Framework disorder and its effect on selective hysteretic sorption of a T-shaped azole-based metal–organic framework

Wang, S.; Wei, Z.-W.; Zhang, J.; Jiang, L.; Liu, D.; Jiang, J.-J.; Si, R.; Su, C.-Y.

doi:10.1107/S2052252518015749

Figure 3
Comparison of the ideally ordered framework and one possible local disordered framework of T_imi-Cu in the a (upper) and b (lower) directions: (a) ordered overlapping of the Cu₈L₄ square-grid sql layers, (b) one possible disordered offsetting model of the Cu₈L₄ square-grid sql layers, (c) top view of 1D straight channel in the ordered framework formed via overlapping of Cu₈L₄ square grids and (d) top view of the 1D distorted channel in the disordered framework formed via offsetting of the Cu₈L₄ square grid.

IUCrJ

Volume 6| Part 1| January 2019| Pages 85-95

ISSN: 2052-2525

https://doi.org/10.1107/S2052252518015749

CHEMISTRY | CRYSTENG

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