77 (8)Ru5A—Al24—Si899.93 (6)
Al29Bvii—Ru5A—Al29Avii7.3 (2)Al20vii—Al24—Si8116.11 (2)
Al25v—Ru5A—Al29Avii84.03 (10)Al22—Al24—Si8100.20 (2)
Al24—Ru5A—Al29Avii61.83 (10)Al29Avii—Al24—Si8151.16 (3)
Al32Bvi—Ru5B—Al32Bx19.2 (2)Ru7—Al24—Si8100.331 (19)
Al32Bvi—Ru5B—Al29Bvii85.9 (4)Al26—Al24—Si856.507 (18)
Al32Bx—Ru5B—Al29Bvii68.5 (4)Al23—Al24—Si857.219 (18)
Al32Bvi—Ru5B—Si17vii126.7 (2)Si9Aix—Al25—Ru5Bxvi128.55 (13)
Al32Bx—Ru5B—Si17vii121.3 (3)Si9Aix—Al25—Si9Bix21.90 (6)
Al29Bvii—Ru5B—Si17vii66.4 (3)Ru5Bxvi—Al25—Si9Bix106.70 (14)
Al32Bvi—Ru5B—Al31Cvi36.2 (4)Si9Aix—Al25—Ru6vii114.15 (3)
Al32Bx—Ru5B—Al31Cvi54.7 (4)Ru5Bxvi—Al25—Ru6vii115.92 (12)
Al29Bvii—Ru5B—Al31Cvi121.9 (5)Si9Bix—Al25—Ru6vii135.61 (6)
Si17vii—Ru5B—Al31Cvi134.6 (3)Si9Aix—Al25—Ru5Axvi131.44 (7)
Al32Bvi—Ru5B—Al10B108.8 (4)Ru5Bxvi—Al25—Ru5Axvi3.09 (11)
Al32Bx—Ru5B—Al10B117.8 (3)Si9Bix—Al25—Ru5Axvi109.56 (8)
Al29Bvii—Ru5B—Al10B142.6 (6)Ru6vii—Al25—Ru5Axvi113.37 (6)
Si17vii—Ru5B—Al10B120.9 (2)Si9Aix—Al25—Al32Avii110.33 (3)
Al31Cvi—Ru5B—Al10B80.8 (6)Ru5Bxvi—Al25—Al32Avii61.68 (10)
Al32Bvi—Ru5B—Al29Avii93.6 (2)Si9Bix—Al25—Al32Avii100.19 (5)
Al32Bx—Ru5B—Al29Avii76.0 (2)Ru6vii—Al25—Al32Avii110.16 (3)
Al29Bvii—Ru5B—Al29Avii7.7 (2)Ru5Axvi—Al25—Al32Avii60.43 (4)
Si17vii—Ru5B—Al29Avii61.77 (15)Si9Aix—Al25—Si19vii164.51 (3)
Al31Cvi—Ru5B—Al29Avii129.6 (4)Ru5Bxvi—Al25—Si19vii58.62 (11)
Al10B—Ru5B—Al29Avii138.2 (6)Si9Bix—Al25—Si19vii159.82 (6)
Al32Bvi—Ru5B—Si19vi105.1 (2)Ru6vii—Al25—Si19vii57.349 (14)
Al32Bx—Ru5B—Si19vi123.0 (2)Ru5Axvi—Al25—Si19vii56.18 (5)
Al29Bvii—Ru5B—Si19vi135.8 (3)Al32Avii—Al25—Si19vii85.14 (2)
Si17vii—Ru5B—Si19vi73.17 (10)Si9Aix—Al25—Al27vii99.80 (3)
Al31Cvi—Ru5B—Si19vi76.0 (3)Ru5Bxvi—Al25—Al27vii112.82 (13)
Al10B—Ru5B—Si19vi74.8 (5)Si9Bix—Al25—Al27vii111.92 (5)
Al29Avii—Ru5B—Si19vi133.56 (19)Ru6vii—Al25—Al27vii62.571 (15)
Al32Bvi—Ru5B—Al25v67.10 (14)Ru5Axvi—Al25—Al27vii110.28 (5)
Al32Bx—Ru5B—Al25v74.45 (15)Al32Avii—Al25—Al27vii59.01 (2)
Al29Bvii—Ru5B—Al25v84.3 (2)Si19vii—Al25—Al27vii87.59 (2)
Si17vii—Ru5B—Al25v65.67 (11)Si9Aix—Al25—Si17xv104.45 (3)
Al31Cvi—Ru5B—Al25v70.8 (3)Ru5Bxvi—Al25—Si17xv55.05 (10)
Al10B—Ru5B—Al25v133.0 (6)Si9Bix—Al25—Si17xv93.09 (5)
Al29Avii—Ru5B—Al25v87.84 (18)Ru6vii—Al25—Si17xv100.998 (18)
Si19vi—Ru5B—Al25v62.70 (9)Ru5Axvi—Al25—Si17xv56.63 (4)
Al32Bvi—Ru5B—Al31Bvi53.4 (2)Al32Avii—Al25—Si17xv116.53 (3)
Al32Bx—Ru5B—Al31Bvi70.9 (2)Si19vii—Al25—Si17xv67.345 (17)
Al29Bvii—Ru5B—Al31Bvi139.2 (4)Al27vii—Al25—Si17xv154.93 (2)
Si17vii—Ru5B—Al31Bvi137.7 (2)Si9Aix—Al25—Al32Bvii102.03 (10)
Al31Cvi—Ru5B—Al31Bvi18.3 (3)Ru5Bxvi—Al25—Al32Bvii52.82 (12)
Al10B—Ru5B—Al31Bvi63.3 (5)Si9Bix—Al25—Al32Bvii87.00 (11)
Al29Avii—Ru5B—Al31Bvi146.8 (3)Ru6vii—Al25—Al32Bvii128.48 (10)
Si19vi—Ru5B—Al31Bvi67.8 (2)Ru5Axvi—Al25—Al32Bvii52.63 (10)
Al25v—Ru5B—Al31Bvi82.13 (19)Al32Avii—Al25—Al32Bvii18.95 (9)
Al32Bvi—Ru5B—Al24126.01 (19)Si19vii—Al25—Al32Bvii92.89 (10)
Al32Bx—Ru5B—Al24110.14 (19)Al27vii—Al25—Al32Bvii76.56 (10)
Al29Bvii—Ru5B—Al2469.6 (3)Si17xv—Al25—Al32Bvii104.12 (10)
Si17vii—Ru5B—Al2486.99 (15)Si9Aix—Al25—Si1697.04 (3)
Al31Cvi—Ru5B—Al24138.4 (3)Ru5Bxvi—Al25—Si16101.30 (8)
Al10B—Ru5B—Al2474.1 (6)Si9Bix—Al25—Si16105.52 (5)
Al29Avii—Ru5B—Al2464.23 (16)Ru6vii—Al25—Si1655.609 (13)
Si19vi—Ru5B—Al24126.23 (15)Ru5Axvi—Al25—Si16101.37 (3)
Al25v—Ru5B—Al24148.3 (3)Al32Avii—Al25—Si16152.62 (3)
Al31Bvi—Ru5B—Al24129.4 (2)Si19vii—Al25—Si1667.479 (16)
Al32Bvi—Ru5B—Si10A111.8 (2)Al27vii—Al25—Si16117.52 (2)
Al32Bx—Ru5B—Si10A118.1 (2)Si17xv—Al25—Si1653.440 (15)
Al29Bvii—Ru5B—Si10A134.7 (3)Al32Bvii—Al25—Si16153.98 (10)
Si17vii—Ru5B—Si10A120.13 (14)Si9Aix—Al25—Al22xxi55.52 (2)
Al31Cvi—Ru5B—Si10A86.6 (4)Ru5Bxvi—Al25—Al22xxi110.56 (8)
Al10B—Ru5B—Si10A7.9 (4)Si9Bix—Al25—Al22xxi56.81 (5)
Al29Avii—Ru5B—Si10A130.4 (2)Ru6vii—Al25—Al22xxi114.61 (2)
Si19vi—Ru5B—Si10A81.33 (19)Ru5Axvi—Al25—Al22xxi110.96 (3)
Al25v—Ru5B—Si10A140.8 (3)Al32Avii—Al25—Al22xxi58.16 (2)
Al31Bvi—Ru5B—Si10A69.6 (2)Si19vii—Al25—Al22xxi138.51 (2)
Al24—Ru5B—Si10A66.34 (15)Al27vii—Al25—Al22xxi58.274 (17)
Si16vii—Ru6—Si1973.752 (14)Si17xv—Al25—Al22xxi143.73 (2)
Si16vii—Ru6—Si8119.473 (16)Al32Bvii—Al25—Al22xxi58.96 (10)
Si19—Ru6—Si884.882 (16)Si16—Al25—Al22xxi146.74 (2)
Si16vii—Ru6—Al2485.523 (14)Ru3xv—Al26—Si16vii102.244 (18)
Si19—Ru6—Al24129.919 (14)Ru3xv—Al26—Al21xv58.455 (14)
Si8—Ru6—Al2466.403 (16)Si16vii—Al26—Al21xv59.966 (17)
Si16vii—Ru6—Al25vii65.368 (14)Ru3xv—Al26—Si895.784 (19)
Si19—Ru6—Al25vii63.124 (14)Si16vii—Al26—Si8111.61 (2)
Si8—Ru6—Al25vii145.654 (17)Al21xv—Al26—Si8146.06 (2)
Al24—Ru6—Al25vii144.281 (16)Ru3xv—Al26—Ru7141.451 (19)
Si16vii—Ru6—Al20vii59.439 (14)Si16vii—Al26—Ru799.520 (18)
Si19—Ru6—Al20vii131.436 (15)Al21xv—Al26—Ru7108.583 (19)
Si8—Ru6—Al20vii128.011 (16)Si8—Al26—Ru7105.23 (2)
Al24—Ru6—Al20vii61.662 (15)Ru3xv—Al26—Al11113.311 (19)
Al25vii—Ru6—Al20vii84.991 (15)Si16vii—Al26—Al11144.17 (2)
Si16vii—Ru6—Al23147.194 (14)Al21xv—Al26—Al11145.26 (2)
Si19—Ru6—Al23135.764 (15)Si8—Al26—Al1161.90 (2)
Si8—Ru6—Al2362.146 (17)Ru7—Al26—Al1154.412 (12)
Al24—Ru6—Al2364.628 (14)Ru3xv—Al26—Ru6105.140 (16)
Al25vii—Ru6—Al23134.258 (15)Si16vii—Al26—Ru655.329 (13)
Al20vii—Ru6—Al2392.788 (15)Al21xv—Al26—Ru6106.047 (19)
Si16vii—Ru6—Al13133.510 (18)Si8—Al26—Ru656.299 (13)
Si19—Ru6—Al1359.769 (18)Ru7—Al26—Ru6113.409 (17)
Si8—Ru6—Al1358.452 (17)Al11—Al26—Ru6108.61 (2)
Al24—Ru6—Al13122.930 (17)Ru3xv—Al26—Al24155.88 (2)
Al25vii—Ru6—Al1392.680 (17)Si16vii—Al26—Al2479.141 (18)
Al20vii—Ru6—Al13163.833 (17)Al21xv—Al26—Al24135.83 (2)
Al23—Ru6—Al1377.385 (18)Si8—Al26—Al2462.192 (16)
Si16vii—Ru6—Al2659.727 (14)Ru7—Al26—Al2459.871 (13)
Si19—Ru6—Al2667.301 (13)Al11—Al26—Al2466.696 (18)
Si8—Ru6—Al2659.762 (16)Ru6—Al26—Al2455.497 (13)
Al24—Ru6—Al2662.875 (14)Ru3xv—Al26—Al26vii56.970 (11)
Al25vii—Ru6—Al26113.153 (15)Si16vii—Al26—Al26vii151.308 (13)
Al20vii—Ru6—Al2697.033 (15)Al21xv—Al26—Al26vii112.414 (15)
Al23—Ru6—Al26112.461 (14)Si8—Al26—Al26vii57.481 (12)
Al13—Ru6—Al2698.582 (17)Ru7—Al26—Al26vii108.889 (11)
Si16vii—Ru6—Al27125.610 (15)Al11—Al26—Al26vii58.656 (12)
Si19—Ru6—Al2789.805 (15)Ru6—Al26—Al26vii107.552 (10)
Si8—Ru6—Al27109.764 (16)Al24—Al26—Al26vii111.536 (14)
Al24—Ru6—Al27137.383 (16)Ru4A—Al27—Al30Avii166.95 (10)
Al25vii—Ru6—Al2761.026 (15)Ru4A—Al27—Ru4B5.8 (4)
Al20vii—Ru6—Al27106.387 (15)Al30Avii—Al27—Ru4B172.7 (5)
Al23—Ru6—Al2776.151 (15)Ru4A—Al27—Al32A65.45 (6)
Al13—Ru6—Al2759.067 (16)Al30Avii—Al27—Al32A126.77 (9)
Al26—Ru6—Al27154.792 (15)Ru4B—Al27—Al32A60.3 (4)
Si16vii—Ru6—Al30Avii102.70 (7)Ru4A—Al27—Al1357.67 (2)
Si19—Ru6—Al30Avii132.20 (5)Al30Avii—Al27—Al13122.47 (7)
Si8—Ru6—Al30Avii131.46 (8)Ru4B—Al27—Al1356.81 (15)
Al24—Ru6—Al30Avii96.30 (4)Al32A—Al27—Al1388.32 (3)
Al25vii—Ru6—Al30Avii72.10 (7)Ru4A—Al27—Al22xx113.48 (4)
Al20vii—Ru6—Al30Avii55.35 (3)Al30Avii—Al27—Al22xx74.19 (9)
Al23—Ru6—Al30Avii69.43 (8)Ru4B—Al27—Al22xx110.7 (3)
Al13—Ru6—Al30Avii108.73 (4)Al32A—Al27—Al22xx59.81 (2)
Al26—Ru6—Al30Avii152.08 (3)Al13—Al27—Al22xx144.86 (3)
Al27—Ru6—Al30Avii52.71 (2)Ru4A—Al27—Ru7xx112.40 (5)
Al21x—Ru7—Al11141.649 (18)Al30Avii—Al27—Ru7xx60.33 (2)
Al21x—Ru7—Si18vii91.431 (15)Ru4B—Al27—Ru7xx116.2 (3)
Al11—Ru7—Si18vii126.820 (18)Al32A—Al27—Ru7xx113.89 (2)
Al21x—Ru7—Al30Ai65.17 (9)Al13—Al27—Ru7xx150.38 (3)
Al11—Ru7—Al30Ai89.79 (9)Al22xx—Al27—Ru7xx64.048 (15)
Si18vii—Ru7—Al30Ai119.80 (5)Ru4A—Al27—Al25vii115.47 (7)
Al21x—Ru7—Al27x74.643 (15)Al30Avii—Al27—Al25vii77.24 (6)
Al11—Ru7—Al27x116.895 (19)Ru4B—Al27—Al25vii109.8 (5)
Si18vii—Ru7—Al27x63.540 (14)Al32A—Al27—Al25vii59.34 (2)
Al30Ai—Ru7—Al27x57.08 (4)Al13—Al27—Al25vii89.33 (2)
Al21x—Ru7—Al30Bi75.60 (15)Al22xx—Al27—Al25vii62.742 (18)
Al11—Ru7—Al30Bi79.40 (15)Ru7xx—Al27—Al25vii118.42 (2)
Si18vii—Ru7—Al30Bi124.40 (8)Ru4A—Al27—Al30Bvii172.03 (8)
Al30Ai—Ru7—Al30Bi10.77 (8)Al30Avii—Al27—Al30Bvii10.21 (7)
Al27x—Ru7—Al30Bi60.87 (9)Ru4B—Al27—Al30Bvii174.26 (18)
Al21x—Ru7—Al26126.897 (15)Al32A—Al27—Al30Bvii116.91 (14)
Al11—Ru7—Al2663.063 (18)Al13—Al27—Al30Bvii128.85 (10)
Si18vii—Ru7—Al2690.562 (14)Al22xx—Al27—Al30Bvii64.32 (14)
Al30Ai—Ru7—Al26148.47 (7)Ru7xx—Al27—Al30Bvii59.63 (7)
Al27x—Ru7—Al26148.316 (15)Al25vii—Al27—Al30Bvii70.90 (10)
Al30Bi—Ru7—Al26140.15 (13)Ru4A—Al27—Ru6115.40 (3)
Al21x—Ru7—Al28xi64.563 (16)Al30Avii—Al27—Ru668.21 (4)
Al11—Ru7—Al28xi95.882 (19)Ru4B—Al27—Ru6113.4 (2)
Si18vii—Ru7—Al28xi116.253 (15)Al32A—Al27—Ru6105.41 (2)
Al30Ai—Ru7—Al28xi102.54 (4)Al13—Al27—Ru658.283 (15)
Al27x—Ru7—Al28xi139.202 (16)Al22xx—Al27—Ru6113.12 (2)
Al30Bi—Ru7—Al28xi106.22 (9)Ru7xx—Al27—Ru6127.19 (2)
Al26—Ru7—Al28xi67.242 (15)Al25vii—Al27—Ru656.403 (14)
Al21x—Ru7—Al24147.730 (15)Al30Bvii—Al27—Ru671.86 (8)
Al11—Ru7—Al2470.529 (17)Ru4A—Al27—Si18viii56.67 (4)
Si18vii—Ru7—Al2456.314 (14)Al30Avii—Al27—Si18viii115.33 (3)
Al30Ai—Ru7—Al24127.09 (6)Ru4B—Al27—Si18viii60.5 (3)
Al27x—Ru7—Al2488.245 (15)Al32A—Al27—Si18viii88.48 (2)
Al30Bi—Ru7—Al24119.75 (13)Al13—Al27—Si18viii108.54 (2)
Al26—Ru7—Al2461.180 (14)Al22xx—Al27—Si18viii86.554 (19)
Al28xi—Ru7—Al24127.289 (15)Ru7xx—Al27—Si18viii55.752 (13)
Al21x—Ru7—Al28vii66.535 (15)Al25vii—Al27—Si18viii143.16 (2)
Al11—Ru7—Al28vii131.540 (19)Al30Bvii—Al27—Si18viii115.37 (7)
Si18vii—Ru7—Al28vii59.617 (14)Ru6—Al27—Si18viii159.70 (2)
Al30Ai—Ru7—Al28vii131.67 (9)Ru4A—Al27—Al1554.37 (6)
Al27x—Ru7—Al28vii107.887 (16)Al30Avii—Al27—Al15112.87 (9)
Al30Bi—Ru7—Al28vii142.13 (15)Ru4B—Al27—Al1559.8 (4)
Al26—Ru7—Al28vii69.242 (15)Al32A—Al27—Al15119.51 (3)
Al28xi—Ru7—Al28vii56.639 (19)Al13—Al27—Al1565.91 (2)
Al24—Ru7—Al28vii94.190 (14)Al22xx—Al27—Al15140.86 (3)
Al21x—Ru7—Al22127.209 (14)Ru7xx—Al27—Al1585.55 (2)
Al11—Ru7—Al2260.831 (18)Al25vii—Al27—Al15155.08 (3)
Si18vii—Ru7—Al2287.294 (15)Al30Bvii—Al27—Al15121.91 (13)
Al30Ai—Ru7—Al2270.12 (7)Ru6—Al27—Al15104.73 (2)
Al27x—Ru7—Al2257.854 (15)Si18viii—Al27—Al1555.05 (2)
Al30Bi—Ru7—Al2262.53 (12)Ru2ix—Al28—Al28xiv165.46 (3)
Al26—Ru7—Al22105.892 (14)Ru2ix—Al28—Si1657.410 (14)
Al28xi—Ru7—Al22154.796 (16)Al28xiv—Al28—Si16109.86 (3)
Al24—Ru7—Al2257.266 (13)Ru2ix—Al28—Si1857.930 (14)
Al28vii—Ru7—Al22145.875 (15)Al28xiv—Al28—Si18114.58 (3)
Si10A—Si8—Al13134.29 (9)Si16—Al28—Si1875.902 (18)
Si10A—Si8—Ru6112.83 (3)Ru2ix—Al28—Ru7xxii123.54 (2)
Al13—Si8—Ru662.754 (12)Al28xiv—Al28—Ru7xxii63.76 (2)
Si10A—Si8—Ru6vii112.83 (3)Si16—Al28—Ru7xxii104.017 (19)
Al13—Si8—Ru6vii62.754 (12)Si18—Al28—Ru7xxii178.26 (2)
Ru6—Si8—Ru6vii124.23 (2)Ru2ix—Al28—Al14xiv59.956 (18)
Si10A—Si8—Al26vii113.89 (8)Al28xiv—Al28—Al14xiv127.43 (3)
Al13—Si8—Al26vii104.28 (2)Si16—Al28—Al14xiv77.13 (2)
Ru6—Si8—Al26vii120.73 (2)Si18—Al28—Al14xiv117.52 (2)
Ru6vii—Si8—Al26vii63.940 (13)Ru7xxii—Al28—Al14xiv64.053 (17)
Si10A—Si8—Al26113.90 (8)Ru2ix—Al28—Al21xvi107.85 (2)
Al13—Si8—Al26104.28 (2)Al28xiv—Al28—Al21xvi65.21 (2)
Ru6—Si8—Al2663.940 (13)Si16—Al28—Al21xvi57.251 (16)
Ru6vii—Si8—Al26120.73 (2)Si18—Al28—Al21xvi125.93 (2)
Al26vii—Si8—Al2665.04 (2)Ru7xxii—Al28—Al21xvi53.162 (13)
Si10A—Si8—Al23vii63.42 (7)Al14xiv—Al28—Al21xvi79.051 (19)
Al13—Si8—Al23vii78.61 (2)Ru2ix—Al28—Ru7vii111.722 (19)
Ru6—Si8—Al23vii117.74 (2)Al28xiv—Al28—Ru7vii59.60 (2)
Ru6vii—Si8—Al23vii60.654 (13)Si16—Al28—Ru7vii94.790 (19)
Al26vii—Si8—Al23vii114.682 (15)Si18—Al28—Ru7vii54.988 (14)
Al26—Si8—Al23vii177.11 (3)Ru7xxii—Al28—Ru7vii123.361 (19)
Si10A—Si8—Al2363.42 (7)Al14xiv—Al28—Ru7vii170.62 (2)
Al13—Si8—Al2378.61 (2)Al21xvi—Al28—Ru7vii100.73 (2)
Ru6—Si8—Al2360.653 (13)Ru2ix—Al28—Al21xvii125.63 (2)
Ru6vii—Si8—Al23117.74 (2)Al28xiv—Al28—Al21xvii59.73 (2)
Al26vii—Si8—Al23177.11 (3)Si16—Al28—Al21xvii145.22 (2)
Al26—Si8—Al23114.681 (15)Si18—Al28—Al21xvii79.480 (18)
Al23vii—Si8—Al2365.44 (2)Ru7xxii—Al28—Al21xvii99.854 (18)
Si10A—Si8—Al1164.29 (9)Al14xiv—Al28—Al21xvii136.84 (3)
Al13—Si8—Al11161.43 (3)Al21xvi—Al28—Al21xvii124.94 (2)
Ru6—Si8—Al11113.799 (13)Ru7vii—Al28—Al21xvii50.654 (12)
Ru6vii—Si8—Al11113.799 (13)Ru5Bvii—Al29A—Ru4Bii124.8 (3)
Al26vii—Si8—Al1160.621 (19)Ru5Bvii—Al29A—Si1758.02 (9)
Al26—Si8—Al1160.621 (19)Ru4Bii—Al29A—Si17164.2 (5)
Al23vii—Si8—Al11116.60 (2)Ru5Bvii—Al29A—Al32Axvii63.08 (13)
Al23—Si8—Al11116.60 (2)Ru4Bii—Al29A—Al32Axvii62.9 (3)
Si10A—Si8—Al10B4.9 (2)Si17—Al29A—Al32Axvii113.93 (14)
Al13—Si8—Al10B129.4 (3)Ru5Bvii—Al29A—Al29Axviii155.59 (12)
Ru6—Si8—Al10B111.37 (10)Ru4Bii—Al29A—Al29Axviii59.50 (11)
Ru6vii—Si8—Al10B111.37 (10)Si17—Al29A—Al29Axviii110.99 (3)
Al26vii—Si8—Al10B117.8 (2)Al32Axvii—Al29A—Al29Axviii110.11 (4)
Al26—Si8—Al10B117.8 (2)Ru5Bvii—Al29A—Ru1ix114.81 (10)
Al23vii—Si8—Al10B59.6 (2)Ru4Bii—Al29A—Ru1ix118.55 (12)
Al23—Si8—Al10B59.6 (2)Si17—Al29A—Ru1ix56.86 (6)
Al11—Si8—Al10B69.2 (3)Al32Axvii—Al29A—Ru1ix154.35 (16)
Si10A—Si8—Al24vii64.91 (3)Al29Axviii—Al29A—Ru1ix60.23 (4)
Al13—Si8—Al24vii118.294 (14)Ru5Bvii—Al29A—Si18110.29 (9)
Ru6—Si8—Al24vii177.69 (3)Ru4Bii—Al29A—Si1864.4 (5)
Ru6vii—Si8—Al24vii57.293 (10)Si17—Al29A—Si18130.88 (19)
Al26vii—Si8—Al24vii61.302 (15)Al32Axvii—Al29A—Si1894.94 (7)
Al26—Si8—Al24vii117.14 (2)Al29Axviii—Al29A—Si1893.31 (3)
Al23vii—Si8—Al24vii61.091 (15)Ru1ix—Al29A—Si18108.8 (2)
Al23—Si8—Al24vii117.26 (2)Ru5Bvii—Al29A—Ru4Aii126.87 (19)
Al11—Si8—Al24vii65.928 (15)Ru4Bii—Al29A—Ru4Aii5.9 (4)
Al10B—Si8—Al24vii66.34 (10)Si17—Al29A—Ru4Aii169.12 (12)
Si9B—Si9A—Al22vii82.44 (11)Al32Axvii—Al29A—Ru4Aii66.40 (11)
Si9B—Si9A—Al2282.44 (11)Al29Axviii—Al29A—Ru4Aii60.32 (4)
Al22vii—Si9A—Al2276.04 (3)Ru1ix—Al29A—Ru4Aii117.76 (8)
Si9B—Si9A—Al1278.41 (14)Si18—Al29A—Ru4Aii58.74 (7)
Al22vii—Si9A—Al12137.27 (3)Ru5Bvii—Al29A—Al29Bxviii150.30 (15)
Al22—Si9A—Al12137.26 (3)Ru4Bii—Al29A—Al29Bxviii55.6 (2)
Si9B—Si9A—Al25ii80.16 (5)Si17—Al29A—Al29Bxviii113.27 (16)
Al22vii—Si9A—Al25ii67.335 (17)Al32Axvii—Al29A—Al29Bxviii102.94 (18)
Al22—Si9A—Al25ii141.05 (4)Al29Axviii—Al29A—Al29Bxviii7.53 (19)
Al12—Si9A—Al25ii71.93 (2)Ru1ix—Al29A—Al29Bxviii65.7 (2)
Si9B—Si9A—Al25i80.16 (5)Si18—Al29A—Al29Bxviii96.40 (12)
Al22vii—Si9A—Al25i141.05 (4)Ru4Aii—Al29A—Al29Bxviii57.23 (17)
Al22—Si9A—Al25i67.334 (17)Ru5Bvii—Al29A—Al20106.68 (14)
Al12—Si9A—Al25i71.93 (2)Ru4Bii—Al29A—Al20112.8 (5)
Al25ii—Si9A—Al25i141.54 (4)Si17—Al29A—Al2078.27 (13)
Si9B—Si9A—Al30Bi146.67 (10)Al32Axvii—Al29A—Al20148.12 (6)
Al22vii—Si9A—Al30Bi103.95 (10)Al29Axviii—Al29A—Al2090.59 (3)
Al22—Si9A—Al30Bi67.98 (7)Ru1ix—Al29A—Al2057.28 (11)
Al12—Si9A—Al30Bi113.01 (9)Si18—Al29A—Al2058.77 (11)
Al25ii—Si9A—Al30Bi132.77 (9)Ru4Aii—Al29A—Al20107.26 (14)
Al25i—Si9A—Al30Bi74.62 (10)Al29Bxviii—Al29A—Al2098.07 (17)
Si9B—Si9A—Al30Bii146.67 (10)Ru5Bvii—Al29A—Ru5Avii0.72 (11)
Al22vii—Si9A—Al30Bii67.98 (7)Ru4Bii—Al29A—Ru5Avii124.7 (3)
Al22—Si9A—Al30Bii103.95 (10)Si17—Al29A—Ru5Avii58.34 (4)
Al12—Si9A—Al30Bii113.01 (9)Al32Axvii—Al29A—Ru5Avii63.15 (10)
Al25ii—Si9A—Al30Bii74.62 (10)Al29Axviii—Al29A—Ru5Avii156.31 (8)
Al25i—Si9A—Al30Bii132.77 (9)Ru1ix—Al29A—Ru5Avii115.09 (6)
Al30Bi—Si9A—Al30Bii60.00 (18)Si18—Al29A—Ru5Avii109.57 (5)
Si9A—Si9B—Al1279.39 (14)Ru4Aii—Al29A—Ru5Avii126.69 (16)
Si9A—Si9B—Al22vii75.46 (12)Al29Bxviii—Al29A—Ru5Avii150.99 (13)
Al12—Si9B—Al22vii134.37 (7)Al20—Al29A—Ru5Avii106.24 (11)
Si9A—Si9B—Al2275.46 (12)Al32Axvii—Al29B—Ru5Bvii69.7 (3)
Al12—Si9B—Al22134.37 (7)Al32Axvii—Al29B—Ru4Bii69.5 (4)
Al22vii—Si9B—Al2273.94 (6)Ru5Bvii—Al29B—Ru4Bii136.4 (6)
Si9A—Si9B—Al25ii77.95 (7)Al32Axvii—Al29B—Ru4Aii72.7 (3)
Al12—Si9B—Al25ii71.75 (5)Ru5Bvii—Al29B—Ru4Aii137.2 (5)
Al22vii—Si9B—Al25ii66.16 (3)Ru4Bii—Al29B—Ru4Aii5.9 (4)
Al22—Si9B—Al25ii136.32 (9)Al32Axvii—Al29B—Al31Cxvii21.2 (4)
Si9A—Si9B—Al25i77.95 (7)Ru5Bvii—Al29B—Al31Cxvii88.6 (6)
Al12—Si9B—Al25i71.75 (5)Ru4Bii—Al29B—Al31Cxvii55.2 (6)
Al22vii—Si9B—Al25i136.32 (9)Ru4Aii—Al29B—Al31Cxvii59.8 (4)
Al22—Si9B—Al25i66.16 (3)Al32Axvii—Al29B—Ru5Avii69.4 (3)
Al25ii—Si9B—Al25i139.17 (10)Ru5Bvii—Al29B—Ru5Avii0.67 (12)
Si8—Si10A—Ru5Avii113.04 (8)Ru4Bii—Al29B—Ru5Avii135.9 (5)
Si8—Si10A—Ru5A113.04 (8)Ru4Aii—Al29B—Ru5Avii136.6 (5)
Ru5Avii—Si10A—Ru5A125.3 (3)Al31Cxvii—Al29B—Ru5Avii88.4 (5)
Si8—Si10A—Al31Avi163.35 (15)Al32Axvii—Al29B—Al29Axviii118.8 (3)
Ru5Avii—Si10A—Al31Avi63.66 (12)Ru5Bvii—Al29B—Al29Axviii160.4 (3)
Ru5A—Si10A—Al31Avi63.66 (12)Ru4Bii—Al29B—Al29Axviii59.88 (17)
Si8—Si10A—Ru5B111.39 (12)Ru4Aii—Al29B—Al29Axviii60.44 (13)
Ru5Avii—Si10A—Ru5B127.3 (3)Al31Cxvii—Al29B—Al29Axviii97.8 (4)
Ru5A—Si10A—Ru5B2.00 (11)Ru5Avii—Al29B—Al29Axviii161.1 (3)
Al31Avi—Si10A—Ru5B65.58 (16)Al32Axvii—Al29B—Si17121.8 (3)
Si8—Si10A—Ru5Bvii111.39 (12)Ru5Bvii—Al29B—Si1757.81 (15)
Ru5Avii—Si10A—Ru5Bvii2.00 (11)Ru4Bii—Al29B—Si17165.4 (4)
Ru5A—Si10A—Ru5Bvii127.3 (3)Ru4Aii—Al29B—Si17164.7 (5)
Al31Avi—Si10A—Ru5Bvii65.58 (16)Al31Cxvii—Al29B—Si17132.2 (5)
Ru5B—Si10A—Ru5Bvii129.3 (3)Ru5Avii—Al29B—Si1758.37 (12)
Si8—Si10A—Al22vii109.66 (18)Al29Axviii—Al29B—Si17105.5 (3)
Ru5Avii—Si10A—Al22vii61.84 (4)Al32Axvii—Al29B—Al29Bxviii111.79 (14)
Ru5A—Si10A—Al22vii124.32 (7)Ru5Bvii—Al29B—Al29Bxviii158.92 (15)
Al31Avi—Si10A—Al22vii83.66 (8)Ru4Bii—Al29B—Al29Bxviii56.5 (2)
Ru5B—Si10A—Al22vii124.72 (10)Ru4Aii—Al29B—Al29Bxviii57.86 (17)
Ru5Bvii—Si10A—Al22vii61.04 (8)Al31Cxvii—Al29B—Al29Bxviii90.7 (4)
Si8—Si10A—Al22109.66 (18)Ru5Avii—Al29B—Al29Bxviii159.53 (12)
Ru5Avii—Si10A—Al22124.32 (7)Al29Axviii—Al29B—Al29Bxviii7.53 (19)
Ru5A—Si10A—Al2261.84 (4)Si17—Al29B—Al29Bxviii108.96 (16)
Al31Avi—Si10A—Al2283.66 (8)Al32Axvii—Al29B—Al32Bxvii18.05 (14)
Ru5B—Si10A—Al2261.04 (8)Ru5Bvii—Al29B—Al32Bxvii55.3 (3)
Ru5Bvii—Si10A—Al22124.72 (10)Ru4Bii—Al29B—Al32Bxvii86.7 (5)
Al22vii—Si10A—Al2271.31 (5)Ru4Aii—Al29B—Al32Bxvii90.3 (4)
Si8—Si10A—Al23vii61.62 (5)Al31Cxvii—Al29B—Al32Bxvii33.4 (4)
Ru5Avii—Si10A—Al23vii62.95 (5)Ru5Avii—Al29B—Al32Bxvii55.1 (2)
Ru5A—Si10A—Al23vii119.35 (13)Al29Axviii—Al29B—Al32Bxvii128.2 (3)
Al31Avi—Si10A—Al23vii104.74 (17)Si17—Al29B—Al32Bxvii103.9 (3)
Ru5B—Si10A—Al23vii119.82 (14)Al29Bxviii—Al29B—Al32Bxvii120.67 (17)
Ru5Bvii—Si10A—Al23vii62.35 (9)Al32Axvii—Al29B—Si1898.6 (3)
Al22vii—Si10A—Al23vii111.61 (3)Ru5Bvii—Al29B—Si18108.7 (2)
Al22—Si10A—Al23vii171.2 (2)Ru4Bii—Al29B—Si1863.5 (5)
Si8—Si10A—Al2361.62 (5)Ru4Aii—Al29B—Si1857.63 (13)
Ru5Avii—Si10A—Al23119.35 (13)Al31Cxvii—Al29B—Si18102.0 (4)
Ru5A—Si10A—Al2362.95 (5)Ru5Avii—Al29B—Si18108.11 (18)
Al31Avi—Si10A—Al23104.74 (17)Al29Axviii—Al29B—Si1888.2 (2)
Ru5B—Si10A—Al2362.35 (9)Si17—Al29B—Si18119.6 (5)
Ru5Bvii—Si10A—Al23119.82 (14)Al29Bxviii—Al29B—Si1892.09 (12)
Al22vii—Si10A—Al23171.2 (2)Al32Bxvii—Al29B—Si18112.4 (3)
Al22—Si10A—Al23111.61 (3)Al32Axvii—Al29B—Ru1ix162.7 (3)
Al23vii—Si10A—Al2364.26 (3)Ru5Bvii—Al29B—Ru1ix110.0 (3)
Si8—Si10A—Al1162.60 (13)Ru4Bii—Al29B—Ru1ix113.5 (4)
Ru5Avii—Si10A—Al11113.16 (11)Ru4Aii—Al29B—Ru1ix112.0 (3)
Ru5A—Si10A—Al11113.16 (11)Al31Cxvii—Al29B—Ru1ix146.8 (4)
Al31Avi—Si10A—Al11134.05 (5)Ru5Avii—Al29B—Ru1ix110.5 (3)
Ru5B—Si10A—Al11111.49 (14)Al29Axviii—Al29B—Ru1ix56.21 (15)
Ru5Bvii—Si10A—Al11111.49 (14)Si17—Al29B—Ru1ix52.7 (2)
Al22vii—Si10A—Al1159.88 (9)Al29Bxviii—Al29B—Ru1ix61.96 (12)
Al22—Si10A—Al1159.88 (9)Al32Bxvii—Al29B—Ru1ix149.2 (2)
Al23vii—Si10A—Al11113.80 (16)Si18—Al29B—Ru1ix97.8 (4)
Al23—Si10A—Al11113.80 (16)Al30B—Al30A—Al27vii106.2 (4)
Al31Avi—Al10B—Ru5Avii71.4 (5)Al30B—Al30A—Ru1ix80.6 (4)
Al31Avi—Al10B—Ru5A71.4 (5)Al27vii—Al30A—Ru1ix168.32 (11)
Ru5Avii—Al10B—Ru5A141.5 (11)Al30B—Al30A—Al2087.8 (4)
Al31Avi—Al10B—Ru5B73.0 (5)Al27vii—Al30A—Al20112.19 (5)
Ru5Avii—Al10B—Ru5B143.2 (11)Ru1ix—Al30A—Al2057.91 (2)
Ru5A—Al10B—Ru5B1.72 (12)Al30B—Al30A—Ru7xxi91.6 (4)
Al31Avi—Al10B—Ru5Bvii73.0 (5)Al27vii—Al30A—Ru7xxi62.59 (3)
Ru5Avii—Al10B—Ru5Bvii1.72 (12)Ru1ix—Al30A—Ru7xxi127.54 (4)
Ru5A—Al10B—Ru5Bvii143.2 (11)Al20—Al30A—Ru7xxi174.32 (4)
Ru5B—Al10B—Ru5Bvii144.9 (11)Al30B—Al30A—Si17135.5 (5)
Al31Avi—Al10B—Al31Bv16.12 (19)Al27vii—Al30A—Si17118.23 (16)
Ru5Avii—Al10B—Al31Bv58.7 (4)Ru1ix—Al30A—Si1755.77 (3)
Ru5A—Al10B—Al31Bv86.1 (7)Al20—Al30A—Si1776.97 (5)
Ru5B—Al10B—Al31Bv87.6 (6)Ru7xxi—Al30A—Si17107.23 (10)
Ru5Bvii—Al10B—Al31Bv60.2 (4)Al30B—Al30A—Al21vii143.3 (4)
Al31Avi—Al10B—Al31Bvi16.12 (19)Al27vii—Al30A—Al21vii72.38 (8)
Ru5Avii—Al10B—Al31Bvi86.1 (7)Ru1ix—Al30A—Al21vii107.95 (8)
Ru5A—Al10B—Al31Bvi58.7 (4)Al20—Al30A—Al21vii127.46 (14)
Ru5B—Al10B—Al31Bvi60.2 (4)Ru7xxi—Al30A—Al21vii54.39 (5)
Ru5Bvii—Al10B—Al31Bvi87.6 (6)Si17—Al30A—Al21vii58.36 (8)
Al31Bv—Al10B—Al31Bvi27.7 (4)Al30B—Al30A—Al14ix73.0 (4)
Al31Avi—Al10B—Al23vii115.5 (7)Al27vii—Al30A—Al14ix127.62 (4)
Ru5Avii—Al10B—Al23vii64.74 (13)Ru1ix—Al30A—Al14ix63.04 (4)
Ru5A—Al10B—Al23vii125.3 (4)Al20—Al30A—Al14ix120.03 (7)
Ru5B—Al10B—Al23vii125.3 (4)Ru7xxi—Al30A—Al14ix65.06 (3)
Ru5Bvii—Al10B—Al23vii64.05 (14)Si17—Al30A—Al14ix79.00 (4)
Al31Bv—Al10B—Al23vii112.9 (6)Al21vii—Al30A—Al14ix79.39 (4)
Al31Bvi—Al10B—Al23vii130.1 (8)Al30B—Al30A—Ru6vii114.5 (4)
Al31Avi—Al10B—Al23115.5 (7)Al27vii—Al30A—Ru6vii59.08 (4)
Ru5Avii—Al10B—Al23125.3 (4)Ru1ix—Al30A—Ru6vii109.64 (4)
Ru5A—Al10B—Al2364.74 (13)Al20—Al30A—Ru6vii54.97 (3)
Ru5B—Al10B—Al2364.05 (14)Ru7xxi—Al30A—Ru6vii120.50 (8)
Ru5Bvii—Al10B—Al23125.3 (4)Si17—Al30A—Ru6vii90.49 (10)
Al31Bv—Al10B—Al23130.1 (8)Al21vii—Al30A—Ru6vii96.54 (12)
Al31Bvi—Al10B—Al23112.9 (6)Al14ix—Al30A—Ru6vii169.37 (11)
Al23vii—Al10B—Al2364.31 (19)Al30A—Al30B—Ru1ix88.0 (5)
Al31Avi—Al10B—Al22vii88.0 (3)Al30A—Al30B—Al2081.1 (4)
Ru5Avii—Al10B—Al22vii61.92 (12)Ru1ix—Al30B—Al2057.90 (7)
Ru5A—Al10B—Al22vii126.1 (3)Al30A—Al30B—Al30Bxviii144.1 (4)
Ru5B—Al10B—Al22vii126.1 (3)Ru1ix—Al30B—Al30Bxviii58.35 (17)
Ru5Bvii—Al10B—Al22vii61.19 (13)Al20—Al30B—Al30Bxviii89.59 (13)
Al31Bv—Al10B—Al22vii73.5 (3)Al30A—Al30B—Si9Aix151.0 (5)
Al31Bvi—Al10B—Al22vii89.1 (3)Ru1ix—Al30B—Si9Aix105.2 (2)
Al23vii—Al10B—Al22vii108.6 (3)Al20—Al30B—Si9Aix84.30 (13)
Al23—Al10B—Al22vii156.4 (10)Al30Bxviii—Al30B—Si9Aix60.00 (9)
Al31Avi—Al10B—Al2288.0 (3)Al30A—Al30B—Al14ix96.5 (5)
Ru5Avii—Al10B—Al22126.1 (3)Ru1ix—Al30B—Al14ix64.97 (8)
Ru5A—Al10B—Al2261.92 (12)Al20—Al30B—Al14ix122.86 (13)
Ru5B—Al10B—Al2261.19 (13)Al30Bxviii—Al30B—Al14ix60.05 (14)
Ru5Bvii—Al10B—Al22126.1 (3)Si9Aix—Al30B—Al14ix112.4 (2)
Al31Bv—Al10B—Al2289.1 (3)Al30A—Al30B—Ru7xxi77.7 (4)
Al31Bvi—Al10B—Al2273.5 (3)Ru1ix—Al30B—Ru7xxi126.25 (15)
Al23vii—Al10B—Al22156.4 (10)Al20—Al30B—Ru7xxi158.1 (3)
Al23—Al10B—Al22108.6 (3)Al30Bxviii—Al30B—Ru7xxi110.95 (13)
Al22vii—Al10B—Al2268.3 (3)Si9Aix—Al30B—Ru7xxi112.11 (19)
Ru7—Al11—Ru7vii134.87 (3)Al14ix—Al30B—Ru7xxi65.67 (7)
Ru7—Al11—Al26vii119.96 (3)Al30A—Al30B—Al27vii63.6 (4)
Ru7vii—Al11—Al26vii62.525 (13)Ru1ix—Al30B—Al27vii150.0 (3)
Ru7—Al11—Al2662.525 (14)Al20—Al30B—Al27vii105.66 (16)
Ru7vii—Al11—Al26119.96 (3)Al30Bxviii—Al30B—Al27vii151.45 (14)
Al26vii—Al11—Al2662.69 (2)Si9Aix—Al30B—Al27vii96.97 (13)
Ru7—Al11—Al22vii130.54 (3)Al14ix—Al30B—Al27vii124.23 (15)
Ru7vii—Al11—Al22vii66.435 (13)Ru7xxi—Al30B—Al27vii59.49 (8)
Al26vii—Al11—Al22vii109.406 (16)Al30A—Al30B—Al22xxi118.9 (5)
Al26—Al11—Al22vii157.46 (3)Ru1ix—Al30B—Al22xxi152.7 (3)
Ru7—Al11—Al2266.435 (13)Al20—Al30B—Al22xxi126.71 (16)
Ru7vii—Al11—Al22130.54 (3)Al30Bxviii—Al30B—Al22xxi94.41 (13)
Al26vii—Al11—Al22157.46 (3)Si9Aix—Al30B—Al22xxi53.74 (12)
Al26—Al11—Al22109.406 (16)Al14ix—Al30B—Al22xxi104.43 (15)
Al22vii—Al11—Al2269.28 (3)Ru7xxi—Al30B—Al22xxi61.37 (7)
Ru7—Al11—Al1467.460 (14)Al27vii—Al30B—Al22xxi57.09 (7)
Ru7vii—Al11—Al1467.460 (14)Al31Bvii—Al31A—Al31B104.6 (8)
Al26vii—Al11—Al1495.15 (2)Al31Bvii—Al31A—Al31C111.1 (6)
Al26—Al11—Al1495.15 (2)Al31B—Al31A—Al31C7.5 (6)
Al22vii—Al11—Al14106.85 (2)Al31Bvii—Al31A—Al31Cvii7.5 (6)
Al22—Al11—Al14106.85 (2)Al31B—Al31A—Al31Cvii111.1 (6)
Ru7—Al11—Si8108.159 (15)Al31C—Al31A—Al31Cvii117.4 (8)
Ru7vii—Al11—Si8108.160 (15)Al31Bvii—Al31A—Al10Bxv113.3 (4)
Al26vii—Al11—Si857.477 (18)Al31B—Al31A—Al10Bxv113.3 (4)
Al26—Al11—Si857.478 (18)Al31C—Al31A—Al10Bxv112.4 (4)
Al22vii—Al11—Si8100.13 (2)Al31Cvii—Al31A—Al10Bxv112.4 (4)
Al22—Al11—Si8100.13 (2)Al31Bvii—Al31A—Ru4B63.1 (4)
Al14—Al11—Si8147.02 (3)Al31B—Al31A—Ru4B63.1 (4)
Ru7—Al11—Si10A111.479 (16)Al31C—Al31A—Ru4B65.0 (4)
Ru7vii—Al11—Si10A111.479 (16)Al31Cvii—Al31A—Ru4B65.0 (4)
Al26vii—Al11—Si10A102.01 (5)Al10Bxv—Al31A—Ru4B172.6 (4)
Al26—Al11—Si10A102.01 (5)Al31Bvii—Al31A—Al32Avii8.9 (4)
Al22vii—Al11—Si10A57.51 (4)Al31B—Al31A—Al32Avii112.1 (4)
Al22—Al11—Si10A57.51 (4)Al31C—Al31A—Al32Avii118.2 (4)
Al14—Al11—Si10A159.87 (6)Al31Cvii—Al31A—Al32Avii1.6 (4)
Si8—Al11—Si10A53.11 (5)Al10Bxv—Al31A—Al32Avii112.72 (12)
Ru1iv—Al12—Si9B105.42 (6)Ru4B—Al31A—Al32Avii64.82 (9)
Ru1iv—Al12—Si9A127.62 (3)Al31Bvii—Al31A—Al32A112.1 (4)
Si9B—Al12—Si9A22.19 (6)Al31B—Al31A—Al32A8.9 (4)
Ru1iv—Al12—Ru2117.87 (3)Al31C—Al31A—Al32A1.6 (4)
Si9B—Al12—Ru2136.71 (7)Al31Cvii—Al31A—Al32A118.2 (4)
Si9A—Al12—Ru2114.52 (3)Al10Bxv—Al31A—Al32A112.72 (12)
Ru1iv—Al12—Si16ii105.283 (19)Ru4B—Al31A—Al32A64.82 (9)
Si9B—Al12—Si16ii111.35 (3)Al32Avii—Al31A—Al32A119.08 (6)
Si9A—Al12—Si16ii101.29 (2)Al31Bvii—Al31A—Si10Axv111.3 (4)
Ru2—Al12—Si16ii58.581 (15)Al31B—Al31A—Si10Axv111.3 (4)
Ru1iv—Al12—Si16i105.283 (19)Al31C—Al31A—Si10Axv110.9 (4)
Si9B—Al12—Si16i111.35 (3)Al31Cvii—Al31A—Si10Axv110.9 (4)
Si9A—Al12—Si16i101.29 (2)Al10Bxv—Al31A—Si10Axv3.7 (3)
Ru2—Al12—Si16i58.581 (15)Ru4B—Al31A—Si10Axv168.9 (3)
Si16ii—Al12—Si16i117.10 (3)Al32Avii—Al31A—Si10Axv111.36 (4)
Ru1iv—Al12—Si17xii56.847 (15)Al32A—Al31A—Si10Axv111.36 (4)
Si9B—Al12—Si17xii96.74 (4)Al31Bvii—Al31A—Si19vii97.6 (4)
Si9A—Al12—Si17xii108.10 (2)Al31B—Al31A—Si19vii148.1 (4)
Ru2—Al12—Si17xii106.339 (18)Al31C—Al31A—Si19vii140.9 (4)
Si16ii—Al12—Si17xii56.184 (13)Al31Cvii—Al31A—Si19vii90.2 (4)
Si16i—Al12—Si17xii150.58 (3)Al10Bxv—Al31A—Si19vii77.3 (3)
Ru1iv—Al12—Si17xiii56.847 (15)Ru4B—Al31A—Si19vii109.3 (2)
Si9B—Al12—Si17xiii96.74 (4)Al32Avii—Al31A—Si19vii88.77 (2)
Si9A—Al12—Si17xiii108.10 (2)Al32A—Al31A—Si19vii139.39 (4)
Ru2—Al12—Si17xiii106.339 (18)Si10Axv—Al31A—Si19vii80.56 (6)
Si16ii—Al12—Si17xiii150.58 (3)Al31Bvii—Al31A—Si19148.1 (4)
Si16i—Al12—Si17xiii56.184 (13)Al31B—Al31A—Si1997.6 (4)
Si17xii—Al12—Si17xiii113.59 (3)Al31C—Al31A—Si1990.2 (4)
Ru1iv—Al12—Al14iv60.71 (2)Al31Cvii—Al31A—Si19140.9 (4)
Si9B—Al12—Al14iv166.13 (7)Al10Bxv—Al31A—Si1977.3 (3)
Si9A—Al12—Al14iv171.68 (4)Ru4B—Al31A—Si19109.3 (2)
Ru2—Al12—Al14iv57.157 (19)Al32Avii—Al31A—Si19139.39 (4)
Si16ii—Al12—Al14iv74.706 (18)Al32A—Al31A—Si1988.77 (2)
Si16i—Al12—Al14iv74.706 (18)Si10Axv—Al31A—Si1980.55 (6)
Si17xii—Al12—Al14iv75.984 (18)Si19vii—Al31A—Si1953.85 (3)
Si17xiii—Al12—Al14iv75.984 (18)Al31Bvii—Al31A—Ru5Axv155.4 (4)
Ru4B—Al13—Ru4A6.2 (4)Al31B—Al31A—Ru5Axv66.3 (4)
Ru4B—Al13—Si8164.9 (5)Al31C—Al31A—Ru5Axv61.9 (4)
Ru4A—Al13—Si8158.75 (8)Al31Cvii—Al31A—Ru5Axv161.0 (4)
Ru4B—Al13—Si19vii109.2 (4)Al10Bxv—Al31A—Ru5Axv56.37 (5)
Ru4A—Al13—Si19vii114.51 (6)Ru4B—Al31A—Ru5Axv123.97 (4)
Si8—Al13—Si19vii84.06 (2)Al32Avii—Al31A—Ru5Axv162.40 (5)
Ru4B—Al13—Si19109.2 (4)Al32A—Al31A—Ru5Axv61.54 (4)
Ru4A—Al13—Si19114.51 (6)Si10Axv—Al31A—Ru5Axv56.78 (4)
Si8—Al13—Si1984.06 (2)Si19vii—Al31A—Ru5Axv100.90 (5)
Si19vii—Al13—Si1955.57 (2)Si19—Al31A—Ru5Axv55.81 (3)
Ru4B—Al13—Ru6vii121.61 (3)Al31A—Al31B—Al31C165.1 (12)
Ru4A—Al13—Ru6vii121.078 (15)Al31A—Al31B—Al31Bvii37.7 (4)
Si8—Al13—Ru6vii58.794 (12)Al31C—Al31B—Al31Bvii154.5 (10)
Si19vii—Al13—Ru6vii57.940 (13)Al31A—Al31B—Al32A166.9 (6)
Si19—Al13—Ru6vii105.19 (2)Al31C—Al31B—Al32A2.0 (9)
Ru4B—Al13—Ru6121.61 (3)Al31Bvii—Al31B—Al32A152.61 (19)
Ru4A—Al13—Ru6121.078 (15)Al31A—Al31B—Al31Cvii47.2 (5)
Si8—Al13—Ru658.794 (12)Al31C—Al31B—Al31Cvii144.7 (13)
Si19vii—Al13—Ru6105.19 (2)Al31Bvii—Al31B—Al31Cvii9.9 (4)
Si19—Al13—Ru657.941 (13)Al32A—Al31B—Al31Cvii142.7 (5)
Ru6vii—Al13—Ru6116.50 (2)Al31A—Al31B—Ru4B97.9 (5)
Ru4B—Al13—Al2760.94 (17)Al31C—Al31B—Ru4B85.6 (10)
Ru4A—Al13—Al2759.05 (2)Al31Bvii—Al31B—Ru4B73.2 (3)
Si8—Al13—Al27113.14 (2)Al32A—Al31B—Ru4B84.3 (3)
Si19vii—Al13—Al27141.60 (3)Al31Cvii—Al31B—Ru4B65.2 (4)
Si19—Al13—Al2790.892 (17)Al31A—Al31B—Al32B156.6 (6)
Ru6vii—Al13—Al27160.34 (3)Al31C—Al31B—Al32B20.9 (9)
Ru6—Al13—Al2762.650 (11)Al31Bvii—Al31B—Al32B158.02 (18)
Ru4B—Al13—Al27vii60.94 (17)Al32A—Al31B—Al32B21.53 (15)
Ru4A—Al13—Al27vii59.05 (2)Al31Cvii—Al31B—Al32B151.1 (5)
Si8—Al13—Al27vii113.14 (2)Ru4B—Al31B—Al32B104.7 (4)
Si19vii—Al13—Al27vii90.892 (16)Al31A—Al31B—Ru4A98.4 (5)
Si19—Al13—Al27vii141.60 (3)Al31C—Al31B—Ru4A84.4 (10)
Ru6vii—Al13—Al27vii62.650 (11)Al31Bvii—Al31B—Ru4A74.96 (19)
Ru6—Al13—Al27vii160.34 (3)Al32A—Al31B—Ru4A83.2 (3)
Al27—Al13—Al27vii110.94 (3)Al31Cvii—Al31B—Ru4A67.2 (4)
Ru4B—Al13—Al31A55.7 (5)Ru4B—Al31B—Ru4A2.6 (2)
Ru4A—Al13—Al31A61.84 (7)Al32B—Al31B—Ru4A103.9 (3)
Si8—Al13—Al31A139.41 (4)Al31A—Al31B—Ru5Axv96.4 (4)
Si19vii—Al13—Al31A60.45 (3)Al31C—Al31B—Ru5Axv74.8 (10)
Si19—Al13—Al31A60.45 (3)Al31Bvii—Al31B—Ru5Axv130.0 (2)
Ru6vii—Al13—Al31A109.49 (2)Al32A—Al31B—Ru5Axv76.5 (2)
Ru6—Al13—Al31A109.49 (2)Al31Cvii—Al31B—Ru5Axv139.5 (5)
Al27—Al13—Al31A88.14 (2)Ru4B—Al31B—Ru5Axv151.4 (4)
Al27vii—Al13—Al31A88.14 (2)Al32B—Al31B—Ru5Axv60.6 (2)
Ru4B—Al13—Al31B47.2 (5)Ru4A—Al31B—Ru5Axv148.9 (3)
Ru4A—Al13—Al31B53.11 (14)Al31A—Al31B—Ru5Bxv98.5 (5)
Si8—Al13—Al31B146.96 (12)Al31C—Al31B—Ru5Bxv72.6 (10)
Si19vii—Al13—Al31B75.54 (16)Al31Bvii—Al31B—Ru5Bxv132.1 (2)
Si19—Al13—Al31B62.99 (11)Al32A—Al31B—Ru5Bxv74.3 (2)
Ru6vii—Al13—Al31B125.08 (16)Al31Cvii—Al31B—Ru5Bxv141.5 (5)
Ru6—Al13—Al31B101.66 (13)Ru4B—Al31B—Ru5Bxv150.0 (4)
Al27—Al13—Al31B72.19 (16)Al32B—Al31B—Ru5Bxv58.5 (2)
Al27vii—Al13—Al31B93.16 (12)Ru4A—Al31B—Ru5Bxv147.5 (3)
Al31A—Al13—Al31B15.97 (15)Ru5Axv—Al31B—Ru5Bxv2.15 (10)
Ru4B—Al13—Al31Bvii47.2 (5)Al31A—Al31B—Al10Bxv50.6 (4)
Ru4A—Al13—Al31Bvii53.11 (14)Al31C—Al31B—Al10Bxv126.5 (10)
Si8—Al13—Al31Bvii146.96 (12)Al31Bvii—Al31B—Al10Bxv76.16 (19)
Si19vii—Al13—Al31Bvii62.99 (11)Al32A—Al31B—Al10Bxv127.8 (3)
Si19—Al13—Al31Bvii75.53 (16)Al31Cvii—Al31B—Al10Bxv85.1 (4)
Ru6vii—Al13—Al31Bvii101.66 (13)Ru4B—Al31B—Al10Bxv147.8 (4)
Ru6—Al13—Al31Bvii125.08 (16)Al32B—Al31B—Al10Bxv107.4 (3)
Al27—Al13—Al31Bvii93.16 (12)Ru4A—Al31B—Al10Bxv148.8 (4)
Al27vii—Al13—Al31Bvii72.19 (16)Ru5Axv—Al31B—Al10Bxv54.54 (15)
Al31A—Al13—Al31Bvii15.97 (15)Ru5Bxv—Al31B—Al10Bxv56.55 (17)
Al31B—Al13—Al31Bvii25.3 (3)Al31A—Al31B—Si1966.3 (4)
Al30Bii—Al14—Al30Bi59.9 (3)Al31C—Al31B—Si1998.8 (9)
Al30Bii—Al14—Ru2iii141.14 (16)Al31Bvii—Al31B—Si19101.39 (16)
Al30Bi—Al14—Ru2iii141.14 (16)Al32A—Al31B—Si19100.7 (2)
Al30Bii—Al14—Al1175.89 (12)Al31Cvii—Al31B—Si19109.1 (4)
Al30Bi—Al14—Al1175.89 (12)Ru4B—Al31B—Si19109.4 (3)
Ru2iii—Al14—Al11132.37 (3)Al32B—Al31B—Si1999.9 (2)
Al30Bii—Al14—Al28xi162.41 (16)Ru4A—Al31B—Si19107.26 (19)
Al30Bi—Al14—Al28xi107.05 (13)Ru5Axv—Al31B—Si1955.09 (12)
Ru2iii—Al14—Al28xi56.454 (17)Ru5Bxv—Al31B—Si1956.06 (14)
Al11—Al14—Al28xi89.86 (2)Al10Bxv—Al31B—Si1967.3 (3)
Al30Bii—Al14—Al28xiv107.05 (13)Al31B—Al31C—Al32A176.2 (17)
Al30Bi—Al14—Al28xiv162.41 (16)Al31B—Al31C—Al32B148.0 (14)
Ru2iii—Al14—Al28xiv56.454 (17)Al32A—Al31C—Al32B33.2 (5)
Al11—Al14—Al28xiv89.86 (2)Al31B—Al31C—Al31A7.4 (6)
Al28xi—Al14—Al28xiv82.78 (3)Al32A—Al31C—Al31A175.7 (11)
Al30Bii—Al14—Al30Aii10.48 (9)Al32B—Al31C—Al31A148.5 (9)
Al30Bi—Al14—Al30Aii69.2 (2)Al31B—Al31C—Al31Bvii15.6 (6)
Ru2iii—Al14—Al30Aii130.97 (8)Al32A—Al31C—Al31Bvii160.7 (11)
Al11—Al14—Al30Aii82.35 (6)Al32B—Al31C—Al31Bvii153.5 (8)
Al28xi—Al14—Al30Aii171.95 (7)Al31A—Al31C—Al31Bvii21.6 (2)
Al28xiv—Al14—Al30Aii99.12 (7)Al31B—Al31C—Al32Bxix138.0 (12)
Al30Bii—Al14—Al30Ai69.2 (2)Al32A—Al31C—Al32Bxix43.3 (6)
Al30Bi—Al14—Al30Ai10.48 (9)Al32B—Al31C—Al32Bxix10.2 (3)
Ru2iii—Al14—Al30Ai130.97 (8)Al31A—Al31C—Al32Bxix138.3 (7)
Al11—Al14—Al30Ai82.35 (6)Al31Bvii—Al31C—Al32Bxix145.3 (7)
Al28xi—Al14—Al30Ai99.12 (7)Al31B—Al31C—Ru4B73.8 (10)
Al28xiv—Al14—Al30Ai171.95 (7)Al32A—Al31C—Ru4B103.9 (9)
Al30Aii—Al14—Al30Ai77.95 (15)Al32B—Al31C—Ru4B134.7 (9)
Al30Bii—Al14—Ru155.27 (7)Al31A—Al31C—Ru4B75.7 (6)
Al30Bi—Al14—Ru155.27 (7)Al31Bvii—Al31C—Ru4B61.0 (5)
Ru2iii—Al14—Ru1105.08 (2)Al32Bxix—Al31C—Ru4B144.0 (7)
Al11—Al14—Ru1122.55 (3)Al31B—Al31C—Ru5Axv86.2 (10)
Al28xi—Al14—Ru1129.33 (2)Al32A—Al31C—Ru5Axv97.1 (9)
Al28xiv—Al14—Ru1129.33 (2)Al32B—Al31C—Ru5Axv71.3 (5)
Al30Aii—Al14—Ru154.97 (2)Al31A—Al31C—Ru5Axv81.9 (5)
Al30Ai—Al14—Ru154.97 (2)Al31Bvii—Al31C—Ru5Axv101.4 (6)
Al30Bii—Al14—Ru7vii57.95 (8)Al32Bxix—Al31C—Ru5Axv63.2 (3)
Al30Bi—Al14—Ru7vii104.88 (16)Ru4B—Al31C—Ru5Axv151.1 (7)
Ru2iii—Al14—Ru7vii113.742 (17)Al31B—Al31C—Ru5Bxv89.1 (10)
Al11—Al14—Ru7vii52.088 (11)Al32A—Al31C—Ru5Bxv94.1 (9)
Al28xi—Al14—Ru7vii120.55 (3)Al32B—Al31C—Ru5Bxv68.6 (5)
Al28xiv—Al14—Ru7vii57.677 (13)Al31A—Al31C—Ru5Bxv84.9 (5)
Al30Aii—Al14—Ru7vii55.52 (2)Al31Bvii—Al31C—Ru5Bxv104.4 (6)
Al30Ai—Al14—Ru7vii115.22 (9)Al32Bxix—Al31C—Ru5Bxv60.6 (3)
Ru1—Al14—Ru7vii110.100 (17)Ru4B—Al31C—Ru5Bxv153.2 (6)
Al30Bii—Al14—Ru7104.88 (16)Ru5Axv—Al31C—Ru5Bxv2.97 (11)
Al30Bi—Al14—Ru757.95 (8)Al31B—Al31C—Ru4A76.9 (10)
Ru2iii—Al14—Ru7113.743 (17)Al32A—Al31C—Ru4A100.9 (9)
Al11—Al14—Ru752.087 (11)Al32B—Al31C—Ru4A132.4 (8)
Al28xi—Al14—Ru757.677 (13)Al31A—Al31C—Ru4A78.5 (5)
Al28xiv—Al14—Ru7120.55 (3)Al31Bvii—Al31C—Ru4A64.4 (4)
Al30Aii—Al14—Ru7115.22 (9)Al32Bxix—Al31C—Ru4A142.0 (7)
Al30Ai—Al14—Ru755.52 (2)Ru4B—Al31C—Ru4A3.9 (3)
Ru1—Al14—Ru7110.100 (17)Ru5Axv—Al31C—Ru4A151.3 (6)
Ru7vii—Al14—Ru7104.15 (2)Ru5Bxv—Al31C—Ru4A153.1 (6)
Ru3—Al15—Ru4A161.17 (5)Al31B—Al31C—Al29Bviii114.2 (11)
Ru3—Al15—Si18viii133.53 (3)Al32A—Al31C—Al29Bviii62.0 (7)
Ru4A—Al15—Si18viii60.00 (3)Al32B—Al31C—Al29Bviii79.7 (6)
Ru3—Al15—Si18ix133.53 (3)Al31A—Al31C—Al29Bviii120.6 (7)
Ru4A—Al15—Si18ix60.00 (3)Al31Bvii—Al31C—Al29Bviii99.0 (6)
Si18viii—Al15—Si18ix66.95 (3)Al32Bxix—Al31C—Al29Bviii86.6 (5)
Ru3—Al15—Ru4B159.3 (2)Ru4B—Al31C—Al29Bviii60.3 (4)
Ru4A—Al15—Ru4B1.90 (19)Ru5Axv—Al31C—Al29Bviii148.5 (6)
Si18viii—Al15—Ru4B61.48 (16)Ru5Bxv—Al31C—Al29Bviii146.4 (6)
Si18ix—Al15—Ru4B61.48 (16)Ru4A—Al31C—Al29Bviii60.1 (3)
Ru3—Al15—Al27vii114.21 (2)Al31B—Al31C—Al31Cvii25.5 (10)
Ru4A—Al15—Al27vii57.01 (2)Al32A—Al31C—Al31Cvii150.9 (7)
Si18viii—Al15—Al27vii111.82 (3)Al32B—Al31C—Al31Cvii152.9 (5)
Si18ix—Al15—Al27vii61.257 (17)Al31A—Al31C—Al31Cvii31.3 (4)
Ru4B—Al15—Al27vii56.29 (8)Al31Bvii—Al31C—Al31Cvii9.9 (4)
Ru3—Al15—Al27114.21 (2)Al32Bxix—Al31C—Al31Cvii147.3 (3)
Ru4A—Al15—Al2757.01 (2)Ru4B—Al31C—Al31Cvii53.3 (5)
Si18viii—Al15—Al2761.258 (17)Ru5Axv—Al31C—Al31Cvii111.0 (4)
Si18ix—Al15—Al27111.82 (3)Ru5Bxv—Al31C—Al31Cvii114.0 (4)
Ru4B—Al15—Al2756.29 (8)Ru4A—Al31C—Al31Cvii56.9 (4)
Al27vii—Al15—Al27101.23 (3)Al29Bviii—Al31C—Al31Cvii89.3 (4)
Ru3—Al15—Al2157.760 (15)Al32B—Al32A—Al31C112.8 (8)
Ru4A—Al15—Al21122.019 (17)Al32B—Al32A—Al32Bxix2.4 (5)
Si18viii—Al15—Al2182.302 (16)Al31C—Al32A—Al32Bxix114.9 (8)
Si18ix—Al15—Al21142.66 (3)Al32B—Al32A—Al31B113.5 (4)
Ru4B—Al15—Al21121.78 (3)Al31C—Al32A—Al31B1.8 (8)
Al27vii—Al15—Al21155.18 (4)Al32Bxix—Al32A—Al31B115.5 (2)
Al27—Al15—Al2166.782 (15)Al32B—Al32A—Al29Bviii111.2 (3)
Ru3—Al15—Al21vii57.759 (15)Al31C—Al32A—Al29Bviii96.8 (7)
Ru4A—Al15—Al21vii122.019 (17)Al32Bxix—Al32A—Al29Bviii111.7 (2)
Si18viii—Al15—Al21vii142.66 (3)Al31B—Al32A—Al29Bviii95.1 (2)
Si18ix—Al15—Al21vii82.302 (16)Al32B—Al32A—Al31A114.0 (3)
Ru4B—Al15—Al21vii121.78 (3)Al31C—Al32A—Al31A2.7 (7)
Al27vii—Al15—Al21vii66.782 (15)Al32Bxix—Al32A—Al31A115.96 (16)
Al27—Al15—Al21vii155.18 (4)Al31B—Al32A—Al31A4.16 (18)
Al21—Al15—Al21vii114.74 (3)Al29Bviii—Al32A—Al31A98.51 (15)
Ru3—Al15—Al13107.37 (3)Al32B—Al32A—Al29Aviii112.6 (3)
Ru4A—Al15—Al1353.79 (3)Al31C—Al32A—Al29Aviii98.7 (7)
Si18viii—Al15—Al13104.09 (3)Al32Bxix—Al32A—Al29Aviii112.93 (15)
Si18ix—Al15—Al13104.09 (3)Al31B—Al32A—Al29Aviii96.98 (19)
Ru4B—Al15—Al1351.9 (2)Al29Bviii—Al32A—Al29Aviii3.24 (15)
Al27vii—Al15—Al1354.228 (18)Al31A—Al32A—Al29Aviii100.31 (5)
Al27—Al15—Al1354.228 (18)Al32B—Al32A—Al32Axix1.5 (3)
Al21—Al15—Al13103.53 (2)Al31C—Al32A—Al32Axix114.2 (7)
Al21vii—Al15—Al13103.53 (2)Al32Bxix—Al32A—Al32Axix0.82 (16)
Si17xv—Si16—Ru6vii111.935 (18)Al31B—Al32A—Al32Axix114.81 (19)
Si17xv—Si16—Ru2ix112.514 (19)Al29Bviii—Al32A—Al32Axix111.50 (14)
Ru6vii—Si16—Ru2ix124.595 (17)Al31A—Al32A—Al32Axix115.28 (5)
Si17xv—Si16—Al20138.74 (2)Al29Aviii—Al32A—Al32Axix112.81 (5)
Ru6vii—Si16—Al2062.558 (15)Al32B—Al32A—Ru5Bxx62.4 (3)
Ru2ix—Si16—Al2062.335 (15)Al31C—Al32A—Ru5Bxx143.9 (7)
Si17xv—Si16—Al12ix62.396 (19)Al32Bxix—Al32A—Ru5Bxx61.60 (19)
Ru6vii—Si16—Al12ix119.15 (2)Al31B—Al32A—Ru5Bxx142.5 (2)
Ru2ix—Si16—Al12ix59.702 (15)Al29Bviii—Al32A—Ru5Bxx58.16 (18)
Al20—Si16—Al12ix84.14 (2)Al31A—Al32A—Ru5Bxx146.61 (11)
Si17xv—Si16—Al26vii111.74 (2)Al29Aviii—Al32A—Ru5Bxx57.75 (13)
Ru6vii—Si16—Al26vii64.944 (14)Al32Axix—Al32A—Ru5Bxx61.87 (11)
Ru2ix—Si16—Al26vii123.088 (19)Al32B—Al32A—Al27140.0 (3)
Al20—Si16—Al26vii102.37 (2)Al31C—Al32A—Al2794.7 (7)
Al12ix—Si16—Al26vii173.49 (2)Al32Bxix—Al32A—Al27137.76 (16)
Si17xv—Si16—Al21xvi62.572 (17)Al31B—Al32A—Al2795.01 (18)
Ru6vii—Si16—Al21xvi114.263 (19)Al29Bviii—Al32A—Al2792.69 (15)
Ru2ix—Si16—Al21xvi114.665 (18)Al31A—Al32A—Al2792.49 (4)
Al20—Si16—Al21xvi158.69 (2)Al29Aviii—Al32A—Al2789.91 (6)
Al12ix—Si16—Al21xvi113.27 (2)Al32Axix—Al32A—Al27138.53 (5)
Al26vii—Si16—Al21xvi60.348 (17)Ru5Bxx—Al32A—Al27110.71 (8)
Si17xv—Si16—Al28110.33 (2)Al32B—Al32A—Ru4B160.5 (5)
Ru6vii—Si16—Al28128.66 (2)Al31C—Al32A—Ru4B56.6 (8)
Ru2ix—Si16—Al2858.969 (15)Al32Bxix—Al32A—Ru4B162.6 (4)
Al20—Si16—Al28101.00 (2)Al31B—Al32A—Ru4B55.5 (4)
Al12ix—Si16—Al28105.54 (2)Al29Bviii—Al32A—Ru4B58.5 (2)
Al26vii—Si16—Al2873.278 (18)Al31A—Al32A—Ru4B56.4 (3)
Al21xvi—Si16—Al2863.524 (17)Al29Aviii—Al32A—Ru4B58.12 (17)
Si17xv—Si16—Al2562.967 (17)Al32Axix—Al32A—Ru4B161.9 (3)
Ru6vii—Si16—Al2559.025 (13)Ru5Bxx—Al32A—Ru4B114.9 (2)
Ru2ix—Si16—Al25118.817 (19)Al27—Al32A—Ru4B59.5 (3)
Al20—Si16—Al2583.338 (19)Al32B—Al32A—Ru5Axv62.3 (3)
Al12ix—Si16—Al2568.317 (19)Al31C—Al32A—Ru5Axv63.0 (7)
Al26vii—Si16—Al25112.27 (2)Al32Bxix—Al32A—Ru5Axv63.20 (16)
Al21xvi—Si16—Al25113.86 (2)Al31B—Al32A—Ru5Axv64.5 (2)
Al28—Si16—Al25172.26 (2)Al29Bviii—Al32A—Ru5Axv148.96 (17)
Ru1ix—Si17—Ru5Bvii122.40 (13)Al31A—Al32A—Ru5Axv62.40 (7)
Ru1ix—Si17—Si16vi111.692 (19)Al29Aviii—Al32A—Ru5Axv152.17 (8)
Ru5Bvii—Si17—Si16vi113.65 (11)Al32Axix—Al32A—Ru5Axv62.89 (6)
Ru1ix—Si17—Ru5Avii125.02 (6)Ru5Bxx—Al32A—Ru5Axv124.72 (10)
Ru5Bvii—Si17—Ru5Avii2.76 (11)Al27—Al32A—Ru5Axv111.33 (4)
Si16vi—Si17—Ru5Avii112.18 (4)Ru4B—Al32A—Ru5Axv116.7 (3)
Ru1ix—Si17—Al29A62.27 (8)Al32Bxix—Al32B—Al32A175.0 (10)
Ru5Bvii—Si17—Al29A60.21 (15)Al32Bxix—Al32B—Al31C150.2 (10)
Si16vi—Si17—Al29A140.22 (10)Al32A—Al32B—Al31C34.0 (5)
Ru5Avii—Si17—Al29A62.89 (9)Al32Bxix—Al32B—Al32Axix2.7 (5)
Ru1ix—Si17—Al23vii125.87 (2)Al32A—Al32B—Al32Axix177.6 (5)
Ru5Bvii—Si17—Al23vii66.12 (10)Al31C—Al32B—Al32Axix148.0 (6)
Si16vi—Si17—Al23vii109.97 (2)Al32Bxix—Al32B—Al31Cxix19.6 (7)
Ru5Avii—Si17—Al23vii64.14 (5)Al32A—Al32B—Al31Cxix156.1 (5)
Al29A—Si17—Al23vii102.62 (5)Al31C—Al32B—Al31Cxix169.8 (3)
Ru1ix—Si17—Al12xii59.105 (16)Al32Axix—Al32B—Al31Cxix21.8 (4)
Ru5Bvii—Si17—Al12xii118.91 (10)Al32Bxix—Al32B—Al31B139.3 (8)
Si16vi—Si17—Al12xii61.419 (18)Al32A—Al32B—Al31B45.0 (3)
Ru5Avii—Si17—Al12xii120.58 (5)Al31C—Al32B—Al31B11.1 (5)
Al29A—Si17—Al12xii86.41 (5)Al32Axix—Al32B—Al31B137.0 (3)
Al23vii—Si17—Al12xii170.93 (2)Al31Cxix—Al32B—Al31B158.9 (4)
Ru1ix—Si17—Al21vii115.734 (19)Al32Bxix—Al32B—Ru5Bxv80.7 (6)
Ru5Bvii—Si17—Al21vii116.11 (12)Al32A—Al32B—Ru5Bxv101.0 (3)
Si16vi—Si17—Al21vii61.723 (16)Al31C—Al32B—Ru5Bxv75.2 (5)
Ru5Avii—Si17—Al21vii113.40 (6)Al32Axix—Al32B—Ru5Bxv79.8 (2)
Al29A—Si17—Al21vii158.05 (10)Al31Cxix—Al32B—Ru5Bxv96.6 (4)
Al23vii—Si17—Al21vii59.590 (16)Al31B—Al32B—Ru5Bxv68.1 (2)
Al12xii—Si17—Al21vii111.82 (2)Al32Bxix—Al32B—Ru5Bxx80.2 (6)
Ru1ix—Si17—Al30A60.19 (7)Al32A—Al32B—Ru5Bxx98.1 (4)
Ru5Bvii—Si17—Al30A130.58 (10)Al31C—Al32B—Ru5Bxx122.9 (5)
Si16vi—Si17—Al30A107.71 (3)Al32Axix—Al32B—Ru5Bxx81.0 (2)
Ru5Avii—Si17—Al30A130.32 (5)Al31Cxix—Al32B—Ru5Bxx64.7 (4)
Al29A—Si17—Al30A102.02 (13)Al31B—Al32B—Ru5Bxx128.6 (3)
Al23vii—Si17—Al30A75.34 (7)Ru5Bxv—Al32B—Ru5Bxx160.8 (2)
Al12xii—Si17—Al30A103.87 (6)Al32Bxix—Al32B—Ru5Axv83.6 (6)
Al21vii—Si17—Al30A62.80 (5)Al32A—Al32B—Ru5Axv98.3 (3)
Ru1ix—Si17—Al29B67.3 (2)Al31C—Al32B—Ru5Axv71.9 (5)
Ru5Bvii—Si17—Al29B55.8 (2)Al32Axix—Al32B—Ru5Axv82.59 (19)
Si16vi—Si17—Al29B134.5 (2)Al31Cxix—Al32B—Ru5Axv99.8 (4)
Ru5Avii—Si17—Al29B58.5 (2)Al31B—Al32B—Ru5Axv64.6 (2)
Al29A—Si17—Al29B7.30 (18)Ru5Bxv—Al32B—Ru5Axv3.53 (12)
Al23vii—Si17—Al29B104.21 (11)Ru5Bxx—Al32B—Ru5Axv163.6 (3)
Al12xii—Si17—Al29B84.64 (11)Al32Bxix—Al32B—Ru5Axx77.5 (6)
Al21vii—Si17—Al29B162.70 (15)Al32A—Al32B—Ru5Axx100.6 (3)
Al30A—Si17—Al29B109.3 (3)Al31C—Al32B—Ru5Axx126.1 (5)
Ru1ix—Si17—Al25vi117.214 (19)Al32Axix—Al32B—Ru5Axx78.50 (18)
Ru5Bvii—Si17—Al25vi59.29 (9)Al31Cxix—Al32B—Ru5Axx61.7 (3)
Si16vi—Si17—Al25vi63.594 (17)Al31B—Al32B—Ru5Axx131.9 (3)
Ru5Avii—Si17—Al25vi59.47 (3)Ru5Bxv—Al32B—Ru5Axx158.1 (2)
Al29A—Si17—Al25vi83.82 (13)Ru5Bxx—Al32B—Ru5Axx3.31 (12)
Al23vii—Si17—Al25vi111.48 (2)Ru5Axv—Al32B—Ru5Axx161.1 (2)
Al12xii—Si17—Al25vi68.218 (19)Al32Bxix—Al32B—Al29Bviii130.1 (7)
Al21vii—Si17—Al25vi113.69 (2)Al32A—Al32B—Al29Bviii50.8 (3)
Al30A—Si17—Al25vi170.09 (4)Al31C—Al32B—Al29Bviii66.8 (5)
Al29B—Si17—Al25vi76.6 (3)Al32Axix—Al32B—Al29Bviii129.7 (3)
Al24vii—Si18—Ru4Aii116.89 (5)Al31Cxix—Al32B—Al29Bviii119.7 (4)
Al24vii—Si18—Ru2ix115.631 (19)Al31B—Al32B—Al29Bviii72.6 (2)
Ru4Aii—Si18—Ru2ix111.39 (3)Ru5Bxv—Al32B—Al29Bviii140.5 (3)
Al24vii—Si18—Ru7vii65.391 (15)Ru5Bxx—Al32B—Al29Bviii56.3 (2)
Ru4Aii—Si18—Ru7vii117.981 (18)Ru5Axv—Al32B—Al29Bviii136.9 (3)
Ru2ix—Si18—Ru7vii122.264 (17)Ru5Axx—Al32B—Al29Bviii59.51 (19)
Al24vii—Si18—Al2062.973 (18)Al32Bxix—Al32B—Al22xx99.0 (7)
Ru4Aii—Si18—Al20111.35 (3)Al32A—Al32B—Al22xx76.1 (3)
Ru2ix—Si18—Al2061.341 (15)Al31C—Al32B—Al22xx108.2 (5)
Ru7vii—Si18—Al20119.95 (2)Al32Axix—Al32B—Al22xx101.6 (2)
Al24vii—Si18—Al29A64.36 (3)Al31Cxix—Al32B—Al22xx81.1 (4)
Ru4Aii—Si18—Al29A60.69 (9)Al31B—Al32B—Al22xx118.9 (2)
Ru2ix—Si18—Al29A111.40 (10)Ru5Bxv—Al32B—Al22xx120.6 (2)
Ru7vii—Si18—Al29A117.65 (6)Ru5Bxx—Al32B—Al22xx62.83 (14)
Al20—Si18—Al29A61.85 (11)Ru5Axv—Al32B—Al22xx122.35 (18)
Al24vii—Si18—Al15ii153.95 (2)Ru5Axx—Al32B—Al22xx61.65 (11)
Ru4Aii—Si18—Al15ii57.69 (5)Al29Bviii—Al32B—Al22xx82.81 (18)
Symmetry codes: (i) x+1/2, y1/2, z+1/2; (ii) x+1/2, y+1, z+1/2; (iii) x1/2, y, z+3/2; (iv) x+1/2, y, z+3/2; (v) x+1/2, y+1/2, z+1/2; (vi) x+1/2, y, z+1/2; (vii) x, y+1/2, z; (viii) x+1/2, y1/2, z1/2; (ix) x+1/2, y+1, z1/2; (x) x+1/2, y, z+1/2; (xi) x, y1/2, z+1; (xii) x+1, y+1, z+1; (xiii) x+1, y1/2, z+1; (xiv) x, y+1, z+1; (xv) x1/2, y, z+1/2; (xvi) x1/2, y+1/2, z+1/2; (xvii) x+1/2, y+1/2, z+1/2; (xviii) x, y+3/2, z; (xix) x, y, z; (xx) x+1/2, y, z1/2; (xxi) x+1/2, y+1/2, z1/2; (xxii) x, y+1/2, z+1.
Trialuminium ruthenium disilicon (IV) top
Crystal data top
~Ru(Al0.57Si0.43)5Dx = 4.248 Mg m3
Mr = 238.38Mo Kα radiation, λ = 0.71073 Å
Tetragonal, I4/mcmCell parameters from 5393 reflections
a = 6.20079 (8) Åθ = 4.2–38.2°
c = 9.6937 (2) ŵ = 5.32 mm1
V = 372.72 (1) Å3T = 297 K
Z = 4Irregular, metallic light silver
F(000) = 440.990.05 × 0.03 × 0.02 mm
Data collection top
XtaLAB Synergy R, HyPix
diffractometer
295 independent reflections
Radiation source: micro-focus sealed X-ray tube, Mova (Mo) X-ray Source279 reflections with I > 2σ(I)
Mirror monochromatorRint = 0.029
Detector resolution: 10.0000 pixels mm-1θmax = 37.9°, θmin = 4.2°
ω scansh = 1010
Absorption correction: gaussian
(CrysAlisPro; Matsumoto et al., 2021)
k = 1010
Tmin = 0.833, Tmax = 0.906l = 1616
8063 measured reflections
Refinement top
Refinement on F2Primary atom site location: dual
Least-squares matrix: full w = 1/[σ2(Fo2) + (0.0084P)2 + 0.2167P]
where P = (Fo2 + 2Fc2)/3
R[F2 > 2σ(F2)] = 0.009(Δ/σ)max < 0.001
wR(F2) = 0.021Δρmax = 0.44 e Å3
S = 1.21Δρmin = 0.42 e Å3
295 reflectionsExtinction correction: SHELXL-2019/3 (Sheldrick, 2015b), Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4
13 parametersExtinction coefficient: 0.0037 (3)
2 restraints
Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Ru10.0000000.0000000.2500000.00545 (5)
Al20.0000000.0000000.0000000.01321 (14)
Si30.14854 (4)0.64854 (4)0.14385 (4)0.01122 (8)0.542 (6)
Al30.14854 (4)0.64854 (4)0.14385 (4)0.01122 (8)0.458 (6)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ru10.00611 (6)0.00611 (6)0.00414 (7)0.0000.0000.000
Al20.0174 (2)0.0174 (2)0.0048 (3)0.0000.0000.000
Si30.01030 (10)0.01030 (10)0.01304 (15)0.00364 (11)0.00111 (8)0.00111 (8)
Al30.01030 (10)0.01030 (10)0.01304 (15)0.00364 (11)0.00111 (8)0.00111 (8)
Geometric parameters (Å, º) top
Ru1—Al2i2.4234 (1)Ru1—Si3ix2.5800 (2)
Ru1—Al22.4234 (1)Al2—Si3x2.7463 (2)
Ru1—Si3ii2.5800 (2)Al2—Si3vii2.7463 (2)
Ru1—Si3iii2.5800 (2)Al2—Si3xi2.7463 (2)
Ru1—Si3iv2.5800 (2)Al2—Si3ix2.7463 (2)
Ru1—Si3v2.5800 (2)Al2—Si3xii2.7463 (2)
Ru1—Si3vi2.5800 (2)Al2—Si3ii2.7463 (2)
Ru1—Si3vii2.5800 (2)Al2—Si3xiii2.7463 (2)
Ru1—Si3viii2.5800 (2)Al2—Si3iv2.7463 (2)
Al2i—Ru1—Al2180.0Si3vii—Al2—Si3xii61.029 (13)
Al2i—Ru1—Si3ii113.504 (7)Si3xi—Al2—Si3xii75.060 (6)
Al2—Ru1—Si3ii66.496 (7)Si3ix—Al2—Si3xii104.940 (6)
Al2i—Ru1—Si3iii66.496 (7)Ru1xiv—Al2—Si3ii120.514 (7)
Al2—Ru1—Si3iii113.504 (7)Ru1—Al2—Si3ii59.486 (7)
Si3ii—Ru1—Si3iii139.656 (16)Si3x—Al2—Si3ii61.029 (13)
Al2i—Ru1—Si3iv113.504 (7)Si3vii—Al2—Si3ii118.971 (13)
Al2—Ru1—Si3iv66.496 (7)Si3xi—Al2—Si3ii104.940 (6)
Si3ii—Ru1—Si3iv80.848 (5)Si3ix—Al2—Si3ii75.060 (6)
Si3iii—Ru1—Si3iv138.167 (15)Si3xii—Al2—Si3ii180.000 (17)
Al2i—Ru1—Si3v66.496 (7)Ru1xiv—Al2—Si3xiii59.486 (7)
Al2—Ru1—Si3v113.504 (7)Ru1—Al2—Si3xiii120.514 (7)
Si3ii—Ru1—Si3v138.167 (15)Si3x—Al2—Si3xiii75.060 (6)
Si3iii—Ru1—Si3v80.848 (5)Si3vii—Al2—Si3xiii104.940 (6)
Si3iv—Ru1—Si3v63.637 (14)Si3xi—Al2—Si3xiii118.971 (13)
Al2i—Ru1—Si3vi66.496 (7)Si3ix—Al2—Si3xiii61.029 (13)
Al2—Ru1—Si3vi113.504 (7)Si3xii—Al2—Si3xiii75.060 (6)
Si3ii—Ru1—Si3vi63.637 (14)Si3ii—Al2—Si3xiii104.940 (6)
Si3iii—Ru1—Si3vi132.991 (15)Ru1xiv—Al2—Si3iv120.514 (7)
Si3iv—Ru1—Si3vi64.724 (16)Ru1—Al2—Si3iv59.486 (7)
Si3v—Ru1—Si3vi80.848 (5)Si3x—Al2—Si3iv104.940 (6)
Al2i—Ru1—Si3vii113.504 (7)Si3vii—Al2—Si3iv75.060 (6)
Al2—Ru1—Si3vii66.496 (7)Si3xi—Al2—Si3iv61.029 (13)
Si3ii—Ru1—Si3vii132.991 (15)Si3ix—Al2—Si3iv118.971 (13)
Si3iii—Ru1—Si3vii63.637 (14)Si3xii—Al2—Si3iv104.940 (6)
Si3iv—Ru1—Si3vii80.848 (5)Si3ii—Al2—Si3iv75.060 (6)
Si3v—Ru1—Si3vii64.724 (16)Si3xiii—Al2—Si3iv180.000 (13)
Si3vi—Ru1—Si3vii139.656 (16)Ru1xv—Al3—Ru1v116.363 (14)
Al2i—Ru1—Si3viii66.496 (7)Ru1xv—Al3—Si3ix110.173 (8)
Al2—Ru1—Si3viii113.504 (7)Ru1v—Al3—Si3ix110.173 (8)
Si3ii—Ru1—Si3viii64.724 (16)Ru1xv—Al3—Si3xvi58.182 (7)
Si3iii—Ru1—Si3viii80.848 (5)Ru1v—Al3—Si3xvi58.182 (7)
Si3iv—Ru1—Si3viii139.656 (16)Si3ix—Al3—Si3xvi130.850 (15)
Si3v—Ru1—Si3viii132.991 (15)Ru1xv—Al3—Al2xv54.019 (3)
Si3vi—Ru1—Si3viii80.848 (5)Ru1v—Al3—Al2xv140.272 (15)
Si3vii—Ru1—Si3viii138.167 (15)Si3ix—Al3—Al2xv108.902 (7)
Al2i—Ru1—Si3ix113.504 (7)Si3xvi—Al3—Al2xv99.916 (13)
Al2—Ru1—Si3ix66.496 (7)Ru1xv—Al3—Al2xvii140.272 (15)
Si3ii—Ru1—Si3ix80.848 (5)Ru1v—Al3—Al2xvii54.019 (3)
Si3iii—Ru1—Si3ix64.724 (16)Si3ix—Al3—Al2xvii108.902 (7)
Si3iv—Ru1—Si3ix132.991 (15)Si3xvi—Al3—Al2xvii99.916 (13)
Si3v—Ru1—Si3ix139.656 (16)Al2xv—Al3—Al2xvii105.930 (12)
Si3vi—Ru1—Si3ix138.167 (15)Ru1xv—Al3—Si3xviii57.638 (8)
Si3vii—Ru1—Si3ix80.848 (5)Ru1v—Al3—Si3xviii105.441 (17)
Si3viii—Ru1—Si3ix63.637 (14)Si3ix—Al3—Si3xviii61.861 (8)
Ru1xiv—Al2—Ru1180.0Si3xvi—Al3—Si3xviii75.218 (17)
Ru1xiv—Al2—Si3x59.486 (7)Al2xv—Al3—Si3xviii98.895 (8)
Ru1—Al2—Si3x120.514 (7)Al2xvii—Al3—Si3xviii155.175 (11)
Ru1xiv—Al2—Si3vii120.514 (7)Ru1xv—Al3—Si3iii105.441 (17)
Ru1—Al2—Si3vii59.486 (7)Ru1v—Al3—Si3iii57.638 (8)
Si3x—Al2—Si3vii180.000 (13)Si3ix—Al3—Si3iii61.861 (8)
Ru1xiv—Al2—Si3xi59.486 (7)Si3xvi—Al3—Si3iii75.218 (17)
Ru1—Al2—Si3xi120.514 (7)Al2xv—Al3—Si3iii155.175 (11)
Si3x—Al2—Si3xi75.060 (6)Al2xvii—Al3—Si3iii98.895 (8)
Si3vii—Al2—Si3xi104.940 (6)Si3xviii—Al3—Si3iii56.280 (15)
Ru1xiv—Al2—Si3ix120.514 (7)Ru1xv—Al3—Si3xix113.504 (7)
Ru1—Al2—Si3ix59.486 (7)Ru1v—Al3—Si3xix113.504 (7)
Si3x—Al2—Si3ix104.940 (6)Si3ix—Al3—Si3xix90.0
Si3vii—Al2—Si3ix75.060 (6)Si3xvi—Al3—Si3xix139.151 (15)
Si3xi—Al2—Si3ix180.00 (2)Al2xv—Al3—Si3xix59.485 (7)
Ru1xiv—Al2—Si3xii59.486 (7)Al2xvii—Al3—Si3xix59.485 (7)
Ru1—Al2—Si3xii120.514 (7)Si3xviii—Al3—Si3xix138.167 (13)
Si3x—Al2—Si3xii118.971 (13)Si3iii—Al3—Si3xix138.167 (13)
Symmetry codes: (i) x, y, z+1/2; (ii) y1, x, z; (iii) y1/2, x+1/2, z+1/2; (iv) x, y1, z; (v) x+1/2, y+1/2, z+1/2; (vi) y+1/2, x1/2, z+1/2; (vii) y+1, x, z; (viii) x1/2, y1/2, z+1/2; (ix) x, y+1, z; (x) y1, x, z; (xi) x, y1, z; (xii) y+1, x, z; (xiii) x, y+1, z; (xiv) x, y, z; (xv) x, y+1, z; (xvi) x+1/2, y+3/2, z+1/2; (xvii) x+1/2, y+1/2, z; (xviii) y+1/2, x+1/2, z+1/2; (xix) x, y, z.
Tetraaluminium diruthenium pentasilicon (V) top
Crystal data top
~Ru2(Al0.46Si0.54)9Dx = 4.512 Mg m3
Mr = 450.41Mo Kα radiation, λ = 0.71073 Å
Orthorhombic, CmcmCell parameters from 11544 reflections
a = 8.63058 (14) Åθ = 2.3–30.7°
b = 8.79888 (15) ŵ = 5.88 mm1
c = 17.4620 (3) ÅT = 301 K
V = 1326.05 (4) Å3Irregular, metallic light silver
Z = 80.05 × 0.04 × 0.04 mm
F(000) = 1664.17
Data collection top
XtaLAB Synergy R, HyPix
diffractometer
1029 independent reflections
Radiation source: micro-focus sealed X-ray tube, Mova (Mo) X-ray Source1001 reflections with I > 2σ(I)
Mirror monochromatorRint = 0.016
Detector resolution: 10.0000 pixels mm-1θmax = 30.8°, θmin = 2.3°
ω scansh = 1211
Absorption correction: gaussian
(CrysAlisPro; Matsumoto et al., 2021)
k = 1111
Tmin = 0.826, Tmax = 0.868l = 2224
17672 measured reflections
Refinement top
Refinement on F2Primary atom site location: dual
Least-squares matrix: full w = 1/[σ2(Fo2) + (0.0114P)2 + 0.7123P]
where P = (Fo2 + 2Fc2)/3
R[F2 > 2σ(F2)] = 0.011(Δ/σ)max = 0.001
wR(F2) = 0.027Δρmax = 0.37 e Å3
S = 1.31Δρmin = 0.42 e Å3
1029 reflectionsExtinction correction: SHELXL-2019/3 (Sheldrick, 2015b), Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4
61 parametersExtinction coefficient: 0.00053 (3)
2 restraints
Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Ru10.25176 (2)0.12442 (2)0.11292 (2)0.00469 (5)
Si20.0000000.50890 (5)0.16887 (2)0.00820 (9)
Si30.0000000.28515 (5)0.56422 (2)0.00938 (9)
Si40.0000000.10304 (5)0.04648 (3)0.01097 (9)
Si50.0000000.23256 (5)0.17514 (2)0.0069 (2)0.65 (4)
Al50.0000000.23256 (5)0.17514 (2)0.0069 (2)0.35 (4)
Al60.26445 (6)0.13651 (5)0.2500000.01175 (12)
Si70.35637 (4)0.38251 (3)0.17041 (2)0.00739 (13)0.63 (2)
Al70.35637 (4)0.38251 (3)0.17041 (2)0.00739 (13)0.37 (2)
Al80.18469 (5)0.37313 (3)0.04292 (2)0.01109 (9)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ru10.00473 (7)0.00517 (7)0.00417 (7)0.00013 (3)0.00034 (2)0.00002 (2)
Si20.00592 (18)0.00705 (19)0.0116 (2)0.0000.0000.00072 (14)
Si30.00535 (18)0.0126 (2)0.01020 (19)0.0000.0000.00283 (15)
Si40.00543 (19)0.0197 (2)0.00778 (19)0.0000.0000.00166 (15)
Si50.0065 (3)0.0070 (3)0.0073 (3)0.0000.0000.00015 (14)
Al50.0065 (3)0.0070 (3)0.0073 (3)0.0000.0000.00015 (14)
Al60.0146 (3)0.0162 (3)0.0045 (2)0.00041 (17)0.0000.000
Si70.0068 (2)0.00576 (18)0.00963 (19)0.00060 (10)0.00059 (11)0.00062 (9)
Al70.0068 (2)0.00576 (18)0.00963 (19)0.00060 (10)0.00059 (11)0.00062 (9)
Al80.0175 (2)0.00624 (17)0.00951 (17)0.00015 (11)0.00498 (14)0.00012 (10)
Geometric parameters (Å, º) top
Ru1—Al62.3986 (1)Si3—Si7x2.6742 (5)
Ru1—Si3i2.4385 (2)Si3—Si7xi2.6742 (5)
Ru1—Si42.4703 (2)Si4—Si4xii2.4337 (9)
Ru1—Si7ii2.5317 (3)Si4—Si52.5192 (6)
Ru1—Si2iii2.5647 (2)Si4—Al8xiii2.8622 (5)
Ru1—Al82.5727 (3)Si4—Al82.8622 (5)
Ru1—Al8ii2.5853 (3)Si5—Si5viii2.6144 (8)
Ru1—Si52.6091 (2)Si5—Al6ix2.7626 (5)
Ru1—Si72.6420 (3)Si5—Al62.7626 (5)
Ru1—Al8iv2.7759 (4)Al6—Si7viii2.6918 (5)
Si2—Si52.4339 (6)Al6—Si72.6918 (5)
Si2—Si3v2.5736 (6)Al6—Si7ii2.8309 (5)
Si2—Al6vi2.7204 (5)Al6—Si7xiv2.8309 (5)
Si2—Al6vii2.7204 (5)Si7—Si7xv2.4792 (7)
Si2—Si2viii2.8334 (8)Si7—Al82.6755 (5)
Si3—Si4viii2.5108 (6)Si7—Si7viii2.7796 (6)
Si3—Al8ix2.5768 (5)Al8—Al8xvi2.6890 (6)
Si3—Al8viii2.5768 (5)Al8—Al8iv2.8658 (7)
Al6—Ru1—Si3i107.063 (16)Si4—Si5—Ru1xiii57.561 (8)
Al6—Ru1—Si4120.811 (16)Ru1—Si5—Ru1xiii112.774 (15)
Si3i—Ru1—Si4129.335 (13)Si2—Si5—Si5viii92.579 (13)
Al6—Ru1—Si7ii70.025 (14)Si4—Si5—Si5viii153.104 (14)
Si3i—Ru1—Si7ii137.435 (12)Ru1—Si5—Si5viii114.611 (8)
Si4—Ru1—Si7ii78.346 (13)Ru1xiii—Si5—Si5viii114.612 (8)
Al6—Ru1—Si2iii66.376 (15)Si2—Si5—Al6ix109.080 (15)
Si3i—Ru1—Si2iii61.852 (12)Si4—Si5—Al6ix106.475 (13)
Si4—Ru1—Si2iii152.066 (14)Ru1—Si5—Al6ix140.67 (2)
Si7ii—Ru1—Si2iii79.843 (11)Ru1xiii—Si5—Al6ix52.949 (6)
Al6—Ru1—Al8116.532 (14)Si5viii—Si5—Al6ix61.760 (9)
Si3i—Ru1—Al875.784 (12)Si2—Si5—Al6109.080 (15)
Si4—Ru1—Al869.127 (14)Si4—Si5—Al6106.475 (13)
Si7ii—Ru1—Al8145.151 (12)Ru1—Si5—Al652.948 (6)
Si2iii—Ru1—Al8134.919 (12)Ru1xiii—Si5—Al6140.67 (2)
Al6—Ru1—Al8ii120.008 (14)Si5viii—Si5—Al661.760 (9)
Si3i—Ru1—Al8ii85.859 (13)Al6ix—Si5—Al6111.41 (2)
Si4—Ru1—Al8ii84.229 (14)Ru1—Al6—Ru1viii172.70 (3)
Si7ii—Ru1—Al8ii63.042 (11)Ru1—Al6—Si7viii124.360 (19)
Si2iii—Ru1—Al8ii70.363 (13)Ru1viii—Al6—Si7viii62.218 (9)
Al8—Ru1—Al8ii123.409 (15)Ru1—Al6—Si762.216 (9)
Al6—Ru1—Si566.810 (15)Ru1viii—Al6—Si7124.362 (19)
Si3i—Ru1—Si5139.280 (14)Si7viii—Al6—Si762.170 (17)
Si4—Ru1—Si559.392 (12)Ru1—Al6—Si2xix122.379 (19)
Si7ii—Ru1—Si580.473 (12)Ru1viii—Al6—Si2xix59.741 (10)
Si2iii—Ru1—Si5132.966 (13)Si7viii—Al6—Si2xix80.955 (15)
Al8—Ru1—Si572.557 (13)Si7—Al6—Si2xix112.37 (2)
Al8ii—Ru1—Si5133.275 (12)Ru1—Al6—Si2iii59.741 (10)
Al6—Ru1—Si764.344 (14)Ru1viii—Al6—Si2iii122.378 (19)
Si3i—Ru1—Si763.371 (12)Si7viii—Al6—Si2iii112.37 (2)
Si4—Ru1—Si7122.988 (13)Si7—Al6—Si2iii80.955 (15)
Si7ii—Ru1—Si7134.263 (14)Si2xix—Al6—Si2iii62.768 (19)
Si2iii—Ru1—Si784.862 (11)Ru1—Al6—Si560.241 (11)
Al8—Ru1—Si761.722 (10)Ru1viii—Al6—Si5116.619 (19)
Al8ii—Ru1—Si7147.382 (11)Si7viii—Al6—Si5103.993 (19)
Si5—Ru1—Si779.214 (11)Si7—Al6—Si575.712 (14)
Al6—Ru1—Al8iv165.673 (16)Si2xix—Al6—Si5171.91 (2)
Si3i—Ru1—Al8iv58.803 (12)Si2iii—Al6—Si5119.817 (12)
Si4—Ru1—Al8iv73.383 (12)Ru1—Al6—Si5viii116.620 (19)
Si7ii—Ru1—Al8iv117.911 (10)Ru1viii—Al6—Si5viii60.241 (11)
Si2iii—Ru1—Al8iv102.208 (12)Si7viii—Al6—Si5viii75.712 (14)
Al8—Ru1—Al8iv64.665 (12)Si7—Al6—Si5viii103.993 (19)
Al8ii—Ru1—Al8iv60.083 (11)Si2xix—Al6—Si5viii119.817 (12)
Si5—Ru1—Al8iv124.747 (12)Si2iii—Al6—Si5viii171.91 (2)
Si7—Ru1—Al8iv107.354 (10)Si5—Al6—Si5viii56.480 (18)
Si5—Si2—Ru1xvii114.396 (11)Ru1—Al6—Si7ii57.194 (10)
Si5—Si2—Ru1vii114.396 (11)Ru1viii—Al6—Si7ii115.982 (18)
Ru1xvii—Si2—Ru1vii113.304 (16)Si7viii—Al6—Si7ii175.46 (2)
Si5—Si2—Si3v137.34 (2)Si7—Al6—Si7ii119.334 (12)
Ru1xvii—Si2—Si3v56.663 (8)Si2xix—Al6—Si7ii101.833 (18)
Ru1vii—Si2—Si3v56.663 (8)Si2iii—Al6—Si7ii72.165 (13)
Si5—Si2—Al6vi112.887 (16)Si5—Al6—Si7ii72.836 (15)
Ru1xvii—Si2—Al6vi53.884 (7)Si5viii—Al6—Si7ii99.76 (2)
Ru1vii—Si2—Al6vi131.23 (2)Ru1—Al6—Si7xiv115.982 (18)
Si3v—Si2—Al6vi94.539 (15)Ru1viii—Al6—Si7xiv57.194 (10)
Si5—Si2—Al6vii112.887 (16)Si7viii—Al6—Si7xiv119.335 (12)
Ru1xvii—Si2—Al6vii131.23 (2)Si7—Al6—Si7xiv175.46 (2)
Ru1vii—Si2—Al6vii53.884 (7)Si2xix—Al6—Si7xiv72.165 (13)
Si3v—Si2—Al6vii94.539 (15)Si2iii—Al6—Si7xiv101.833 (18)
Al6vi—Si2—Al6vii96.71 (2)Si5—Al6—Si7xiv99.76 (2)
Si5—Si2—Si2viii87.421 (13)Si5viii—Al6—Si7xiv72.836 (15)
Ru1xvii—Si2—Si2viii112.394 (9)Si7ii—Al6—Si7xiv58.805 (16)
Ru1vii—Si2—Si2viii112.394 (9)Si7xv—Si7—Ru1xvii111.632 (8)
Si3v—Si2—Si2viii135.240 (14)Si7xv—Si7—Ru1109.982 (7)
Al6vi—Si2—Si2viii58.617 (10)Ru1xvii—Si7—Ru1116.489 (12)
Al6vii—Si2—Si2viii58.617 (10)Si7xv—Si7—Si3i62.385 (8)
Ru1x—Si3—Ru1xi122.944 (17)Ru1xvii—Si7—Si3i111.082 (14)
Ru1x—Si3—Si4viii118.472 (9)Ru1—Si7—Si3i54.602 (9)
Ru1xi—Si3—Si4viii118.472 (9)Si7xv—Si7—Al8123.630 (11)
Ru1x—Si3—Si2xviii61.485 (9)Ru1xvii—Si7—Al859.457 (9)
Ru1xi—Si3—Si2xviii61.485 (9)Ru1—Si7—Al857.864 (9)
Si4viii—Si3—Si2xviii174.90 (2)Si3i—Si7—Al870.290 (12)
Ru1x—Si3—Al8ix134.314 (19)Si7xv—Si7—Al6107.139 (13)
Ru1xi—Si3—Al8ix67.148 (10)Ru1xvii—Si7—Al6140.547 (17)
Si4viii—Si3—Al8ix68.456 (15)Ru1—Si7—Al653.439 (8)
Si2xviii—Si3—Al8ix107.696 (16)Si3i—Si7—Al692.927 (14)
Ru1x—Si3—Al8viii67.148 (10)Al8—Si7—Al6103.982 (14)
Ru1xi—Si3—Al8viii134.314 (19)Si7xv—Si7—Si7viii89.999 (1)
Si4viii—Si3—Al8viii68.456 (15)Ru1xvii—Si7—Si7viii113.363 (7)
Si2xviii—Si3—Al8viii107.696 (17)Ru1—Si7—Si7viii112.333 (7)
Al8ix—Si3—Al8viii76.42 (2)Si3i—Si7—Si7viii133.900 (10)
Ru1x—Si3—Si7x62.028 (9)Al8—Si7—Si7viii146.312 (11)
Ru1xi—Si3—Si7x110.212 (16)Al6—Si7—Si7viii58.914 (9)
Si4viii—Si3—Si7x100.475 (18)Si7xv—Si7—Al6vi111.613 (13)
Si2xviii—Si3—Si7x84.035 (16)Ru1xvii—Si7—Al6vi52.782 (8)
Al8ix—Si3—Si7x162.921 (18)Ru1—Si7—Al6vi137.671 (17)
Al8viii—Si3—Si7x112.484 (11)Si3i—Si7—Al6vi161.207 (16)
Ru1x—Si3—Si7xi110.212 (16)Al8—Si7—Al6vi103.230 (14)
Ru1xi—Si3—Si7xi62.028 (9)Al6—Si7—Al6vi105.829 (11)
Si4viii—Si3—Si7xi100.475 (18)Si7viii—Si7—Al6vi60.597 (8)
Si2xviii—Si3—Si7xi84.035 (16)Ru1—Al8—Si3viii103.213 (14)
Al8ix—Si3—Si7xi112.484 (11)Ru1—Al8—Ru1xvii117.073 (14)
Al8viii—Si3—Si7xi162.921 (18)Si3viii—Al8—Ru1xvii137.009 (16)
Si7x—Si3—Si7xi55.233 (16)Ru1—Al8—Si760.413 (10)
Si4xii—Si4—Ru1xiii111.712 (13)Si3viii—Al8—Si7162.927 (17)
Si4xii—Si4—Ru1111.713 (13)Ru1xvii—Al8—Si757.501 (9)
Ru1xiii—Si4—Ru1123.183 (18)Ru1—Al8—Al8xvi166.190 (12)
Si4xii—Si4—Si3viii87.82 (2)Si3viii—Al8—Al8xvi81.071 (16)
Ru1xiii—Si4—Si3viii108.238 (13)Ru1xvii—Al8—Al8xvi63.478 (11)
Ru1—Si4—Si3viii108.238 (13)Si7—Al8—Al8xvi115.988 (15)
Si4xii—Si4—Si5158.73 (3)Ru1—Al8—Ru1iv115.335 (12)
Ru1xiii—Si4—Si563.047 (10)Si3viii—Al8—Ru1iv54.048 (10)
Ru1—Si4—Si563.046 (10)Ru1xvii—Al8—Ru1iv114.514 (12)
Si3viii—Si4—Si5113.45 (2)Si7—Al8—Ru1iv134.909 (17)
Si4xii—Si4—Al8xiii127.17 (2)Al8xvi—Al8—Ru1iv56.439 (12)
Ru1xiii—Si4—Al8xiii57.123 (9)Ru1—Al8—Si453.750 (9)
Ru1—Si4—Al8xiii115.901 (18)Si3viii—Al8—Si454.678 (14)
Si3viii—Si4—Al8xiii56.864 (14)Ru1xvii—Al8—Si4144.883 (17)
Si5—Si4—Al8xiii69.132 (14)Si7—Al8—Si4108.417 (15)
Si4xii—Si4—Al8127.17 (2)Al8xvi—Al8—Si4134.546 (16)
Ru1xiii—Si4—Al8115.902 (18)Ru1iv—Al8—Si497.920 (13)
Ru1—Si4—Al857.123 (9)Ru1—Al8—Al8iv61.104 (11)
Si3viii—Si4—Al856.864 (14)Si3viii—Al8—Al8iv68.684 (15)
Si5—Si4—Al869.132 (14)Ru1xvii—Al8—Al8iv144.14 (2)
Al8xiii—Si4—Al867.682 (18)Si7—Al8—Al8iv103.923 (19)
Si2—Si5—Si4114.32 (2)Al8xvi—Al8—Al8iv109.65 (2)
Si2—Si5—Ru1110.218 (11)Ru1iv—Al8—Al8iv54.231 (12)
Si4—Si5—Ru157.562 (8)Si4—Al8—Al8iv66.587 (13)
Si2—Si5—Ru1xiii110.218 (11)
Symmetry codes: (i) x+1/2, y+1/2, z1/2; (ii) x+1/2, y1/2, z; (iii) x+1/2, y1/2, z; (iv) x+1/2, y+1/2, z; (v) x, y+1, z1/2; (vi) x+1/2, y+1/2, z+1/2; (vii) x1/2, y+1/2, z; (viii) x, y, z+1/2; (ix) x, y, z+1/2; (x) x+1/2, y+1/2, z+1/2; (xi) x1/2, y+1/2, z+1/2; (xii) x, y, z; (xiii) x, y, z; (xiv) x+1/2, y1/2, z+1/2; (xv) x+1, y, z; (xvi) x, y+1, z; (xvii) x+1/2, y+1/2, z; (xviii) x, y+1, z+1/2; (xix) x+1/2, y1/2, z+1/2.
 

Acknowledgements

Polycrystalline samples from which single crystals were obtained were prepared with the help of Ms Itaya and Ms Nakamura at The University of Tokyo.

Funding information

Funding for this research was provided by: JSPS KAKENHI (grant No. JP19H05818, JP19H05819 and JP19K15274).

References

First citationBurkhardt, U., Grin, Yu., Ellner, M. & Peters, K. (1994). Acta Cryst. B50, 313–316.  CrossRef ICSD CAS Web of Science IUCr Journals Google Scholar
First citationGrin, Y., Peters, K., Burkhardt, U., Gotzmann, K. & Ellner, M. (1997). Z. Kristallogr. 212, 439–444.  CrossRef ICSD CAS Google Scholar
First citationGueneau, C., Servant, C., d'Yvoire, F. & Rodier, N. (1995). Acta Cryst. C51, 177–179.  CrossRef ICSD CAS IUCr Journals Google Scholar
First citationIwasaki, Y., Kitahara, K. & Kimura, K. (2019). Phys. Rev. Mater. 3, 061601, 1–5.  Google Scholar
First citationKitahara, K., Takakura, H., Iwasaki, Y. & Kimura, K. (2023). Mater. Trans. submitted.  Google Scholar
First citationLi, H. & Fan, C. (2019). Crystals, 9, 526, 1–11.  Google Scholar
First citationLima-de-Faria, J., Hellner, E., Liebau, F., Makovicky, E. & Parthé, E. (1990). Acta Cryst. A46, 1–11.  CrossRef CAS IUCr Journals Google Scholar
First citationLiu, W., Hu, J., Zhang, S., Deng, M., Han, C.-G. & Liu, Y. (2017). Mater. Today Phys. 1, 50–60.  CrossRef Google Scholar
First citationMatsumoto, T., Yamano, A., Sato, T., Ferrara, J. D., White, F. J. & Meyer, M. (2021). J. Chem. Crystallogr. 51, 438–450.  CSD CrossRef CAS Google Scholar
First citationMomma, K. & Izumi, F. (2011). J. Appl. Cryst. 44, 1272–1276.  Web of Science CrossRef CAS IUCr Journals Google Scholar
First citationReisinger, G. R., Effenberger, H. S. & Richter, K. W. (2018). J. Alloys Compd. 762, 849–857.  CrossRef ICSD CAS Google Scholar
First citationRoger, J., Jeanneau, E. & Viala, J.-C. (2011). Z. Kristallogr. 226, 805–813.  CrossRef CAS Google Scholar
First citationSasaki, T., Kato, T., Fukushima, J., Hayashi, Y. & Takizawa, H. (2019). J. Alloys Compd. 806, 58–62.  CrossRef ICSD CAS Google Scholar
First citationSheldrick, G. M. (2015a). Acta Cryst. A71, 3–8.  Web of Science CrossRef IUCr Journals Google Scholar
First citationSheldrick, G. M. (2015b). Acta Cryst. C71, 3–8.  Web of Science CrossRef IUCr Journals Google Scholar
First citationSimura, R., Sugiyama, K., Suzuki, S. & Kawamata, T. (2017). Mater. Trans. 58, 1101–1105.  CrossRef ICSD CAS Google Scholar
First citationSnyder, G. J. & Toberer, E. S. (2008). Nat. Mater. 7, 105–114.  Web of Science CrossRef PubMed CAS Google Scholar
First citationSugiyama, K., Kaji, N. & Hiraga, K. (2004). J. Alloys Compd. 368, 251–255.  CrossRef ICSD CAS Google Scholar
First citationVinokur, A. I., Hilleke, K. P. & Fredrickson, D. C. (2019). Acta Cryst. A75, 297–306.  Web of Science CrossRef ICSD IUCr Journals Google Scholar
First citationWestrip, S. P. (2010). J. Appl. Cryst. 43, 920–925.  Web of Science CrossRef CAS IUCr Journals Google Scholar
First citationWu, Z., Hoffmann, R.-D. & Pöttgen, R. (2002). Z. Anorg. Allg. Chem. 628, 1484–1488.  CrossRef ICSD CAS Google Scholar
First citationYamamoto, A. (1996). Acta Cryst. A52, 509–560.  CrossRef CAS Web of Science IUCr Journals Google Scholar
First citationZagorac, D., Müller, H., Ruehl, S., Zagorac, J. & Rehme, S. (2019). J. Appl. Cryst. 52, 918–925.  Web of Science CrossRef CAS IUCr Journals Google Scholar
First citationZhang, X. & Zhao, L.-D. (2015). J. Materiomics, 1, 92–105.  CrossRef Google Scholar
First citationZhou, Y., Wu, J., Ma, W., Lei, Y. & Dai, Y. (2018). J. Alloys Compd. 751, 257–265.  CrossRef CAS Google Scholar

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