Crystal structure of a water oxidation catalyst solvate with composition (NH4)2[FeIV(L-6H)]·3CH3COOH (L = clathrochelate ligand)

Plutenko, M.O.; Shylin, S.I.; Shova, S.; Blinder, A.V.; Fritsky, I.O.

doi:10.1107/S2056989023010514

Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

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Figure 1
The molecular moieties in the crystal structure of (NH₄)₂[Fe^IV(L-6H)]·3CH₃COOH with ellipsoids drawn at the 50% probability level. Hydrogen bonds are shown as dashed lines; H atoms of the disordered CH₃COOH molecule are omitted for clarity. [Symmetry codes: (i) 1 − x, y, $[{3\over 2}]$ − z; (ii) 1 − x, 1 − y, 2 − z; (iii) x, 1 − y, − $[{1\over 2}]$ + z; (iv) − $[{1\over 2}]$ + x, − $[{1\over 2}]$ + y, z; (v) $[{3\over 2}]$ − x, $[{1\over 2}]$ + y, $[{3\over 2}]$ − z; (vi) − $[{1\over 2}]$ + x, $[{1\over 2}]$ + y, z; (vii) $[{1\over 2}]$ − x, $[{1\over 2}]$ + y, $[{3\over 2}]$ − z.]

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 80| Part 1| January 2024| Pages 25-28

https://doi.org/10.1107/S2056989023010514

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