Synthesis and crystal structure of N-benzyl-5,6-ep­oxy-7-oxabi­cyclo­[2.2.1]heptane-2,3-dicarboximide

DeJesus, J.F.; Marmande, M.H.; Baxter, B.N.; Nambo, M.; Crudden, C.M.; Forbes, D.C.

doi:10.1107/S2056989026009205

Figure 1
(A) Synthesis of alkene synthon of 7-oxabicyclo[2.2.1]hept-5-ene core (1) and transformation of anhydride moiety into more stable 2,3-dicarboximide group (3). (B) Transformation of 3 to 4 using mCPBA oxidation, and its three-dimensional arrangement with conserved stereochemical control.

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 82| Part 10| October 2026|

https://doi.org/10.1107/S2056989026009205

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