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Figure 3
The distances between atoms in the N∊ binding site of the crystals grown in NaBr conditions. (a) The Cu Kα data set and (b) the I04 Diamond data set. (a) The Pt—N∊ bond distance is 2.5 ± 0.6 Å, the Pt—Br distance is 2.4 ± 0.5 Å and the Br to NH distance is 3.6 ± 0.4 Å. (b) The Pt—N∊ bond distance is 2.6 ± 0.1 Å, the Pt—Br distance is 2.5 ± 0.1 Å and the Br to NH distance is 3.5 ± 0.1 Å. The sigmas given on the bond distances, which were unrestrained, were calculated using the Cruickshank DPI values (Cruickshank, 1999 ![]() |