Figure 1
Structures of AEPz-SnS-1 and trenH-SnS-1: (a) Molecular structures of AEPz and tren (shown in their unprotonated forms). (b) Side-view showing the thiostannate layers stacked along the crystallographic c axis. (c) Top-view of a porous thiostannate layer. (d) Fundamental building block of the R-SnS-1 structures, i.e. the Sn3S4 broken-cube cluster, which is connected to three neighboring clusters through double sulfur bridges. Sn is shown in gray and sulfur is shown in orange. The structural drawings are based on the single-crystal structure of trenH-SnS-1 (Filsø et al., 2017). |