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Figure 3
(a) CV performed with a scan rate of 0.5 mV s−1 in Ar-saturated electrolyte in a potential range starting in proximity to the open circuit potential, and in between 0.85 VRHE and 1.25 VRHE. (b) Contour plot of the PDFs with a time resolution of 1 s. (c) PCC matrix between the time-resolved PDFs with an r range 0–100 Å, indicating structurally distinct regions. The color scale goes from blue, which represents the most dissimilar areas with a PCC of −0.95, to yellow corresponding to a PCC of 1. (d) Potential versus time plot indicating the time of the switching potentials. (e) Two NMF components from NMF analysis (Comp 0 and Comp 1) together with (f) the evolution of the components with time. (g) Comparison of the components with the calculated patterns of Ag f.c.c. [ICSD 64706 (Swanson & Tatge, 1953BB75)], Ag2CO3 [ICSD 8011 (Masse et al., 1979BB48)], Ag2O [ICSD 20368 (Vereshchagin et al., 1963BB78)] and AgO [ICSD 27659 (McMillan, 1960BB49)]. Vertical lines represent characteristic peaks for Ag f.c.c. (black) and Ag2CO3 (pink).

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