Synthesis, crystal structure and Hirshfeld analysis of the bis­{(E)-2-[1-(benzo[d][1,3]dioxol-5-yl)ethylidene]-N-ethyl­hydrazine-1-carbo­thio­amide-κS}di­chlorido­mercury(II) complex

Farias, R.L. de; Beck, J.; Daniels, J.; Oliveira, A.B. de

doi:10.1107/S2056989026004822

Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

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Figure 10
Crystal structure section of HgCl₂(TSC4)₂ (MOCXAH; Nath & Baruah, 2023

), in which the H-bonding is drawn as dashed lines. The molecules are linked by N—H⋯Cl interactions, building a 1-D ribbon-like supramolecular arrangement along the a-axis direction. A ball-and-stick model is used for the graphical representation; only key atoms are labelled and the distorted tetrahedral coordination polyhedron is drawn with 70% transparency for clarity. [Symmetry codes: (i) −x + $[{3\over 2}]$ , y, −z + 1; (ii) −x + 2, −y + 1, −z + 1; (iii) x − $[{1\over 2}]$ , −y + 1, z.]

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 82| Part 6| June 2026| Pages 656-664

https://doi.org/10.1107/S2056989026004822

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