Figure 2
(a) Formation of the dicesium(I) complex of H2L1,4, {[Cs2(H2L1,4)(H2O)]·CHCl3}n (3); (b) capture of two Cs+; (c) space-filling structure; and (d) pseudo one-dimensional polymeric zigzag chain via intermolecular cation–π interactions (purple dashed lines). |