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The Fourier coefficients of the X-ray diffraction line profiles from an ordered face-centred tetragonal (L10) structure such as MgIn or CuAu have been calculated assuming the presence of twin and incoherent boundaries on (101). It is found that reflection components with (h-l) = 0 are not affected by twinning on (101). The theoretical expression for the effective particle size is compared with some measured particle sizes for cold-worked MgIn.
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