Crystal structures of seven mixed-valence gold compounds of the form [(R1R2R3PE)2AuI]+[AuIIIX4]− (R = tert-butyl or isopropyl, E = S or Se, and X = Cl or Br)

Upmann, D.; Bockfeld, D.; Jones, P.G.; Târcoveanu, E.

doi:10.1107/S2056989024009095

Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

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Figure 13
Packing diagram of compound 4a. The layer structure is parallel to the ab plane, but for clarity has been rotated significantly from the ideal view direction perpendicular to this plane. The region z ≃ 0 is shown. Methyl groups are omitted. Dashed lines indicate H⋯Br contacts (thin) or Br⋯Br and S⋯Br contacts (thick).

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 80| Part 10| October 2024| Pages 1087-1096

https://doi.org/10.1107/S2056989024009095

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