Synthesis and crystal structures of bis­[1-oxopyridin-2-olato(1−)]bis­(penta­fluoro­phen­yl)silicon(IV)–tetra­hydro­furan–pentane (2/1/1), bis­[1-oxopyridin-2-olato(1−)]bis­(p-tol­yl)silicon(IV), and dimesitylbis[1-oxopyridin-2-olato(1−)]silicon(IV)

Kraft, B.M.; Brennessel, W.W.; Andrews, J.W.; Viggiani, M.T.; Kittrell, N.F.; Heckman, M.T.

doi:10.1107/S2056989024001543

Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

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Figure 8
Possible π–π interaction in 3 shown by thick dashes. Centroid–centroid distances, 3.74 Å. Angles between ring planes, 23°. Edge-to-face C—H⋯π interactions shown by thin dashes between H atoms and the π systems at the edge of each acceptor ring. Symmetry-equivalent molecules generated by $[{1\over 2}]$ + x, $[{3\over 2}]$ − y, 1 − z and $[{1\over 2}]$ + x, $[{3\over 2}]$ − y, 1 − z.

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 80| Part 3| March 2024| Pages 318-324

https://doi.org/10.1107/S2056989024001543

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