Figure 8
Structural details of the imine connection as encountered in COF-300 (phenyl–N=CH–phenyl). SCXRD data [COF-300_hydrated, blue (Ma et al., 2018b)] and 3DED data (COF-300, green) are compared with values reported in the CSD (Groom et al., 2016). A numerical comparison, including standard deviations, can be found in Table S6. Observed bonds and angles are illustrated on the central drawing of the asymmetric unit: (a) Θ1, (b) Θ2, (c) D1, (d) D2, (e) D3. |