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Figure 6
Ray diagram of a Debye–Scherrer XRD experiment showing the effect of speci­men displacement on 2θ value. The speci­men capillary is at S, the idealized speci­men position (typically the goniometer center) is at O, which is a length R from the detector, length d becomes more positive as S moves towards the detector, and X-rays are traveling from right to left. X-rays are diffracted through an angle 2θ at S, hitting the detector at D, which are measured at an angle 2θδ.

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