Figure 11
(a) XANES-EC spectra for CuIII:Aβ4–12/16 at oxidative potentials. (b) Enlarged XANES-EC spectra showing the pre-edge peak of CuIII at 8979.5 eV, which corresponds to the 1s–3d electron transition in copper. CuIII:Aβ4–8 does not show any pre-edge feature at this energy, indicating no copper oxidation in the Aβ4–8 fragment. |