Tetrakis­(tri­phenyl­phosphine)silver(I) tetra­phenyl­borate aceto­nitrile solvate

In the title compound, [Ag{P(C₆H₅)}₄][B{P(C₆H₅)}₄]·CH₃CN, the Ag ion resides on a crystallographic twofold rotation axis and is tetrahedrally coordinated. There is a disparity between the two independent Ag-P distances. This is due, in part, to the temperature differences (all previous determinations are at room temperature) but also to the packing effects of various anions.

S1. Comment

In the title compound, (I), the Ag ion resides on a crystallographic twofold rotation axis and is tetrahedrally coordinated, with P—Ag—P angles ranging from 107.98 (7) to 111.02 (4)° [average 109.5 (13)°]. There is a disparity between the two independent Ag—P distances [2.6014 (13) and 2.6435 (14) Å], these values being somewhat shorter than those found in six related [Ag{P(C₆H₅)}₄]⁺ cations in the Cambridge Structural Database (Version 5.18, April 2000; Allen & Kennard, 1993). This is, in part, due to the temperature differences (all previous determinations are at room temperature) but also the packing effects of various anions. The B atom in the tetraphenylborate anion and all the non-H atoms in the acetonitrile solvent molecule are also located on twofold axes. The geometric parameters associated with the [BPh₄]⁻ anion are normal. The solvent appears to be disordered across the twofold axis, resulting in a shorter than expected C—C bond. Complex (I) is isomorphous with an Au analogue also measured at 150 K (Jones, 1980), but shows none of the 7:1 tetrahedral–trigonal disorder associated with the central Au atom in the latter complex. The Ag—P distances are longer than the Au—P distances observed in studies on isostructural Ag/Au phosphine complexes (Bowmaker et al., 1997). \scheme

S2. Experimental

The title compound was obtained while attempting to synthesize a silicate-based nitrogen pincer ligand coordinated to a platinum centre (Kleij et al., 1999). The counter-ion in the synthesis was tetraphenylborate, whilst the triphenylphosphine was added to complete the coordination around the platinum. The complex decomposed in the presence of silver trifluoromethanesulfonate to give the final product. Colourless block-like crystals were obtained by recrystallization from a solution in acetonitrile. The colour changed to orange on irradiation in the X-ray beam.

S3. Refinement

The acetonitrile molecule is possibly disordered over the twofold axis resulting in large displacement parameters and a shorter than expected C—C bond. The orientation of the solvent was chosen with respect to that found in the isostructural Au complex (Jones, 1980). The R_int value is indicative of the large number of weak data. All H atoms were constrained (C—H = 0.95 and 0.98 Å) and allowed to ride on their C atoms with U_iso(H) = 1.2U_eq(C). The methyl H atoms on the acetonitrile solvent are positionally disordered across the twofold axis.

Computing details

Data collection: locally modified CAD-4 Software (Enraf-Nonius, 1989); cell refinement: SET4 (de Boer & Duisenberg, 1984); data reduction: HELENA (Spek, 1997); program(s) used to solve structure: DIRDIF (Beurksens et al., 1999); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); software used to prepare material for publication: PLATON (Spek, 2000).

(I)

Crystal data

[Ag(C18H15P)4](C24H20B)·C2H3N	F(000) = 6320
Mr = 1517.21	Dx = 1.311 Mg m^−3
Orthorhombic, Ibca	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -I 2b 2c	Cell parameters from 22 reflections
a = 21.763 (2) Å	θ = 11.6–13.6°
b = 22.955 (2) Å	µ = 0.40 mm^−1
c = 30.767 (2) Å	T = 150 K
V = 15370 (2) Å^3	Block, colourless
Z = 8	0.30 × 0.30 × 0.30 mm

Data collection

Enraf-Nonius CAD-4T diffractometer	Rint = 0.103
Radiation source: rotating anode	θmax = 25°, θmin = 1.3°
Graphite monochromator	h = −5→25
ω scans	k = −5→27
11437 measured reflections	l = −36→36
6511 independent reflections	3 standard reflections every 60 min
3689 reflections with I > 2σ(I)	intensity decay: 0.5%

Refinement

Refinement on F^2	Primary atom site location: heavy-atom method
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.058	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.140	H-atom parameters constrained
S = 1.01	w = 1/[σ^2(Fo^2) + (0.0514P)^2] where P = (Fo^2 + 2Fc^2)/3
6511 reflections	(Δ/σ)max < 0.001
476 parameters	Δρmax = 0.72 e Å^−3
0 restraints	Δρmin = −0.69 e Å^−3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Ag1	0.0000	0.2500	0.06285 (2)	0.01927 (14)
P1	−0.06671 (6)	0.31841 (6)	0.11337 (5)	0.0226 (3)
P2	0.06968 (6)	0.31386 (6)	0.01336 (5)	0.0194 (3)
C1	−0.1198 (2)	0.3690 (2)	0.08737 (18)	0.0206 (12)
C2	−0.1059 (3)	0.3932 (3)	0.0480 (2)	0.0369 (16)
H2	−0.0690	0.3822	0.0336	0.044*
C3	−0.1447 (3)	0.4339 (2)	0.0283 (2)	0.0400 (17)
H3	−0.1339	0.4506	0.0010	0.048*
C4	−0.1986 (3)	0.4499 (3)	0.0484 (2)	0.0401 (17)
H4	−0.2250	0.4780	0.0355	0.048*
C5	−0.2137 (3)	0.4247 (2)	0.0873 (2)	0.0303 (15)
H5	−0.2517	0.4344	0.1007	0.036*
C6	−0.1752 (2)	0.3858 (2)	0.1072 (2)	0.0307 (14)
H61	−0.1860	0.3700	0.1348	0.037*
C7	−0.0240 (2)	0.3658 (2)	0.1504 (2)	0.0274 (13)
C8	−0.0367 (2)	0.4246 (2)	0.15618 (19)	0.0270 (13)
H8	−0.0685	0.4424	0.1397	0.032*
C9	−0.0036 (3)	0.4575 (2)	0.1856 (2)	0.0349 (13)
H9	−0.0121	0.4979	0.1886	0.042*
C10	0.0416 (3)	0.4321 (3)	0.2104 (2)	0.0364 (16)
H10	0.0636	0.4546	0.2311	0.044*
C11	0.0547 (3)	0.3738 (3)	0.2051 (2)	0.0389 (16)
H11	0.0861	0.3563	0.2222	0.047*
C12	0.0229 (3)	0.3409 (2)	0.17552 (19)	0.0326 (15)
H12	0.0328	0.3008	0.1720	0.039*
C13	−0.1176 (2)	0.2789 (2)	0.15006 (19)	0.0266 (13)
C14	−0.1216 (3)	0.2895 (2)	0.19466 (19)	0.0326 (14)
H14	−0.0970	0.3190	0.2075	0.039*
C15	−0.1615 (3)	0.2572 (3)	0.2202 (2)	0.0420 (17)
H15	−0.1638	0.2643	0.2505	0.050*
C16	−0.1975 (3)	0.2149 (3)	0.2018 (2)	0.0439 (19)
H16	−0.2244	0.1926	0.2195	0.053*
C17	−0.1950 (3)	0.2045 (3)	0.1581 (2)	0.0404 (17)
H17	−0.2207	0.1756	0.1455	0.049*
C18	−0.1549 (2)	0.2363 (2)	0.1321 (2)	0.0310 (16)
H18	−0.1531	0.2287	0.1018	0.037*
C19	0.1205 (2)	0.2777 (2)	−0.02543 (19)	0.0209 (12)
C20	0.1535 (3)	0.2288 (2)	−0.0117 (2)	0.0303 (15)
H201	0.1499	0.2154	0.0174	0.036*
C21	0.1912 (3)	0.2002 (3)	−0.0406 (2)	0.0379 (16)
H21	0.2132	0.1667	−0.0313	0.045*
C22	0.1979 (3)	0.2191 (3)	−0.0830 (2)	0.0382 (16)
H22	0.2243	0.1993	−0.1026	0.046*
C23	0.1655 (3)	0.2674 (3)	−0.0961 (2)	0.0435 (18)
H23	0.1696	0.2809	−0.1252	0.052*
C24	0.1271 (2)	0.2964 (2)	−0.06802 (19)	0.0311 (13)
H24	0.1050	0.3296	−0.0779	0.037*
C25	0.0291 (2)	0.3661 (2)	−0.02123 (18)	0.0237 (12)
C26	−0.0191 (2)	0.3454 (2)	−0.0467 (2)	0.0280 (14)
H26	−0.0300	0.3054	−0.0453	0.034*
C27	−0.0507 (3)	0.3819 (3)	−0.0734 (2)	0.0433 (17)
H27	−0.0837	0.3671	−0.0904	0.052*
C28	−0.0353 (3)	0.4398 (3)	−0.0762 (2)	0.0477 (19)
H28	−0.0576	0.4651	−0.0948	0.057*
C29	0.0132 (3)	0.4609 (3)	−0.0515 (2)	0.047 (2)
H29	0.0246	0.5008	−0.0536	0.056*
C30	0.0448 (3)	0.4242 (2)	−0.0240 (2)	0.0347 (15)
H30	0.0776	0.4390	−0.0069	0.042*
C31	0.1218 (2)	0.3606 (2)	0.04394 (18)	0.0232 (12)
C32	0.1839 (2)	0.3644 (2)	0.0365 (2)	0.0352 (15)
H32	0.2018	0.3425	0.0136	0.042*
C33	0.2207 (3)	0.3994 (3)	0.0618 (2)	0.0503 (19)
H33	0.2637	0.4011	0.0564	0.060*
C34	0.1954 (3)	0.4320 (3)	0.0949 (2)	0.0437 (18)
H34	0.2208	0.4565	0.1120	0.052*
C35	0.1332 (3)	0.4290 (2)	0.1032 (2)	0.0342 (15)
H35	0.1157	0.4515	0.1259	0.041*
C36	0.0967 (3)	0.3931 (2)	0.07824 (18)	0.0241 (13)
H36	0.0540	0.3904	0.0843	0.029*
B1	0.2161 (4)	0.0000	0.2500	0.0234 (19)
C37	0.1712 (2)	−0.0363 (2)	0.21717 (18)	0.0234 (13)
C38	0.1227 (2)	−0.0703 (2)	0.23330 (19)	0.0279 (13)
H38	0.1165	−0.0720	0.2638	0.033*
C39	0.0830 (3)	−0.1019 (3)	0.2061 (2)	0.0353 (15)
H39	0.0511	−0.1247	0.2185	0.042*
C40	0.0897 (3)	−0.1004 (3)	0.1622 (2)	0.0361 (16)
H40	0.0639	−0.1230	0.1439	0.043*
C41	0.1348 (3)	−0.0652 (3)	0.1447 (2)	0.0429 (17)
H41	0.1386	−0.0615	0.1141	0.051*
C42	0.1748 (3)	−0.0352 (3)	0.17210 (18)	0.0309 (14)
H42	0.2064	−0.0126	0.1592	0.037*
C43	0.2614 (2)	0.0445 (2)	0.22240 (17)	0.0221 (12)
C44	0.3144 (3)	0.0240 (2)	0.20171 (16)	0.0247 (13)
H44	0.3229	−0.0165	0.2029	0.030*
C45	0.3549 (2)	0.0594 (3)	0.17965 (19)	0.0328 (14)
H45	0.3908	0.0432	0.1669	0.039*
C46	0.3434 (3)	0.1188 (2)	0.17599 (19)	0.0336 (15)
H46	0.3710	0.1436	0.1607	0.040*
C47	0.2914 (3)	0.1406 (2)	0.19496 (18)	0.0313 (14)
H47	0.2825	0.1810	0.1926	0.038*
C48	0.2511 (3)	0.1044 (2)	0.21769 (18)	0.0268 (12)
H48	0.2154	0.1210	0.2304	0.032*
N200	0.0000	0.2500	0.3637 (5)	0.172 (8)
C100	0.0000	0.2500	0.3285 (5)	0.079 (4)
C300	0.0000	0.2500	0.2850 (6)	0.264 (16)
H301	0.0076	0.2896	0.2744	0.396*	0.50
H302	−0.0400	0.2365	0.2744	0.396*	0.50
H303	0.0324	0.2239	0.2744	0.396*	0.50

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Ag1	0.0199 (2)	0.0211 (2)	0.0168 (3)	−0.0021 (4)	0.000	0.000
P1	0.0234 (7)	0.0224 (7)	0.0221 (8)	0.0009 (6)	0.0045 (6)	−0.0016 (6)
P2	0.0178 (7)	0.0194 (7)	0.0212 (8)	−0.0016 (6)	0.0019 (6)	0.0015 (6)
C1	0.021 (3)	0.017 (3)	0.024 (3)	0.000 (2)	−0.003 (2)	−0.007 (2)
C2	0.034 (4)	0.039 (4)	0.037 (4)	0.006 (3)	0.002 (3)	0.001 (3)
C3	0.064 (5)	0.030 (3)	0.026 (4)	0.005 (3)	−0.006 (3)	0.004 (3)
C4	0.037 (4)	0.035 (4)	0.048 (4)	0.010 (3)	−0.015 (3)	−0.005 (3)
C5	0.021 (3)	0.029 (3)	0.041 (4)	0.004 (3)	−0.006 (3)	−0.010 (3)
C6	0.025 (3)	0.034 (3)	0.034 (4)	−0.005 (3)	0.003 (3)	−0.005 (3)
C7	0.025 (3)	0.028 (3)	0.030 (4)	0.000 (2)	0.007 (3)	−0.008 (3)
C8	0.024 (3)	0.030 (3)	0.027 (3)	0.000 (3)	0.003 (3)	0.000 (3)
C9	0.036 (3)	0.025 (2)	0.044 (3)	−0.002 (3)	0.006 (4)	−0.010 (3)
C10	0.025 (3)	0.048 (4)	0.036 (4)	−0.002 (3)	−0.002 (3)	−0.010 (3)
C11	0.029 (3)	0.046 (4)	0.041 (4)	0.008 (3)	−0.006 (3)	−0.003 (3)
C12	0.038 (3)	0.029 (3)	0.031 (4)	0.007 (3)	−0.007 (3)	−0.007 (3)
C13	0.023 (3)	0.031 (3)	0.026 (3)	0.008 (3)	0.003 (3)	0.007 (3)
C14	0.036 (3)	0.028 (3)	0.033 (4)	0.003 (2)	0.007 (3)	0.002 (3)
C15	0.049 (4)	0.048 (5)	0.029 (3)	0.020 (4)	0.018 (3)	0.010 (3)
C16	0.044 (4)	0.035 (4)	0.053 (5)	0.006 (3)	0.019 (3)	0.023 (3)
C17	0.025 (3)	0.029 (3)	0.068 (5)	0.005 (3)	0.002 (3)	−0.001 (3)
C18	0.031 (3)	0.035 (4)	0.027 (4)	0.000 (3)	0.004 (3)	0.004 (3)
C19	0.011 (3)	0.015 (2)	0.037 (4)	−0.003 (2)	0.004 (2)	−0.001 (2)
C20	0.028 (3)	0.025 (3)	0.038 (4)	0.004 (2)	0.007 (3)	0.007 (3)
C21	0.033 (3)	0.035 (3)	0.047 (4)	0.010 (3)	−0.001 (3)	−0.010 (3)
C22	0.032 (4)	0.043 (4)	0.040 (4)	0.001 (3)	0.011 (3)	−0.011 (3)
C23	0.044 (4)	0.055 (5)	0.033 (4)	0.007 (3)	0.013 (3)	0.003 (3)
C24	0.032 (3)	0.031 (3)	0.030 (4)	0.005 (3)	0.005 (3)	0.002 (3)
C25	0.019 (3)	0.028 (3)	0.024 (3)	0.004 (2)	0.002 (2)	−0.003 (3)
C26	0.021 (3)	0.029 (3)	0.034 (4)	−0.006 (2)	0.001 (2)	0.003 (3)
C27	0.039 (4)	0.060 (4)	0.031 (4)	0.001 (3)	−0.007 (3)	0.006 (3)
C28	0.066 (5)	0.040 (4)	0.037 (4)	0.020 (4)	−0.010 (4)	0.012 (3)
C29	0.077 (7)	0.024 (3)	0.039 (4)	0.006 (3)	−0.009 (3)	0.005 (3)
C30	0.044 (4)	0.030 (3)	0.030 (4)	−0.002 (3)	−0.006 (3)	−0.001 (3)
C31	0.023 (3)	0.023 (3)	0.024 (3)	0.000 (2)	0.002 (2)	0.001 (2)
C32	0.022 (3)	0.038 (3)	0.046 (4)	−0.005 (3)	0.007 (3)	−0.015 (3)
C33	0.024 (3)	0.055 (4)	0.072 (6)	−0.008 (3)	0.008 (4)	−0.024 (4)
C34	0.045 (4)	0.034 (4)	0.052 (5)	−0.014 (3)	−0.015 (4)	−0.016 (3)
C35	0.039 (4)	0.034 (3)	0.030 (4)	0.004 (3)	0.000 (3)	−0.010 (3)
C36	0.026 (3)	0.021 (3)	0.025 (3)	0.001 (3)	0.002 (2)	−0.001 (2)
B1	0.029 (5)	0.019 (4)	0.022 (5)	0.000	0.000	−0.004 (4)
C37	0.027 (3)	0.022 (3)	0.021 (3)	0.006 (2)	0.001 (2)	−0.002 (2)
C38	0.033 (3)	0.030 (3)	0.020 (3)	−0.004 (3)	0.000 (3)	0.002 (2)
C39	0.028 (3)	0.038 (4)	0.041 (4)	−0.004 (3)	−0.001 (3)	−0.001 (3)
C40	0.035 (4)	0.038 (4)	0.035 (4)	−0.006 (3)	−0.002 (3)	−0.011 (3)
C41	0.046 (4)	0.060 (5)	0.023 (4)	−0.005 (4)	−0.003 (3)	−0.010 (3)
C42	0.027 (3)	0.038 (3)	0.028 (3)	−0.006 (3)	0.007 (3)	−0.007 (3)
C43	0.023 (3)	0.025 (3)	0.018 (3)	0.002 (2)	−0.005 (2)	−0.006 (2)
C44	0.033 (3)	0.023 (3)	0.018 (3)	0.000 (2)	0.003 (2)	0.004 (2)
C45	0.028 (3)	0.044 (3)	0.027 (4)	−0.001 (3)	0.008 (3)	−0.005 (3)
C46	0.034 (3)	0.037 (3)	0.030 (4)	−0.014 (3)	0.011 (3)	0.003 (3)
C47	0.047 (3)	0.026 (3)	0.020 (3)	−0.002 (3)	−0.001 (3)	0.005 (2)
C48	0.025 (3)	0.032 (3)	0.024 (3)	−0.001 (2)	0.002 (3)	−0.005 (3)
N200	0.28 (2)	0.175 (14)	0.065 (11)	0.120 (16)	0.000	0.000
C100	0.118 (10)	0.060 (7)	0.060 (9)	0.039 (9)	0.000	0.000
C300	0.59 (5)	0.119 (14)	0.088 (17)	0.17 (2)	0.000	0.000

Geometric parameters (Å, º)

Ag1—P2^i	2.6013 (13)	C25—C30	1.378 (7)
Ag1—P2	2.6014 (13)	C25—C26	1.393 (7)
Ag1—P1^i	2.6435 (14)	C26—C27	1.360 (8)
Ag1—P1	2.6436 (14)	C26—H26	0.9500
P1—C1	1.822 (5)	C27—C28	1.373 (9)
P1—C13	1.823 (6)	C27—H27	0.9500
P1—C7	1.829 (6)	C28—C29	1.387 (9)
P2—C31	1.822 (5)	C28—H28	0.9500
P2—C19	1.827 (5)	C29—C30	1.380 (8)
P2—C25	1.830 (6)	C29—H29	0.9500
C1—C2	1.368 (8)	C30—H30	0.9500
C1—C6	1.405 (7)	C31—C32	1.374 (7)
C2—C3	1.398 (8)	C31—C36	1.403 (8)
C2—H2	0.9500	C32—C33	1.374 (8)
C3—C4	1.376 (9)	C32—H32	0.9500
C3—H3	0.9500	C33—C34	1.378 (9)
C4—C5	1.367 (9)	C33—H33	0.9500
C4—H4	0.9500	C34—C35	1.378 (9)
C5—C6	1.372 (8)	C34—H34	0.9500
C5—H5	0.9500	C35—C36	1.377 (8)
C6—H61	0.9500	C35—H35	0.9500
C7—C8	1.388 (7)	C36—H36	0.9500
C7—C12	1.404 (7)	B1—C37	1.633 (7)
C8—C9	1.380 (8)	B1—C37^ii	1.633 (7)
C8—H8	0.9500	B1—C43^ii	1.656 (7)
C9—C10	1.376 (9)	B1—C43	1.656 (7)
C9—H9	0.9500	C37—C42	1.389 (8)
C10—C11	1.377 (8)	C37—C38	1.404 (7)
C10—H10	0.9500	C38—C39	1.405 (8)
C11—C12	1.372 (8)	C38—H38	0.9500
C11—H11	0.9500	C39—C40	1.359 (8)
C12—H12	0.9500	C39—H39	0.9500
C13—C18	1.385 (7)	C40—C41	1.380 (8)
C13—C14	1.397 (8)	C40—H40	0.9500
C14—C15	1.385 (8)	C41—C42	1.393 (8)
C14—H14	0.9500	C41—H41	0.9500
C15—C16	1.370 (9)	C42—H42	0.9500
C15—H15	0.9500	C43—C44	1.398 (7)
C16—C17	1.367 (9)	C43—C48	1.400 (7)
C16—H16	0.9500	C44—C45	1.378 (7)
C17—C18	1.390 (8)	C44—H44	0.9500
C17—H17	0.9500	C45—C46	1.390 (8)
C18—H18	0.9500	C45—H45	0.9500
C19—C24	1.387 (8)	C46—C47	1.369 (8)
C19—C20	1.397 (7)	C46—H46	0.9500
C20—C21	1.379 (8)	C47—C48	1.396 (7)
C20—H201	0.9500	C47—H47	0.9500
C21—C22	1.381 (9)	C48—H48	0.9500
C21—H21	0.9500	N200—C100	1.083 (17)
C22—C23	1.374 (8)	C100—C300	1.34 (2)
C22—H22	0.9500	C300—H301	0.9800
C23—C24	1.374 (8)	C300—H302	0.9800
C23—H23	0.9500	C300—H303	0.9800
C24—H24	0.9500
P2^i—Ag1—P2	108.34 (6)	C23—C24—H24	119.7
P2^i—Ag1—P1^i	109.24 (4)	C19—C24—H24	119.7
P2—Ag1—P1^i	111.02 (4)	C30—C25—C26	118.8 (5)
P2^i—Ag1—P1	111.02 (4)	C30—C25—P2	123.4 (4)
P2—Ag1—P1	109.24 (4)	C26—C25—P2	117.8 (4)
P1^i—Ag1—P1	107.98 (7)	C27—C26—C25	120.7 (5)
C1—P1—C13	101.7 (2)	C27—C26—H26	119.6
C1—P1—C7	102.5 (2)	C25—C26—H26	119.6
C13—P1—C7	102.6 (3)	C26—C27—C28	120.6 (6)
C1—P1—Ag1	117.93 (18)	C26—C27—H27	119.7
C13—P1—Ag1	113.70 (18)	C28—C27—H27	119.7
C7—P1—Ag1	116.17 (18)	C27—C28—C29	119.4 (6)
C31—P2—C19	103.2 (2)	C27—C28—H28	120.3
C31—P2—C25	102.4 (2)	C29—C28—H28	120.3
C19—P2—C25	102.1 (3)	C30—C29—C28	120.1 (6)
C31—P2—Ag1	113.09 (18)	C30—C29—H29	120.0
C19—P2—Ag1	118.64 (16)	C28—C29—H29	120.0
C25—P2—Ag1	115.38 (18)	C25—C30—C29	120.4 (6)
C2—C1—C6	117.6 (5)	C25—C30—H30	119.8
C2—C1—P1	120.6 (4)	C29—C30—H30	119.8
C6—C1—P1	121.8 (4)	C32—C31—C36	118.2 (5)
C1—C2—C3	121.5 (6)	C32—C31—P2	124.4 (4)
C1—C2—H2	119.2	C36—C31—P2	117.3 (4)
C3—C2—H2	119.2	C31—C32—C33	121.1 (6)
C4—C3—C2	119.8 (6)	C31—C32—H32	119.4
C4—C3—H3	120.1	C33—C32—H32	119.4
C2—C3—H3	120.1	C32—C33—C34	120.1 (6)
C5—C4—C3	119.1 (6)	C32—C33—H33	119.9
C5—C4—H4	120.4	C34—C33—H33	119.9
C3—C4—H4	120.4	C33—C34—C35	120.1 (6)
C4—C5—C6	121.3 (6)	C33—C34—H34	119.9
C4—C5—H5	119.3	C35—C34—H34	119.9
C6—C5—H5	119.3	C36—C35—C34	119.6 (6)
C5—C6—C1	120.6 (6)	C36—C35—H35	120.2
C5—C6—H61	119.7	C34—C35—H35	120.2
C1—C6—H61	119.7	C35—C36—C31	120.8 (6)
C8—C7—C12	118.1 (5)	C35—C36—H36	119.6
C8—C7—P1	123.9 (5)	C31—C36—H36	119.6
C12—C7—P1	118.0 (4)	C37—B1—C37^ii	106.6 (6)
C9—C8—C7	120.8 (5)	C37—B1—C43^ii	111.0 (2)
C9—C8—H8	119.6	C37^ii—B1—C43^ii	110.7 (3)
C7—C8—H8	119.6	C37—B1—C43	110.7 (3)
C10—C9—C8	120.3 (5)	C37^ii—B1—C43	111.0 (2)
C10—C9—H9	119.8	C43^ii—B1—C43	106.8 (6)
C8—C9—H9	119.8	C42—C37—C38	113.9 (5)
C9—C10—C11	119.7 (6)	C42—C37—B1	125.1 (5)
C9—C10—H10	120.2	C38—C37—B1	121.0 (5)
C11—C10—H10	120.2	C37—C38—C39	122.6 (6)
C12—C11—C10	120.6 (6)	C37—C38—H38	118.7
C12—C11—H11	119.7	C39—C38—H38	118.7
C10—C11—H11	119.7	C40—C39—C38	120.8 (6)
C11—C12—C7	120.5 (5)	C40—C39—H39	119.6
C11—C12—H12	119.7	C38—C39—H39	119.6
C7—C12—H12	119.7	C39—C40—C41	118.7 (6)
C18—C13—C14	118.5 (5)	C39—C40—H40	120.7
C18—C13—P1	117.5 (5)	C41—C40—H40	120.7
C14—C13—P1	124.0 (4)	C40—C41—C42	119.9 (6)
C15—C14—C13	120.1 (6)	C40—C41—H41	120.1
C15—C14—H14	119.9	C42—C41—H41	120.1
C13—C14—H14	119.9	C37—C42—C41	124.0 (6)
C16—C15—C14	120.3 (6)	C37—C42—H42	118.0
C16—C15—H15	119.9	C41—C42—H42	118.0
C14—C15—H15	119.9	C44—C43—C48	114.6 (5)
C17—C16—C15	120.5 (6)	C44—C43—B1	121.2 (5)
C17—C16—H16	119.7	C48—C43—B1	124.3 (4)
C15—C16—H16	119.7	C45—C44—C43	123.6 (5)
C16—C17—C18	119.8 (6)	C45—C44—H44	118.2
C16—C17—H17	120.1	C43—C44—H44	118.2
C18—C17—H17	120.1	C44—C45—C46	120.2 (5)
C13—C18—C17	120.7 (6)	C44—C45—H45	119.9
C13—C18—H18	119.6	C46—C45—H45	119.9
C17—C18—H18	119.6	C47—C46—C45	118.2 (5)
C24—C19—C20	118.8 (5)	C47—C46—H46	120.9
C24—C19—P2	122.7 (4)	C45—C46—H46	120.9
C20—C19—P2	118.6 (4)	C46—C47—C48	121.1 (5)
C21—C20—C19	119.5 (6)	C46—C47—H47	119.5
C21—C20—H201	120.2	C48—C47—H47	119.5
C19—C20—H201	120.2	C47—C48—C43	122.4 (5)
C20—C21—C22	121.5 (6)	C47—C48—H48	118.8
C20—C21—H21	119.2	C43—C48—H48	118.8
C22—C21—H21	119.2	N200—C100—C300	180.0
C23—C22—C21	118.5 (6)	C100—C300—H301	109.5
C23—C22—H22	120.7	C100—C300—H302	109.5
C21—C22—H22	120.7	H301—C300—H302	109.5
C22—C23—C24	121.2 (6)	C100—C300—H303	109.5
C22—C23—H23	119.4	H301—C300—H303	109.5
C24—C23—H23	119.4	H302—C300—H303	109.5
C23—C24—C19	120.5 (5)
P2^i—Ag1—P1—C1	−58.1 (2)	Ag1—P2—C19—C20	−43.5 (4)
P2—Ag1—P1—C1	61.3 (2)	C24—C19—C20—C21	−0.5 (8)
P1^i—Ag1—P1—C1	−177.8 (2)	P2—C19—C20—C21	178.8 (5)
P2^i—Ag1—P1—C13	60.8 (2)	C19—C20—C21—C22	0.8 (9)
P2—Ag1—P1—C13	−179.7 (2)	C20—C21—C22—C23	−0.5 (9)
P1^i—Ag1—P1—C13	−58.9 (2)	C21—C22—C23—C24	−0.1 (9)
P2^i—Ag1—P1—C7	179.7 (2)	C22—C23—C24—C19	0.3 (9)
P2—Ag1—P1—C7	−60.9 (2)	C20—C19—C24—C23	0.0 (8)
P1^i—Ag1—P1—C7	59.9 (2)	P2—C19—C24—C23	−179.3 (5)
P2^i—Ag1—P2—C31	−179.4 (2)	C31—P2—C25—C30	7.2 (6)
P1^i—Ag1—P2—C31	−59.4 (2)	C19—P2—C25—C30	−99.4 (5)
P1—Ag1—P2—C31	59.5 (2)	Ag1—P2—C25—C30	130.5 (5)
P2^i—Ag1—P2—C19	−58.4 (2)	C31—P2—C25—C26	−174.3 (4)
P1^i—Ag1—P2—C19	61.6 (2)	C19—P2—C25—C26	79.0 (5)
P1—Ag1—P2—C19	−179.5 (2)	Ag1—P2—C25—C26	−51.1 (5)
P2^i—Ag1—P2—C25	63.18 (19)	C30—C25—C26—C27	−0.8 (9)
P1^i—Ag1—P2—C25	−176.86 (19)	P2—C25—C26—C27	−179.3 (5)
P1—Ag1—P2—C25	−57.9 (2)	C25—C26—C27—C28	0.6 (10)
C13—P1—C1—C2	−158.1 (5)	C26—C27—C28—C29	0.3 (11)
C7—P1—C1—C2	96.0 (5)	C27—C28—C29—C30	−1.0 (11)
Ag1—P1—C1—C2	−33.0 (6)	C26—C25—C30—C29	0.1 (9)
C13—P1—C1—C6	23.8 (5)	P2—C25—C30—C29	178.5 (5)
C7—P1—C1—C6	−82.1 (5)	C28—C29—C30—C25	0.8 (11)
Ag1—P1—C1—C6	148.9 (4)	C19—P2—C31—C32	0.4 (6)
C6—C1—C2—C3	0.9 (9)	C25—P2—C31—C32	−105.4 (5)
P1—C1—C2—C3	−177.3 (5)	Ag1—P2—C31—C32	129.8 (5)
C1—C2—C3—C4	−0.7 (10)	C19—P2—C31—C36	−177.4 (4)
C2—C3—C4—C5	−1.0 (9)	C25—P2—C31—C36	76.8 (5)
C3—C4—C5—C6	2.6 (9)	Ag1—P2—C31—C36	−48.0 (5)
C4—C5—C6—C1	−2.4 (9)	C36—C31—C32—C33	−0.3 (9)
C2—C1—C6—C5	0.6 (8)	P2—C31—C32—C33	−178.0 (5)
P1—C1—C6—C5	178.8 (4)	C31—C32—C33—C34	−0.9 (11)
C1—P1—C7—C8	3.7 (6)	C32—C33—C34—C35	1.0 (11)
C13—P1—C7—C8	−101.6 (5)	C33—C34—C35—C36	0.2 (10)
Ag1—P1—C7—C8	133.8 (4)	C34—C35—C36—C31	−1.4 (9)
C1—P1—C7—C12	−178.4 (5)	C32—C31—C36—C35	1.5 (9)
C13—P1—C7—C12	76.3 (5)	P2—C31—C36—C35	179.3 (4)
Ag1—P1—C7—C12	−48.4 (5)	C37^ii—B1—C37—C42	127.5 (6)
C12—C7—C8—C9	0.5 (9)	C43^ii—B1—C37—C42	−111.8 (5)
P1—C7—C8—C9	178.3 (5)	C43—B1—C37—C42	6.6 (8)
C7—C8—C9—C10	−1.6 (10)	C37^ii—B1—C37—C38	−49.7 (4)
C8—C9—C10—C11	1.6 (10)	C43^ii—B1—C37—C38	71.0 (7)
C9—C10—C11—C12	−0.4 (10)	C43—B1—C37—C38	−170.6 (5)
C10—C11—C12—C7	−0.7 (10)	C42—C37—C38—C39	2.2 (8)
C8—C7—C12—C11	0.7 (9)	B1—C37—C38—C39	179.7 (5)
P1—C7—C12—C11	−177.3 (5)	C37—C38—C39—C40	−0.7 (9)
C1—P1—C13—C18	77.3 (4)	C38—C39—C40—C41	−2.5 (10)
C7—P1—C13—C18	−176.8 (4)	C39—C40—C41—C42	4.0 (10)
Ag1—P1—C13—C18	−50.5 (5)	C38—C37—C42—C41	−0.7 (9)
C1—P1—C13—C14	−101.8 (5)	B1—C37—C42—C41	−178.0 (5)
C7—P1—C13—C14	4.0 (5)	C40—C41—C42—C37	−2.5 (10)
Ag1—P1—C13—C14	130.3 (4)	C37—B1—C43—C44	−79.6 (6)
C18—C13—C14—C15	1.1 (8)	C37^ii—B1—C43—C44	162.1 (5)
P1—C13—C14—C15	−179.7 (4)	C43^ii—B1—C43—C44	41.3 (4)
C13—C14—C15—C16	−0.5 (9)	C37—B1—C43—C48	100.5 (5)
C14—C15—C16—C17	−0.7 (10)	C37^ii—B1—C43—C48	−17.7 (7)
C15—C16—C17—C18	1.2 (10)	C43^ii—B1—C43—C48	−138.5 (6)
C14—C13—C18—C17	−0.6 (8)	C48—C43—C44—C45	2.3 (8)
P1—C13—C18—C17	−179.8 (4)	B1—C43—C44—C45	−177.6 (5)
C16—C17—C18—C13	−0.5 (9)	C43—C44—C45—C46	−1.8 (9)
C31—P2—C19—C24	−98.3 (5)	C44—C45—C46—C47	0.3 (9)
C25—P2—C19—C24	7.7 (5)	C45—C46—C47—C48	0.5 (9)
Ag1—P2—C19—C24	135.8 (4)	C46—C47—C48—C43	0.0 (9)
C31—P2—C19—C20	82.4 (4)	C44—C43—C48—C47	−1.4 (8)
C25—P2—C19—C20	−171.6 (4)	B1—C43—C48—C47	178.5 (5)

Symmetry codes: (i) −x, −y+1/2, z; (ii) x, −y, −z+1/2.