Figure 3
The molecular structure of TAAP (a) with the relevant atom-numbering scheme. The non-hydrogen atoms are represented as displacement ellipsoids plotted at the 30% probability level. (b) Side-by-side arrangement of two neighbouring chromophores with an interplanar distance of 3.413 Å. Intramolecular hydrogen bonds and the gravity centre distance are marked by dashed lines. (c) Packing scheme along [10]. Gravity-centre-to-gravity-centre distance for planar chromophores in the dimer is marked by a turquoize line. H atoms have been omitted for clarity and the unit cell is marked by a black line. |