Figure 8
Section of the crystal structure of HgCl2(TSC2)2 (EFUKEX; Trzesowska-Kruszynska, 2014 ), with the H-bonding being drawn as dashed lines. The structure is expanded by the N1—H1N⋯Cli and N1—H1O⋯Cl2i interactions, forming a graph-set motif of
R22(6) and a chelate-type environment for the Hg1i center, and by the N11—H11O⋯Cl2ii interaction into a hydrogen-bonded tape-like supramolecular arrangement along the ac-plane. A ball-and-stick model is used for the graphical representation, which is simplified for clarity. Only key atoms are labelled and the distorted tetrahedral coordination polyhedra are drawn with 70% transparency. [Symmetry codes: (i) x + 1, y, z; (ii) x, −y + , z + .] |