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Figure 2
(a) Part of the crystal structure of (I) showing the R22(8) motif formed by inter­molecular N—H⋯O hydrogen bonds. (b) The N1—H1⋯O4 and O4—H4B⋯O1 hydrogen bonds connect neighbouring hippurate anions and water mol­ecule O4 (water – 1), forming a one-dimensional chains runs along the [010] direction. (c) The O4—H4A⋯O3, N1—H1⋯O4 and O4—H4B⋯O1 hydrogen bonds generate an R44 (16) motif, resulting in a supra­molecular ladder-like arrangement running parallel to [010].

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