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Figure 13
(a) GIWAXS pattern of SM2:PC71BM, cast from chlorobenzene with 0.8% DIO in a 1:1 blend. Dots indicate the fitted scattering pattern for the first (lamellar) polymorph. (b) GIWAXS pattern of neat SM2, same conditions as (a). (c) Same as (a), zoomed-in and with a different color scale for detail, overlaid with the scattering pattern for the second polymorph which is not present in the neat film (b). SM2 crystal structure: (d) bird's-eye view of film; (e), (f) side views from two different directions, perpendicular to the b–c plane (e) and a–c plane (f). In (e), the molecular structure is drawn approximately to scale. |