Synthesis and crystal structure of tetra­methyl (E)-4,4′-(ethene-1,2-di­yl)bis­(5-nitro­benzene-1,2-di­carboxyl­ate)

Businski, A.; Ta, T.C.; Gindullis, N.; Näther, C.; Herges, R.

doi:10.1107/S2056989024002676

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ISSN: 2056-9890

Volume 80| Part 4| April 2024| Pages 435-438

https://doi.org/10.1107/S2056989024002676

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Synthesis and crystal structure of tetramethyl (E)-4,4′-(ethene-1,2-diyl)bis(5-nitrobenzene-1,2-dicarboxylate)

Artjom Businski,^a Thuy C. Ta,^a Niklas Gindullis,^b Christian Näther ^c and Rainer Herges ^a ^*

^aOtto-Diels-Institut für Organische Chemie, Universität Kiel, Otto-Hahn-Platz 4, D-24098 Kiel, Germany, ^bInstitut für Organische Chemie, Leibniz Universität Hannover, Schneiderberg 1 B, D-30167 Hannover, Germany, and ^cInstitut für Anorganische Chemie, Universität Kiel, Max-Eyth-Str. 2, D-24118 Kiel, Germany
^*Correspondence e-mail: rherges@oc.uni-kiel.de

Edited by M. Weil, Vienna University of Technology, Austria (Received 29 February 2024; accepted 22 March 2024; online 28 March 2024)

The title compound, C₂₂H₁₈N₂O₁₂, was obtained as a by-product during the planned synthesis of 1,2-bis(2-nitro-4,5-dimethyl phthalate)ethane by oxidative dimerization starting from dimethyl-4-methyl-5-nitro phthalate. To identify this compound unambiguously, a single-crystal structure analysis was performed. The asymmetric unit consists of half a molecule that is located at a centre of inversion. As a result of symmetry restrictions, the molecule shows an E configuration around the double bond. Both phenyl rings are coplanar, whereas the nitro and the two methyl ester groups are rotated out of the ring plane by 32.6 (1), 56.5 (2) and 49.5 (2)°, respectively. In the crystal, molecules are connected into chains extending parallel to the a axis by pairs of C—H⋯O hydrogen bonds that are connected into a tri-periodic network by additional C—H⋯O hydrogen-bonding interactions.

Keywords: crystal structure; synthesis; stilbene derivative; diazocine.

CCDC reference: 2342598

1. Chemical context

In recent years, molecular photoswitches have gained much attraction because of their wide range of potential applications, e.g. as photoresponsive materials (Pang et al., 2019 ) or as drugs (Kobauri et al., 2023 ). Bridged azobenzenes, so-called diazocines, are photoswitches, in which the thermodynamically stable Z isomer can be reversibly converted to the metastable E isomer through irradiation with visible light of different wavelengths (Fig. 1). Compared to azobenzenes, these compounds exhibit superior photophysical properties such as well-separated absorption bands, high quantum yields and high switching efficiencies (Siewertsen et al., 2009 ). Additionally, the light-driven E/Z isomerization leads to a reversible molecular movement between the bent, sterically demanding Z, and the stretched E isomer (Moormann et al., 2019 ), which can be used for reversible expansion and contraction between polymer strands (Burk et al., 2023 ) or reversible receptor–substrate binding (Cabré et al., 2019 ; Ewert et al., 2022 ).

Figure 1
Light-induced reversible isomerization between the thermodynamically stable Z and the metastable E isomer of the parent diazocine with different wavelengths in the visible range. In addition, thermal relaxation leads to re-isomerization.

The general synthesis of diazocines usually includes two key reactions: the formation of the ethylene unit and the azo group. Common synthesis strategies for C—C linkage include an oxidative dimerization (Moormann et al., 2017 ), a Sonogashira cross-coupling (Maier et al., 2019 ), Wittig reaction (Samanta et al., 2012 ) or organolithium-mediated reductive couplings (Li et al., 2020 ). In contrast, N—N formation is usually achieved by reductive/oxidative coupling starting from dinitro/diamino compounds (Moormann et al., 2017; Maier et al., 2019; Klockmann et al., 2021 ) or by a Cu-catalysed cascade reaction using diiodide compounds (Li et al., 2020). Unfortunately, late-stage functionalization after formation of the diazocine ring is difficult. Therefore, substituents have to be introduced at an earlier stage in synthesis, ideally before the oxidative C—C bond-formation stage.

Along these lines, we aimed at the synthesis of a tetramethylester substituted diazocine with two ester groups each in the meta and para positions to the azo group. After ester hydrolysis, the carboxylic acids were converted to the cyclic anhydrides, which were reacted with different amines to yield the corresponding imides. The tetraester, therefore, is an ideal precursor for further functionalization of the diazocine chromophore.

Starting from commercially available 4-methylphthalic anhydride, we carried out nitration and esterification reactions according to literature procedures (Hao et al., 2019 ) yielding dimethyl-4-methyl-5-nitro phthalate (1, Fig. 2). Dimerization of 1 by oxidative C—C bond formation was achieved through consecutive addition of potassium tert-butoxide and bromine in tetrahydrofuran yielding a crude product. According to ¹H NMR spectroscopy, the raw material contained a structurally similar by-product in addition to the expected main product 1,2-bis(2-nitro-4,5-dimethyl phthalate)ethane (2, Fig. 2). From vapour diffusion experiments of the crude product, we obtained crystals of the pure product, which were characterized by single crystal structure analysis, proving that (E)-1,2-bis(2-nitro-4,5-dimethyl phthalate)ethene, C₂₂H₁₈N₂O₁₂, (3) has formed as by-product (Fig. 2).

Figure 2
Reaction scheme to obtain the title compound (3) as a by-product.

2. Structural commentary

The asymmetric unit of 3 consists of half of a molecule that is located at a centre of inversion (Fig. 3). As a result of symmetry restrictions, the molecule shows the E configuration around the double bond, which can be traced back to steric hindrance. Both phenyl rings are oriented in a coplanar fashion (Fig. 4). The nitro group is rotated out of the phenyl ring plane by 32.6 (1)°, whereas the dihedral angles between the six-membered ring and the two methyl ester groups amount to 56.5 (2) and 49.5 (2)°, respectively.

Figure 3
Crystal structure of the title compound with labelling and displacement ellipsoids drawn at the 50% probability level. [Symmetry code: (i) −x, −y + 1, −z + 1.]

Figure 4
Side view of the title compound showing the torsion of the nitro and the ester groups.

3. Supramolecular features

In the crystal of 3, the molecules are connected into chains by centrosymmetric pairs of C—H⋯O hydrogen bonds between the methyl hydrogen atom H11C and the carbonyl oxygen atom O5 (Fig. 5). The C—H⋯O angle is close to linearity, indicating that this is a significant interaction (Table 1). These chains propagate parallel to the a axis, with each chain surrounded by six neighbouring chains (Fig. 6). The chains are additionally linked into a tri-periodic network by centrosymmetric pairs of C—H⋯O hydrogen bonds between the methyl hydrogen atom H9B and the carbonyl O atoms O5, forming 16-membered rings that are located around centres of inversion (Fig. 6). The corresponding O⋯H distance and the C–H⋯O angle point to a weaker interaction (Table 1). There is one additional C—H⋯O hydrogen bond but with a significant longer O⋯H distances (Table 1), which consolidates the packing. Finally, the molecules are arranged in a way that phenyl rings of neighbouring molecules are parallel but the ring planes are shifted relative to each other and the distance between the centroids of the six-membered rings amount to 4.144 (1) Å, which does not point to significant π–π interactions (Fig. 7).

Table 1
Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
C9—H9B⋯O5ⁱ	0.98	2.42	3.308 (2)	150
C11—H11A⋯O3ⁱⁱ	0.98	2.52	3.3650 (19)	144
C11—H11C⋯O5ⁱⁱⁱ	0.98	2.39	3.364 (2)	173
Symmetry codes: (i) ; (ii) ; (iii) .

Figure 5
Crystal structure of the title compound along the b axis in a view of the hydrogen-bonded chains. Intermolecular C—H⋯O hydrogen bonding is shown as dashed lines.

Figure 6
Crystal structure of the title compound in a view along the a axis. Intermolecular C—H⋯O hydrogen bonding is shown as dashed lines.

Figure 7
View of two neighbouring molecules. The distance between the centroids of the six-membered rings is given.

4. Database survey

A search of the CSD (version 5.43, last update March 2023, Groom et al., 2016 ) using CONQUEST (Bruno et al., 2002 ) revealed that thousands of stilbene derivatives are reported. With only nitro groups in an ortho-position, only three hits are found, including trans-1,1′-(ethene-1,2-diyl)-bis(2-nitrobenzene [1,2-bis(2-nitrophenyl)ethene] or trans-2,2′-dinitrostilben (refcodes WIXJIZ and WIXJIZ01, Bulatov & Haukka, 2019 ; Blelloch et al., 2021 ). In addition, a hydrate of trans-1,1′-(ethene-1,2-diyl)-bis(4-carboxylato-2-nitrobenzene) (refcode JAWYIS, Song et al., 2017 ) matches the search criterion. Finally, there is one zinc carboxylate compound with carboxylate groups in the 4-position (refcode BOZYOG, Li et al. 2014 ). With each two carboxylate or ester groups in ortho positions to each other, no hits are found. In fact, there is no compound reported in the CCDC that is more closely related to the title compound.

5. Synthesis and crystallization

General

Dimethyl-4-methyl-5-nitro phthalate (1) was prepared according to the literature (Hao et al., 2019) starting from 4-methylphthalic anhydride (> 98%), which was purchased from TCI. Potassium tert-butoxide (> 97%) was purchased from TCI and bromine (99%) from Thermo Scientific. Tetrahydrofuran (99.9%) was purchased from Fisher Scientific and dried using the solvent purification system PureSolv MD 5 from Inert Corporation.

Synthesis

Under a nitrogen atmosphere, dimethyl-4-methyl-5-nitro phthalate (1, 10.0 g, 39.5 mmol) was dissolved in dry tetrahydrofuran (330 ml) and cooled to 263 K. Potassium tert-butoxide (5.76 g, 51.3 mmol) was added in one portion. The reaction mixture was stirred for 30 s, whereupon bromine (2.02 ml, 39.5 mmol) was immediately added. After complete addition, the reaction mixture was stirred at 263 K for 10 min and then quenched with ice. The precipitate was filtered off, washed with the smallest possible amount of ice-cold ethyl acetate and dried in vacuo. The crude product was obtained as a pale-yellow solid.

Crystallization

Single crystals of 3 were obtained by vapour diffusion using chloroform/methanol as solvent/antisolvent.

6. Refinement

Crystal data, data collection and structure refinement details are summarized in Table 2. C-bound hydrogen atoms were positioned with idealized geometry (methyl H atoms allowed to rotate but not to tip) and were refined isotropically with U_ĩso(H) = 1.2 U_eq(C) (1.5 for methyl hydrogen atoms) using a riding model.

Table 2
Experimental details

Crystal data
Chemical formula	C₂₂H₁₈N₂O₁₂
M_r	502.38
Crystal system, space group	Triclinic, P $[\overline{1}]$
Temperature (K)	100
a, b, c (Å)	5.9454 (2), 7.9543 (3), 12.0673 (4)
α, β, γ (°)	72.124 (3), 79.661 (3), 86.052 (3)
V (Å³)	534.25 (3)
Z	1
Radiation type	Cu Kα
μ (mm⁻¹)	1.12
Crystal size (mm)	0.19 × 0.08 × 0.02

Data collection
Diffractometer	XtaLAB Synergy, Dualflex, HyPix
Absorption correction	Multi-scan (CrysAlis PRO; Rigaku OD, 2022 $[Rigaku OD (2022). CrysAlis PRO. Rigaku Oxford Diffraction, Yarnton, England.]$ )
T_min, T_max	0.791, 1.000
No. of measured, independent and observed [I > 2σ(I)] reflections	5274, 2211, 2042
R_int	0.020
(sin θ/λ)_max (Å⁻¹)	0.639

Refinement
R[F² > 2σ(F²)], wR(F²), S	0.043, 0.125, 1.09
No. of reflections	2211
No. of parameters	165
H-atom treatment	H-atom parameters constrained
Δρ_max, Δρ_min (e Å⁻³)	0.37, −0.30
Computer programs: CrysAlis PRO (Rigaku OD, 2022 $[Rigaku OD (2022). CrysAlis PRO. Rigaku Oxford Diffraction, Yarnton, England.]$ ), SHELXT (Sheldrick, 2015a ), SHELXL (Sheldrick, 2015b ), DIAMOND (Brandenburg & Putz, 1999 ), XP in SHELXTL-PC (Sheldrick, 2008 ) and publCIF (Westrip, 2010 ).

Supporting information

CCDC reference: 2342598

Crystal structure: contains datablock I. DOI: https://doi.org/10.1107/S2056989024002676/wm5712sup1.cif

Structure factors: contains datablock I. DOI: https://doi.org/10.1107/S2056989024002676/wm5712Isup2.hkl

Supporting information file. DOI: https://doi.org/10.1107/S2056989024002676/wm5712Isup3.cml

checkCIF report

Computing details top

Tetramethyl (E)-4,4'-(ethene-1,2-diyl)bis(5-nitrobenzene-1,2-dicarboxylate) top

Crystal data top

C₂₂H₁₈N₂O₁₂	Z = 1
M_r = 502.38	F(000) = 260
Triclinic, P1	D_x = 1.561 Mg m⁻³
a = 5.9454 (2) Å	Cu Kα radiation, λ = 1.54184 Å
b = 7.9543 (3) Å	Cell parameters from 3255 reflections
c = 12.0673 (4) Å	θ = 3.9–78.8°
α = 72.124 (3)°	µ = 1.12 mm⁻¹
β = 79.661 (3)°	T = 100 K
γ = 86.052 (3)°	Plate, colourless
V = 534.25 (3) Å³	0.19 × 0.08 × 0.02 mm

Data collection top

XtaLAB Synergy, Dualflex, HyPix diffractometer	2211 independent reflections
Radiation source: micro-focus sealed X-ray tube, PhotonJet (Cu) X-ray Source	2042 reflections with I > 2σ(I)
Mirror monochromator	R_int = 0.020
Detector resolution: 10.0000 pixels mm^-1	θ_max = 80.1°, θ_min = 3.9°
ω scans	h = −7→7
Absorption correction: multi-scan (CrysAlisPro; Rigaku OD, 2022)	k = −9→6
T_min = 0.791, T_max = 1.000	l = −15→15
5274 measured reflections

Refinement top

Refinement on F²	Primary atom site location: dual
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F² > 2σ(F²)] = 0.043	H-atom parameters constrained
wR(F²) = 0.125	w = 1/[σ²(F_o²) + (0.071P)² + 0.2093P] where P = (F_o² + 2F_c²)/3
S = 1.09	(Δ/σ)_max < 0.001
2211 reflections	Δρ_max = 0.37 e Å⁻³
165 parameters	Δρ_min = −0.30 e Å⁻³
0 restraints

Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
C1	0.0359 (3)	0.5721 (2)	0.51241 (15)	0.0281 (3)
H1	−0.031345	0.684945	0.481716	0.034*
C2	0.2167 (3)	0.55372 (19)	0.58634 (13)	0.0233 (3)
C3	0.3159 (3)	0.69811 (19)	0.60246 (13)	0.0227 (3)
C4	0.4711 (3)	0.6807 (2)	0.67872 (13)	0.0231 (3)
H4	0.530524	0.782718	0.687774	0.028*
C5	0.5389 (3)	0.5136 (2)	0.74157 (13)	0.0228 (3)
C6	0.4506 (3)	0.36589 (19)	0.72551 (13)	0.0232 (3)
C7	0.2901 (3)	0.3868 (2)	0.65094 (14)	0.0240 (3)
H7	0.228245	0.284508	0.643620	0.029*
N1	0.2610 (2)	0.88106 (17)	0.53758 (12)	0.0251 (3)
O1	0.2657 (2)	0.99488 (15)	0.58698 (11)	0.0322 (3)
O2	0.2220 (2)	0.91252 (15)	0.43721 (11)	0.0326 (3)
C8	0.6966 (3)	0.50015 (19)	0.82811 (13)	0.0232 (3)
O3	0.8602 (2)	0.59305 (14)	0.80816 (10)	0.0283 (3)
O4	0.62797 (19)	0.37663 (14)	0.93005 (9)	0.0258 (3)
C9	0.7826 (3)	0.3411 (2)	1.01503 (15)	0.0302 (4)
H9A	0.933156	0.306373	0.979732	0.045*
H9B	0.722258	0.245232	1.085262	0.045*
H9C	0.796944	0.447755	1.037561	0.045*
C10	0.5267 (3)	0.1811 (2)	0.78464 (14)	0.0259 (3)
O5	0.3990 (2)	0.05833 (16)	0.82506 (13)	0.0407 (3)
O6	0.75063 (19)	0.17046 (14)	0.78393 (10)	0.0261 (3)
C11	0.8374 (3)	−0.0025 (2)	0.84384 (17)	0.0332 (4)
H11A	0.806798	−0.087882	0.804802	0.050*
H11B	0.761355	−0.039755	0.926402	0.050*
H11C	1.002594	0.003374	0.840751	0.050*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
C1	0.0292 (8)	0.0238 (8)	0.0394 (9)	0.0083 (6)	−0.0167 (7)	−0.0170 (6)
C2	0.0255 (7)	0.0214 (7)	0.0276 (7)	0.0048 (5)	−0.0089 (6)	−0.0128 (6)
C3	0.0273 (7)	0.0172 (7)	0.0268 (7)	0.0060 (5)	−0.0088 (6)	−0.0099 (5)
C4	0.0268 (7)	0.0186 (7)	0.0279 (7)	0.0021 (5)	−0.0088 (6)	−0.0110 (6)
C5	0.0243 (7)	0.0207 (7)	0.0264 (7)	0.0035 (5)	−0.0081 (6)	−0.0100 (6)
C6	0.0255 (7)	0.0188 (7)	0.0276 (7)	0.0033 (5)	−0.0082 (6)	−0.0093 (6)
C7	0.0268 (7)	0.0187 (7)	0.0316 (8)	0.0030 (5)	−0.0105 (6)	−0.0124 (6)
N1	0.0276 (6)	0.0196 (6)	0.0319 (7)	0.0046 (5)	−0.0117 (5)	−0.0107 (5)
O1	0.0396 (7)	0.0196 (6)	0.0455 (7)	0.0080 (4)	−0.0185 (5)	−0.0169 (5)
O2	0.0418 (7)	0.0262 (6)	0.0326 (6)	0.0038 (5)	−0.0183 (5)	−0.0071 (5)
C8	0.0282 (7)	0.0166 (7)	0.0289 (7)	0.0053 (5)	−0.0105 (6)	−0.0110 (6)
O3	0.0309 (6)	0.0226 (6)	0.0356 (6)	0.0005 (4)	−0.0138 (5)	−0.0102 (4)
O4	0.0327 (6)	0.0202 (5)	0.0272 (5)	0.0016 (4)	−0.0126 (4)	−0.0069 (4)
C9	0.0366 (8)	0.0265 (8)	0.0311 (8)	0.0045 (6)	−0.0171 (7)	−0.0085 (6)
C10	0.0306 (8)	0.0193 (7)	0.0319 (8)	0.0021 (6)	−0.0137 (6)	−0.0094 (6)
O5	0.0386 (7)	0.0223 (6)	0.0605 (8)	−0.0023 (5)	−0.0246 (6)	−0.0018 (5)
O6	0.0297 (6)	0.0185 (5)	0.0333 (6)	0.0066 (4)	−0.0129 (4)	−0.0097 (4)
C11	0.0373 (9)	0.0200 (8)	0.0443 (9)	0.0099 (6)	−0.0173 (7)	−0.0084 (7)

Geometric parameters (Å, º) top

C1—C1ⁱ	1.383 (3)	N1—O1	1.2316 (17)
C1—H1	0.9500	N1—O2	1.2208 (18)
C1—C2	1.488 (2)	C8—O3	1.2065 (19)
C2—C3	1.406 (2)	C8—O4	1.3335 (19)
C2—C7	1.403 (2)	O4—C9	1.4497 (18)
C3—C4	1.388 (2)	C9—H9A	0.9800
C3—N1	1.4710 (19)	C9—H9B	0.9800
C4—H4	0.9500	C9—H9C	0.9800
C4—C5	1.386 (2)	C10—O5	1.202 (2)
C5—C6	1.398 (2)	C10—O6	1.3268 (19)
C5—C8	1.5000 (19)	O6—C11	1.4515 (18)
C6—C7	1.394 (2)	C11—H11A	0.9800
C6—C10	1.502 (2)	C11—H11B	0.9800
C7—H7	0.9500	C11—H11C	0.9800

C1ⁱ—C1—H1	119.4	O2—N1—C3	118.67 (12)
C1ⁱ—C1—C2	121.20 (18)	O2—N1—O1	123.86 (13)
C2—C1—H1	119.4	O3—C8—C5	123.87 (14)
C3—C2—C1	123.55 (13)	O3—C8—O4	124.94 (14)
C7—C2—C1	121.09 (13)	O4—C8—C5	111.17 (13)
C7—C2—C3	115.26 (13)	C8—O4—C9	115.16 (12)
C2—C3—N1	121.38 (13)	O4—C9—H9A	109.5
C4—C3—C2	123.52 (13)	O4—C9—H9B	109.5
C4—C3—N1	115.10 (12)	O4—C9—H9C	109.5
C3—C4—H4	120.2	H9A—C9—H9B	109.5
C5—C4—C3	119.57 (13)	H9A—C9—H9C	109.5
C5—C4—H4	120.2	H9B—C9—H9C	109.5
C4—C5—C6	118.99 (13)	O5—C10—C6	123.44 (14)
C4—C5—C8	117.98 (13)	O5—C10—O6	124.79 (14)
C6—C5—C8	122.98 (13)	O6—C10—C6	111.75 (13)
C5—C6—C10	122.09 (13)	C10—O6—C11	115.35 (12)
C7—C6—C5	120.29 (13)	O6—C11—H11A	109.5
C7—C6—C10	117.60 (13)	O6—C11—H11B	109.5
C2—C7—H7	118.9	O6—C11—H11C	109.5
C6—C7—C2	122.30 (13)	H11A—C11—H11B	109.5
C6—C7—H7	118.9	H11A—C11—H11C	109.5
O1—N1—C3	117.41 (12)	H11B—C11—H11C	109.5

C1ⁱ—C1—C2—C7	−11.9 (3)	C1—C2—C7—C6	−176.69 (14)
C1ⁱ—C1—C2—C3	171.9 (2)	C4—C3—N1—O2	146.08 (15)
C7—C2—C3—C4	−1.7 (2)	C2—C3—N1—O2	−33.6 (2)
C1—C2—C3—C4	174.69 (15)	C4—C3—N1—O1	−31.3 (2)
C7—C2—C3—N1	177.99 (13)	C2—C3—N1—O1	148.99 (15)
C1—C2—C3—N1	−5.6 (2)	C4—C5—C8—O3	−43.2 (2)
C2—C3—C4—C5	1.5 (2)	C6—C5—C8—O3	139.53 (16)
N1—C3—C4—C5	−178.24 (13)	C4—C5—C8—O4	134.90 (14)
C3—C4—C5—C6	0.7 (2)	C6—C5—C8—O4	−42.34 (19)
C3—C4—C5—C8	−176.63 (13)	O3—C8—O4—C9	−8.0 (2)
C4—C5—C6—C7	−2.5 (2)	C5—C8—O4—C9	173.88 (12)
C8—C5—C6—C7	174.67 (14)	C7—C6—C10—O5	−40.6 (2)
C4—C5—C6—C10	176.16 (14)	C5—C6—C10—O5	140.64 (18)
C8—C5—C6—C10	−6.6 (2)	C7—C6—C10—O6	137.89 (15)
C5—C6—C7—C2	2.3 (2)	C5—C6—C10—O6	−40.8 (2)
C10—C6—C7—C2	−176.45 (14)	O5—C10—O6—C11	−4.0 (2)
C3—C2—C7—C6	−0.2 (2)	C6—C10—O6—C11	177.52 (13)

Symmetry code: (i) −x, −y+1, −z+1.

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
C9—H9B···O5ⁱⁱ	0.98	2.42	3.308 (2)	150
C11—H11A···O3ⁱⁱⁱ	0.98	2.52	3.3650 (19)	144
C11—H11C···O5^iv	0.98	2.39	3.364 (2)	173

Symmetry codes: (ii) −x+1, −y, −z+2; (iii) x, y−1, z; (iv) x+1, y, z.

Acknowledgements

This work was supported by the State of Schleswig-Holstein.

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