Structural disorder and transformation in crystal growth: direct observation of ring-opening isomerization in a metal–organic solid solution

Jiang, J.-J.; He, J.-R.; Lü, X.-Q.; Wang, D.-W.; Li, G.-B.; Su, C.-Y.

doi:10.1107/S2052252514015966

Figure 4
Structural motifs in the crystal structures of complex 1: (a) Ag₂L₂ ring and its space-filling model extracted from the (idealized) structure of form A; (b) twisted (AgL)_∞ double chains extracted also from form A (dotted lines indicate Ag⋯Ag contacts); (c) Ag₂L₂ rings and (AgL)_∞ double chains co-existing in a disordered fashion in form B. Differently orientated methylene imidazole donors are distinguished by the solid and dotted bonds as well as C atoms in different colours.

IUCrJ

Volume 1| Part 5| August 2014| Pages 318-327

ISSN: 2052-2525

doi:10.1107/S2052252514015966

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