Figure 4
(a) A representative X-ray reflectivity profile of a nanoporous PMSSQ film imprinted with 10 wt% mPCL6. The symbols are the measured data and the solid line represents the fit curve assuming a homogeneous electron density distribution within the film except for a thin surface layer, in which the electron density is slightly different. The inset shows a magnification of the region around the two critical angles: θc,film is the critical angle of the film and θc,Si is the critical angle of the Si substrate. (b) A model of the electron density distribution across the film thickness between the silicon substrate and air, which gives the best fit for the XR profile in (a). |