On the mechanism of solid-state phase transitions in molecular crystals – the role of cooperative motion in (quasi)racemic linear amino acids

Smets, M. M. H.; Kalkman, E.; Krieger, A.; Tinnemans, P.; Meekes, H.; Vlieg, E.; Cuppen, H. M.

doi:10.1107/S2052252520001335

Figure 6
Characteristics of the solid-state phase transitions of linear-chain racemic and quasi-racemic amino acids; (a) transition enthalpies, (b) transition entropies and (c) transition Gibbs free energy [driving force, equation (3)

] versus the number of carbon atoms per molecule.

IUCrJ

Volume 7| Part 2| March 2020| Pages 331-341

ISSN: 2052-2525

https://doi.org/10.1107/S2052252520001335

CHEMISTRY | CRYSTENG

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